Fig. 3: Substrate scope of hydroxypentafluorosulfanylation of styrenes.

aCondition A: 1 (0.05 mmol), 2 (0.1 mmol, ~0.3 M in n-hexane), H2O (0.05 mmol), O2 (0.09 mmol), 1-hexene (0.01 mmol), DCM (0.5 mL), 365 nm LEDs, r.t., 4 h, N2 atmosphere, isolated yields; bCondition B: 1 (0.1 mmol), 2 (0.05 mmol), H2O (0.05 mmol), O2 (0.09 mmol), 1-hexene (0.01 mmol), DCM (0.5 mL), 365 nm LEDs, r.t., 4 h, N2 atmosphere, isolated yields.