The strength of electrostatic interactions in semiconductors strongly affects their performance in optoelectronic devices. Now, doping two-dimensional naphthalene-based lead halide perovskites with tetrachloro-1,2-benzoquinone has been shown to introduce donor–acceptor interactions within the organic network, without disrupting the inorganic sublattice. This in turn altered the energy of the materials’ electron–hole electrostatic Coulomb interactions.
- James V. Passarelli
- Catherine M. Mauck
- Samuel I. Stupp