Photocatalytic Nanocomposites with Carbon Nanotubes and Titanium Dioxide
Summary
Photocatalytic nanocomposites combining carbon nanotubes (CNTs) and titanium dioxide (TiO₂) harness the complementary properties of both materials to drive light-induced redox reactions with increased efficiency. TiO₂, particularly in its anatase form, offers a robust semiconductor platform but is limited by a wide bandgap and rapid recombination of photogenerated electron–hole pairs. Integrating CNTs creates intimate interfacial contacts that serve as electron highways, extending charge-carrier lifetimes and broadening the light-absorption spectrum into the visible region. Morphological control—through hydrothermal, sol–gel or solvothermal routes—and strategies such as nitrogen or metal doping further narrow the effective bandgap and introduce mid-gap states that enhance visible-light responsiveness. Such nanocomposites have found applications in wastewater remediation, solar-driven hydrogen evolution, CO₂ reduction and air purification, demonstrating scalable routes to environmental decontamination and solar-fuel generation.
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Photocatalytic Nanocomposites with Carbon Nanotubes and Titanium Dioxide publication trend
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Technical terms
Photocatalysis: acceleration of chemical reactions by a catalyst activated through photon absorption.
Electron–hole recombination: process by which a photogenerated electron returns to fill the corresponding hole, reducing photocatalytic efficiency.
Bandgap: energy difference between valence and conduction bands governing the wavelengths of light that a semiconductor can absorb.
Carbon nanotubes (CNTs): cylindrical carbon allotropes offering high surface area and electrical conductivity that facilitate charge transport.
Doping: intentional introduction of foreign atoms into a semiconductor lattice to modify its electronic structure and optical response.
References
- Modified hydrothermal method for synthesizing titanium dioxide-decorated multiwalled carbon nanotube nanocomposites for the solar-driven photocatalytic degradation of dyes. RSC Advances (2024).
- Photocatalytic Reduction of CO2 with N-Doped TiO2-Based Photocatalysts Obtained in One-Pot Supercritical Synthesis. Nanomaterials (2022).
- Preparation of TiO2/Carbon Nanotubes/Reduced Graphene Oxide Composites with Enhanced Photocatalytic Activity for the Degradation of Rhodamine B. Nanomaterials (2018).
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