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Showing 1–8 of 8 results
Advanced filters: Author: Karthish Manthiram Clear advanced filters
  • Lithium-mediated nitrogen fixation is a promising pathway to electrochemical ammonia synthesis, but the role of metallic lithium and its passivation layer are unclear. Here the authors employ cryogenic transmission electron microscopy to explore these components, finding that the proton donor is the key determinant of lithium reactivity.

    • Katherine Steinberg
    • Xintong Yuan
    • Yuzhang Li
    Research
    Nature Energy
    Volume: 8, P: 138-148
  • Using an electrochemical continuous flow cell, nitrogen reduction to ammonia is rigorously demonstrated through a calcium-mediated approach.

    • Michael A. Yusov
    • Karthish Manthiram
    News & Views
    Nature Materials
    Volume: 23, P: 31-32
  • Iron sulfide nanoclusters enable on-demand and local generation of nitric oxide, an important lipophilic messenger in the brain, allowing the modulation and investigation of nitric oxide-triggered neural signalling events.

    • Jimin Park
    • Kyoungsuk Jin
    • Polina Anikeeva
    Research
    Nature Nanotechnology
    Volume: 15, P: 690-697
  • The Tafel slope in electrochemical catalysis is usually determined from experimental data and remains error-prone. Here, the authors develop a Bayesian approach for Tafel slope quantification, and apply it to study the prevalence of certain "cardinal" Tafel slopes in the electrochemical CO2 reduction literature.

    • Aditya M. Limaye
    • Joy S. Zeng
    • Karthish Manthiram
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-10
  • Non-polar gaseous reactants such as N2 and H2 exhibit low solubility and slow transport in non-aqueous solvents and conventional gas diffusion electrodes cannot avoid non-aqueous electrolyte penetration. Here, transport limitations and catalyst flooding in tetrahydrofuran are overcome by using a stainless steel cloth-based support for lithium-mediated ammonia synthesis paired with H2 oxidation.

    • Nikifar Lazouski
    • Minju Chung
    • Karthish Manthiram
    Research
    Nature Catalysis
    Volume: 3, P: 463-469
  • This Primer discusses key principles and experiments in quantitative ultraviolet–visible spectroelectrochemistry experiments with a focus on data-rich set-ups. The authors demonstrate the various data outputs of these experiments using worked examples and discuss the practical applications of quantitative ultraviolet–visible spectroelectrochemistry in the study of energy materials.

    • Benjamin Moss
    • Caiwu Liang
    • James R. Durrant
    Reviews
    Nature Reviews Methods Primers
    Volume: 5, P: 1-20
  • The electrochemical synthesis of ammonia via the lithium-mediated reduction of N2 holds great promise to replace the carbon- and energy-intensive Haber–Bosch process. This Review discusses this approach and examines the critical role of the catalytic solid–electrolyte interphase formed on the electrode.

    • Wesley Chang
    • Anukta Jain
    • Karthish Manthiram
    Reviews
    Nature Catalysis
    Volume: 7, P: 231-241