Fig. 2: Product comparation over various Ga contents.

a Yields of C2H4, C3H6, C8H10, CH4, (b) H2 production and (c) the real-time yields (C%) of HCHO in MTH reaction over parent HZSM-5 and various Ga(IM)HZSM-5. Reaction conditions of SR-PIMS experiments: 400 °C; MeOH WHSV = 12.52 gMeOHgcatalyst−1h−1; and P = 2 Torr. C3H6 = propylene; and C8H10 = C8 aromatics. The yields in (a) were obtained during the steady-state reaction period. The H2 production of the catalyst samples in (b) was obtained under atmospheric pressure, which was carried out by GC‒MS. Each reaction in (c) proceeded until the C2H4 yield dropped to 0.5 C%. In (c), the original yield curves (transparent solid lines) have been smoothed as bright solid lines. Error bars obtained from repeated three sets of experiments on the same catalyst.