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Showing 1–2 of 2 results
Advanced filters: Author: Jungi Jung Clear advanced filters

  • A regiochemically distinctive single nitrogen atom insertion of indoles is enabled by a tandem 1,3 nitroso translocation followed by a concerted nitrogen migration mechanism. This non-nitrene mediated aromatic C–C bond activation process generates a rare 1,4-dinitrogen connectivity within the scaffold, enabling access to previously underexplored quinoxaline pharmacophores through late-stage diversification of bio-relevant indoles.

    • Mugeon Song
    • Ilju Jeong
    • Won-jin Chung
    Research
    Nature Synthesis
    P: 1-9

  • Restricted reaction mechanism of anti-dihalogenation of alkenes makes it challenging to alter the diastereochemical course into the complementary syn-dihalogenation process. Here, the authors report a conceptually distinctive strategy for the simultaneous double electrophilic activation of the two alkene carbons from the same side to realize syn-dihalogenation.

    • Hyeon Moon
    • Jungi Jung
    • Won-jin Chung
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-8