Fig. 4: Scope of Ni-electrocatalyzed hydroalkylation.
From: Tunable enantioselective electrocatalytic functionalization of unactivated alkenes
Reactions were performed by using 1 (0.1 mmol), 2 (2 mmol), Ni(OAc)2·4H2O (10 mol%), L5 (11 mol%), A1 (10 mol%), (TMS)3Si-H (0.5 mmol), 2,6-Lutidine (0.1 mmol), nBu4NPF6 (0.1 M) and MeOH/TFE under constant-current conditions in an undivided cell, 6.0 F/mol. Isolated yields after chromatography are shown. aL2 (11 mol%) in DCE/TFE.
