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Showing 1–14 of 14 results
Advanced filters: Author: Shigeyoshi Inoue Clear advanced filters

  • Multiple bonds involving heavier elements were considered impossible but have recently been shown to be stable and offer divergent reactivity. Here the isolation of an alumene (a compound containing an Al=C bond) via direct CO reduction is described. Analysis of the alumene and its ability to homologate CO is reported.

    • John A. Kelly
    • Arseni Kostenko
    • Shigeyoshi Inoue
    ResearchOpen Access
    Nature Synthesis
    Volume: 4, P: 1577-1586

  • While catalytic reduction of quinolines has gained interest as a way to provide direct and efficient access to tetrahydroquinolines or 1,2-dihydroquinolines, the catalytic synthesis of 1,2-dihydroquinolines remains underdeveloped. Here, the authors demonstrate a catalytic 1,2-reduction of quinolines using a dinuclear aluminum complex.

    • Xufang Liu
    • Arseni Kostenko
    • Shigeyoshi Inoue
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-10

  • As the structure of bulk aluminium chalcogenides is composed of three dimensional networks their molecular congeners exhibit a strong tendency to oligomerize. Here, the authors describe the isolation of a monotopic aluminium telluride and probe its structural and bonding characteristics.

    • Daniel Franz
    • Tibor Szilvási
    • Shigeyoshi Inoue
    ResearchOpen Access
    Nature Communications
    Volume: 6, P: 1-6

  • Multiple bonds between heavier main-group elements may exhibit different properties and reactivity compared with their second-row counterparts. Now it has been shown that a NHC-stabilized phosphasilyne, a heavier analogue of nitrile, undergoes thermal isomerization to yield a phosphasilenylidene; this represents a rare example of heavier nitrile–isonitrile isomerization.

    • Martin E. Doleschal
    • Arseni Kostenko
    • Shigeyoshi Inoue
    ResearchOpen Access
    Nature Chemistry
    Volume: 16, P: 2009-2016

  • The heavy analogues of ynolates or ketenyl anions have not yet been studied. Here the synthesis, isolation and characterization of a sila-ketenyl anion, the silicon analogue of a ketenyl anion, are reported through the reaction of silyl-radical anions with CO.

    • Shiori Fujimori
    • Arseni Kostenko
    • Shigeyoshi Inoue
    Research
    Nature Synthesis
    Volume: 2, P: 688-694

  • Aluminium and silicon, two Earth-abundant, well-understood elements, typically form weak Al–Si bonds. Now, complexes featuring an anionic Al–Si core stabilized by bulky substituents and a Si–Na interaction have been isolated. This Al–Si interaction possesses partial double bond character, which can be increased by sequestration of the sodium counterion.

    • Moritz Ludwig
    • Daniel Franz
    • Shigeyoshi Inoue
    Research
    Nature Chemistry
    Volume: 15, P: 1452-1460

  • Silyl-substituted silicon–carbonyl complexes that are stable at room temperature have been prepared by exposure of highly reactive bis(silyl)silylenes to carbon monoxide. The compounds show structural features and reactivity that are reminiscent of their ubiquitous transition-metal–carbonyl counterparts, including π-backbonding and ligand liberation as well as substitution and functionalization reactions.

    • Dominik Reiter
    • Richard Holzner
    • Shigeyoshi Inoue
    Research
    Nature Chemistry
    Volume: 12, P: 1131-1135

  • Genome sequencing of fractionated T-, B- and natural killer cells from patients with chronic active Epstein–Barr virus (EBV) infection sheds light on the nature of the EBV-infected progenitor and suggests a link between intragenic EBV deletions and EBV-associated neoplastic proliferations.

    • Yusuke Okuno
    • Takayuki Murata
    • Hiroshi Kimura
    Research
    Nature Microbiology
    Volume: 4, P: 404-413

  • Ikuo Ogiwara et al. find that nonsense mutations in the gene coding for the voltage-gated sodium channel Nav1.2, SCN2A, cause absence-like seizures in mice. They also find that Nav1.2 haplodeficiency in excitatory, but not in inhibitory, neurons contributes to epileptogenesis.

    • Ikuo Ogiwara
    • Hiroyuki Miyamoto
    • Kazuhiro Yamakawa
    ResearchOpen Access
    Communications Biology
    Volume: 1, P: 1-16

  • The chemistry of carbon monoxide (CO) as a ligand has evolved significantly and transition-metal carbonyl complexes have been widely used as catalysts in many important catalytic processes. Here the authors comment on the recent progress of main-group element carbonyl complexes along with their future prospects.

    • Shiori Fujimori
    • Shigeyoshi Inoue
    Comments & OpinionOpen Access
    Communications Chemistry
    Volume: 3, P: 1-4