Table 2 Scope for (hetero)aryl bromides in the α-arylation reaction

From: Cooperative triple catalysis enables regioirregular formal Mizoroki–Heck reactions

  1. Reactions were conducted on a scale of 0.15 mmol. The yields correspond to the isolated material after purification. Reaction conditions: aryl bromide (0.15 mmol), alkene (0.3 mmol), NiCl2·glyme (10 mol%), dtbbpy (15 mol%), Ru(bpy)3(PF6)2 (1 mol%), 4-F-C6H4SO2Na (30 mol%), B2pin2 (0.85 equiv.), Na3PO4 (1.1 equiv.) and DMSO–DMF (0.9:0.6 ml) under irradiation with a 10 W blue LED for 24 h. See the Supplementary Information for details. aThe reaction was performed for 30 h. r.t., room temperature; Bz, benzoyl; Boc, tert-butoxycarbonyl; TMS, trimethylsilyl.
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