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Advanced filters: Author: Tian-Jiao Han Clear advanced filters

Catalytic asymmetric dearomatization of phenols via divergent intermolecular (3 + 2) and alkylation reactions

The catalytic asymmetric dearomatization (CADA) reaction is a powerful protocol for the assembly of three-dimensional cyclic compounds but phenols have been considered challenging substrates. Here, the authors report the chiral phosphoric acidcatalyzed divergent intermolecular CADA reactions of phenols with azoalkenes to obtain tetrahydroindolone and cyclohexadienone products in good yields with excellent ee values.

Xiang Gao
Tian-Jiao Han
Guang-Jian Mei
ResearchOpen Access25 Aug 2023
Nature Communications

Volume: 14, P: 1-9
Organocatalytic asymmetric synthesis of Tröger’s bases

Few general strategies are available to access enantioenriched Tröger’s base (TB). Herein, the authors report the organocatalytic asymmetric synthesis of TBs via the aminalization of tetrahydrodibenzodiazocines with aromatic aldehydes.

Yu-Wei Li
Nan-Nan Mo
Guang-Jian Mei
ResearchOpen Access10 Jul 2025
Nature Communications

Volume: 16, P: 1-13
TET1 downregulates epithelial-mesenchymal transition and chemoresistance in PDAC by demethylating CHL1 to inhibit the Hedgehog signaling pathway

Hao Li
Wang Jiang
Liang Liu
Research04 Aug 2020
Oncogene

Volume: 39, P: 5825-5838

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