Fig. 3: Substrate scope of sulfilimine.
From: Photo-induced selective N-N bond construction via harnessing nitrene release and transfer
a scope of nitrene precursor. b, scope of sulfonyl nitrene precursor. c, scope of natural product or drug molecule moieties. Reaction conditions: sulfilimines (0.2 mmol), amines (2.0 equiv.), CHCl3 (2 mL), N2, 365 nm LEDs, 24 h. All yields are isolated yields. Selectivity refers to the ratio of hydrazine product/urea by-product. a12 h, b14 h, c15 h, d16 h, e18 h, f20 h, g22 h, h24 h, i26 h.
