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Showing 1–2 of 2 results
Advanced filters: Author: Ying-Guo Liu Clear advanced filters

  • P-centered ring-opening of quaternary phosphirenium salts (QPrS) predominantly leads to hydrophosphorylated products, while the C-centered ring-opening results mainly in the formation of phosphorus-containing cyclization products. Here the authors synthesize β-functionalized vinylphosphine oxides by the P addition of QPrS intermediates generated in situ.

    • Bingbing Dong
    • Fengqian Zhao
    • Yonggui Robin Chi
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-9

  • The site-selective acylation of saccharides without extensive pre-protection of alcohol units has been a longstanding objective in organic synthesis. Here, the authors demonstrate that by simply altering the chirality of N-heterocyclic carbene (NHC) organic catalysts, the site-selectivity of saccharide acylation can be effectively modulated.

    • Ying-Guo Liu
    • Zetao Zhong
    • Yonggui Robin Chi
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-10