Catalyst Support Mechanisms in Fuel Cell Technologies

Summary

The efficient operation of fuel cells relies upon the intimate interplay between catalytically active nanoparticles and their underlying support. Unlike passive carriers, catalyst supports regulate dispersion, electrical conductivity, mass transport and chemical stability. Optimisation of support porosity and surface chemistry can enhance oxygen reduction reaction kinetics by providing a high density of accessible active sites and facilitating ionomer distribution. Surface functionalisation or heteroatom doping can strengthen metal–support interactions, suppress agglomeration and mitigate carbon corrosion under dynamic operating conditions. Advanced supports include nanostructured carbons such as ordered mesoporous frameworks, carbon nanowalls and graphene derivatives, which offer tailored pore architectures and enhanced conductivity. Metal oxide supports, exemplified by corrosion-resistant titanium suboxides, promise to extend catalyst lifetime by resisting oxidative degradation. The integration of polymer layers or polymerisation strategies on support surfaces further reinforces stability and optimises the three-phase boundary essential for proton and gas transport. A coherent design of support mechanisms thus underpins both the activity and durability of modern fuel cell technologies for transport and stationary power applications.

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Catalyst Support Mechanisms in Fuel Cell Technologies publication trend

The graph below shows the total number of articles in catalyst support mechanisms in fuel cell technologies across all publications each year (not limited to Nature Index journals).

Technical terms

Proton exchange membrane fuel cell (PEMFC): A device that converts chemical energy into electricity via hydrogen oxidation and oxygen reduction across a polymer electrolyte membrane.

Oxygen reduction reaction (ORR): The electrochemical process at the cathode of a fuel cell whereby O2 is reduced to water, often the rate-limiting step.

Catalyst support: A material that disperses and stabilises catalyst nanoparticles, while providing electrical conductivity and facilitating mass transport.

Electrochemical surface area (ECSA): The effective area of catalyst sites accessible for electrochemical reactions, indicative of catalyst utilisation.

Carbon corrosion: The oxidative degradation of carbon supports under fuel cell operating conditions, leading to loss of catalyst dispersion and performance.

References

  1. Magnéli TiO2 as a High Durability Support for the Proton Exchange Membrane (PEM) Fuel Cell Catalysts. Energies (2022).
  2. Power Generation Characteristics of Polymer Electrolyte Fuel Cells Using Carbon Nanowalls as Catalyst Support Material. C – Journal of Carbon Research (2022).
  3. Synthesis of Highly Active and Stable Carbon by a Soft‐Template Hydrothermal Route as Pt Substrate for Oxygen Reduction Reaction. ChemCatChem (2023).

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