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Showing 1–3 of 3 results
Advanced filters: Author: Xi-Cun Wang Clear advanced filters

  • Palladium-catalyzed β-carbon elimination for selective synthesis of diverse heterocyclic skeletons has been a persistent challenge. Here, the authors achieve switchable chemoselective synthesis of C4-carbamoylated indoles and C10-aminophenanthridinones by controlling β-carbon elimination using chlorocarbamates.

    • Bo-Sheng Zhang
    • Yi-Ming Wang
    • Yong-Min Liang
    ResearchOpen Access
    Communications Chemistry
    Volume: 8, P: 1-8

  • The limited solubility, inherent chemical stability, and low reactivity of inorganic phosphates pose hinder their conversion into organophosphates under mild conditions. Here, the authors report a method for the direct conversion of phosphates into P(V)-X reagents via a redox-neutral halogenation process, using cyanuric chloride or cyanuric fluoride as the halogenation reagent.

    • Yaling Tian
    • Dong-ping Chen
    • Zheng-Jun Quan
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-11

  • Inverse vulcanization (IV) generates sulfur-rich functional polymers from elemental sulfur and organic crosslinkers, but the harsh reaction conditions required limit the scope of suitable crosslinkers. Now, a photoinduced IV has been shown to proceed at ambient temperatures, enabling the use of volatile and gaseous alkenes and alkynes as crosslinkers and broadening the range of products.

    • Jinhong Jia
    • Jingjiang Liu
    • Zheng-Jun Quan
    Research
    Nature Chemistry
    Volume: 14, P: 1249-1257