Organic Chemistry articles for Germany

Time frame: 1 May 2025 - 30 April 2026

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Count: 516

Article ‘Count’ for Organic Chemistry.

Journal Count Share
4 1.86
Micropatterned DNA Hydrogels for Spatiotemporal Programming of Chemical Reaction Networks 1.00
Charge Transfer between Quantum Dots and Redox Molecules Is Not Auger-Assisted 0.18
Tip-Induced Nitrene Generation 0.22
Molecular Biomimicry and the Synthetic Synapse: Engineering a Stable Synaptogenic Extracellular Matrix 0.45
1 0.60
Polyferrocene-Based Cubosomes: Conversion to Magnetic Mesoporous Microparticles, Supramolecular Modification, and Oxidation Response 0.60
1 1.00
Electrochemical Chlorine Shuttle from PVC Waste to Vinyl Ether Acceptors for the Synthesis of Biodegradable Polyester Precursors 1.00
1 1.00
High-Throughput Testing for Unknown Mutagens and Cytotoxica via Duplex Planar Ames–Cytotoxicity Bioassay Including Metabolic S9 Activation 1.00
136 101.19
Selective Para-Functionalization of Aromatic C(sp2)─H Bonds via Atomically Dispersed Photocatalysis 0.31
Site-Selective B─H Activation via HAT Toward Xanthyl-closo-Carboranes as Bench-Stable Precursors of Organosulfur Boron Clusters 0.10
Radical Cascade Combining Cross-Olefin Coupling with the Smiles-Truce Rearrangement 1.00
Sulfur‐Directed Construction of Vinyl Cyclopropanes from 1,3‐Dienes 1.00
Diazo Transfer From Nitrous Oxide Employing Phosphorus Ylides 1.00
Biocatalytic Access to Natural Mosquito Repellent p-Menthane-3,8-diol via Direct Asymmetric Prins Cyclohydration 0.67
Discovery of a Plant Pictet–Spenglerase With R-Stereoselectivity 1.00
Isolation and Reactivity of a Square‐Planar Trisamido Silane 1.00
Stimuli‐Responsive Silsesquioxane Nanozymes for Organocatalysis in Water and Prodrug Activation in Cells 0.60
Alkyltransferase Ribozyme for Site-Specific N4-Cytidine Alkylation 1.00
o-Terphenyl-Based Family of Conjugated Macrocycles: Selective Recognition of Phenylalanine in Water and Interaction With Insulin 1.00
Dissipatively Fueled Unidirectionally Communicating DNA Circuits That Control Biocatalysis 0.86
Sequential Homo- and Hetero-Coupling of Isocyanide and Carbon Monoxide Mediated by Acyclic Imino(silyl)Silylene 1.00
Photochemical Cyclization of Tertiary Buta‐2,3‐dienamides to β‐Lactams Upon Triplet Energy Transfer 1.00
Self‐assembled Helical Tetramer Stack of Terrylene Bisimide in Solution and Crystalline State 1.00
Traces of Elements in the Electrochemical Reductive Amination of Acetone: Uncovering Bi as Substitute for Pb 0.50
A Mechanochemical Kolbe–Schmitt Reaction: Catechol Carboxylation Provides Building Blocks for Renewable Plasticizers 0.60
A Monkey-Saddle-Shaped Nanographene Embedding a Dicyclohepta[cd,fg]-as-Indacene Core and Two Additional Heptagons, and Its Paddle-Wheel Co-Assembly With Fullerenes 0.29
Biocatalytic Regioselective C‐Formylation of Resorcinol Derivatives 0.29
Hidden Diradical: Conformational Switch for Solvatochromic NIR Emission With Unity Quantum Yield in Thiele's Hydrocarbon 0.13
Predictive, Data‐Driven Design of Red‐Light Photoredox Catalysts for C─Heteroatom Bond Formation 0.29
Experimental Isolation of Single Impact, Cumulative Energy, Aging, and Liquid‐Assisted Grinding Effects in Mechanochemical Reactions 1.00
Structural Revision of the C16 Sesquiterpene Hegelenether and the Mechanism of C6-Methylation in Terpene Biosynthesis 1.00
Dibenzazepine Bridged Network Polymeric Phthalocyanines as Degradable Heterogeneous Photocatalysts 0.93
Alkynyltriazenes in Photochemical Metal‐Free Doyle–Kirmse Rearrangements 0.94
Growth, Dissolution and Segregation of Genetically Encoded RNA Droplets by Ribozyme Catalysis 1.00
Synergistic Effects of Electricity and Light for Efficient Iron‐Catalyzed Recycling of Polystyrene Waste 1.00
An Electrocatalytic/Heterogeneous Catalytic Cascade for Selective Production of Propylene Oxide via Anodic H2O2 Generation 1.00
Photochemical Deracemization of Chromanes and its Application to the Synthesis of Enantiopure Bioactive Compounds 1.00
From Plastic Waste to Pharmaceutical Precursors: PET Upcycling Through Ruthenium Catalyzed Semi-Hydrogenation 0.15
Twist and Shine: The Impact of Halogen Substitution on Thiele Hydrocarbon's Optical Properties 0.17
Stereochemical Dissection of the Strobilurin PKS Reveals the Complex Biosynthetic Logic of Iterative EZE Triene Construction 0.92
Translation‐Promoting Effects of RNA Template Overhangs in the Absence of Ribosomes 1.00
Photocatalyzed Ring Expansion of α-Ketosulfonylaziridines: Ready Access to δ-Sultams 0.50
Harnessing Cooperative Energy Transfer and Hydrogen Atom Transfer for Direct Nitrogenations of Non‐Activated Alkanes 0.70
Influence of Rare Earth Elements on Prebiotic Reaction Networks Resembling the Biologically Relevant Krebs Cycle 1.00
Homoleptic Bismuth Alkynes: Isolable Reagents for Selective Alkynyl Radical Transfer 1.00
Amination and Para-C─H Arylation of Aryl Fluorides Enabled by α-Methylnaphthyl (MeNAP) Palladium Catalysts 1.00
Predicting the Stability of Base-mediated C─H Carboxylation Adducts Using Data Science Tools 0.50
Homoterpene Biosynthesis in Fungi 1.00
The Methylbismuth Dication: Pentagonal Pyramidal Coordination and Ligand-Induced Lewis Superacidity 1.00
Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross-Coupling of 1,1′-Biaryl-2,6-diyl Bis(nonaflates) 1.00
Hierarchical, Template-Controlled Self-Assembly of Two Different Organometallic Capsules from a Tetrakisimidazolium Salt 0.17
Mechanistic Characterisation of Bacterial Terpene Synthases from Chitinophagaceae Producing Marine-Type Diterpenes 1.00
Triplet Metallovinylidenes of Palladium and Platinum Based on a Chelating P/Diazoalkene Ligand 1.00
Reaction of Blatter and Verdazyl Radicals with Arynes: Synthesis and Investigation of N‐Chiral, Antiaromatic Triazines, and Tetrazinones 0.75
Through Stronger Hindrance to Higher Reactivity: Influence of the Alkyl Chains on the Activation Energy of Ether Cleavage on Silicon 0.88
Biosynthesis of the Biphenomycin Family of Potent Antibiotics 1.00
EDA Complex‐Driven Desaturation of Heterocyclic Carbonyl Compounds Enabled by HFIP 0.57
Redox-Acidity Interplay in Eu-Promoted PtSn2 Catalysts for Selective and Stable Propane Dehydrogenation 0.18
A Photoswitchable HaloTag for Spatiotemporal Control of Fluorescence in Living Cells 1.00
Deciphering Ball Milling Mechanochemistry via Molecular Simulations of Collision‐Driven and Liquid‐Assisted Reactivity 0.58
Regulating Promiscuous Catalysis via Substrate‐Induced Transient Assembly 1.00
Facile Access to Chelating CAArC‐Phosphine (CAArCPhos) Palladium Complexes 1.00
Isolation of Anionic N-Heterocyclic Olefins and Their Versatile Reactivity 1.00
Observation of Near‐Infrared Photothermal and Photoacoustic Effects in a Metallosupramolecular Trefoil Knot 0.17
Collective Total Synthesis of a Unique Class of Liverworts‐Derived Cembrane Diterpenoids 1.00
A Robust Heterometallic Pt2Pd2L8 Double Cage Catenane 0.90
Si−H Activation via Dynamic Permutational Isomerism: A Ligand-Directed Route to Dehydrogenative Coupling 1.00
Engineering Artificial Mitochondria with Self-Amplifying Proton Generation for Autonomous Energy Supply and Metabolic Coupling in Artificial Cells 0.13
Silicon-Based Azo Compound-Mediated CO Activation and N2 Release 1.00
Polycyclic Heteroaromatics with Planar‐Curved Hybrid Skeletons for High‐Performance Photocatalytic Hydrogen Peroxide Evolution 0.06
Enhancing Cascade Reaction Efficiency by Local pH Regulation for Integrated Anodic H2O2 Generation and Ammoximation 1.00
Amine‐Ligated Boryl Radicals Enables Direct C─F Borylation and Cross‐Couplings of Polyfluoroarenes 0.22
Transition‐Metal‐Free Carbonyl Redox: A Ketene in Three Oxidation States 0.33
Computational Study of Ignored Pericyclic Reactions: Rearrangements of 1,2-Bis(Diazo)Alkanes to 1,2,3,4-Tetrazines and Subsequent Fragmentations 1.00
Chirality Makes or Breaks Chemically Driven Self‐Assembly 1.00
Ligand Type Guided Keto-Arylation Enables Modular Total Synthesis of Polycyclic CBS Xanthones 1.00
Radical C─H-Aroylation of Allenes via Cooperative Photoredox and N-Heterocyclic Carbene Catalysis 1.00
Functionalized Calix[4]Nanocones 1.00
Copper(II)‐Photocatalyzed Radical Anellation of Nitroalkanes with Alkenes or Alkynes for the Synthesis of Isoxazolines and Isoxazoles 1.00
Platinum-Catalysed Hydrofluorination of Alkynes at Room Temperature Promoted by a Fluoride Shuttle 1.00
Dual-Stimulus Programmed Multiphase Separation and Organization in Coacervate Droplets 1.00
A Facile and Efficient Route to Achieve Polythiophene‐Based Nanoparticles With Various Morphologies 0.08
Nickelaelectro‐Catalyzed C─H Activation to iβ/i‐Arylated Pyrroles ivia/i Multiple Dehydrogenation 1.00
The Origin of the Feedstock Molecules for Life on the Hadean Earth 1.00
Biocatalytic Alkylation of Ambident Nucleophiles Enables Selective iN/i‐Functionalization of Heterocycles and Late‐Stage Modifications 1.00
Assessing Fluorosulfonyl Pentafluorooxosulfate (FSO2–OSF5) Reservoir Capacity: Selective SOF4, SO2F2, and [OSF5]– Anion Release 1.00
The Overlooked Dual Phosphorescence of Lappert's Diamino Stannylene Sn[N(SiMesub3/sub)sub2/sub]sub2/sub 1.00
Monomer‐Dependent Selectivity in Sulfur‐Containing Ring‐Opening Copolymerisation: Bimetallic Catalysis for Predictive Design of Degradable Polymers 0.67
Total Synthesis and Structural Revision of (−)‐Sodagnitin E 1.00
Bicyclic Selenenyl Sulfides with Tuned Bioreductive Step Rates Reveal Constraints for Probes Targeting Thioredoxin Reductase 0.43
Efficient Red Light–Driven Singlet Oxygen Photocatalysis with an Osmium‐Based Coulombic Dyad 1.00
Photocatalytic Synthesis of Unprotected Sulfonimidamides and Their Application in Photochemical Nitrene Transfer Reactions 0.78
Iron‐Catalyzed itrans/i‐Hydrostannation of Terminal Alkynes 1.00
Stopping the Chain: Isolated Molecular Intermediates of Anionic Styrene Polymerization 1.00
Indeno[2,1‐ic/i]fluorene Quasi[8]circulenes Through Intramolecular Cyclization 0.25
Regioselective C─H Functionalization by the Combination of Enzymatic and Chemocatalytic Reactions in Water 0.75
Regiodivergent Photocatalytic Annulation for the Synthesis of igem/i‐Difluorinated Cyclic Hydrocarbons 0.22
Sustainable Closed‐Loop Recycling of Polyester Waste Using Reconstructed Defective‐Metal–Organic Frameworks 0.14
Tunable Endo/Exo Selectivity in Direct Catalytic Asymmetric 1,3-Dipolar Cycloadditions with Polyfunctional Lewis Acid / Azolium–Aryloxide Catalysts 1.00
Enantioselective Rhodium‐Catalyzed Cycloisomerization of 1,5‐Bis(allenes) to Access 1,2‐icis/i‐Ethynyl‐ and Vinyl‐Substituted Five‐Membered (Hetero)Cycles 1.00
An Atomically Dispersed Photocatalyst for Undirected para-Selective C─H Bond Functionalizations 0.24
Methylthiohexa‐1,3‐Diene: Anionic Polymerization of a Diene with Thioether Moiety Enables Post‐Polymerization Modification and Antimicrobial Materials 1.00
Catalytic 1,2‐Migratory Insertion in a Bismuth Redox Platform: Reductive Arylation of Aldehydes 1.00
Intramolecular Lithiation‐Borylation for the Stereoselective Synthesis of Cyclopentyl and Cyclobutyl Bis‐Boronic Esters 0.11
A Monolithium Monohydrogen Porphyrin 1.00
The Role of Reducibility of PtGaOisubx/sub/i‐Based Catalysts for Efficient and Durable Propane Dehydrogenation 0.51
Identification of Ti(salen) Complexes for Efficient Catalysis in Single‐Electron Steps by Cyclic Voltammetry 1.00
Titanium‐Catalyzed C─X and C─H Borylation of Aryl Halides for the Synthesis of Bis(boronate)benzenes 0.25
Reactivity of Pnictaalumenes Towards 1,3‐Dipole Molecules 1.00
Unlocking a Ferrocenium Superoxidizer with the Perfluorinated Cp* Ligand 1.00
Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles? 0.43
iZ/i‐Selective Alkyne Semireduction by an Organic Photoreductant 1.00
Revealing the Nature of Non‐Covalent Interactions in Ionic Liquids by Combined Pulse EPR and sup19/supF NMR Spectroscopy 0.14
Access to iN/i‐Monofluoromethylated (Thio)Carbamates, Formamides, Alkynamides, and Related Derivatives 1.00
Dinitrogen Activation with Low‐Valent Strontium 1.00
icloso/i‐Carboranyl Analogs of β‐Arylethylamines: Direct Synthesis from Alkenes via EnT‐Catalysis 1.00
Clsub3/subAl‐PHsub3/sub Is a Weak Lewis Pair Allowing the Synthesis of Sterically Highly Hindered Primary and Secondary Alkyl Phosphanes 0.13
Introducing Photochemical Action Plots as a Tool for Unlocking On–Off Switchable Behavior in a Polymeric Eosin Y Photocatalyst 0.45
Nitrate Reduction for Deaminative Suzuki–Miyaura Coupling of Anilines 1.00
Unsaturated Phosphine Oxides for Modular Antibody Rebridging and Single Reagent Peptide‐Cyclisation‐Bioconjugation 1.00
Mixing and Matching of Hybrid Megasynthases is a Hub for the Evolution of Metabolic Diversity in Cyanobacteria 0.57
Absolute Asymmetric Synthesis of a Homochiral Polymer from an Achiral Monomer 0.25
Desulfurizative Fluorination of iN/i‐CFsub3/sub Thioformamides for the Efficient Synthesis of iN/i(CFsub3/sub)(CFsub2/subH) Amines with Enhanced Stability 1.00
Ribozyme‐Catalyzed Site‐Specific Labeling of RNA Using iO/isup6/sup‐alkylguanine SNAP‐Tag Substrates 1.00
Ruthenium Catalyzed Ortho-Arylation Reaction of Benzoic Acids with Arylthianthrenium Salts 0.10
Redox‐Switchable Poly‐Lewis Acids Allow the Controlled Release of Guests 1.00
α-Amination of 1,3-Dicarbonyl Compounds and Analogous Reactive Enolate-Precursors Using Ammonia under Oxidative Conditions 0.14
Excited‐State Basicity Diverts the Site‐Selectivity of Aromatic Deuteration: Application to the Late‐Stage Labeling of Pharmaceuticals 1.00
Engineering of Transmembrane Alkane Monooxygenases to Improve a Key Reaction Step in the Synthesis of Polymer Precursor Tulipalin A 0.21
Photoelectrochemical Iron(III) Catalysis for Late‐Stage C─H Fluoroalkylations 1.00
Nitrogen Insertion via Asymmetric Condensation and Chirality Transfer: A Stereodivergent Entry to Cyanocyclopropanes 1.00
Late‐Stage Cross‐Electrophile Coupling of Arylthianthrenium Salts with (Hetero)aryl (Pseudo)halides via Palladium Catalysis 1.00
Redox‐Controlled, Sequential Self‐Sorting of Supramolecular Assemblies in Model Protocells 0.17
Oxidative Rearrangements of the Alkaloid Intermediate Geissoschizine 0.71
An Immobilized Rh‐based Solid Molecular Catalyst for the Reductive Hydroformylation of 1‐Octene 1.00
Prebiotic Interconversion of Pyruvate and Lactate over Zeolite‐Supported Ni Catalyst 0.70
Routes to Pt Derivatives of High‐Valent Sulfur Oxofluorides S(═O)sub2/subF, S(═O)Fsub2/sub, and S(═O)Fsub3/sub by Fluorination and Oxygenation 1.00
Enantioselective Photochemical Generation of a Short‐Lived, Twisted Cycloheptenone Isomer: Catalytic Formation, Detection, and Consecutive Chemistry 1.00
Photocatalytic Generation of a Ground‐State Electron Donor Through Water Activation 1.00
Conversion of Bestmann Ylide into Carbophosphinocarbene 0.80
PPh3/Isocyanide and N2/Isocyanide Exchange: Pathways to Isolable Alkali Metal Keteniminyl Anions 0.69
Activating Molybdenum Peroxide Scissors for Converting Polyamide Plastic into Low Carbon Alcohols 0.14
Mechanism Switch Between Radical‐Polar Crossover and Radical Buffering 0.60
AIE Bottlebrush Polymers: Verification of Internal Crowdedness in Bottlebrush Polymers Using the AIE Effect 0.17
1 0.21
Pan-modification profiling facilitates a cross-evolutionary dissection of the thermoregulated ribosomal epitranscriptome 0.21
39 28.38
Attempted halogenation of ambiphilic 1,2,3-benzodiazaborines: balancing Lewis acidity and Lewis basicity 1.00
A route to asymmetrically substituted secondary phosphines 1.00
Catalyst-free insertion of carbon monoxide into terminal Mg–C(sp3) bonds 0.67
A solid-phase click2 strategy for chromophore–DNA conjugates and their application as a light harvesting system 1.00
Photocatalytic S-alkylation of sulfinamides: access to sulfoximines 1.00
Quantifying the enamine-type nucleophilic reactivity of α-aryl vinyl azides 1.00
Reactivity of ketenyl anions towards ammonia 1.00
Atom-efficient iron-catalyzed cascade synthesis of pyrroles from nitroarenes under low-pressure conditions 1.00
Molecular communication system using Zn2+ selective supramolecular nanochannel to induce photoregulated catalysis 0.20
Organocatalytic α-deuteration of carbonyl compounds: a pTSA/D2O strategy for bioactive and natural products 0.20
Turn left and turn right: recent advances in selectivity controlled carbonylation 0.17
Chemoselective nickel-catalyzed difluoromethylation of aryl halides with (SIPr)AgCF2H as transmetalation reagent 1.00
Adaptive crystals of homothiacalix[4]arene capable of molecular recognition, with preferential uptake of benzene over cyclohexane 0.33
Temperature-jump QCL spectroscopy of peptide dynamics: expanding spectral accessibility by dual-combs 0.67
Dynamic activation of alcohols by an electrophilic phosphinine 0.78
Carbon monoxide as the key: carbonylation triggered (hetero)aryl migration transformations 0.50
Targeted synthesis of a positional isomer of aromatic N-methyl N-confused corrole and its organocopper(iii) complex 0.50
A radical path to 1,2-diphosphacyclobutenes 1.00
β-Carboxyphospholes via carboxylative desilylation: luminophores with a versatile connectivity attached 1.00
Cobaltaelectro-catalyzed C–H acyloxylation of aromatic and vinylic amide derivatives at room temperature 0.25
Solid-state polycyclotrimerization of diynes to porous organic polymers 1.00
Photo-induced ruthenium-catalyzed alkene C–H-arylation at room temperature 1.00
A diazadiphospholenium cation featuring a reactive P[double bond, length half m-dash]P bond: synthesis and reversible main-group bond activation 1.00
A facile route to cis-olefin-linked phosphino-phosphonium salts of the form: [Ph2PC(R)C(H)P(R′)2H][AlCl4] 0.10
Di-π-methane rearrangement in 1-phosphabarrelenes: formation and reactivity of an unprecedented 2-phosphasemibullvalene 1.00
Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles 1.00
Imidazopyridine substituted cyclic selenonium(iv) salts as chalcogen bond catalysts 0.75
Lanthanide complexes of aminopolycarboxylates reveal deuteration of aminoacetate carbons in alkaline aqueous media 1.00
A preorganized triarmed bis-triazolylpyridine-calix[4]arene with high affinity and selectivity for minor actinides for nuclear waste treatment 0.36
Photochemical rearrangements of a [2.2]paracyclophane-based nitrene studied by vibrational CD spectroscopy 1.00
Low-coordinate calcium peroxide and oxide complexes 1.00
C(sp3)–H functionalization of N-protected dialkylpyrrole derivatives with azodicarboxylates 0.29
Electrochemical synthesis of cyclic sulfites using diols and sulfur dioxide 1.00
One-pot synthesis of primary phosphines from white phosphorus 0.75
Electrochemical iS/i-vinylation of sulfinamides with β-bromostyrenes 0.80
Encasing the paramagnetic copper(scpii/scp)-ion by the ring-contracted corrin ligand of vitamin Bsub12/sub 0.18
Electrochemical C–H functionalization reaction of N-heterocycles with alkyl iodides 0.75
Electrochemical reaction of indole-tethered alkynes enabling stereoselective synthesis of iodovinyl spiroindolenine-cyclopentanes 0.14
Photocatalytic reductive incorporation of carbon dioxide into double bonds 1.00
65 37.49
Non-covalent assembly-enabled selectivity in aqueous microdroplets 0.11
Al(ii) transfer harnessing a well-defined cadmium precursor 1.00
Lipid-donor-anchored genome mining uncovers dioxanopeptins, antibacterial lipopeptides with a 1,3-dioxane functionalized polyunsaturated lipid tail 0.10
Peptide–based artificial cytoskeleton enhances colocalized cascade reactions in cell-like microreactors 0.70
Stepwise B≡N bond cleavage by isocyanides: access to the 3-azaborole structural motif 0.38
Wavelength-resolved heterodimer [2 + 2] photocycloadditions for reversible surface grafting 0.08
Undirected ruthenium-catalyzed C–H activation using arylsulfonium salts: direct arylation without ruthenacycle intermediates revealed by computation and data science 0.90
Making room for reactivity in topochemical transformations under pressure 0.22
Alumanyl silanides as multifunctional reagents for olefin cycloaddition, CO hydrosilylation, and reductive CO coupling 0.80
Abiotic formation of nitrile precursors to amino acids and nucleobases in interstellar ice analogues 0.11
Controllable copper-catalysed photo-induced carbonylative cyclization to access dihydroquinolinones and oxindoles 0.67
Isolation of arylhalodiphosphenes: periodic trends in R–P[double bond, length as m-dash]P–X bonding (X = Cl, Br, I) 0.17
Why is a dicationic digallene so reactive towards activation of strong covalent bonds? Scope and mechanistic investigations 1.00
Visible light-induced 1,2-alkoxy shift of α-diazoacetates for Wolff rearrangements – access to oxyketenes 0.20
Reductive rearrangement of substituted quinolines to 2,3-disubstituted indoles enabled by water activation 1.00
HCl-mediated silylation of C–H bonds in (hetero)arenes with trialkylsilanes 0.29
A donor–acceptor photosensitizer-catalyst dyad for light-driven nicotinamide hydrogenation 1.00
Boraindenes as versatile precursors to benzannulated boron heterocycles 1.00
Unveiling the molecular dynamics of a nitrile-containing 5-lipoxygenase-activating protein antagonist in primary macrophages through Raman spectroscopy 0.78
Metal-free visible-light carbonylation of alkyl iodides to amides via consecutive photoinduced electron transfer 0.04
Biomimetic sulfur-catalyzed carbonyl transfer enables the carbonylative difunctionalization of unactivated alkenes 0.17
Chemoselectivity in the cationic Phospha-Wittig reaction: accessing phosphorus heterocycles, phosphaalkenes, and their annulated [4 + 2] dimers 0.60
Unusual nitrene reactivity: imine formation in the photochemical reaction of a borylnitrene with ethene 1.00
Heteroaryl iminothioindoxyl (HA-ITI) photoswitches via regioselective aza-Wittig synthesis: unifying red-shifted absorption, large E/Z band separation, and tunable thermal recovery 0.04
Palladium-catalyzed amidocarbonylation of thioethers: access to α-amide-substituted thioether derivatives 0.50
Photocatalyzed hydrogen atom transfer enables multicomponent olefin oxo-amidomethylation under aerobic conditions 0.25
Palladium-catalyzed carbonylative synthesis of acrylamides from alkenyl thianthrenium salts 0.50
A photochemical strategy for aromatic nitrogen ortho-isomerization 0.92
Visible-light induced click reactions of acylsilanes with pyruvate electrophiles 0.40
A printable, unimolecular, core–shell polymer bottlebrush-based signal transducer using solvatochromatic reporting 0.25
Interstellar formation of 1,2-propanediol (CH3CH(OH)CH2OH) and 1,2-ethenediol (HOCHCHOH)—key precursors to sugars and sugar derivatives 0.25
An Intelligence Programmable Intrathecal Injection System Based on Tween 80-Confined Halide Perovskite Optoelectronic Memristor 0.06
Synthesis of chiral lactams by asymmetric nitrogen insertion 1.00
A facile route to ‘naked’ Ag+ ions enabling the coordination of the weak Lewis base Ni(CO)4 0.94
Nickel-catalyzed aminocarbonylation of aryl chlorides enabled by a newly designed CO source 0.38
Fused 3D boron heterocycles via EnT catalysis: synthesis, modification and validation as beta-lactamase inhibitors 1.00
Gas-phase synthesis of naphthalene through an unconventional thermal alkyne–alkene [2 + 2] cycloaddition mechanism 0.30
Aggregation of DNA oligomers with a neutral polymer facilitates DNA solubilization in organic solvents for DNA-encoded chemistry 1.00
Elucidating the reaction kernel and probing the effect of anharmonicity in the ring-closing reaction of fulgide single crystals 0.13
Iron photocatalysis towards site-selective C(sp3)–H alkylation of glycines and peptides 0.20
Cobalt-catalyzed direct carbonylative 3-acylation of (N–H)Indoles with alkyl halides 0.33
Lewis-acid induced mechanochemical degradation of polyvinylidene fluoride: transformation into valuable products 1.00
eCarbonyls: an electrochemical thioether mediated oxidation of alcohols to aldehydes and ketones 0.20
Photomediated C–H trifluoromethoxylations enabled by bis(trifluoromethyl)peroxide 1.00
Asymmetric ring contraction of 2-hydroxypyranones by borrowing hydrogen biocatalysis 0.13
A titanium redox-switch enables reversible C–C bond forming and splitting reactions 0.25
A new generation of N-heterocyclic carbene (NHC) gold–selenolato complexes as potent anticancer agents: distinct synthetic routes and evaluation in 2D and 3D cancer models 0.18
Enantioselective synthesis and racemization dynamics of trithia[5]helicenes derived from the dithieno[2,3-b:3′,2′-d]-thiophene unit 1.00
Depolymerization of PLA catalyzed by guanidine-modified microgels 0.94
Photochemical deracemization of 2,3-allenoic acids mediated by a sensitizing chiral phosphoric acid catalyst 1.00
Synthesis of perhalogenated silylboranes (X = Cl, I) and their application in regiodivergent alkene silaboration 0.86
Force-induced transition state rupture enables mechanistic control in aziridine mechanochemistry 1.00
Photostable triphenylmethyl-based diradicals with a degenerate singlet-triplet ground state and strong photoluminescence 1.00
Lateral π-extended helical nanographenes with large spin polarization 0.83
Diastereoselective arylation of bis-lactim ethers catalyzed by N-coordinating ylide-functionalized phosphine (NYPhos) 0.81
Photocatalytic regioselective four-component radical relay carbonylation for α-aminoketones synthesis 0.75
On the synthesis and structure of reactive halonium ions 1.00
Structural control of dynamic covalent cages: kinetic vs. thermodynamic assembly and PFAS removal from water 0.60
Activation of perfluoro(methyl vinyl ether) at Rh(scpi/scp) complexes: metal-centered iversus/i phosphine-mediated decarbonylation 1.00
Synthesis of gem-di(boryl)cyclopropanes from non-activated olefins via Mn-photocatalyzed atom transfer radical addition 0.29
The genesis of OH-stretching vibrational circular dichroism in chiral molecular crystals 0.33
Alkali metal salts of 1,2,3-benzodiazaborines: platforms for late-stage iN/i-functionalization and metal complexation 1.00
A unified approach to meta-selective methylation, mono-, di- and trifluoromethylation of arenes 0.50
Boradigermaallyl: inhibition of CH bond activation by borane CO adduct formation followed by CO insertion 1.00
Diazomethyl-λ3-iodane meets aryne: dipolar cycloaddition and C-to-N iodane shift leading to indazolyl-λ3-iodanes 0.08
1 0.10
Continuous-flow organic electrosynthesis of a conjugated bipolar polymer cathode for high-performance low-temperature aqueous aluminum-ion batteries 0.10
1 0.67
Kinetic study of the effect of Mg2+ and Ca2+ on the hydrolysis of ATP up to 120 °C 0.67
22 13.44
Revealing Low-Barrier Conformational Flexibility in Perfluoropropanoyl Halides: A Structural Gas Phase Study of CF3CF2C(O)X (X = Cl, Br, I) 0.25
Tuning the Lewis Basicity of Pyridine: Structural and Theoretical Characterization of the SO3 Adducts of Pyridine Derivatives 0.50
Guest Exchange among Distinct Water-Soluble Supramolecular Nanocages 0.40
A Substrate-Dependent Redox Catalysis of Tellurenyl Species Involving Oxidation States +I, +II, and +IV 0.33
Structural, Thermodynamic, and Spectroscopic Characterization of Diphosgene and Triphosgene 0.67
Isoselenocyanates with Sterically Encumbered Substituents─Synthesis, Structures, and Spectroscopic Properties 0.50
Bis(pentafluoroethyl)arsinous Acid and the Bis(pentafluoroethyl)arsinite─Synthesis, Structural Characterization and Transition-Metal Complexes 0.83
4-Fold Protonation of Tetracyanometalates in Superacids: Hydrogen and π-Hole Bonding in the Solid State 0.50
Martin’s Spirophosphorane: A Platform for the Design of [OPO] Pincer Ligands and Their Group 4 Complexes 1.00
Laterally Distorted 1,2-Dibora-4-gallatacyclopentane Anion 0.40
N-Indolylsilylene Cobalt(I) Chloride: A Base Metal Catalyst for Alkene Hydrosilylation 0.20
Bimetallic Activation of SF6 by a Bis(Gallylene) 1.00
Syntheses and Solid-State Structure Analyses of Pentafluoroethylated Arsanes 1.00
A Series of Trigonal Arylimido Iron Complexes and the Influence of Oxidation State and Steric Demand on Reactivity 1.00
Electronic Structure and Hypercorrole Features of Deprotonated Free-Base and Reduced Copper Corroles 0.29
Activation of Sulfur Dioxide by a Phosphazene Base: Synthesis and Solid-State Structure of a Phosphazenium SO2 Adduct 1.00
A General Approach for the Synthesis of Arylxenonium(II) Tetrafluoroborates 1.00
Chemical Bonding Trends in Y2M3Si5 (M = Mn–Cu, Tc–Pd, Re–Pt): A Study within the Broad R2M3X5 Intermetallic Family 0.40
Magnetospectroscopic Studies of a Series of Fe(II) Scorpionate Complexes: Assessing the Relationship between Halide Identity and Zero-Field Splitting 0.13
Antimony and Bismuth Complexes as Visible Light Photosensitizers in Catalytic Oxidation Reactions 0.88
Preparation and Characterization of Phosphazenium Trifluoromethylselanide and Trifluoromethyltellanide Salts Starting from HCF3 1.00
Hydrogen-Bond-Assisted Chalcogen Transfer between Phosphine Selenides and Arsine Oxides 0.17
1 0.13
Construction of general N-body lattice operators with arbitrary momenta 0.13
84 63.87
Distorted Nanographenes by Embedding a Cyclopenta[a]heptalene Core and Multiple Additional Heptagons: Chiral Supramolecular π-Dodecamer and Co-crystal with Fullerenes 0.29
The Pyridylketenyl Anion: Entry to Diverse N-Heterocycles 1.00
Pyridine to Pyridazine Skeletal Editing via CN-to-NN Atom-Pair Swap 1.00
A Magnetically Bistable Rigid Carbene─2,3-Benzofluorenylidene 0.50
Chemical Proteomics Reveal the Inventory of Pyrroloquinoline Quinone Binding Proteins in Bacteria 1.00
Photocatalytic, Regioselective Enone Deconjugation: An Enabling Platform for Terpene Modification 1.00
Navigating the Landscape of Cycloartanyl Cations: Synthesis of Fortunefuroic Acid I, Parkeol, 25,26,27-Trinor-3α-hydroxy-17,13-friedolanosta-8,12-dien-23-one, and Spirochensilide A 1.00
Synthesis of 1,3-Dienes from Alkenes via Alkenyl Thianthrenium Salts 1.00
Conformational Switching Controls Biradical Spin Dynamics in Flavin–Tryptophan Dyads 0.67
Synthesis of an o-Benzoquinone Arsenic Mononitride (As≡N) Complex and Its Reaction to Singlet Arsinonitrene 0.60
Flexibility Induced by Four Heptagons: A Negatively Curved Polycyclic Aromatic Hydrocarbon Cut-Out of Schwarzite P216 1.00
The Catalytic Asymmetric Mukaiyama–Michael Reaction of Silyl Ketene Acetals with Cyclic Enones: Short Routes to Jasmonates 0.44
Myxarylin: Total In Vitro Biosynthesis, Expansion of Substrate Scope, and Bioengineered Thioamidated Biarylitides 0.72
Switching Shapes: Reversible Three Species Photoisomerization of Substituted 1,2-Dihydro-1,2-azaborinines 1.00
Inverse Molecular Design for the Discovery of Organic Energy Transfer Photocatalysts: Bridging Global and Local Chemical Space Exploration 0.70
A C1-Homologative Trifluoromethylation: Light-Driven Decarboxylative Trifluoroethylation of Carboxylic Acids 0.05
Shifting Merocyanine-Imine Exchange with Visible Light 1.00
Oxidation of a Dihydrophenazine Molecular Wire Attenuates Molecular Conductance 0.40
A Hooker Oxygenase Archetype in Polyketide Biosynthesis Challenging the Baeyer–Villiger Monooxygenase Paradigm 0.50
Controlling Reductive Elimination Pathways in Ti(IV) Pincer Complexes: Concerted versus Radical Mechanisms via Ligand Design 1.00
Tailored Phosphate Leaving Groups Direct Pathway-Dependent Self-Assembly 1.00
A Diazo-free Equivalent of the Unsubstituted Carbyne Cation: Straightforward Synthesis of Naphthalenes and Pyridines via [12/13CH]+ Insertion 1.00
Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand 0.95
Asymmetric Carbonium Ion Catalysis: The Intramolecular Hydroalkoxylation of Cyclopropanes 0.79
An Aluminum-Stabilized Aminonitrene 1.00
Electrochemical Hydrogenation of Aza-Arenes Using H2O as H Source 1.00
Catalytic Asymmetric Carbosilylation of Methyl Propiolate with Bis-silyl Ketene Acetals 1.00
Dual Cation/Anion Binding in Crown Ether-Based Coordination Cages 0.92
Enantioselective Intramolecular C–H Alkylation Catalyzed by a Nonsymmetric Chiral Cobalt Porphyrin 1.00
Dispersive Fluorine/Bromine Interactions as Key Selectivity Determinant: Asymmetric Cyclopropanations with 3,3,3-Trifluoro-2-diazopropionate Catalyzed by a Heterochiral-at-The-Metal Centers Dirhodium Paddlewheel Complex 0.60
Valorization of CO2 and N2O Gas Enabled by a Single Multi-Photoinduced Electron Transfer Catalyst 0.38
Unified Total Synthesis of Phrymarolin and Haedoxan Natural Products 0.40
CO2 Unlocks Reactivity: Boryl Silyl Ketene Acetals Enable Mild and Direct C═C Bond Cleavage 1.00
Boron-Enabled Stereoselective Synthesis of Polysubstituted Housanes 0.63
Catalytic Enantioselective [6π] Photocyclization Reactions by Chromophore Activation with a Chiral Lewis Acid 1.00
Thianthrenium Chemistry for Identification of Protein–Protein Interactions in Cells 1.00
On-Surface Synthesis of Nonbenzenoid PAHs Using Intermolecular π-Radical C–C Coupling 0.38
Direct Interconversion between Bis(borylenes) and Diborenes 1.00
Selective Chiral Diamine-bisoxazoline Iron(II) Catalysts for Pyrrolidine Formation via Intramolecular C(sp3)–H Amination of Aliphatic Azides 0.05
On-Surface Synthesis of a Nitrogen-Doped Curved Cycloarene: π-Extended Pentaazaquintulene and Its Gold Complex 1.00
Ligand-Controlled Chemodivergent Bismuth Catalysis 0.67
Visualizing the Invisible: Dual Click Imaging of Ruthenium-Based Photoactivated Chemotherapy Agents and Their DNA Synthesis Inhibition in Fixed Cancer Cells 0.27
A Heterogenized Molecular Catalyst for the Gas-Phase Cyclotrimerization of Acetylene to Benzene 1.00
Catalytic Enantioselective Diels–Alder Reaction of Dienes with Acyclic and α,β- and β,β-Disubstituted Enones 0.81
Visible-Light-Induced Bond Homolysis in Titanacyclopentadienes for the Catalytic Cyclodimerization of Internal Alkynes 1.00
A Highly Selective Cobalt Catalyst for Primary Amine Synthesis from Carboxylic Acids, Esters, and Vegetable Oils 0.88
Ultradurable Regenerative Propane Dehydrogenation Catalyst by Fluorination-Induced Confining and Positioning 0.07
Ir(III) Pincer Complex with Solo Coordinatively Active Site as a Surrogate for Half-Sandwich Catalysts: Enabling Asymmetric Acylnitrenoid Transfer and Structure–Activity Relationship Studies 0.17
Photochemical Generation and Characterization of Alanine Imine: A Key Intermediate in Prebiotic Amino Acid Formation 0.67
Synthesis of Metallostannylenes from Transition Metal Polyhydride Complexes 0.20
Bio-inspired Deconjugative Isomerization of Borylated Dienoates 1.00
Palladium-Catalyzed Asymmetric Carbonylation of Alkynes to Axially Chiral Carbothioate Esters 0.10
In Cellulo Cysteine Umpolung for Protein Structure Probing 1.00
Photochemical Metallonitrene Formation for N Atom Transfers. Metal- versus Azide-Centered Excited States and the Role of Their Energetic Order 1.00
Ruthenium-Mediated N-Arylation for DNA-Encoded Libraries 1.00
Catalytic Asymmetric (ene–endo)-Carbonyl–Ene Type Cyclizations 0.67
Highly Selective Carbonylation of Olefins Using CO2 and H2 0.93
Photochemical Insights on Acyl Azolium Salts Enable the Design of a Tandem Hydrogen Atom Transfer/Halogen Atom Transfer Acylation of Alkyl Bromides and Chlorides 0.50
Functional Al/Cd Heterometallics─From Controlled Al(I) Transfer to Nucleophilic Transfer of Cadmium Ions 1.00
Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles 1.00
Application of Solid Higher-Order Zincates Enables a Ni/Lassaletta-Ligand-Catalyzed, Atroposelective Negishi Cross-Coupling Reaction 1.00
Diblock Copolypeptoid Micelles as Platform for Aqueous Photoredox Cyanation of Arenes 1.00
Supramolecular Complexation of Quenched Rosamines with Cucurbit[7]Uril: Fluorescence Turn-ON Effect for Super-Resolution Imaging 1.00
Reversible C–H Bond Activation of Unactivated Arenes by a Nickel-Silylene Complex 1.00
Leveraging Data Science to Elucidate Ligand Features for Pd-Catalyzed Enantioretentive iN/i-Arylations of Cyclic α-Substituted Amines in Aqueous Media 0.20
Breaking Bonds with Short-Wave Infrared Light: BODIPY Photocages for Two-Photon Activation in the 900–1500 nm NIR-II Window 0.50
BNB-Modified Perylene, Terrylene, and Quaterrylene Diimides: Introduction of the π-Accepting and Aggregation-Suppressing Diborinic Imide Group in Rylene Dyes 1.00
Accelerated Discovery of Energy Transfer-Catalyzed Dearomative Cycloadditions through a Data-Driven Three-Layer Screening Strategy 1.00
Iridium-Catalyzed Regio- and Enantioselective Reverse Prenylation of Tryptamines and Other 3-Substituted Indoles 1.00
Reversible CO Insertion into the Si = Si Double Bond Enables a Disila-Bislactone Formation via Subsequent CO2 Addition 1.00
Pericyclic Umpolung in a Catalytic Asymmetric Diels–Alder Reaction of Tropone with Enol Ethers 1.00
Kinetic Resolution of Heterocyclic Lactams by a Photocatalytic Cobalt-Catalyzed Dehydrogenation 1.00
Hydrogen Activation by a σσ*-Carbene Through Quantum Tunneling 1.00
Impact of Induced Fitting and Secondary Noncovalent Interactions on Site-Selective and Enantioselective C–H Functionalization of Arylcyclohexanes 0.29
Highly Antiaromatic Naphtho-1,2-Diboretes as Precursors for Tunable, Unsymmetrical 1,4-Diboraanthracenes 1.00
Sulfur Vacancy Boosts Light-Driven C–N Coupling in Upcycling of Polylactic Acid to Alanine 0.13
Orthogonal Thiol Addition Chemistry Based on Ether Acrylates 0.83
All-Heteroatom-Substituted Carbon Spiro Stereocenters: Synthesis, Resolution, Enantiomeric Stability, and Absolute Configuration 0.29
A Nitrilium-Type N-Heterocyclic Aryne 0.22
Sterically Induced Acceleration of Aryl Halide Activation by Pd(0): A Radical Alternative to 2-Electron Oxidative Addition 1.00
Planarity Is Not Plain: Closed- vs Open-Shell Reactivity of a Structurally Constrained, Doubly Reduced Arylborane toward Fluorobenzenes 0.75
Orthogonal Site-Specific Dual Bioconjugation of Aryl and Alkyl Thiols 1.00
Cage Alkyl Carbenes Provide Experimental Evidence for Isotope-Controlled Selectivity in Competing Tunneling Reactions 0.80
Iron-Mediated Nitrate Reduction at Ambient Temperature for Deaminative Sulfonylation and Fluorination of Anilines 1.00
14 8.81
Hydration Dynamics of Perdeuterated PNIPAM in Aqueous Solution 0.69
Poly(pentafluorophenyl acrylamide): Novel Platform for Selective Post-Polymerization Modification via para-Fluoro-Thiol Reaction 1.00
Are Electron-Withdrawing Groups Affecting Polyester Hydrolysis? A Comprehensive Study on Poly(thioether-ester)s and Poly(sulfone-ester)s 1.00
Determinants of π-π Stacking Motifs in Polymers with Different Aromatic Side Groups 0.08
Selective Upcycling of Mixed Polyesters into Valuable Polysulfone 0.14
Varying Monomer Charge in SI-bioATRP Polymer Grafting from Mesoporous Silica 0.83
Tracer Diffusivity in Amphiphilic Polymer Model Co-Networks 0.79
Synthesis of Cleavable Polyolefins via Ring-Opening Insertion Metathesis Polymerization (ROIMP) of Cyclopentene with Unsaturated Polyester Oligomers 0.18
Reaction Temperature and Solvent Influence Reactivity Ratios in the Copolymerization of Ethylene Oxide and Propylene Oxide 1.00
Thermogels Based on Block versus Gradient Terpolymers: Differences in the Nano- and Macro-Scale 0.36
Tethered Cation Size Affects the Imbibition of Polymerized Ionic Liquids and the Ionic Conductivity in Nanopores 0.48
Free-Radical (Co)polymerization of Tulipalin A─Analyzing Copolymerization Behavior 1.00
Dramatic Effect of Alkali Metal Alkoxides on the Anionic Copolymerization of Styrene and Isoprene 1.00
Microfluidic Reactor for Studying Aqueous Phase Polymerization Events of Relevance to Emulsion Polymerization: Methyl Methacrylate 0.25
4 3.75
Decarboxylative alkylation of alkenes 1.00
The asymmetric synthesis of an acyclic N-stereogenic amine 0.88
Deaminative cross-coupling of amines by boryl radical β-scission 0.88
C-to-N atom swapping and skeletal editing in indoles and benzofurans 1.00
2 1.02
Biomolecular condensates mediate C–N bond formation 0.20
SNAP-tag2 for faster and brighter protein labeling 0.82
5 2.66
Mineral-to-molecule arsenic transfer via photoredox catalysis 0.25
Biomolecular condensates sustain pH gradients at equilibrium through charge neutralization 0.32
Bright triplet and bright charge-separated singlet excitons in organic diradicals enable optical read-out and writing of spin states 0.09
Energy transfer-enabled enantioselective photocyclization using a privileged Al–salen catalyst 1.00
A selenoxide for single-atom protein modification of tyrosine residues enabled by water-resistant chalcogen and hydrogen bonding 1.00
37 22.05
Sn catalyst reconstruction and microenvironment modulation for efficient amino acid electrosynthesis via C–N coupling 0.32
Sustainable recycling of polyester wastes using a coordinatively unsaturated Zn catalyst 0.10
Metal-dependent and metal-free mechanisms of peptide condensate catalysts 0.04
DNA affects the phenotype of fuel-dependent coacervate droplets 1.00
A high-affinity split-HaloTag for live-cell protein labeling 0.93
Large-scale multi-omics profiling reveals environmental and evolutionary drivers of fungal phylogeographic and metabolic diversity 0.05
Pathway selection between click and acyl transfer reactions driven by aminoacyl phosphates 1.00
Covalent warhead assembly in fostriecin biosynthesis involves malonylation-lactonisation by a bifunctional thioesterase and enzymatic demalonylation 1.00
Radiolabeling of oligopeptides by selective hydrogen isotope exchange with deuterium and tritium in aqueous buffers 1.00
Organocatalyzed bottom-up formation of protocells 1.00
“” photosensitization enables redox neutral acylation and alkylation of quinones 1.00
Ultrafast solvent-modulated roaming mechanism in bromoform revealed by femtosecond X-ray solution scattering 0.39
Divergent photochemical ring-replacement of isoxazoles 0.75
Expanding the payload scope in antibody-drug conjugates by delivery of hydroxy-containing drugs through self-immolative phosphoramidates 1.00
Construction of remote dual stereocenters by electrochemical cobalt-catalyzed enantioselective desymmetrization 1.00
Mechanochemical ligand-controlled regiodivergent hydroarylation of alkenes via iron-catalyzed C−H activation 1.00
Scalable reductive deuteration of (Hetero)Aryl chlorides with D2O 0.17
Diaryl Bismuthides and Acyl Bismuthanes Enable Visible-Light-Induced Reversible Carbon Monoxide Insertion and Extrusion 0.86
Direct detection of an NH-π hydrogen bond in an intrinsically disordered peptide 0.67
Formal pyridine meta-azidation and its application for the synthesis of diazepines, ring-fused δ-carbolines and 1,2,3-triazolylpyridines 1.00
RNA-peptide interactions tune the ribozyme activity within coacervate microdroplet dispersions 1.00
Regulation of lattice oxygen reactivity of ZrO2 to promote efficient chemical looping oxidative dehydrogenation of ethane 0.90
Oxy-reductive C-N bond formation via pulsed electrolysis 0.13
Modular multi-enzyme cascades enable green and sustainable synthesis of non-canonical amino acids from glycerol 0.13
Exploring the space of self-reproducing ribozymes using generative models 0.09
Near-infrared photon-triggered CH-to-CHOH conversion over plasmonic oxyselenides 0.03
Photochemical permutation of -substituted phenols 0.92
Mechanistic analysis and kinetic profiling of Soai’s asymmetric autocatalysis for pyridyl and pyrimidyl substrates 1.00
Cobalt catalyst with exclusive metal-centered chirality for asymmetric photocatalysis 0.44
Highly parallel optimisation of chemical reactions through automation and machine intelligence 0.17
Phylogenomics and metabolic engineering reveal a conserved gene cluster in Solanaceae plants for withanolide biosynthesis 0.98
Amines tuned controllable carbonylation for the synthesis of -lactones and 1,4-diones 0.12
Enzymatic twists evolved stereo-divergent alkaloids in the Solanaceae family 0.05
Chemoselective dual functionalization of proteins via 1,6-addition of thiols to trifunctional -alkylpyridinium 0.81
Amino acids catalyse RNA formation under ambient alkaline conditions 0.50
Expedient access to bora-butenolide bioisosteres by counteranion-mediated trans-hydroboration of alkynes 0.11
Copper-catalyzed photoinduced carbonylation of C1-C3 gaseous alkanes 0.42
1 0.75
Membraneless protocell confined by a heat flow 0.75
69 51.54
Progressive Chemoselective Reductive Deuteration and Deuterodefluorination of Fluoroalkyl Ketones Using D2O 0.25
Red-Light Photoredox C–H Alkylation of Acceptor Heterocycles Enabled by Substoichiometric NADH 0.25
Nickel-Photocatalytic Deoxygenative Arylation toward β-Methyl-Branched α-Amino Acids 1.00
Enantioselective Rh/Cu-Catalyzed Addition of Terminal Alkynes to Allenes for the Synthesis of Chiral 1,4-Enynes 1.00
Ring-Enlargement of in Situ Generated Cyclopropanones with Carbonyls and Imines: Synthesis of γ-Butyrolactones and -lactams 1.00
Gold-Catalyzed Regioselective Remote B(9)–H Activation of o-Carboranes with Silylenynones: Access to B(9)-α-Furylsilyl-o-carboranes 0.14
Nickel-Catalyzed Aminocarbonylation of Aryl Trifluoromethoxides 0.33
Visible-Light-Induced Carbonylative Synthesis of Aliphatic Thioesters 0.50
Improved Total Synthesis of Cannabioxepane, a Minor Phytocannabinoid from Cannabis sativa L 1.00
Photocatalytic Perfluoroalkenylation of Ketones and Its Application in the Synthesis of Fluorinated Heterocycles 1.00
Copper-Catalyzed Amino-alkoxycarbonylation of Unactivated Alkenes: Synthesis of β-Amino Esters via Primary Tosyl Amidyl Radical 0.40
CuCl-Promoted β-Acylation of Cyclopropanols with Thioesters 1.00
Zinc-Mediated Four-Component Carbonylation toward Direct Synthesis of α-Amino Ketones 0.50
Dearomatization of Aromatic Carbonyl Compounds by Photocycloaddition Reactions to 1,1-Dimethylallene 1.00
An Unexpected Isomerization for the Total Synthesis of Daphnepapytone A 1.00
Cyclover-Assisted Liquid-Phase Peptide Synthesis Using T3P® as a Green Coupling Reagent 0.29
Electrochemical Synthesis of 1,2-Substituted N-Amido Benzimidazoles by Reduction of Nitroarenes 0.90
Electrochemical Activation of Bicyclo[1.1.0]butanes 1.00
Stereoselective Synthesis of the Western Fragment of Vancoresmycin 1.00
Bromination Functionalization of Diazo Compounds with CBr4 via Convergent Paired Electrolysis 0.29
Iron-Catalyzed C–H Alkylative Ring Openings of Oxabicyclic Alkenes 0.14
Oxidative Cleavage of β-Substituted Primary Alcohols in Flow 1.00
Mallory-Type Reactivity of 1,2-Dihydroazaborinines: 6π-Electrocyclization-[1,5]-H Shift Cascade toward BN-Doped Polycyclic Frameworks 1.00
Iron-Catalyzed Synthesis of Primary Sulfinamidines from Sulfenamides 1.00
Rhodium-Catalyzed O–H Insertion Reactions to (2-Diazo-1,1,3,3,3-pentafluoropropyl)phosphonate: A Convenient Route to Fluorinated β-Alkoxy Vinylphosphonates 0.56
The epi-Matteson Reaction: Addition of Sodium Iodide in the Substitution Step Allows for a Stereodivergent Outcome 1.00
Photoinduced Deoxygenative Boration of Unactivated Alcohols Involving In-Situ-Formed Alkyl Iodides 1.00
Nitrene Transfer Radical Relay: A Light-Enabled Strategy for Accessing Tetrahydropyridine 0.75
Bidirectional Synthesis of C2-Symmetric Unilateral Substituted Acenes: 1,10,11,12-Tetrafluorotetracene 1.00
Nickelaelectro-Catalyzed Glycosyl-Donor Activation Enabling α-C-Alkenyl Glycoside Assembly 1.00
N-Selective Difluoromethylation of 4-Hydroxyquinolines 0.38
Synthesis of α-Substituted β,γ-Unsaturated Cyclobutanecarboxamides via Palladium-Catalyzed Aminocarbonylation of Vinylcyclobutanols 0.75
Synthesis of Sulfondiimidoates by Desoxychlorination of Sulfonimidamides 1.00
Sterically Controlled C(sp2)–H Carboxylation and Formylation: A Complementary Strategy to SEAr Approaches 1.00
Fluoranthene-Containing Distorted Nanographenes Exhibiting Two-Photon Absorption Response 0.50
Gold-Catalyzed Highly Regioselective Cage B(9)-H Alkylation of io/i-Carboranes with 1,6-Enynes 0.13
Copper-Catalyzed Electrophilic Amination of Aryl and Pyridylzinc Pivalates Mediated by N-Based Hypervalent Iodine(III) Reagents 0.10
Nickel-Catalyzed Carbonylative Cyclization of Bromodifluoroacetamides with Arylboronic Acids toward δ-Lactams 0.10
Site-Selective C–H Mono- and Bis-Thianthrenation of Polycyclic Aromatic Hydrocarbons 1.00
Palladium-Catalyzed Carbonylative Fluoroalkylation of 1,3-Enynes to Access Allenyl Primary Amides 0.33
Naphthyl-Separated Stone–Wales Defect-Type Nanographene via Scholl Cyclization of Tetra(1-naphthyl)naphthalene 1.00
Deaminative Cyanation of Anilines by Oxylanion Radical Transfer 1.00
DAST Enabled Synthesis of Fluorinated Amides and Fatty Acid Amides Including Drugs under Ambient Conditions 0.50
Addition of Organometallic Reagents to an Episulfoxide Delivers Sulfenate Anions: Modular Synthesis of Sulfoxides and Sulfinamides 1.00
Fluoride-Effect-Directed Catalyst-Controlled Regioselective Acylation of Carbohydrate Diols and Triols 0.14
Camphor-Based NHC Ligands with a Sulfur Ligator Atom in Rhodium Catalysis: Catalytic Advances in the Asymmetric Ring Opening of N-Protected Azabenzonorbornenes 1.00
Palladium-Catalyzed Intermolecular Tandem Difunctional Carbonylation of 1,3-Enynes: Synthesis of Fluoroalkylated Butenolides 0.33
Access to SCF3-Substituted Indolizines via a Photocatalytic Late-Stage Functionalization Protocol 1.00
Stereospecific Insertion of Cyclic Amidines into Aryl-Substituted Cyclopropanones: Access to Complex Spirocyclic Aminals 1.00
α-Ketol Rearrangement for Accessing Tetracyclic Natural Products 1.00
HFIP-Mediated Spiro-annulation of Bicyclo[1.1.0]butanes with α-Halo Hydroxamates: Access to Functionalized Spirocyclobutenes 0.29
Z-Selective Iron-Catalyzed C–H Alkylations with Allenes: Access to Stereodefined Olefins 0.43
Embedding a Planar Antiaromatic Cyclooctatetraene into a Truxene-Derived Polycyclic Aromatic Hydrocarbon 1.00
Palladium-Catalyzed Selenylative Alkoxycarbonylation of Alkynes toward β-Selenated Cinnamic Acid Esters 0.17
Total Synthesis of Jerangolid B via spsup3/sup–spsup2/sup Stille Coupling 1.00
Synthesis of Okaramine M, Its Conversion to Amauromines, and Concise Bidirectional and Biomimetic Total Synthesis of Amauromines 1.00
Kinetic Resolution of BINAMs by Stereoselective Copper-Catalyzed Dehydrogenative Si–N Coupling with Prochiral Dihydrosilanes 1.00
Photochemical Dearomative Vicinal Aminooximation of Heteroarenes with N-Nitrosamines 1.00
Electrochemical Synthesis of Disubstituted Alkynes from Dihydrazones 1.00
Diethylzinc Amylates: Selective Iodine–Zinc Exchange Reagents at Room Temperature 1.00
Direct Pd-Catalyzed β-C(spsup3/sup)–H Hydroxylation of Aliphatic Carboxylic Acids 1.00
Total Synthesis of Epicoccolides A and B by Oxidative Skeleton Rearrangement Leads to a Structural Revision and Questions the Proposed Biosynthesis 1.00
Stable Tribrominated Phenalenyl Radical Exhibiting Long-Lived Luminescence from a Monomer−π-Dimer Equilibrium 0.10
Nine-Membered Ketolactams by Oxidative Cyclization Expansion 1.00
Synthesis and Nucleophilic Ring-Opening of 1,1-Dicyanocyclopropanes: Accessing β-Aminocarbonyl Derivatives from Olefins 1.00
Radical Addition to 2-Allenylaryl Isocyanides for the Preparation of 2,3-Difunctionalized Quinolines 1.00
Room-Temperature Copper Cross-Coupling Reactions of Anilines with Aryl Bromides 1.00
Stereoselective [2 + 2 + 2] Cycloaddition of Benzocyclobutanones and Norbornadienes through Nickel-Catalyzed C–C Bond Activation 1.00
Lewis Acid-Catalyzed Domino Inverse Electron-Demand Diels–Alder/Thermal Ring Expansion Reaction for the Synthesis of Arene-Annulated Eight-Membered Nitrogen Heterocycles 1.00
2 2.00
The adapt-to-nutrient NRPS-like secondary metabolite gene cluster facilitates Verticillium dahliae adaptation to different nutrient environments 1.00
Genome-wide identification of genes involved in beetle odoriferous defensive stink gland function recognizes Laccase2 as the phenoloxidase responsible for toxic para-benzoquinone synthesis 1.00
1 1.00
Investigating anharmonicities in polarization-orientation Raman spectra of acene crystals with machine learning 1.00
5 2.51
Violation of Local Reciprocity in Charge-Orbital Interconversion 0.33
Self-Propulsion via Nontransitive Phase Coexistence in Chemically Active Mixtures 1.00
Non-Markovian Linear Vibrational Absorption Spectroscopy for Nonharmonic Bond Potentials: A Perturbative Approach 1.00
Attosecond Optical Orientation 0.17
Universal Effective Charges in the 𝑠⁢𝑑 and 𝑓⁡𝑝 Shells 0.01
1 0.27
Identification of a hydroxycinnamoyl-CoA double bond reductase (HDR) affirms multiple pathways for dihydrochalcone formation in apple 0.27
5 4.04
Phase separation induced by active polymerization makes protocells robust against environmental changes 1.00
Theory for sequence selection via phase separation and oligomerization 0.88
Deciphering guanidine assimilation and riboswitch-based gene regulation in cyanobacteria for synthetic biology applications 1.00
Global profiling of polyketide synthases in facultative multicellular eukaryotes 1.00
Thioether editing generally increases the photostability of rhodamine dyes on self-labeling tags 0.17
2 0.20
A molecule with half-Möbius topology 0.08
Integrated low-temperature PVC and polyolefin upgrading 0.13
3 1.02
Dynamic breaking of mirror symmetry in spin-dependent electron transport through chiral media causes enantiomeric excesses 0.13
Magmatic immiscibility provides phosphate for prebiotic chemistry 0.75
Functional divergence of tandem duplicate SCPL acyltransferase genes reveals convergent evolution of chicoric acid biosynthesis 0.14
1 0.50
A Deep Search for Ethylene Glycol and Glycolonitrile in the V883 Ori Protoplanetary Disk 0.50
7 3.31
Excited-State Proton Transfer in Solution under Vibrational Strong Coupling 0.40
Amphidynamic Molecular Crystal with Temperature-Controlled Helical Hydrogen-Bonded Network: Proton Dynamics and Order–Disorder Phase Transition 0.43
Unconventional Formation of Cyanamide, a Key Intermediate in Prebiotic Chemical Evolution, in Interstellar Ice Analogues 0.25
Pyrrole without Life: Reaction of Aminomethylene with the Propargyl Radical 0.29
Differentiating Between Enantiomers with Nuclear Quadrupole Coupling Using Microwave Three-Wave Mixing 1.00
Accelerated Free Energy Estimation in Ab Initio Path Integral Monte Carlo Simulations 0.71
From Ground to Excited State: Revealing Bond Polarity Change via K–2V Spectroscopy and Brillouin Inverse Theorem (BIT) 0.23

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