Dispersive Fluorine/Bromine Interactions as Key Selectivity Determinant: Asymmetric Cyclopropanations with 3,3,3-Trifluoro-2-diazopropionate Catalyzed by a Heterochiral-at-The-Metal Centers Dirhodium Paddlewheel Complex

Journal:
Journal of the American Chemical Society
Published:
DOI:
10.1021/jacs.5c17842
Affiliations:
2
Authors:
5
Institutions Authors Share
Max Planck Institute for Coal Research (MPIKOFO), Germany
3.000000
0.60
University of Perugia, Italy
2.000000
0.40