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Showing 1–5 of 5 results
Advanced filters: Author: Zi-Qiang Rong Clear advanced filters

  • Atomic catalytic pairs enable multistep transformations, yet the roles of spatial arrangement and coordination symmetry in homonuclear pairs remain unclear. Here, the authors construct atomically dispersed homonuclear Pt₁–Pt₁ pairs with asymmetric Pt₁C₃–Pt₁O₁C₃ coordination on reduced graphene oxide, enabling efficient transfer hydrogenation of azobenzene.

    • Yiyun Fang
    • Wen Zhao
    • Bin Liu
    ResearchOpen Access
    Nature Communications
    Volume: 17, P: 1-9

  • Chromosome-level genome assemblies of three Allium crops (onion, garlic and Welsh onion) and spatial RNA sequencing provide insights into Allium trait evolution and gene expression patterns during onion bulb formation.

    • Fei Hao
    • Xue Liu
    • Jing Cai
    Research
    Nature Genetics
    Volume: 55, P: 1976-1986

  • Catalytic asymmetric hydroboration of unsaturated bonds is the most straightforward method for the construction of chiral organoboron compounds but enantioselective hydroboration of allenes is challenging. Here, the authors report a cobalt-catalyzed asymmetric dihydroboration of allenes using a ligand relay strategy with two simple ligands to obtain chiral 1,4-diboronate products.

    • Yaqin Lei
    • Yu Kong
    • Wanxiang Zhao
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-10

  • Using readily accessible tropones and γ-methylidene-δ-valerolactones, the divergent synthesis of three classes of challenging [5.5.0] or [4.4.1] bicyclic systems has been achieved—with high efficiency and stereoselectivity—through Pd-catalysed higher-order cycloaddition. Mechanistic studies and density functional theory calculations indicate that the divergent reactions arise from the different reactivity of two diastereomeric intermediates.

    • Li-Cheng Yang
    • Ya-Nong Wang
    • Yu Zhao
    Research
    Nature Chemistry
    Volume: 12, P: 860-868