Fig. 2: In situ generation of reactive organosodium species, its reactivity in the presence and absence of Me6TREN with N-methyl-N-methoxybenzamide. | Nature Communications

Fig. 2: In situ generation of reactive organosodium species, its reactivity in the presence and absence of Me6TREN with N-methyl-N-methoxybenzamide.

From: Isolation and reactivity of sodium benzyl cations

Fig. 2

The scheme illustrates the formation of mesitylsodium through metal exchange between NaTpMe2 and mesityllithium, followed by its rearrangement to the 3,5-dimethylbenzyl anion via intramolecular deprotonation of the mesityl anion in the presence of Me6TREN.

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