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Photobiocatalytic radical repositioning for enantioselective acylation of remote C–C/C–H bonds

Radical repositioning to activate remote bonds is underdeveloped in synthetic biocatalysis. Now a photobiocatalytic system couples light-driven single-electron transfer and the relocation of unpaired electrons to activate remote C–C and C–H bonds for enzymatically controlled enantioselective acylation.

Yang Ming
Zhouping Wu
Xiaoqiang Huang
Research03 Nov 2025
Nature Catalysis

Volume: 8, P: 1198-1207
Contrasting epigenetic control of transgenes and endogenous genes promotes post-transcriptional transgene silencing in Arabidopsis

Accumulating evidences point to a discrepancy in the epigenetic behaviour of transgenes and endogenous genes. Here, via characterization of mutants impaired in histone demethylases JMJ14 and IBM1, the authors show that transgenes and endogenous genes are regulated by different epigenetic mechanisms in Arabidopsis.

Nicolas Butel
Agnès Yu
Hervé Vaucheret
ResearchOpen Access13 May 2021
Nature Communications

Volume: 12, P: 1-12
Relationship between three body obesity indicators, WWI, BMI, WtHR, and periodontitis

XingJin Chen
ChongWen Zeng
Jukun Song
ResearchOpen Access03 Jan 2025
Scientific Reports

Volume: 15, P: 1-12
Association between “a body shape index” (ABSI) with periodontitis in a hypertension population from the NHANES 2009–2014

Xuanyan Gu
Shiyi Luo
Jukun Song
ResearchOpen Access08 Oct 2024
Scientific Reports

Volume: 14, P: 1-10
Serum anion gap is associated with mortality in intensive care unit patients with diastolic heart failure

Hongyu Xu
Jiangling Xia
Xiaoling Sun
ResearchOpen Access04 Oct 2023
Scientific Reports

Volume: 13, P: 1-14
Activated mouse CD4⁺Foxp3⁻ T cells facilitate melanoma metastasis via Qa-1-dependent suppression of NK-cell cytotoxicity

Xiaojuan Wang
Yanyan Cui
Jun Wu
ResearchOpen Access04 Sept 2012
Cell Research

Volume: 22, P: 1696-1706

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Photobiocatalytic radical repositioning for enantioselective acylation of remote C–C/C–H bonds

Contrasting epigenetic control of transgenes and endogenous genes promotes post-transcriptional transgene silencing in Arabidopsis

Relationship between three body obesity indicators, WWI, BMI, WtHR, and periodontitis

Association between “a body shape index” (ABSI) with periodontitis in a hypertension population from the NHANES 2009–2014

Serum anion gap is associated with mortality in intensive care unit patients with diastolic heart failure

Activated mouse CD4+Foxp3− T cells facilitate melanoma metastasis via Qa-1-dependent suppression of NK-cell cytotoxicity

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Activated mouse CD4⁺Foxp3⁻ T cells facilitate melanoma metastasis via Qa-1-dependent suppression of NK-cell cytotoxicity