Fig. 3: Substrate scope of α-silyl-substituted allylboronate esters. | Nature Communications

Fig. 3: Substrate scope of α-silyl-substituted allylboronate esters.

From: Desilylative allylation of 3,3-borylsilylpropene under metallaphotoredox catalysis

Fig. 3: Substrate scope of α-silyl-substituted allylboronate esters.The alternative text for this image may have been generated using AI.

Reaction conditions for 6: 1 (0.1 mmol, 1.0 equiv.), 2 (0.15 mmol, 1.5 equiv.), PC-1 (2 mol%), CrCl2 (10 mol%), MeCN/DCM (V/V = 1/1, 1 mL), blue LEDs, N2, rt, 12–18 h, then HCl (2 M, 2.0 equiv.), 30 min; a3 mol% PC-1; b20 mol% CrCl2; cMeOH (2.0 equiv.) was added without a deprotection step; dbenzyldimethylsilyl substrate was used.

Back to article page