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Showing 1–3 of 3 results
Advanced filters: Author: Aiko Kurimoto Clear advanced filters

  • Enzymatic catalysis requires cofactors such as NAD(P)H, whose regeneration is currently accomplished via secondary enzymes or electrolytic cell. Here, the authors report an electrochemical method of cofactors regeneration without supporting enzymes or mediators, nor formation of NAD2 dimers.

    • Aiko Kurimoto
    • Seyed A. Nasseri
    • Curtis P. Berlinguette
    ResearchOpen Access
    Nature Communications
    Volume: 14, P: 1-10

  • The ability to maximize electron utilization in electrosynthesis has been a long-standing goal, with research typically focusing on catalyst design or pairing disparate reactions. Now, electrocatalytic hydrogenation is performed with Faradaic efficiencies approaching 200% by producing hydrogen atoms from both the reduction and oxidation reactions simultaneously.

    • Rebecca S. Sherbo
    • Aiko Kurimoto
    News & Views
    Nature Catalysis
    Volume: 6, P: 218-219

  • The reductive deuteration of unsaturated hydrocarbons is a promising deuterium-labelling strategy, although it requires expensive gaseous D2 or other stoichiometric reagents. Here, an electrocatalytic palladium membrane reactor is employed to selectively generate C(sp3)–D bonds via reduction of unsaturated compounds using D2O.

    • Aiko Kurimoto
    • Rebecca S. Sherbo
    • Curtis P. Berlinguette
    Research
    Nature Catalysis
    Volume: 3, P: 719-726