This study demonstrated convenient preparation methods for the introduction of cationic and cross-linkable moieties into 2-branched and 4-branched PCL and their corresponding stable materials. The cationic content and the ratio of 2-branched and 4-branched monomers could be simultaneously controlled by incorporating non-cationic macromonomers. Zeta potential measurements proved that the cationic charge could be controlled by changing the temperatures. Human MSC adhesion was observed on the PCL materials with different cationic contents and lower contents of cationic contents seem to be preferable. Consequently, such materials are promising for biomaterials research.
- Kohei Iwamatsu
- Koichiro Uto
- Takao Aoyagi
