Table 1 The optimized UPLC-MS/MS acquisition parameters, LOD and LOQ of the method for fluorinated alternatives
Fluorinated alternatives | Precursor ions (m/z) | Productions (m/z) | Collision energy (v) | Retention times (min) | LOD (ng/g) | LOQ (ng/g) |
|---|---|---|---|---|---|---|
6:2 Cl-PFAES | 531 | 351 | 27 | 9.278 | 0.16 | 0.64 |
6:2 FTS | 427 | 407 | 23 | 8.527 | 0.20 | 0.80 |
OBS | 603 | 172 | 41 | 9.713 | 0.16 | 0.64 |
Et-PFOA | 413 | 369 | 10 | 8.567 | 0.14 | 0.56 |
13C4-PFOA | 417 | 372 | 51 | / | / | |
13C4-PFOS | 503 | 80 | 27 | / | / | |
13C2-PFOA | 415 | 370 | 10 | / | / |