Table 1 Mean Pd–O bond lengths.

From: Intramolecular crossover from unconventional diamagnetism to paramagnetism of palladium ions probed by soft X-ray magnetic circular dichroism

 

Sample

\(d_{\mathrm{{{mean}}}}^{\mathrm{{{Pd - O}}}}\) (Å)

Δmax (%)

Pd location

Formal coordination

Ref.

(1)

CoPd12P8

1.994

5.3

Shell

Square-planar

3

(2)

FePd12P8

2.000

2.9

Shell

Square-planar

3

(3)

FePd12(PhAs)8

2.009

4.1

Shell

Square-planar

2

(4)

PdPd12As8

2.020

6.9

Shell + centre

Square-planar

1

  1. Mean Pd–O bond lengths \(d_{\mathrm{{{mean}}}}^{\mathrm{{{Pd - O}}}}\), maximum variations Δmax of bond lengths which are much larger than the experimental uncertainties, as well as location and formal coordination symmetry of palladium(II) ions in palladate samples investigated in this work.
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