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Showing 1–3 of 3 results
Advanced filters: Author: Feliu Maseras Clear advanced filters

  • Saturated heterocycles are prevalent motifs in organic synthesis but their synthesis still presents persistent challenges. Now, a hypervalent iodine(III)-mediated selective intramolecular C(sp3)–H functionalization, facilitated by hexafluoroisopropanol, is reported, which via single-electron transfer provides access to pyrrolidines, piperidines and O-heterocycles in the presence or absence of light.

    • Jiale Xie
    • Jiayu Zhang
    • Mónica H. Pérez-Temprano
    ResearchOpen Access
    Nature Synthesis
    Volume: 3, P: 1021-1030

  • Efficient and stable water oxidation catalysts are important if photoelectrochemical cells are to be used to provide clean and sustainable solar fuels. A water oxidation catalyst that operates at neutral pH has now been developed that features ruthenium coordination oligomers anchored onto the surfaces of graphitic materials through CH–π interactions.

    • Md Asmaul Hoque
    • Marcos Gil-Sepulcre
    • Antoni Llobet
    Research
    Nature Chemistry
    Volume: 12, P: 1060-1066

  • Databases of computational results hold high promise for accelerating catalysis research. Still, many challenges remain and consensus on facets such as metadata, reliability and curation is crucial to transform the hype into an attractive technology.

    • Carles Bo
    • Feliu Maseras
    • Núria López
    Comments & Opinion
    Nature Catalysis
    Volume: 1, P: 809-810