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Showing 1–2 of 2 results
Advanced filters: Author: Myoung Hyeon Shin Clear advanced filters

  • Asymmetric binary catalysis combining chiral Brønsted acids with Lewis acids is currently limited to pre-organized, activated substrates. Here, the authors report binary catalysis combining an organosuperacid with bismuth, where the counteranion of chiral N-triflyl phosphoramide acts as a flexible-coordinating ligand for the asymmetric allylation of α-keto thioesters.

    • Jin Hyun Park
    • Seok Yeol Yoo
    • Han Yong Bae
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-13

  • The α-tertiary amine functional group is an essential structure of diverse naturally occurring alkaloids and pharmaceuticals. Here the authors show an efficient water-accelerated organocatalytic method to access α-tertiary amines incorporating homoallylic amine structures by exploiting ketones as useful starting material.

    • Prithwish Goswami
    • Sung Yeon Cho
    • Han Yong Bae
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-13