Table 5 Summary of VPP hybridization with other 3D printing modalities

From: Multi-material vat photopolymerization 3D printing: a review of mechanisms and applications

Combined technologies

Advantages of combining technologies

Important highlights

Req. manual intervention?

Applications

References

SLA + DIW

Functional structure fabrication with diverse inks and materials, including shape memory polymers, magnetoactive soft materials, liquid elastomers, and conductive inks (DIW) featuring intricate details and complex geometry (SLA).

Exchange of parts between DIW and SLA system

Yes

Embedded circuitry

130

First reported process that does not switch parts between systems, though it still requires pausing to clean substrates and insert electrical components.

Embedded electronic circuit, monolithic 3D packages

111

DLP + FFF

Creating bulk structure of specific mechanical, biological, and thermal properties (FFF) with detailed features or functional materials (DLP)

Though the fabrication approach is hybrid, overall systems are separate, as parts were printed separately using FFF and DLP methods.

Bio-scaffold with HA slurry

116

SLA + IJP

Local precise placement of functional material (IJP) into the substrate part (SLA)

Thermally stable SLA ink endured the high temperatures needed for piezopolymer annealing during post-processing.

Piezopolymer-based inertial sensor

113

DLP + DIW

Produce higher-resolution parts (DLP) from high-viscosity materials (DIW). Expand photo-curable ink use to include varied chemistries and increased molecular weights and particle/composite loadings.

Separate printing and manual assembly for full sensor integration

Sensors

107

Used laser-assisted DIW to preserve the shape and functionality of the deposited LCE, stretching it during deposition to enhance actuation capabilities.

Fully automated

4D printing of LCEs, potential applications in soft robotics, smart structures, active metamaterials, and smart wearable devices

106

Printed multiple DLP layers per DIW layer due to resolution disparities.

Multi-color parts, strain sensor, soft robots

103

Expanded materials library for viscosities up to 1350 Pa∙s, enabling printing with up to 85 wt.% particle loading.

Parts printed with sharp features despite high viscosity material

99

DLP-assisted varying curing degrees across locations introduced functional gradients, enabling multi-level electrical responses.

Integrated mTENG in footwear soles to harvest energy from body motion and monitor motion state, creating functional wearable electronics.

108

SLA + DIW

See previously mentioned “SLA + DIW

Implemented a bottom-up process where DIW material is deposited within the matrix and photo-cured via double or triple exposure to attach the deposited ink to an inverted building platform.

Multi-material ant, multi-material wheel, strain sensor

105

VAM + DIW

DIW prints suspension in the material matrix to achieve multi-material parts

Sacrificial gelatin material usage to modulate the viscosity of bioinks for 3D suspension prints of soft hydrogels

Tissue engineering, regenerative medicine

68

SLA + IJP

See previously mentioned “SLA + IJP

Controlled drug release kinetics by strategically positioning the drug or a drug depot with a gradient from the inside to the outside.

Drug delivery

112

DLP + IJP

Depositing functional materials (IJP) onto the substrate (DLP)

Showcased the ability to create interconnected multi-layer electronic circuits in 3D structures.

Green part (before sintering), embedded circuit

114

SLA + AJP

Aerosol jet enables deposition of significantly higher-viscosity materials than inkjet printing (10–1000 mPa∙s)

Replaced the SLA ink vat with a substrate (Bottom-up), mixing materials on-the-fly for specific compositions, unlike traditional bath-based SLA.

Cylindrical multi-material body with graduated material combination change

95,115

DLP + EHD jetting

Directly printed high resolution ( ~ 2.6 μm) functional pixels (EHD jetting) onto DLP substrates/frames.

Eliminated need for extra thermal annealing/drying, enabling direct printing of transparent OLED pixels onto 3D structures at high resolution in ambient conditions.

Transparent OLEDs

118

VPP + BJT + IJP + DIW + FFF

Multi-functional parts, functionally gradient parts, multi-color parts, multi-material parts.

System combined different processes, but demonstrated parts were only produced using VPP and paste extrusion.

N/A

119

DLP + TPL

Scalable features (DLP) with microscale precision capabilities (TPL) significantly reduces production time.

Requires precise/difficult alignment pre-setup due to higher precision of both TPL and DLP

Hierarchical superhydrophobic surfaces; aspherical microlens Composite of microlens & microfluidics

117