Table 1 Comparison of population dynamics derived from experimental measurements and theoretical calculations
n = 3 | n = 4 | n = 5 | |
|---|---|---|---|
Calculation τ1 | 350±5) fs (rise) | 1452 (±7) fs (rise) | 500 (±82) fs (rise) |
Experimental τ1 | 261 (±122) fs (rise) | 1026 (±741.7) fs (rise) | 339 (±124) fs (rise) |
Calculation τ2 | 1300 (±8) fs (decay) | 11 (±0.01) ps (decay) | 1411 (±76) fs (rise) |
Experimental τ2 | 1047 (±429) fs (decay) | 20.49 (±4) ps (decay) | 2270 (±727) fs (rise) |
Calculation τ3 | 10 (±0.01) ps (decay) | 500 (±32) ps (decay) | Inf |
Experimental τ3 | 25.5 (±5) ps (decay) | 203 (±88) ps (decay) | Inf |