Fig. 5: Tandem electro-thermo catalysis enables divergent alkene carbonylative functionalization using CO2 as the C1 source. | Nature Communications

Fig. 5: Tandem electro-thermo catalysis enables divergent alkene carbonylative functionalization using CO2 as the C1 source.

From: Pincer-cobalt boosts divergent alkene carbonylation under tandem electro-thermo-catalysis

Fig. 5: Tandem electro-thermo catalysis enables divergent alkene carbonylative functionalization using CO2 as the C1 source.

Reaction conditions: Sulfonyl chloride or alkyl halides (0.4 mmol, 2.0 equiv), Ar‒ZnOPiv (0.6 mmol, 3.0 equiv), alkene (0.2 mmol, 1.0 equiv), CoI2 (10 mol %), bpp (L17, 12 mol %), CO:H2 ( > 90:10, 1 atm), 1,4-dioxane, @ 23 °C, 2 h. † Yields in parentheses are obtained under 1 atm of CO gas. [a] 2.0 mmol scale.

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