Fig. 4: Compilation of models and estimates of the evolution of the partial pressure of dinitrogen in the Earth’s atmosphere.
From: Fluid inclusions: tiny windows into global paleo-environments

For the Archean, available data suggest that the pN2 was on the same order of magnitude as or lower than the modern value. However, all models predict fluctuations of more than 50% over Earth’s history. Dramatic changes in the pN2 could have occurred after the Great Oxidation Event75, but the lack of data does not allow one to reliably test this hypothesis22,68,70,71,72,73,74,75,77,114,115.