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Showing 1–3 of 3 results
Advanced filters: Author: Achyut R. Gogoi Clear advanced filters

  • As aromatic compounds can be obtained easily, their functionalization is a cornerstone of organic synthesis. Here, the authors report a dearomatization of aromatic isocyanides, installing three carbon-carbon bonds, two quaternary stereocenters, and three orthogonal functionalities in one operation.

    • Bilal Altundas
    • Embarek Alwedi
    • Fraser F. Fleming
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-8

  • Polypyridine-ligated nickel complexes can mediate a variety of cross-coupling reactions. However, some mechanistic details remain poorly understood. Now, it is demonstrated that the nature of the anionic ligand strongly influences key electron-transfer events in these complexes during elementary reaction steps.

    • Craig S. Day
    • Ángel Rentería-Gómez
    • Ruben Martin
    Research
    Nature Catalysis
    Volume: 6, P: 244-253

  • Three-component, iron-based catalytic transformations offer a promising and sustainable approach to building complex molecules in a single step. This Review highlights advances and ongoing challenges in the development of iron-catalysed difunctionalization of alkenes. Mechanistic insights that enhance our understanding and guide the development of new transformations are discussed.

    • Achyut R. Gogoi
    • Ángel Rentería-Gómez
    • Osvaldo Gutierrez
    Reviews
    Nature Synthesis
    Volume: 4, P: 1036-1055