Fluoride Removal Mechanisms in Water Treatment Systems

Summary

Excess fluoride in drinking water poses widespread public health challenges, notably dental and skeletal fluorosis in affected regions. Diverse treatment strategies have been developed to lower fluoride concentrations to safe levels. Adsorption processes harness a range of solid materials—including activated alumina, engineered nanoparticles and biosorbents—to sequester fluoride ions via surface binding. Ion-exchange resins selectively replace fluoride with less harmful anions, offering regenerable operation. Coagulation-precipitation methods employ metal salts to form insoluble fluoride complexes, which can then be removed by sedimentation or filtration. Membrane-based approaches such as reverse osmosis and nanofiltration achieve high removal efficiencies through size exclusion and charge repulsion. Electrochemical techniques and hybrid systems combine these principles to enhance performance under variable water chemistries. Recent advances focus on tailoring adsorbent surface chemistry, integrating renewable feedstocks and developing low-cost modular units for decentralised applications.

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Fluoride Removal Mechanisms in Water Treatment Systems publication trend

The graph below shows the total number of articles in fluoride removal mechanisms in water treatment systems across all publications each year (not limited to Nature Index journals).

Technical terms

Adsorption: The process by which fluoride ions adhere to the surface of a solid sorbent through physical or chemical interactions.

Ion exchange: A mechanism in which fluoride ions in solution are swapped for hydroxide or other anions bound to a polymeric resin.

Coagulation-precipitation: Removal of fluoride by inducing it to form insoluble metal–fluoride compounds that settle out of suspension.

Membrane filtration: Separation of fluoride from water using semipermeable membranes under pressure, such as reverse osmosis or nanofiltration.

Isotherm model: A mathematical description of how fluoride concentration at equilibrium relates to the amount adsorbed on a solid surface.

References

  1. A Review on Adsorption of Fluoride from Aqueous Solution. Materials (2014).
  2. Zeolitic imidazolate framework-8 nanoparticle: a promising adsorbent for effective fluoride removal from aqueous solution. Applied Water Science (2019).
  3. Removal of Fluoride from Drinking Water by Sorption Using Diatomite Modified with Aluminum Hydroxide. Journal of Analytical Methods in Chemistry (2019).

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