Table 1 Synthesis parameters with thermodynamic competition analysis and experimental results from X-ray diffraction measurements for the synthesis of LiIn(IO3)4
From: Optimal thermodynamic conditions to minimize kinetic by-products in aqueous materials synthesis
ID | Lithium source | [Li] | [In] | [I] | pH | E (V) | ΔΦ (meV per atom) | X-ray diffraction results |
|---|---|---|---|---|---|---|---|---|
A1 | LiCl + Li(CH3COO) | 1.5 | 0.1 | 0.8 | 0.77 | 1.58 | −58 | LiIn(IO3)4 |
A2 | LiCl | 1.5 | 0.1 | 0.8 | 0.66 | 1.59 | −56 | LiIn(IO3)4 |
A3 | LiCl + Li(CH3COO) | 1.2 | 0.1 | 0.8 | 0.56 | 1.59 | −51 | LiIn(IO3)4 |
A4 | LiCl | 1.2 | 0.1 | 0.8 | 0.43 | 1.60 | −46 | In(IO3)3 |
A5 | LiCl + Li(CH3COO) | 0.8 | 0.1 | 0.8 | 0.87 | 1.57 | −15 | In(IO3)3 |
A6 | LiCl | 0.8 | 0.1 | 0.8 | 0.71 | 1.58 | −13 | In(IO3)3 |
A7 | LiCl + Li(CH3COO) | 0.5 | 0.1 | 0.8 | 0.65 | 1.59 | −11 | In(IO3)3 |
A8 | LiCl | 0.5 | 0.1 | 0.8 | 0.52 | 1.60 | −9 | In(IO3)3 |
A9 | Li(CH3COO) | 0.15 | 0.1 | 0.8 | 0.91 | 1.57 | −8 | In(IO3)3 |
A10 | LiCl | 0.15 | 0.1 | 0.8 | 0.85 | 1.58 | −8 | In(IO3)3 |
