Fig. 1: Schematic diagram of the solvothermal temperature-regulated pore evolution of Zn₂(datrz)₂CO₃ series.

Increasing solvothermal temperature induces gradual ligand rotation, widening the pores from Zn₂(datrz)₂CO₃-180 to -220 and shifting molecular recognition from C₃H₆/C₃H₈ sieving to CO₂ capture. (Color code: C, gray; N, blue; O, red; H, white).