Fig. 7: Scale-up synthesis of axially chiral amides and their applications in enantioselective catalysis. | Nature Communications

Fig. 7: Scale-up synthesis of axially chiral amides and their applications in enantioselective catalysis.

From: Enantioconvergent synthesis of axially chiral amides enabled by Pd-catalyzed dynamic kinetic asymmetric aminocarbonylation

Fig. 7

a Scale-up reaction using (±)-1a and pyridin-2-ylmethanamine. b Copper-catalyzed enantioconvergent radical C(sp3)-N cross-coupling reactions. c Copper-catalyzed enantioconvergent radical C(sp3)-P cross-coupling reactions. d Copper-catalyzed enantioselective radical 1, 2-carbophosphonylation.

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