Fig. 9: Molecular structures of 6 and 7 in the solid state. | Nature Communications

Fig. 9: Molecular structures of 6 and 7 in the solid state.

From: Synthesis, structural characterization, and reactivity of homocatenated Ga₄ complexes with unsaturated Ga–Ga=Ga–Ga chains

Fig. 9

H atoms are omitted for clarity; Me-, iPr-, Ph, and Dip-substituents are depicted as a wireframe for simplicity. Selected bond lengths (Å) and angles (°) for 6: Ga2-S1 2.465(1), Ga3-S1 2.457(2), Ga1-Ga2 2.395(2), Ga2-Ga3 2.509(1), Ga3-Ga4 2.395(2); Ga2-S1-Ga3 60.28(4), S1-Ga2-Ga3 59.20(4), S1-Ga3-Ga2 59.52(4); for 7: Ga2-O1 1.886(1), Ga3-C38 2.169(1), O1-C38 1.411(1), Ga1-Ga2 2.515(1), Ga2-Ga3 2.509(1), Ga3-Ga4 2.571(1); O1-Ga2-Ga3 77.23(3), O1-C38-Ga3 100.07(4), C38-Ga3-Ga2 71.20(3).

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