Summary

Thermal conversion of solid waste fuels encompasses a suite of high-temperature processes—incineration, gasification and pyrolysis—aimed at transforming heterogeneous waste streams into energy, syngas, biochar and inert residues. Driven by mounting municipal and industrial waste volumes, these technologies offer integrated solutions for waste management, resource recovery and greenhouse-gas mitigation. Incineration relies on excess oxygen to oxidise organic matter, yielding heat and flue gases that can be harnessed for power generation. Gasification operates under sub-stoichiometric oxygen or steam conditions to produce a combustible synthesis gas rich in carbon monoxide and hydrogen. Pyrolysis, conducted in the absence of oxygen, decomposes biomass and polymeric wastes into liquid tars, non-condensable gases and a solid carbonaceous char. Key challenges include feedstock variability, emissions control, reactor design and process optimisation to maximise energy efficiency while minimising pollutant release. Advances in feedstock pretreatment and catalyst development have enhanced conversion rates and selectivity, enabling co-processing of mixed municipal solids, agricultural residues and polymeric wastes. Globally, thermal conversion plants have been deployed to reduce landfill dependence, recover energy in urban centres and valorise industrial by-products. Ongoing research integrates numerical simulation, advanced monitoring and hybrid process schemes to deliver modular, low-emission systems that align with circular-economy objectives and net-zero targets.

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Thermal Conversion of Solid Waste Fuels publication trend

The graph below shows the total number of articles in thermal conversion of solid waste fuels across all publications each year (not limited to Nature Index journals).

Technical terms

Incineration: Complete combustion of waste in excess oxygen to convert organic material into heat, carbon dioxide, water and ash.

Gasification: Partial oxidation of solid or liquid feedstock under controlled oxygen or steam to produce synthesis gas (CO and H₂).

Pyrolysis: Thermal decomposition of organic matter in an oxygen-free environment, yielding gaseous, liquid and solid products.

Thermogravimetric Analysis (TGA): A technique that measures the change in mass of a sample as it is heated, providing insights into decomposition kinetics.

Activation Energy: The minimum energy required to initiate a chemical reaction, often derived from kinetic modelling of thermal processes.

Hydrothermal Carbonization: Thermochemical conversion of biomass in hot, pressurised water to produce hydrochar and process water.

References

  1. Study on the Co-Combustion Behavior of Municipal Sludge and Bagasse: Evaluation of Ultrasonic Pretreatment. Energies (2024).
  2. Comprehensive Estimation of Combustion Behavior and Thermochemical Structure Evolution of Four Typical Industrial Polymeric Wastes. Energies (2022).
  3. Quest for the Co-Pyrolysis Behavior of Rice Husk and Cresol Distillation Residue: Interaction, Gas Evolution and Kinetics. Energies (2022).
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