Fig. 2: Aromatic acceptor substrate scope. | Nature Synthesis

Fig. 2: Aromatic acceptor substrate scope.

From: Anti-Friedel–Crafts alkylation via electron donor–acceptor photoinitiation

Fig. 2: Aromatic acceptor substrate scope.

Experimental conditions: RAE (1) = 1 equiv., 0.15 mmol; DABCO = 0.5 equiv., 75 μmol; Cs2CO3 = 0.05 equiv., 7.5 μmol; DMSO = 1 ml; aromatic acceptor (3–5 equiv.): a3 equiv.; b5 equiv.; cflow conditions (Supplementary Section 4.3); dbatch conditions (Supplementary Section 4.4); eno Cs2CO3. Isolated yield. A, carbon or nitrogen; NR, no reaction.

Back to article page