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Showing 1–4 of 4 results
Advanced filters: Author: Andrea Gardin Clear advanced filters

  • Living supramolecular polymerization can produce precise covalent polymers, but the scope of monomers is still narrow. Here the authors show a molecular platform for living supramolecular polymerization that is based on the unique structure of all-cis 1,2,3,4,5,6- 22 hexafluorocyclohexane, the most polar aliphatic compound reported to date.

    • Oleksandr Shyshov
    • Shyamkumar Vadakket Haridas
    • Max von Delius
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-11

  • Coulombic interactions can be used to assemble charged nanoparticles into higher-order structures, but this process typically requires similarly sized oppositely charged partners. Now, small anions or cations with as few as three charges have been shown to induce attractive interactions between oppositely charged nanoparticles in water, guiding the assembly of colloidal crystals.

    • Tong Bian
    • Andrea Gardin
    • Rafal Klajn
    Research
    Nature Chemistry
    Volume: 13, P: 940-949

  • Defects and disordered local domains in soft, self-assembled aggregates determine their dynamic and adaptive properties, and enable communication between entities, but characterizing and classifying such intricate dynamic behaviors is highly complex. Here, the authors report on a data-driven workflow to identify objective criteria for the comparison of complex dynamic features in soft supramolecular materials, deriving a data-driven ’defectometer’ that allows to classify soft self-assembled materials based on the structural dynamics of the ordered/disordered molecular environments that statistically emerge within them.

    • Andrea Gardin
    • Claudio Perego
    • Giovanni M. Pavan
    ResearchOpen Access
    Communications Chemistry
    Volume: 5, P: 1-15