Organic Chemistry articles for United Kingdom (UK)

Time frame: 1 June 2025 - 30 May 2026

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Count: 287

Article ‘Count’ for Organic Chemistry.

Journal Count Share
2 1.11
Tip-Induced Nitrene Generation 0.11
Design Principles for Engineering Ionic Liquid-Gold Nanoparticles for Therapeutic Delivery to the Brain 1.00
54 38.50
Three Component Thio‐ and Carboboration of Alkynes: A Modular Route to Functionalised Bicyclic Boronates 1.00
Supramolecular Near‐Infrared Photocatalysts for Efficient and Oxygen‐Tolerant Aqueous RAFT Polymerization 0.14
Reduced Symmetry Metal–Organic Cage‐to‐Framework Materials 1.00
Iron-Photocatalyzed C(sp3)–H Phosphonylation of Alkanes 1.00
Steric Hindrance and Secondary Interactions Govern Reconfiguration Between Two Complex CuI Coordination Cages 1.00
Tandem Reactivity of Metal−Carbon and Carbon−Silicon Bonds in Mononuclear α-Silyl Organolithium or Organosodium Complexes Towards CO, CO2 and Heteroallenes 0.78
Synthesis, Functionalization, and Reactivity of Vinyl Sulfondiimidamides 1.00
Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross-Coupling 1.00
Anion-Controlled Structural Interconversion of Palladium Cages Enables Separations by Selective Guest Capture and Release 1.00
Light‐Driven Competitive Selection in a Protein‐Catalyzed Dissipative Peptide Replication 0.04
An Iridium‐Catalyzed Conia‐ene Reaction for the Diastereo‐ and Enantioselective Synthesis of Complex Ring Systems 1.00
Selective N‐Terminal Modification of Peptides and Proteins Using Fatty Acyl Phosphates 1.00
Atroposelective Suzuki–Miyaura Coupling to Form 2-Amino-2′-Hydroxybiphenyls Enabled by sRuPhos 1.00
Tin—Tin π Bonding as a Conduit for Alkali-Metal Reduction 1.00
Asymmetric Hydride Shift Reactions Catalyzed by Chiral Aluminium Complexes 1.00
From Plastic Waste to Pharmaceutical Precursors: PET Upcycling Through Ruthenium Catalyzed Semi-Hydrogenation 0.62
A Para‐Selective Kolbe–Schmitt Reaction 0.33
Hydroxyl Radicals Unlock Strong C(sp3)─Si Bonds: Photocatalytic Alkylation and Silacycle Engineering 0.13
18F-Radiopharmaceutical Diversification Enabled by Deaminative Cross-Electrophile Couplings 0.36
Hydrophobic NIR Photocatalysts for High-Throughput RAFT Aqueous Solution Polymerization: Achieving Ultrahigh Molecular Weights with 4-ppm Dye Colloids 0.33
Ring Expansion of Oximes via Photochemical Aza‐di‐π‐methane Rearrangement 0.25
Time-Resolved SAXS Studies During the Synthesis of Hydrolytically Degradable Poly(ε-caprolactone)-Poly(N,N′-dimethylacrylamide) Diblock Copolymer Nanoparticles in Aqueous Media 0.80
Defluoroalkylation of Trifluoromethane with Organolithium Reagents: Mechanism and Synthesis of Fluoroalkenes 1.00
Synthesis, Isolation, and Reactivity of a Phosphinidene Telluride 0.10
Reactivity of Low Valent Magnesium(I) Complexes with Epoxides and Episulfides 1.00
Design and Structural Transformations of Zinc(II) Knotted Cage Frameworks 1.00
Smiles‐Truce Cascades Enable Heteroaryl Cyclopropane and Sultine Synthesis 1.00
Regioselective Zr5 Nanocluster Photocatalyst for Precise Protein Editing Under Mild Conditions 0.33
Synthesis of Thiophenes from Pyridines Using Elemental Sulfur 1.00
Transition Metal-Free Formal C─H/C─H Coupling of Arylacetamides and Sulfoxides: An Interrupted Pummerer/[2,3]-sigmatropic Rearrangement Sequence 0.92
Are Grignard Reactions in Deep Eutectic Solvents Interface-Driven? 0.45
The Discovery and Development of an Iridium‐Catalyzed N→C Alkyl Transfer Reaction 1.00
A Tertiary Amine‐Based Electrolyte with Methylation‐Mediated Steric and Electronic Synergy for High‐Performance Lithium Metal Batteries 0.08
Intermolecular Spsup3/supC─H Metalation of Non‐Nucleophilic Brønsted Bases Using Simple Lewis Acids 0.75
SmIsub2/sub‐Catalyzed Coupling of Alkyl Housane Ketones and Alkenes in an Approach to Norbornanes 0.94
Counterintuitive Photochemistry of an Isolated Acridinyl Radical: ConPET via Preassembly, Solvated Electrons or a Long‐Lived Excited State? 0.67
An Atomically Dispersed Photocatalyst for Undirected para-Selective C─H Bond Functionalizations 0.06
Molecular Insights into the Formation and Functionalization of Carbon Nanodots: From Precursor Intermediates to Surface Chemistry Quantification 0.14
Crown Ether–Peptide Rotaxanes 0.40
Electrolyte‐Controlled Regiodivergent Continuous Flow Electroselenocyclisations 1.00
Intramolecular Lithiation‐Borylation for the Stereoselective Synthesis of Cyclopentyl and Cyclobutyl Bis‐Boronic Esters 0.78
Isothiourea‐Catalysed Acylative Kinetic and Dynamic Kinetic Resolution of Planar Chiral Paracyclophanols 1.00
Asymmetric Intramolecular α‐Arylation of Polar Amino Acids Bearing β‐Leaving Groups 0.93
Asymmetric Aziridination of Allylic Carbamates Using Ion‐Paired Rhodium Complexes and Extrapolation to C─H Amination of Phenethyl Carbamates 1.00
Fluoride Enhances Alcohol Binding Within a Trigonal‐Prismatic Metal‐Organic Capsule 0.90
Revealing the Nature of Non‐Covalent Interactions in Ionic Liquids by Combined Pulse EPR and sup19/supF NMR Spectroscopy 0.86
Clsub3/subAl‐PHsub3/sub Is a Weak Lewis Pair Allowing the Synthesis of Sterically Highly Hindered Primary and Secondary Alkyl Phosphanes 0.13
The Mechanism of Ruthenium‐Catalyzed Directed C─H Arylation of Arenes: The Key Role of Bis‐Cyclometalated Intermediates 1.00
β‐Quaternary α‐Amino Acids via Iridium‐Catalyzed Branched and Enantioselective Hydroalkylation of 1,1‐Disubstituted Styrenes 1.00
Direct Activation of Sulfides by C–H Oxidation with Photoexcited Nitroarenes: Formal Manipulations of the C─S Bond 1.00
A Cobotic, Digitally Controlled Schlenk‐line Unlocks Access to Elusive Lewis‐Base Stabilised Copper Bis(Disilylamides) 1.00
Development of an Automated Workflow for Screening the Assembly and Host–Guest Behavior of Metal‐Organic Cages Towards Accelerated Discovery 1.00
Oxidative Rearrangements of the Alkaloid Intermediate Geissoschizine 0.21
Single‐Step Synthesis of a Heterometallic [Cusub2/subPdLsub4/sub]sup2+/sup Hybrid Metal–Organic Coordination Cage 0.09
1 0.40
Advanced monometallic and bimetallic catalysts for energy efficient propylene production via propane dehydrogenation pathways–A review 0.40
25 15.20
Unified, catalyst-controlled, bioinspired total synthesis of dimeric piperine alkaloids in batch and flow 0.40
Bioinspired total synthesis of (dibromo)sceptrin and (dibromo)ageliferin 0.33
Squaratides: a tunable platform for anion binding in peptide-inspired macrocycles 0.14
Copper-catalyzed allylic substitution of nitroallyl derivatives with Grignard reagents 0.25
Concise synthesis of triasteranones from barbaralones 1.00
Switchable N–H vs. C3–H carboxylation of indoles using dual-function reagents 0.83
Investigating the bioorthogonality of isocyanides 0.75
A palladium inverse crown: synthesis and characterisation 0.75
Mechanochemical one-pot Barbier/Simmons–Smith reaction via sequential zinc activation 0.88
Photocyclisations of o-iodobenzyl-indanones and tetralones infer the intermediacy of triplet aryl cations 0.64
Exploring the limits of inductive electron withdrawal in fused bicyclic azaheterocycles 0.21
Palladium-catalysed asymmetric allylic alkylation of hydantoins using bench-stable chiral palladium precatalysts 0.45
Synthesis of ketones and mono-fluoro ketones via boron enolates formed by substitution of esters with benzylboronic esters 1.00
Towards a glutathione-cleavable azobenzene linker for antibody–drug conjugates 1.00
Dynamic activation of alcohols by an electrophilic phosphinine 0.22
The photoluminescence behaviour of monosubstituted non-benzenoid polycyclic-aromatic-substituted ortho-carboranes 0.50
A multicomponent approach for the stereoselective synthesis of atropisomeric N–N peptide analogues 1.00
A direct comparison of lithium tetra(n-butyl) manganate(ii) and magnesiate: structural insights and catalytic hydroamination of styrenes 0.83
Electrochemical dehydrogenative intramolecular C–C coupling for expedient carbazole synthesis 0.43
Imidazopyridine substituted cyclic selenonium(iv) salts as chalcogen bond catalysts 0.25
Unconventional diastereoselectivity and mechanism of Cp*Co(iii)-catalyzed C–H functionalization of asymmetric dienes: a DFT perspective 0.07
Flow electrochemical oxidation of iN/i-nitrosamines to iN/i-nitramines 1.00
Scalable biocatalytic oxygenation of aliphatic amine derivatives using a class I unspecific peroxygenase 1.00
Environment-sensitive fluorescent tryptophan analogues ivia/i indole C-2 alkenylation reactions 1.00
One-pot synthesis of primary phosphines from white phosphorus 0.25
40 29.10
The palladium-catalysed modular annulative synthesis of cyclic sulfonimidamides 1.00
Formation of cyclopentanes and cyclopropanes through alkylation of benzylic anions using ethers, thioethers and alcohols as substrates under Grubbs–Stoltz (Et3SiH/KOtBu) conditions 1.00
Computational study of the effect of Lewis base additives and molecular spin state in SmI2-chemistry 0.88
Regioselective synthesis of aza-saccharins via anionic [1,4] Fries-type rearrangement of aryl sulfonimidoyl fluorides 0.05
Supramolecular protecting groups can impart prosthetic stereoselectivity to catalytic systems employing unmodified achiral heterogenous catalysts 1.00
eCyclopropanation – a safe and scalable electrochemical route to cyclopropanes 1.00
Negative cooperativity in the formation of two H-bonds with an oxygen H-bond acceptor 1.00
Hypervalent chalcogenonium organocatalysis for the direct stereoselective synthesis of deoxyglycosides from hemiacetals 0.75
Widely-used boronic esters as synthetically-versatile directing groups for C–H activation and hydrogen isotope exchange 1.00
Expanding the chemical space of ionic liquids using conditional variational autoencoders 1.00
Automated closed-loop continuous flow block copolymer synthesizer 0.50
Isolation of arylhalodiphosphenes: periodic trends in R–P[double bond, length as m-dash]P–X bonding (X = Cl, Br, I) 0.83
Peptide ligand isomerism drives divergent stability and guest binding in Pd3L4 metal-peptidic cages 1.00
N-terminal protein-macrocycles enabled by conjugate addition/ring expansion cascade reactions 1.00
Metal ligand cooperativity in the direct carboxylation and esterification of terminal alkynes by Cu-CNC complexes bearing 2,6-lutidine linkers 0.40
Asymmetric vicinal C(sp3)–H difunctionalization of saturated cyclic amines via synergistic photoredox, copper and chiral phosphoric acid catalysis 0.20
Photocatalyzed hydrogen atom transfer enables multicomponent olefin oxo-amidomethylation under aerobic conditions 0.13
Photoredox catalysed reductive cleavage of dibenzothiophene dioxides enabled by a temperature-controlled photoreactor 0.50
DiICz MR-TADF emitters as potent energy transfer photocatalysts 1.00
MMP-cleavable linker platform for tumour-responsive homo- and heterobivalent antibody–drug conjugates 1.00
Oxidative rearrangement of alkynes to chiral α-arylalkanoic esters 0.77
Molecular-level insight into the multiple mechanistic pathways in iron-catalysed alkene dimerisation 1.00
Autonomous optimisation of biocatalytic reactions: enzymatic synthesis of N-benzyl acetoacetamide in continuous flow 1.00
Switchable supramolecular polycationic assemblies for tunable antibacterial strategies against antibiotic resistance 0.15
eCarbonyls: an electrochemical thioether mediated oxidation of alcohols to aldehydes and ketones 0.80
Silver(i)-mediated oxazoline formation: a mild route to 2,4-oxazoles in peptides 0.08
Learning radical excited states from sparse data 1.00
Oxidative benzylic C(sp3)–H functionalisation of electron-poor substrates with photoexcited DDQ 1.00
Synthesis of perhalogenated silylboranes (X = Cl, I) and their application in regiodivergent alkene silaboration 0.14
Harnessing the copper surface for direct mechanocatalysis: a case study on mechanochemical sulfonylurea synthesis 0.13
Coordination sphere interactions drive isomer selection in heteroleptic Pd(ii) cages with low-symmetry ligands 1.00
Measuring the efficiency of synthetic routes and transformations using vectors derived from similarity and complexity 0.50
Isolation of a phosphinidene sulfide and selenide 0.50
Probing substrate binding and release events in iridium-catalysed hydrogen isotope exchange reactions 1.00
Visible light activation of C–Cl and C–F bonds in persistent organic pollutants using cerium(iii) triamidoamine complex 0.21
Biochemical dissection of a fungal highly reducing polyketide synthase condensing region reveals basis for acyl group selection 0.67
Predicting pore-carrier solubility and size-exclusivity towards the rational design of type II porous liquid solutions 1.00
C=O methylenation mediated by organo-alkali metal reagents: metal identity and ligand effects 1.00
A platform for SpyCatcher conjugation to native antibodies 0.92
Isothiourea catalysed enantioselective generation of point and axially chiral iminothia- and iminoselenazinanones 1.00
1 1.00
Biphasic valorization of byproducts from biodiesel synthesis using floating photochemo-enzymatic domino catalysis 1.00
1 0.50
Modeling the Effect of Microbially Induced Calcium Carbonate Precipitation (MICP) on CO2 Trapping 0.50
7 5.19
Comparisons and Contrasts in a Complete Set of Alkali Metal Cumyl Structures 0.75
Structural, Thermodynamic, and Spectroscopic Characterization of Diphosgene and Triphosgene 0.33
Zinc Metallacarborane Chemistry 1.00
Structure and Spectroscopy of Triruthenium Dodecacarbonyl, Ru3(CO)12 1.00
Steric Bulk Controls Δ/Λ Handedness Enabling Stereodivergent Self-Assembly of FeII2L3 Cages 0.11
Reactivity of a Sodium Anion with Alkenes: 1-Electron vs 2-Electron Reductions 1.00
Stereogenic-at-Metal Ir(III) Complexes as Platforms for the Construction of Asymmetric Bimetallic Complexes 1.00
2 1.13
SolvSpace: Towards sustainable solvent selection for micro- and nanomanufacturing 1.00
Amino acid mediated hydration of caustic calcined magnesia: dual-function for efficient conversion and purification 0.13
64 36.75
In Vivo Imaging of a Photoactivatable Platinum Prodrug by Metal-Centered Radiolabeling 0.78
Biomimetic Synthesis of Seven Halenaquinone Meroterpenoids 0.06
Catalytic Enantioselective Dearomatizing [2,3]-Wittig Rearrangements Allow Divergent [2,3]-, [1,2]-, and Sommelet–Hauser-Type Products 0.93
Conformationally Switchable Molecular Trefoil Knot Assembled From 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Building Blocks 0.75
Chelation-Driven Self-Assembly of Luminescent Magnesium Coordination Cages 0.83
Coordination Chemistry of a Star of David [2]Catenand 0.61
Unexpected Chemoselectivity in Radical Aryl Translocation via Photosensitization 0.06
Controlled Pyrolysis of Polystyrene Using Metal–Organic Frameworks 0.25
Direct Synthesis of Pure Aqueous H2O2 Solutions Catalyzed by C60-Buffered Proton–Electron Transfer on Palladium Adatoms 0.09
Unraveling Quinone Degradation Enables Stabilization Using Redox Helpers in Biological and Electrochemical Systems 1.00
Femtosecond-to-Second Time-Resolved Spectroscopy Brings Unparalleled Insight Into the Life Cycle of the Versatile Manganese Photocatalyst [Mn2(CO)10] 0.88
A Magnetically Bistable Rigid Carbene─2,3-Benzofluorenylidene 0.50
Synergistic Transition Metal and Hydrogen Bonding Phase-Transfer Catalysis Enables Enantioconvergent Allylic Fluorination with KF 0.86
Synthesis and Isolation of α-Diazophosphonium Ylides 0.25
Reductive Cyclopentamerization of Carbon Monoxide to the Elusive Croconate Radical Trianion 0.50
Electroreductive Cleavage of C(sp3)–N Bonds in Saturated N-Carbonyl Heterocycles 0.72
Automated Discovery of Algorithms for Molecular Electronic Structure Calculations Using Physics-Informed Program Synthesis 1.00
Synthesis of an o-Benzoquinone Arsenic Mononitride (As≡N) Complex and Its Reaction to Singlet Arsinonitrene 0.40
How Alkali Metal Alkoxides Initiate Organic Radical Reactions 1.00
Myxarylin: Total In Vitro Biosynthesis, Expansion of Substrate Scope, and Bioengineered Thioamidated Biarylitides 0.28
Thiol-Free Sulfenylation Redefined: A Single-Atom Transfer Pathway to Symmetrical Di(hetero)arylthioethers via B(C6F5)3 Catalysis 0.93
Depolymerization-Induced Morphological Transformation 0.17
Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand 0.05
Catalytic Deracemization of 1,2-Aminoalcohols through Enantioselective Hydrogen Atom Abstraction 1.00
Mechanical Energy Drives Dissipative Self-Assembly of Nanocoacervates into Vesicles with Cell-like Properties 0.14
A Divergent Asymmetric Total Synthesis of Coprophilin and Four Trichodermic Acids via a [1,5]-Hydride Shift–Aldol Cascade 0.75
Disrupting the Photochemical Landscape of a β-Diketone via Electrostatic Perturbation of Ground-State Tautomers 0.57
A Unified Synthetic Approach to 2-Alkyl Azetidines, Oxetanes, Thietanes and Cyclobutanes from Unactivated Alkenes 0.88
Protocell Survival Networks in Spatially Modulated Chemical Gradients 0.50
Selective Chiral Diamine-bisoxazoline Iron(II) Catalysts for Pyrrolidine Formation via Intramolecular C(sp3)–H Amination of Aliphatic Azides 0.20
Structural Interconversions and Guest Binding Properties of Tetrakis(formylpyridine)-Based Pseudo-Cubic and Trigonal-Prismatic Metal–Organic Capsules 1.00
β-Substituted Styrenes in Heteroaryl-Directed Hydroalkylative Cross-Couplings: Regio-, Diastereo-, and Enantioselective Formation of β-Stereogenic Tertiary Alcohols 1.00
Chemical Recycling of Polyesters and Polycarbonates: Why Is Zinc(II) Such an Effective Depolymerization Catalyst? 1.00
Biocatalytic Activation of Sulfur Heteroaromatics Facilitates Dearomatizing Cross-Couplings to Set Stereogenic Centers or Axes 1.00
Bifunctional Iminophosphorane Superbases Enable the Highly Enantioselective Sulfa-Michael Addition to Fully Substituted Cyclopropene Carboxylic Acid Derivatives 1.00
Synthesis and Characterization of a π-Extended Clar’s Goblet 0.14
The Boroxine–Boronic Acid Equilibrium 1.00
Photochemical Generation and Characterization of Alanine Imine: A Key Intermediate in Prebiotic Amino Acid Formation 0.33
Enzyme-like Enantioselectivity in GTM Chiral Zeolite Catalysts upon Preactivation of Ge Sites 0.44
Alkenyl- and Aryl-Borane Nucleophiles in Enantioselective Iridium-Catalyzed Allylic Substitution of Vinyl Epoxides 0.71
Pd-Catalyzed O-Arylation of Phenols Mediated by a Weak, Soluble Organic Base: Methodology, Mechanism, and Compatibility with Enabling Technologies 1.00
Selective Toluene Electrooxidation to Benzyl Alcohol 0.25
Interfacial Self-Assembly of Sugars at Nanoscale Membranes Leads to Micron-Scale, Spectroscopically Ice-Like Chiral Suprastructures of Water 0.11
Divergent Synthesis of 1-Azabicyclo[n.1.1]alkane Bioisosteres via Photoinduced Palladium Catalysis 0.17
Ultralow Content of Chromium Species in Zeolite for Efficient Catalytic Propane Dehydrogenation 0.13
Near-Infrared Photoenzymatic Catalysis at ppb Levels Enables Ultrahigh-Molecular-Weight Polymers 0.17
An 18-Porphyrin Nanoring at the Size Limit for Global Aromaticity 1.00
Multiple Template Site Nitrogen Atom Deletions from Rotaxanes, Catenanes, and a Molecular Knot 0.93
A Data Science-Guided Approach for the Development of Nickel-Catalyzed Homo-Diels–Alder Reactions 0.08
Fluorinated Twists: A Pathway to a Stable Pdsub8/subLsub16/sub Square Antiprism 1.00
A Dynamic Silver(I) Nanocluster Holds Together a 3 × 3 Self-Assembled Grid 0.62
Modular Synthetic Platform for the Elaboration of Fragments in Three Dimensions for Fragment-Based Drug Discovery 1.00
Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates 0.10
Unveiling Janus Chemical Processes in Contact-Electro-Chemistry through Oxygen Reduction Reactions 0.05
Near-Infrared Light-Accelerated Bioorthogonal Drug Uncaging and Photothermal Ablation by Anisotropic Pd@Au Plasmonic Nanorods 0.78
Biosynthesis of Biphenomycin-like Macrocyclic Peptides by Formation and Cross-Linking of iOrtho/i-Tyrosines 0.04
iMechanometallaphotoredox/i Catalysis: Utilizing Increased Throughput Mechanochemistry to Develop Solvent-Minimized Aryl Amination and C(sp2)-C(sp3) Cross-Coupling Reactions with Increased Tolerance to Aerobic Conditions 1.00
The Science of Polymer Chemical Recycling Catalysis: Uncovering Kinetic and Thermodynamic Linear Free Energy Relationships 1.00
Divergent Total Syntheses of Rearranged Steroids Swinhoeisterols A–C 0.25
Persistent Boryl Radicals as Highly Reducing Photoredox Catalysts for Debrominative Borylations 1.00
Planarity Is Not Plain: Closed- vs Open-Shell Reactivity of a Structurally Constrained, Doubly Reduced Arylborane toward Fluorobenzenes 0.13
Spontaneous Emergence of Homochiral Suspensions from Racemic Solutions via Stochastic Nucleation 0.17
Non-Aqueous Binary and Ternary in/iHF·Base Fluoride Reagents: Characterization of Structure, Properties, and Reactivity 1.00
Guanine Crystallization by Particle Attachment 0.22
10 6.30
From Flory Theory to Real Systems: Decoding Polymerization Deviations in Poly(β-amino ester)s (PAEs) 0.33
Synthesis of Poly(δ-valerolactone)-poly(N,N-dimethylacrylamide) Supermicelles in Concentrated Aqueous Media via Reverse Sequence Polymerization-Induced Self-Assembly 0.75
Function Meets Circularity: Metal–Ionomer Cross-Links Toughen and Recycle CO2-Derived Polymers 1.00
Varying Monomer Charge in SI-bioATRP Polymer Grafting from Mesoporous Silica 0.17
Backbone Dynamics of Bottlebrush Polymers Studied by Neutron Scattering 0.25
Rational Design of Zwitterionic Polymers with Tunable Phase Separation Propensity 0.17
Single-Unit Comonomer Insertion Initiates Radical Polymerization of Thionolactone to Give Chemically and Thermally Degradable Polythioesters 1.00
Thermogels Based on Block versus Gradient Terpolymers: Differences in the Nano- and Macro-Scale 0.64
Access to Self-Assembled Poly(2-Oxazoline)s through Cationic Ring Opening Polymerization-Induced Self-Assembly (CROPISA) 1.00
Access to Microstructurally Complex Block Copolymers via Switchable Ring-Opening Polymerization of Cyclic Ester Mixtures 1.00
1 0.25
Sub-2 Å cryo-EM structures of transcribing RNA polymerase II reveal critical roles of water molecules in catalysis 0.25
1 0.67
Programmable RNA Nanostructures Enable Nanopore Detection of Cotranscriptionally Introduced RNA Modifications 0.67
5 2.56
Dominant contribution of Asgard archaea to eukaryogenesis 0.13
Nanobody-based recombinant antivenom for cobra, mamba and rinkhals bites 0.21
Thioester-mediated RNA aminoacylation and peptidyl-RNA synthesis in water 1.00
Catalytic enantioselective synthesis of alkylidenecyclopropanes 0.62
Boron-mediated modular assembly of tetrasubstituted alkenes 0.60
9 7.20
Synthesis of aryl-fused bicyclo[3.1.1]heptanes and validation as naphthyl bioisosteres 1.00
Spontaneous trisulfide metathesis in polar aprotic solvents 0.12
Biomolecular condensates sustain pH gradients at equilibrium through charge neutralization 0.54
Collective asymmetric synthesis of the Strychnos alkaloids via thiophene S,S-dioxide cycloadditions 1.00
Biocompatible ligand balancing in transition metal coordination enables benign in-cell protein arylation 1.00
The catalytic enantioselective [1,2]-Wittig rearrangement cascade of allylic ethers 0.95
Bright triplet and bright charge-separated singlet excitons in organic diradicals enable optical read-out and writing of spin states 0.59
A biocompatible Lossen rearrangement in Escherichia coli 1.00
Information propagation through enzyme-free catalytic templating of DNA dimerization with weak product inhibition 1.00
21 9.56
Alternative enzymatic pathways to penicillin antibiotics 1.00
Gallium in liquid state shows nuclease-mimicking activity 0.18
Expression of nano-engineered RNA organelles in bacteria 0.92
Mechanistic insights into the non-equilibrium thermodynamics of nitrogen fixation via acoustic cavitation 0.88
Chemoenzymatic synthesis of pentalenolactones via stereoselective Riley oxidation by engineered P450 0.20
Trifunctional flavoenzyme-catalyzed asymmetric 4-alkyl-butenolide assembly in avenolide biosynthesis 0.03
A neutral cyclic aluminium (I) trimer 0.83
Divergent photochemical ring-replacement of isoxazoles 0.17
Photo-initiated solvent-mediated depolymerization of consumer poly(methyl methacrylate) without chlorinated reagents 1.00
Manganese catalyzed oximation of hydrocarbons to oximes 0.18
High-throughput triazole-based combinatorial click chemistry for the synthesis and identification of functional metal complexes 0.70
Asymmetric synthesis of stereogenic-at-sulfur compounds via biocatalytic oxidation with Unspecific Peroxygenases 1.00
Controlling solvation in conducting redox polymers for selective electrochemical separation of nitrate from wastewater 0.09
Copper integrative catalytic pairs with mixed-valence Cu-Cu Species for selective alkyne conversion 0.14
Photochemical rearrangement of isonitriles via energy transfer catalysis 0.20
Differential stability and dynamics of DNA-based and RNA-based coacervates affect non-enzymatic RNA chemistry 0.58
Redox-innocent scandium(III) as the sole catalyst in visible light photooxidations 0.10
Photochemical permutation of -substituted phenols 0.08
Biosynthesis and bioactivity of anti-inflammatory triterpenoids in Calendula officinalis 1.00
Chemoselective synthesis of 1,3,4-thiadiazoles from acyl hydrazines and nitroalkanes using elemental sulfur 0.14
Amino acids catalyse RNA formation under ambient alkaline conditions 0.13
26 18.19
Catalyst-Free Photoinduced ortho C–H Heteroarylation of Phenols 0.17
Continuous Photoflow Synthesis of Heterohelicenes 1.00
Visible Light-Promoted Cascade Cyclization/Allylation of 2-Allyloxyaryl Sulfonium Salts with Morita-Baylis-Hillman Acetates 0.19
Decarboxylative and Deoxygenative/Decarbonylative Alkylation of Heterocycles with α-Keto Acids 0.14
A Polarity-Mismatched Photocatalytic Cross-Coupling Enables Diversity-Oriented Synthesis of aza-Heterocycles 1.00
Synthesis of the Proposed Structure of Celacarfurine and Analogues Using Sequential Cascade Ring Expansion Reactions 1.00
e-Carbonyl: Electrochemical Synthesis of α-Keto Esters via α-Carbonyl Carbocations 0.57
Biocatalytic Enantioselective Oxidation of N-Acyl-S-Methyl Sulfenamides for the Asymmetric Synthesis of S-Methyl Sulfoximines 0.40
Orthogonal Regioselective Synthesis of Folic Acid γ-Conjugates 1.00
Copper-Mediated Photoinduced Trifluoromethylation of Arylsulfonium Salts with Yagupolskii–Umemoto Reagent 0.20
Site-Selective C–H Sulfinamidation through Electron-Donor–Acceptor Complex Photoactivation and Radical Addition into Sulfinylamine Reagents 0.67
Synthesis of the Tetracyclic Core of the Daphlongeranines 1.00
On-Resin Synthesis and Late-Stage Functionalization of Macrocyclic Atosiban Mimetics via 5-Iodo-1,4-triazoles 1.00
Light-Mediated Tandem Giese/C–H Functionalizations Toward Cyclopenta[b]indoles 1.00
Umpolung Approach for the α-Alkylation of Benzylic Amines Enabled by Superelectron Donors 0.17
Iron-Catalyzed Decarboxylative Sulfinylation of Alkyl Carboxylic Acids 1.00
B(C6F5)3-Catalyzed Coupling of N-Alkyl Arylamines and Alkenes for the Synthesis of Tetrahydroquinolines 1.00
Synthesis of Indoloazepinone Scaffolds Using Sequential Photochemical and Photocatalytic Reactions 1.00
Enantioselective Formal Synthesis of (−)-Aflatoxin Bsub2/sub Enabled by Pd-Catalyzed Carboetherification of 2,3-Dihydrofuran 1.00
An Asymmetric Approach toward the iAristotelia/i Alkaloid (−)-Penduncularine 1.00
Synthesis of the Spirotetracyclic Core of the Ginkgolides via a Malonyl Radical Cascade 1.00
One-Pot Synthesis of Alkynyl-Conjugated Phenylalanine Analogues for Peptide-Based Fluorescent Imaging 1.00
Visible Light-Promoted Construction of Cage-Like Frameworks by Sequential [2 + 2] Cycloaddition 0.14
Chemoselective Difluoromethylation of Nucleosides 1.00
Base-Mediated Formal Denitrogenative Insertion of Nonactivated Triazoles into Aldehydes: Stereospecific Synthesis of Highly Substituted Acrylamides 0.13
Elucidation of a Parasitic Proton-Coupled Electron Transfer in a Photocatalytic Benzylic C–H Sulfonamidation 0.42
1 0.88
Selection for growth drives the emergence of genetic heredity in protocells 0.88
3 1.23
Nonreciprocal Interactions between Condensates in Chemically Active Mixtures 0.13
Synergistic Motifs in Gaussian Systems 1.00
Attosecond Optical Orientation 0.10
4 2.08
Chemputer and chemputation—A universal chemical compound synthesis machine 1.00
Coevolution of RNase P and the ribosome 0.08
Structure and encapsulation of carbonic anhydrase within the α-carboxysome 0.92
Divergent sustainability profiles of molnupiravir synthesis routes are governed by solvent use and process design 0.08
4 2.40
A molecule with half-Möbius topology 0.31
A small polymerase ribozyme that can synthesize itself and its complementary strand 0.88
Access to four-membered cyclic sulfinamides by energy transfer catalysis 1.00
Diversity-oriented photobiocatalytic synthesis via stereoselective three-component radical coupling 0.22
3 0.92
Water doping sodium battery electrolyte controls nanostructure, interactions, and electrochemical properties 0.03
Molecular basis of the biogenesis of a protein organelle for ethanolamine utilization 0.72
The minimal chemotactic cell 0.17
2 1.13
Vibrational Quantum-State-Controlled Reactivity in the O2+ + C3H4 Reaction 0.13
Ultrafast Excited-State Dynamics of the Organic Photoredox Catalyst DDQ 1.00

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