Moisture Transport Mechanisms in Cement-Based Materials

Summary

Cementitious composites transport moisture by a combination of capillary suction, vapour diffusion and permeation through micro- and nano-porous networks. Capillary absorption drives liquid water into pore systems under a pressure gradient, while vapour diffusion redistributes moisture in response to relative-humidity differences. Together these mechanisms govern sorptivity, permeability and long-term moisture equilibration. The interfacial transition zone adjacent to aggregate particles often presents higher porosity and preferential pathways, accelerating ingress. Changes in pore geometry and connectivity during hydration, carbonation or mechanical loading further alter transport rates. Advanced imaging and non-destructive sensing have revealed how microstructural evolution of calcium-silicate-hydrate phases modulates pore size distributions and moisture retention. A quantitative understanding of these processes underpins durability assessments, informs prediction of corrosion risk at the steel-concrete interface and supports the optimisation of low-carbon binders and self-healing formulations essential for sustainable infrastructure.

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Moisture Transport Mechanisms in Cement-Based Materials publication trend

The graph below shows the total number of articles in moisture transport mechanisms in cement-based materials across all publications each year (not limited to Nature Index journals).

Technical terms

Sorptivity: The capacity of a porous material to absorb and transmit liquid by capillary forces, typically expressed as a coefficient of mass gain per square root of time.

Capillary pores: Micrometre-scale voids in hardened cement paste that facilitate liquid transport through capillary suction.

Vapour diffusion: The movement of water vapour through pore networks driven by gradients in relative humidity.

Porosity: The fraction of a material’s volume occupied by void spaces, determining its storage and transport capacity for fluids.

Wettability (Contact angle): A measure of the affinity between a liquid and a solid surface, defined by the angle formed at the liquid–solid–air interface.

Interfacial transition zone (ITZ): A region of altered microstructure around aggregates with higher porosity and connectivity that affects overall moisture transport.

References

  1. Developing a novel non-destructive method to monitor relative humidity at the steel-concrete interface using RFID-MEMS sensors. Results in Engineering (2025).
  2. Rapid prediction of cementitious initial sorptivity via surface wettability. npj Materials Degradation (2023).
  3. Factors Influencing the Capillary Water Absorption Characteristics of Concrete and Their Relationship to Pore Structure. Applied Sciences (2022).

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