Table 3 Magnetic moments of Pd as determined by sum-rules based analyses of experimental data.

From: Intramolecular crossover from unconventional diamagnetism to paramagnetism of palladium ions probed by soft X-ray magnetic circular dichroism

 

Sample

Pd position

\(n_h^d\)

\(m_{\mathrm{{s}}}^{\mathrm{{{eff}}}}\left( {{\mathrm{Pd}}} \right)\) (10−2 µB/atom)

ml (pd) (10−2 µB/atom)

\(m_{\mathrm{{l}}}/m_{\mathrm{{s}}}^{\mathrm{{{eff}}}}\) (%)

mtot (pd) (10−2 µB/atom)

(3)

FePd12(PhAs)8

Shell

1.47

0.06 ± 0.04

−0.04 ± 0.01

−63 ± 15

0.02 ± 0.02

(4)

PdPd12As8

Averaged

1.48

1.0 ± 0.2

0.33 ± 0.10

35 ± 9

1.3 ± 0.2

  1. Estimated relative effective spin and orbital contributions to the magnetic moment assigned to palladium as well as the ratio of orbital-to-spin magnetic moment and total magnetic moments per palladium(II) ion in 6 T at 4.3–4.6 K as extracted from experimental spectra using estimated numbers of unoccupied d states \(n_h^d\) from DFT. The white line intensity was estimated from simulated data.
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