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Showing 1–5 of 5 results
Advanced filters: Author: Michael S. Inkpen Clear advanced filters

  • Cyclic molecules often exhibit unusual properties; consider for example the resonance stabilization energy of benzene or the strong cation binding of crown ethers. Now, a family of rings comprising varying numbers of directly linked ferrocenes has been prepared. These compounds are highly symmetric in solution and undergo rapid ‘oxidation-state isomerism’ when charged.

    • Michael S. Inkpen
    • Stefan Scheerer
    • Nicholas J. Long
    Research
    Nature Chemistry
    Volume: 8, P: 825-830

  • The stochastic nature of single-molecule charge transport measurements requires collection of large data sets to capture their full complexity. Here, the authors adopt strategies from machine learning for the unsupervised classification of single-molecule charge transport data without a prioriassumptions.

    • Mario Lemmer
    • Michael S. Inkpen
    • Tim Albrecht
    ResearchOpen Access
    Nature Communications
    Volume: 7, P: 1-10

  • Metal-metal interfaces hold promise as contacting moieties for single-molecule devices with tunable functionality, yet the direct bonding has remained a challenge. Here, Lee et al. report the formation of Fe-Au bond without chemical ligand support in ferrocene-based molecular junctions.

    • Woojung Lee
    • Liang Li
    • Latha Venkataraman
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-9

  • Gold–thiol contacts are ubiquitous across the physical and biological sciences, connecting organic molecules to surfaces. Now, conductance measurements of different sulfur-bound single-molecule junctions show that thiols—in contrast to the prevailing view—are not chemisorbed on gold, which strongly suggests that the thiol hydrogen is retained.

    • Michael S. Inkpen
    • Zhen–Fei Liu
    • Latha Venkataraman
    Research
    Nature Chemistry
    Volume: 11, P: 351-358