Table 2 Calculated secondary structure content and structural features of [C − Mb][S]

From: Unlocking the full compositional control of hydrophilic and hydrophobic deep eutectic solvents over protein structure and stability

System

α-helix / %

β-sheet / %

Turn / %

Unordered / %

req / Å

rpo / Å

ChCl:Glyc

51.1

17.9

10.5

20.5

22.3 ± 0.8

65.3 ± 2.4

TBAC:Glyc

34.5

10.4

11.2

43.9

18.0 ± 1.1

115 ± 6

TBAC:OA

65.6

8.8

14.2

11.4

11.3 ± 1.4

390 ± 40

Water

57.2

9.1

9.7

24.0

21.4 ± 0.4

68.3 ± 1.9

  1. The results were derived from the analysis of the CD, SANS, and UV-vis data shown in Fig. 1. The structural parameters derived from SANS analysis are: req – equatorial radius and rpo – polar radius.
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