Titanosilicates in combination with H2O2 catalyse the ammoxidation of cyclohexanone to cyclohexanone oxime, a key Nylon precursor. Integrating a step for the in situ synthesis of H2O2 can lead to important efficiency gains but remains challenging. Here the authors report low-loaded subnanometric Pd clusters on titanium mordenite as an efficient catalyst for this transformation.
- Zhipeng Wan
- Qingjie Zeng
- Peng Wu
