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Showing 1–2 of 2 results
Advanced filters: Author: Kyungsup Lee Clear advanced filters

  • While directing group-assisted ortho-B−H activation of o-carboranes is well established, meta-B−H functionalization remains rare. Here, the authors report an iridium(III)-catalyzed remote B(9)−H alkylation of o-carboranes using a nitrile-based directing template.

    • Kyungsup Lee
    • Jiwon Kim
    • Phil Ho Lee
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-9

  • Functionalization of carboranes, icosahedral boron−carbon molecular clusters, is of great interest as they have wide applications in medicinal and materials chemistry. Herein, the authors report an asymmetric Rh(II)-catalyzed insertion reactions of carbenes into cage B–H bonds of carboranes.

    • Kyungsup Lee
    • Gisela A. González-Montiel
    • Phil Ho Lee
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-9