Fig. 4: Redox-mediated Pd/C-catalyzed H/D exchange of secondary alcohols and mechanistic studies42. | Communications Chemistry

Fig. 4: Redox-mediated Pd/C-catalyzed H/D exchange of secondary alcohols and mechanistic studies42.

From: Supported nanoparticles and single-atom catalysts for the synthesis of deuterated alcohols

Fig. 4

a Reversible redox-mediated H/D exchange between 2 and its corresponding ketone. b Redox-mediated H/D exchange of linear and cyclic aliphatic alcohols and ketones. c Racemization of a chiral secondary alcohol supporting a ketone-mediated H/D exchange pathway. d Proposed redox-mediated mechanism for Pd/C-catalyzed H/D exchange of secondary alcohols.

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