Organic Chemistry articles for Chinese Academy of Sciences (CAS), China

Time frame: 1 June 2025 - 30 May 2026

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Count: 541

Article ‘Count’ for Organic Chemistry.

Journal Count Share
1 0.50
A Cyclic Photosensitizer Nanoplatform for Effective Pyroptosis and Enhanced Photoimmunotherapy 0.50
2 0.72
Retractable Cages with Continual Change of Cavity Size and High Iodine Capture 0.17
CuO@TiO2 Hollow Cubes Enable Highly Selective and Stable Photocatalytic Non-Oxidative Methane Coupling to Ethylene 0.56
5 2.09
A Bipolar Integrated Electro‐Chemocatalysis System for Continuous‐Flow Paired Synthesis of Cyclohexanone Oxime at Industrial‐Relevant Current Density 0.38
Pairs of Zirconium Site and Hydroxyl in MOFs Enable Generating Peroxo Species for Efficiently Tandem Oxidative Condensation of Aromatic Amines 0.55
Suppressing Hydrogen Transfer and Aromatization Reactions Enables Efficient Photothermal Recycling of Polyethylene into Platform Olefins 0.67
Dynamic Geminal-Atom Coordination for Highly Efficient Photo-Fenton Catalysis 0.29
Upgrading Natural Ores for Efficient Photothermal Polyester Recycling 0.20
2 0.36
Cucurbit[n]uril (n = 6 and 7)-Based High Affinity Enrichment of Basic Peptides Containing Multiple K/R Residues via Supramolecular Affinity Chromatography 0.17
Detection and Identification of Alkenes and Alkynes Using a 19F‑Labeled NMR Probe 0.19
113 33.71
Single-Atom Iron-Catalyzed Oxidative Esterification: From Methylarenes to the Upcycling of Polystyrene and Lignin-Derived Feedstocks 0.28
Palladium-Catalyzed Regiodivergent Telomerization of Isoprene With Oxindoles 0.57
Steric‐Engineered Thermodynamic Gating: Metastable Assemblies for Chemical‐Class Discrimination of Synthetic Cannabinoids 0.60
Nearly 100% Valorization in Seconds: Transforming PET-Metal Oxide Mixtures Into M1Ox Clusters on rGO and Premium Syngas/Aromatics Products 0.13
Intermolecular Interactions Regulating Exciton Behavior in Hydrogen‐Bonded Organic Framework for Photocatalytic Aerobic Oxidation 0.63
Ligand‐Controlled Chemoselective and Enantioselective Cyclization of Enynes With Aroyl Chlorides 0.35
Electrophotocatalysis Enables Birch‐Type Dearomative Alkylation 0.29
Polyethylene as a Hydrogen Source for C─O Bond Cleavage Via Transfer Hydrogenation 0.30
Threading an Aluminum Molecular Ring Onto a Chemically Growing Copper-Directed Polyrotaxane 0.86
Proteolysis‐Assisted Cyclization Facilitates Site‐Centric Target Deconvolution of Isothiocyanates 0.12
Cooperative Sulfate Binding Drives Hierarchical Assembly of Supramolecular Trimers 0.36
Highly Regioselective Trifluoromethylation of Unprotected Phenols and Anilines Enabled by an Engineered P450 Peroxizyme System 0.77
Enzymatic Redox Gating Directs Oxidative Divergence in Acyclic Peroxides Biosynthesis 0.65
Catalytic Asymmetric Construction of Si‐Chiral Silabicyclo[3.3.1]Nonanes Using Functionalized Prochiral Silacyclohexanones 0.27
Enantioselective Synthesis of Inherently Chiral Tetraphenylene Analogues Enabled by NHC‐Catalyzed Benzoin Condensation 0.18
Integrative, Orientational Self‐Sorting at the Four‐Crossing Level in Molecular Knots and Links 0.11
Solar-Driven Photocatalytic C─S Coupling for Organosulfur Synthesis Via Upcycling SO2 and Plastic Waste 0.36
Room-Temperature Gas-Phase CO2-to-C3 Coupling by a 4f-Aromatic Cluster 0.13
Palladium/Photoredox-Catalyzed Three-Component Coupling for Glycoconjugation 0.06
Selective π‑Metalation of Nut[6]Arene With Large and Chiral Cavity for Recognition Toward Bulky Anions in Water 0.20
Replacing Metabolically Unstable Amides With Stable α‐Trifluoromethylamines via Decarboxylative Synthesis 0.04
Enantioselective Synthesis of Polycyclic Spiroheterocycles by Chiral Phosphoric Acid Catalyzed Dearomative Cyclization of γ-Hydroxy Ynamides 0.05
Ligand-Intercalated MOFs Enable Reaction-Pathway Engineering in Biomass Electrooxidation via Steric and π-Electronic Microenvironment Control 0.38
Enantioselective Intermolecular Photocycloaddition of Indoles 0.11
Captodative Radicals Coupling Into Homochiral Molecular Nanotubes With Conglomerate Crystallization 0.55
Ambient One-Pot Electrocatalytic Synthesis of Caprolactam From Cyclohexanone and Nitrate Over Ag-Ag4Sn-SnO2 Nanoparticles 0.01
Enantioselective Synthesis of Axially Chiral Anthracenes via [4+2] Cycloaddition and Cycloreversion of Cyclopentadienones 0.07
α-Trifluoromethyl Substituted α-Hydroxyhydrazides as Dianionic Ligands Enable Cu-Catalyzed Aryl Amination With Higher Turnovers 0.07
Electrosynthesis of Chlorohydrins From Alkenes in Seawater Enabled by On‐Site Generated Active Surface Chlorine Intermediate 0.13
Isolable Monocyclic N-Heterocyclic Radicals Supported by Rare-Earth Organometallics 0.63
A Modular Approach to N-Fluoroalkyl Amides via Nitrene Insertion Into Fluoroalkylcopper(I) 0.25
Mild Generation of Highly Nucleophilic N-Heterocyclic Carbene Boryl Anion From Neutral sp2–sp3 Diboron Reagents and Its Applications in Nucleophilic Borylation 0.06
Palladium‐Catalyzed Enantioselective Four‐Component Carbonylative Dicarbofunctionalization of Internal Alkenes With 1 Atm CO 0.05
Minimizing H2O2 Loss in Industrial Electrosynthesis via Asymmetric Main-Group Sn Single-Atom Catalysts 0.53
Charge‐Regulated Pyridinic Nitrogen in Covalent Organic Frameworks for Metal‐Free Heterogeneous Photocatalytic C─H Arylation of Pyrroles 0.48
Energy‐Transfer‐Enabled Copper‐Catalyzed Direct Site‐Selective Cycloaddition of Unprotected Oximes with Alkenes 0.58
<atl>Photoredox/Cobalt‐Catalyzed Asymmetric Radical Addition to Imines with Furanosyl 1,4‐Dihydropyridines to Access iC/i ‐Glycosyl Amino Esters</atl> 0.04
Dynamic Metal-Organic Tube Isomers 0.90
A Stable Triindenobenzotrithiophene Triradical with Equilateral Ferromagnetic Spin Coupling 0.31
Total Syntheses of Diketopiperazine Alkaloids via Divergent C3–N1' and C3–C5' Bond Anchor 0.35
Electrocatalytic Migratory Carboxylation of Unactivated Olefins or Halides with CO2 0.46
Streamlined Sugar Diversification via Photoredox-Catalyzed Regio- and Stereoselective 1,2-Alkylarylation of Glycals 0.83
Synthesis and Upcycling of All‐Carbon‐Backbone Degradable Polyethylene with Dispersed On‐Chain Ketones 0.67
Ring Expansion of Oximes via Photochemical Aza‐di‐π‐methane Rearrangement 0.03
Synergistic Enhancement of Photoredox Catalysis Beyond the Singlet Bottleneck Through Triplet Charge Recombination and Magnetic Field Effects 0.11
Decarboxylative Arene Ring-Opening of Benzoic Acids 0.10
Miniature Photoenzyme Enables Organelle-Specific Cellular Control via Deboronative Hydroxylation 0.38
Cationic‐Catalyst Strategy Enabling Ultrafast and Controlled Polymerization and Efficient Depolymerization Toward a Circular Polymer Economy 0.08
A Photo- and Cobalt-Catalyzed Enantioselective Hydroamination of Unactivated Alkenes with Amines 0.06
Integrating the Substituent Effect into the Wade–Mingos Rules for Dicarboranes 0.07
Integrated Conversion of Polyesters, CO2, and Glycerol via Ethylene Oxide-Mediated Tandem Process 0.36
Anion-Assisted Copper/Chiral Diamine-Catalyzed Aerobic Oxidation for the Kinetic Dearomative Spirocyclization of Arenols 0.29
Successive Sulfur Oxidation Directs Topological Transformation From 4 1 Knot to 62 3 Link 0.13
Efficient Electrosynthesis of Dinitrile from Nylon-66-Derived Diamine Enabled by Highly Active Mn–O–Co Motifs in Spinel Oxides 0.12
Diversity-Oriented Post-Polymerization Modifications by Developing gem-Diboryl Polyolefin as a Platform Polymer 0.03
“Noninnate” Ring-Opening Polymerization: Palladium-Catalyzed Stereoselective 1,4-Polymerization of Alkynylcyclopropanes 0.50
Asymmetric N‐alkylation of Carbazoles by Cooperative Potassium‐Hydrogen‐Bond‐Aryloxide Catalysis 0.08
Directing the Electrochemical C─N Coupling Toward Efficient Amide Synthesis via Ammonia Activation‐Mediated Pathway 0.52
Complete Recycling of Polyester Wastes with Dialkyl Carbonates 0.31
Machine Learning‐Driven Automated Synthesis of Polysubstituted Gentisaldehydes 0.06
Ruthenium-Catalyzed Diversified Kinetic Resolutions of Diaryl-Substituted Cyclobutenones via Asymmetric Transfer Hydrogenation 0.73
Visible-Light-Induced [2π+2σ] Cycloaddition Enabled by Cage-Confined Photocatalysis for Precise Bicyclo[2.1.1]Hexane Construction 0.13
Regio-, Stereo-, and Enantioselective Copper-Catalyzed Allylation of Sulfinylamines with Allenes 0.08
Synthesis, Structures, and CPL Property of Inner-Wall Modified Pagoda[5]Arenes Driven by Cavity Microenvironment 0.25
N‐Doped Nonalternant Molecular Bowl/Saddle Hybrids 0.02
Site-Selective α─C─H Functionalization of Saturated Heterocycles via Copper-Photoredox Catalysis 0.08
Engineering Cavity and Aperture Binding Sites Within a Metal–Organic Cage for Up‐ and Down‐Regulation of Catalysis 0.21
A Highly Selective Nucleophilic and Radical Relay Difluorination of Cyclopropanes and Alkenes 0.05
Photo-Induced Catalytic Dearomative Coupling of N-Heteroarenes 0.57
Programmable Vertical Expansion of Bilayer 2D Supramolecular Frameworks via Molecular Pillar Engineering 0.19
Photocatalytic Formamide Synthesis from Plastic Waste and Ammonia via C─N Bond Construction Under Mild Conditions 0.17
Enantioselective Synthesis of Cyclobutane‐fused Heterocycles via Lewis Acid‐Catalyzed Dearomative [2+2] Photocycloaddition of Indoles, Benzofurans, and Benzothiophenes with Alkenes 0.36
Corral[in/i]Bicarbazoles: Redox‐Active Chiral Macrocycles for Air‐Stable Radical Cations Formation and Guest Capture/Release 0.05
Enantioselective Synthesis of Chiral Azepines: A Cascade Strategy Featuring 1‐Aza‐Cope Rearrangement 0.04
iN,O/i‐Alternant Belt[3]arene Utilized for Construction of Multi‐Color Supramolecular TADF Materials and Highly Selective Detection of 2‐Cyanopyrazine 0.30
Hydrophilic Iridium Bis‐iN/i‐Heterocyclic Carbene Complexes Catalyze Linear‐Selective, Additive‐Free Hydroaminomethylation of Long‐Chain Olefins in Water 0.06
Length Ratio-Driven Configurational Modulation of Heteroleptic Pd6L6L’6 Cages 0.17
Photoredox‐Catalyzed Radical Relay for C─N Cleavage and Ring Expansion: Accessing Medium‐Sized Lactams From Unstrained Cyclic Amines 0.22
Multicomponent Assembly of High‐Component Covalent Organic Cages 0.60
Efficient Glycine Electrosynthesis via CO2-Recyclable Hydrogen Donation on Pb/Pb7Bi3 Heterointerfaces 0.38
An Atomically Dispersed Photocatalyst for Undirected para-Selective C─H Bond Functionalizations 0.02
Semiconductor Cluster with High Reduction Potential and Efficient Charge Transfer Enables Visible‐Light‐Driven Activation of Inert Organic Substrates 0.10
The Role of Reducibility of PtGaOisubx/sub/i‐Based Catalysts for Efficient and Durable Propane Dehydrogenation 0.02
Rhodium‐Catalyzed 1,5‐Sigma Migratory Ring Expansion of igem/i‐Difluorodienyl Cyclopropanes and Cyclobutanes 0.50
Titanium‐Catalyzed C─X and C─H Borylation of Aryl Halides for the Synthesis of Bis(boronate)benzenes 0.33
Fluoride Enhances Alcohol Binding Within a Trigonal‐Prismatic Metal‐Organic Capsule 0.05
Intracellular Polymerization Induced Self‐Assembly and Gold Nanocomposite Synthesis in Living Bacteria 0.75
Divergent Construction of Cyclobutane‐Fused Pentacyclic Scaffolds via Double Dearomative Photocycloaddition 0.69
Iridium‐Catalyzed Asymmetric β‐Selective Hydroamination of Enamides for the Synthesis of 1,2‐Diamines 0.08
Enantioselective Palladium‐Catalyzed α‐Arylation of Acyclic Esters 0.27
Preparation of Cyclic Olefin Polymers via Group Transfer Radical Cyclopolymerization for High Performance in Anode‐Free Batteries 0.02
Natural Sunlight‐Driven Activation of Inert Aryl Halides Using Plasmonic Cu@CdS with Polysulfide Active Sites 0.17
Design, Synthesis, and Application of a Family of Chiral Non-C2-Symmetric NHCs with a Fused Sidechain 0.13
Palladium‐Catalyzed Enantioselective Arylative Dearomatization of Naphthols and Phenols for Constructing Quinazoline‐Containing Spirocycles 0.42
Electrocatalytic C─S Cross‐Coupling via Engineered Frustrated Lewis Acid‐Base Pairs for High‐Efficiency Methanesulfonate Synthesis 0.50
Visible Light‐Driven Deracemization of Cyclic Sulfonamides by Quinuclidine and Chiral Arylthiol Catalysis 0.30
Highly Efficient Suzuki–Miyaura Polymerization Enabled by Direct Transmetalation with Boronic Esters 0.01
Modular Synchronous Synthesis of Amides and α‐Ketoamides Realized by Matching Electrolysis‐Paired Tandems 0.48
Bio‐Sourced 4‐Aryl‐1,2‐Dithiolanes for Recyclable Poly(disulfide)s with High Performance 0.50
Copper‐Catalyzed Asymmetric Cyanation of Propargylic Radicals Derived From Silyl‐Substituted Allenes and Alkynes 0.13
Constructions of Biaryl‐Bridged Macrocycles Through Phosphine‐Ligand‐Controlled Switch of Selectivity Between Intra‐ and Intermolecular Cyclizations 0.50
Modulating Electron Transfer via Cerium Photocatalysis for Alkoxy Radical‐Mediated Selective Hydroetherification 0.30
Copper‐Catalyzed Radical Enantioconvergent C─O Bond Formation for Asymmetric Cross‐Coupling of Allylamines and COsub2/sub 0.78
A Nitrogen‐Containing Graphenic Buckybowl for Photocatalysis and Assembly With Fullerenes 0.08
Catalytic α‐Site‐Selective Hydrogen‐Deuterium Exchange of Benzylic Alcohols by Palladium Single‐Atom Catalyst 0.79
Internally BN‐Doped Coronene 0.50
Efficient Electro-Oxidation of Ethylene to 2-Chloroethanol on SnO2 Through Dual-Adsorbate Pathway 0.50
Synthesis of Porous Carbon‐Based Network Containing Ultranarrow Nonplanar Nanopores on Surfaces 0.04
Redox-Driven In Situ Formation of Bimetallic Catalysts via Sn2+/Sn4+ Interconversion 0.29
Visible Light‐Driven Benzaldoxime Synthesis by Glutathione‐Modified CdS Quantum Dots 0.25
Nickel‐Catalyzed Umpolung Difluoroalkylation of Imines Enables General Access to β‐Difluoroalkylated Amines 0.13
Rhodium‐Catalyzed Atroposelective Synthesis of Axially Chiral 1‐Aryl Isoquinolines via De Novo Isoquinoline Formation 1.00
Regiospecific 2,3‐Dialkylindole Synthesis Enabled by Alkylpalladium 1,2‐Migration to In Situ Formed Aldimine 0.50
22 8.82
Rapid synthesis of nucleoside diphosphates accelerated by water 0.21
Supramolecular network-based artificial light-harvesting system employing an AIE-active metallacycle for aqueous-phase photocatalytic oxidation 0.17
A photo-induced three-component reaction of N-aryl piperidines, sulfur dioxide, and cycloketone oxime esters 0.07
Fabrication of lithium phenoxide complexes for hydrogen storage evaluation 0.30
Direct carbonylative amidation of benzylic alcohols with alkylamines via palladium catalyzed C–O bond activation 0.17
A direct route to ynones: Pd-catalyzed Sonogashira carbonylative coupling of ethers with alkynes via C–O cleavage 0.17
Synthesis of S-alkyl sulfilimines via ring-opening sulfilimination of sulfonium salts 0.08
Controlled ROS generation in pyridinium-functionalized nanocatalysts for selective photooxidation 0.08
Turn left and turn right: recent advances in selectivity controlled carbonylation 0.83
G-quadruplex DNA/iron cationic porphyrin catalyzes enantioselective carbon–silicon bond formation 0.75
Biochar-supported Cu catalyst for low-temperature base-free oxidative N-formylation of amines with paraformaldehyde in green solvent 0.69
Carbon monoxide as the key: carbonylation triggered (hetero)aryl migration transformations 0.50
Direct and affordable alcohol phosphorylation through ambient electrochemical oxidation of phosphorous acid 0.50
Electrochemically driven bromochlorination of alkenes 0.67
Trace water-induced anomalous diffusion in chlorinated imidazolium ionic liquids 0.40
Visible-light photoredox catalyzed thioesterification of sulfoxonium ylides with elemental sulfur and α-ketoacids 0.25
Regioselective C7 sulfinylation of 4-aminoindoles with sulfinates 0.07
Nickel-catalyzed Barbier-type reaction of carbonyl derivatives with unactivated alkyl halides 1.00
Pd-catalyzed asymmetric (6+2) dipolar cyclization for medium-sized spirooxindoles 0.03
Reduction of nitrobenzene to phenylhydroxylamine with anthraquinone-2-sulfonic sodium as an electron mediator 0.86
Pillar[5]arene-based ionic single crystals formed by dual self-assemblies through host–guest and ionic interactions for iodine capture 0.64
Coupling Dy3 toroics in macrocycles 0.39
24 6.79
Sterically controlled 5-exo-dig cyclization enables synthesis of non-benzenoid polycyclic aromatic hydrocarbons with intriguing (anti)aromaticity and diradical properties 0.11
Lipid-donor-anchored genome mining uncovers dioxanopeptins, antibacterial lipopeptides with a 1,3-dioxane functionalized polyunsaturated lipid tail 0.60
Stereospecific alkenylation of carboranes: copper-catalyzed access to pyridylcarboranyl alkenes 0.03
Neutral anion-detecting organic cages based on anion–π interactions 0.01
A dicationic ionic liquid strategy to enhance the thermal stability of manganese bromide scintillators 0.33
Controllable copper-catalysed photo-induced carbonylative cyclization to access dihydroquinolinones and oxindoles 0.33
Biomimetic sulfur-catalyzed carbonyl transfer enables the carbonylative difunctionalization of unactivated alkenes 0.42
Palladium-catalyzed amidocarbonylation of thioethers: access to α-amide-substituted thioether derivatives 0.50
Acetic anhydride as a versatile carbon source in carbonylation reactions 0.41
Enantioselective synthesis of vicinal amino alcohols promoted by fluorine-containing counteranions 0.29
A 4,4′,4″-nitrilotriphenoxyl radical derived from Yang's biradical 0.33
Single atom-bridged Au nanozymes boost glucose oxidase-like activity in acidic media 0.10
Palladium-catalyzed carbonylative synthesis of acrylamides from alkenyl thianthrenium salts 0.50
Acyl-oxyallenes as α,β-unsaturated ketone surrogates for Giese radical addition 0.08
Enantioselective copper-catalysed defluorinative alkylation of polyfluoroarenes with alkenes and 1,3-dienes 0.05
Nickel-catalyzed aminocarbonylation of aryl chlorides enabled by a newly designed CO source 0.63
Desulfurative modification of cysteine residues in peptides and proteins via the installation and photoexcitation of thieno[2,3-c]-pyrroles 0.21
Cobalt-catalyzed direct carbonylative 3-acylation of (N–H)Indoles with alkyl halides 0.46
Asymmetric ring contraction of 2-hydroxypyranones by borrowing hydrogen biocatalysis 0.17
Modular and diverse synthesis of oxaheterocycles via Pd-catalyzed migratory 1,n-cycloannulation of alkenes 0.61
Enhancing photoredox catalysis by suppressing back electron transfer with the aid of a spin catalyst 0.08
Photocatalytic regioselective four-component radical relay carbonylation for α-aminoketones synthesis 0.25
Asymmetric intramolecular reductive coupling of bisimines templated by chiral diborons 0.19
Rh-catalyzed enantioselective hydrosilylation of unactivated alkenes 0.12
1 0.60
Molecular engineering of an ether–nitrile constructs robust dual-interphases for ultra-stable 4.5 V lithium metal batteries 0.60
1 0.06
Formation and stability of environmental persistent free radicals (EPFRs) from the reaction between phenolic compounds and Fe(III)-loaded particles 0.06
2 0.66
Synergistic Mechanisms of Formaldehyde-Induced Radicals Enhancing Photothermal Catalytic Oxidation of Toluene 0.54
Enhancing Photocatalytic Decarboxylation by Frustrated Lewis Acid–Base Pairs for Efficient Degradation of Perfluorooctanoic Acid 0.13
7 2.92
Constructing Metallo-Supramolecular Cuboctahedra Incorporating Flexible Alkyl-Diamines via Postassembly Ligand Exchange 0.55
Designing Copper(I) Iodide Clusters with Tunable D−π–A Ligands for Photocatalytic Thiocyanation 0.83
Adaptive Self-Assembly of Lanthanide-Covalent Organic Polyhedra: from Triangular Prism to Octahedron 0.60
Copper Halide Hybrids Driven by Irreversible Structural Transitions for Anti-Counterfeiting and Traceability 0.57
Three-Component CO2 Conversion to Carbonyl Carboxylates Catalyzed by a Copper-Based Metal–Organic Framework under Mild Conditions 0.13
Study on the Quenching Mechanism of Radicals by Fullerenes (C60 and C70) 0.11
Anion- and Conjugated Building Block-Driven Construction of Handcuffs and Cages, Featuring In Situ Topological Transformation from Handcuff to Double-Z Cage 0.13
1 0.13
Amino acid mediated hydration of caustic calcined magnesia: dual-function for efficient conversion and purification 0.13
1 0.15
Construction of general N-body lattice operators with arbitrary momenta 0.15
122 41.51
Dynamic Kinetic Asymmetric Allylation of Ketones: Stereodivergent Synthesis of E- or Z‑Substituted α,β-Stereogenic Tertiary Alcohols 0.77
A Methyltransferase Catalyzing Reactions More Than Methylation 0.42
Nickel-Catalyzed Regioselective Dihydrosilylation of Allenes 0.26
Spontaneous and Efficient Oxime Synthesis by Al-Catalyst Assembly 0.25
Discovery of a Potent Antisarcopenia Drug Molecular Scaffold Derived from Ligusticum chuanxiong and Its Photochemical Synthesis 0.07
Asymmetric Radical Allylic Cyanation of Electron-Deficient Alkenes with a Low Copper Catalyst Loading: Development and Mechanism 0.10
Characterization of UDP-Sugar 3‑Dehydrase KsgR in the Biosynthesis of a Distinctive Multideoxy Diamino-Sugar Kasugamine of Kasugamycin 0.09
Enhancing the Tsuji–Trost Reaction via 1,3-Diene Formation 0.37
Unexpected Chemoselectivity in Radical Aryl Translocation via Photosensitization 0.01
Controllable Difluorocarbene Elongation via Copper Catalysis 0.10
Electroenzymatic C1 Fixation to Glycine via Dithiothreitol Regeneration on Functionalized 1T′-MoS2 0.10
Hexacoordinate Ti-Anchored Single-Atom Pd Catalyst for High-Efficiency Cyclohexanone Ammoximation with H2 and O2 0.24
Copper(I)–NHC-Catalyzed Enantioselective Borylation and Silylation of Ketimines 0.08
The Salting-Out Effect Enables Highly Selective Electrochemical Ammoxidation of Aldehydes to Nitriles 0.42
Rhodium-Catalyzed Desymmetric Addition of Boronic Acids to Malononitriles 0.08
Facile Synthesis of Gem-Difluoroalkene-Based Bis(silanes) via Copper-Catalyzed Disilylative Defluorination of 1-Chloro-1-trifluoromethylalkenes 0.01
Asymmetric Alkene Boration and Z-Retentive Allylic Substitution Reactions under Cu/Pd Relay Catalysis 1.00
Linker Torsional Angle Engineering in Metal–Organic Frameworks Enables Boosted O2 Photoactivation for Organic Synthesis 0.08
Spin Alignment in Cr–W–Cr Motif Promotes N, N-Dimethylformamide Electrosynthesis from Dimethylamine Self-Coupling 0.32
One-Step-Three-Ring Propellanation Reaction of Yne-Vinylcyclobutanones Catalyzed by Nickel: Reaction Development, Mechanism, and Formal Synthesis of Modhephene 0.50
Unraveling the Single-Site Origin of Strong Brønsted Acidity in Fluorinated γ-Al2O3 0.75
Reductive Cyclopentamerization of Carbon Monoxide to the Elusive Croconate Radical Trianion 0.17
SPSiP-Enabled Pd-Catalyzed Enantioselective Alkynylamination of Alkenes 0.76
Divergent Radical and Ionic Electroreductive Regulation for Disulfuration 0.36
Deciphering the Stepwise N–O Activation of Nitroarenes: Electronic Structure and Reactivity of Iron-Nitrosoarene Intermediates 0.13
Facile Synthesis of Nonalternant π-Conjugated Azaborines via Boron-Deleting Annulation 0.04
Perfectly Alternating Copolymerizations of Methacrylates and Coumarin to Robust C–C Main-Chain Polymers with Full Degradability and Depolymerizability 0.22
Polymerization Chaperone for the Controlled, Homogeneous Synthesis of Proline-Based Homo- and Copolypeptides 0.42
Electrocatalytic Oxidative Coupling of CO with Amines toward Symmetrical and Asymmetrical Urea Derivatives 0.45
Deciphering Mechanistic Pathways and Selectivity in Electrochemical Oxidative C–N Bond Formation between Olefins and Sulfonamides 0.05
Copper-Catalyzed Asymmetric Vinylation of α-Cyano Substituted Carbonyl Compounds 0.07
Solar-Driven Upcycling of Polystyrene Enabled by Elemental Sulfur 0.43
All-Hydrocarbon Polymers with Chemical Recyclability via a Catalyst-Free and Solvent-Free Method 0.63
Catalytic Remote Dihalogenation of Alkenes Induced by Transposition of Esters 0.67
Artificial Spherical Chromatophore Mimicking LH2 and LH1–RC for Highly Efficient Photocatalytic Hydrogen Production with Turnover Number >667,000 0.08
Strategy for the Synthesis of Inverse Sandwich 1,4-Diarylbutadiene Dianionic Rare-Earth Metal Complexes via Directing Coupling of β-Aryl Vinyl Boron Reagents 0.04
Palladium-Catalyzed Autotandem Hydrogenolysis/Hydrogenation for the Synthesis of Hexahydro-β-carbolines Containing Three Contiguous Stereocenters 0.67
Co-Catalyzed Asymmetric Carbamoyl Radical Addition of Imines 0.04
Photodriven Enantioselective 6-endo Hydroaminative Cyclization to Chiral 4-Substituted 3,4-Dihydroisoquinolones 0.42
Waveform-Enhanced Alternating Current Electrocatalysis Enables Cu-Catalyzed Carbon–Oxygenation of β-Keto Carbonyls with Alkenes and Alkynes 0.02
Intermolecular Cyclization of Alkyl Chains of Ketones for Constructing ortho-Diacylbenzenes 0.36
Copper(I)-N-Heterocyclic Carbene-Catalyzed Enantioselective Conjugate Allylation of α,β-Unsaturated Esters 0.16
Diazulenopentalene: Facile Synthesis of Linear Non-Alternant Molecular Carbons through Pt-Mediated Rearrangement 0.03
Concise Synthesis of Deoxylimonin 0.42
Regulating π-Stacked Micelle-Like Assembly via Anion Coordination to Achieve Frank–Kasper C15 Phases 0.76
Ambimodal (2 + 1)/(4 + 1) Pseudopericyclic Transition States in Reactions between Dihalocarbenes and Olefins 0.19
Construction of Heteroleptic Copper Complexes in Perylene Diimide-Based COFs for Heterogeneous Metallaphotoredox Catalysis 0.03
Doping a Nanographene with a Formal NiIV Center 0.14
Photo- and Copper Dual-Catalyzed Z-Selective Chlorosulfonylation of Allenes for Tetrasubstituted Alkenes 0.30
Enantioselective Radical Addition of Carboxylic Acids to Imines through Cooperative Copper/Acridine Catalysis 0.75
Mechanistic Study of Cycloisomerization of 1,7-Allenenes and Guidance to Develop a [2 + 1 + 2] Reaction of 1,7-Allenenes with CO for Accessing cis- and trans-5/5 Skeletons 0.50
Enabling Proteins with Photocatalytic Functions via HisTag–Iridium Coordination 0.38
Reversible Interconversion between a Carbon–Carbon Double Bond and Diradical beyond External Stimulus 0.63
O2-Mediated Reactivity of Confined Carbenium Ions in Zeolites 0.92
Cascade Dearomative Hydride Transfer/Enantioselective Semipinacol Rearrangement of Quinolines by a Chiral Brønsted Acid 0.88
Total Synthesis of Acoapetaludine A Enabled by a Rhodium-Catalyzed Domino Cyclization 0.13
Boron Nitride-Confined Nanographene as a Metal-Free Catalyst for Acetylene Hydrochlorination 0.57
Proton-Regulated C–N Coupling for Efficient Amino Acid Electrosynthesis 0.35
Copper-Catalyzed Asymmetric Alkynylation of sp2 Allenic C–H Bonds for the Synthesis of Skipped Diynes 0.40
Conformationally Adaptive Molecular Cages Enabled by Metal Cluster-Mediated Assembly 0.13
Protocells with ATP-Fueled Dissipative Behaviors as Functional Regulators 0.50
Bioorthogonal Photocatalytic Protein Labeling and Cross-Linking Enabled by Stabilized Ketyl Radicals 0.41
Catenanes of Twin-Cavity Cages 0.17
Pd/SadPhos Enabled Modular and Enantioselective Assembly of Triarylmethanes 0.03
Entropy-Driven Amino Acid-Based Coacervates with Enzyme-Free Metabolism and Prebiotic Robustness 0.69
Solar-Driven Upcycling of Polylactic Acid to Alanine over Pt/CdS–TiO2 Heterojunction Single-Atom Photocatalyst 0.18
General Photo-Driven Chemoselective and Rapid Hydropentafluorosulfanylation of Alkenes via an Orchestrated Radical Chain Process 0.01
Palladium-Catalyzed Site– and Enantiodifferentiating Allylic C–H Alkylation of Internal Alkenes 0.07
Stereoselective De Novo Construction of Cyclopropane by a Multifunctional Class I Aldolase 0.75
Total Synthesis of (+)-Resiniferatoxin via a Pyridinium Salt Photorearrangement 0.45
Conjugated Networked Poly(ionic liquid)-Accommodating Organic Cages: A Matter of Interhost Electron Communications 0.03
From Alkylarenes to α-Amino Acid Derivatives via C-Difunctionalization 0.06
Enantioselective Redox-Neutral Radical Addition of α-Imino Esters with Sulfonyl Hydrazides 0.03
Bioinspired Total Syntheses of Skeletally Diverse Lycopodium Alkaloids 0.83
Curvature-Directed Selective C–C Bond Cleavage Driven by Electric Fields 0.25
A Highly Selective Cobalt Catalyst for Primary Amine Synthesis from Carboxylic Acids, Esters, and Vegetable Oils 0.04
Ultradurable Regenerative Propane Dehydrogenation Catalyst by Fluorination-Induced Confining and Positioning 0.37
Bridged-Backbone Strategy Enables Asymmetric Synthesis of Highly Functionalized Oxabicyclo[3.3.1]nonanes with Anti-Osimertinib-Resistant NSCLC Activity 0.07
In Situ Probing Two Radicals in Halogenation Couplings from Photoanodic Single-Atom Catalysis 0.14
Inhibiting Isomerization via Confinement in Ice–Water Interfaces Enhances Stereoselectivity in [2 + 2] Cycloaddition 0.18
Unlocking Difluorocarbene as a Fluorocarbanion and a Fluorocarbon Radical Precursor for Sequential Catalytic Coupling 0.13
Rapid Activation of Amino Acids with Cyanide and Hypochlorite 0.25
Enantioselective Synthesis of Atropisomeric 3-Arylindoles via Cobalt-Catalyzed Electroreductive Cross-Coupling 1.00
Palladium-Catalyzed Asymmetric Carbonylation of Alkynes to Axially Chiral Carbothioate Esters 0.90
Cyclic BODIPY Arrays: A Class of Macrocycle-Based Molecular Solids for Hydrogen Isotope Separation and Iodine Capture 0.41
Late-Stage Tryptophan Modification of Native Peptides through Photochemical Indole-to-Quinazoline Editing 0.02
Harnessing Chromium(V) Hydrazido Intermediates for N2 Functionalization to Multisubstituted Hydrazines through Ligand Migration 0.50
Construction of Zeolite Framework-Anchored Rh–(O–Zn)x Sites for Ethylene Hydroformylation 0.72
Enantioselective Assembly of (Hetero)aryl Alkyl Sulfilimines via Copper-Catalyzed S-Arylation of S-Alkyl Sulfenamides with (Hetero)aryl Iodides 0.12
Water as an Electron Donor for Cross-Electrophile Coupling Reactions 0.25
Ultralow Content of Chromium Species in Zeolite for Efficient Catalytic Propane Dehydrogenation 0.33
Modular Access to Medium-to-Large Sized Lactams through Alkyne-Bridging C–C Bond Activation of Unstrained Carbonyls 0.17
Asymmetric Total Synthesis of (−)-Psychotriadine Featuring [3,3]-Rearrangement and Stereo-Controllable Ring-Contraction 0.03
Trisilylation of a Formal Cr(−I) Bis-dinitrogen Complex 0.54
Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols via Tandem Etherification/Claisen Rearrangement 0.50
Carbon-Caged-Yttria Catalysts for Stable Electrosynthesis of H2O2 in Concentrated Acid 0.07
Construction of a Chiral Click Chemistry Platform via Enantioselective F/Cl Exchange at S(VI) Centers 0.29
Bimolecular Nucleophilic Substitution (SN2) Reaction Catalyzed by l-Threonine Aldolase 0.83
Chiral Porous Sheet Assembly for Multiple Chirality Induction in Macrocycle Formation 0.20
Ultraconjugated Electron–Proton Transfer Mechanism in the Product Selectivity-Controllable Electrocatalytic Oxidation of Binary Primary Alcohols 0.38
Enantioselective Construction of Aza-bicyclo[3.2.1]octane Skeletons via Substituted π-Allyl Palladium Dipoles Originated from Neutral η3-Propargyl Palladium Species 0.67
Electron Donors in the Intertwined Interface Restore Oxy-Substituted Selenides 0.82
Cobalt-Catalyzed Asymmetric Reductive Coupling of Isocyanates with Tertiary Alkyl Halides for Sterically Bulky Chiral Amide Synthesis 0.05
Concise Syntheses of Harziane Diterpenoids by Merging Local Desymmetrization and Radical Retrosynthesis 1.00
8-Quinox Cobalt Catalyst Enables the Reductive Alkylative Addition of Sulfinylamines with Unactivated Alkyl Halides 0.04
Radical 1,3-Difunctionalization of β,γ-Unsaturated Ketones via Concomitant 1,2-Carbonyl Migration: An Entrance to β-SF5-/β-CF3SF4 Ketones 0.02
Melt Rheology of Dendritic Hyperbranched Polyacrylates Synthesized by Controlled Radical Polymerization: Evidence of Self-Similar Branch Structure Formation 0.08
Cu/Ir Relay Catalysis for Regio- and Enantioselective Alkene Borylation/Allylic Alkylation 1.00
Stereoconvergent Aminoboration of (Z/E)-Mixed Alkenes via Bimetallic Asymmetric Relay Catalysis 0.06
Unveiling Janus Chemical Processes in Contact-Electro-Chemistry through Oxygen Reduction Reactions 0.36
DACH-ZYC-Phos/Pd-Catalyzed Enantioselective Allenylation of Secondary Phosphine Oxides via Ligand Relay 0.19
Copper-Catalyzed Highly Efficient and Asymmetric Allylic C–H Oxidation of 3-Aryl-Substituted Terminal Alkenes 0.17
Tuning Covalent Organic Frameworks for Nucleic Acid Loading: Toward Creating a Hierarchical Artificial Cell 0.28
Collective Biosynthesis of Plant Spirooxindole Alkaloids through Enzyme Discovery and Engineering 0.78
Iridium-Catalyzed Z-Selective Asymmetric Allylic Substitution Reaction via Z/E Kinetic Resolution 1.00
A Tailored Quinoline-Locked Covalent Organic Framework for Metal-Free Photocatalytic α-Amino C–H Annulation 0.70
Divergent Total Syntheses of Rearranged Steroids Swinhoeisterols A–C 0.38
Silicon Rhodamine-Catalyzed Near-Infrared Light-Induced Photodecaging of Ortho-Nitrobenzyl Groups In Vitro and In Vivo 0.03
Piercing Molecular Graphenes: Precision Synthesis and Photophysics of NBN-Edged Porous Molecular Carbons 0.05
Concise Total Synthesis of Ambiguine P 0.29
Stereoselective 1,3-Cyclotelomerization of Butadiene with Dienophiles under Nickel Catalysis 0.69
Multiple Secondary Bond-Mediated C–N Coupling over N-Doped Carbon Electrocatalysts 0.31
5 2.25
Self-Sacrificing Photocatalyst Enables Polymer Synthesis and In Situ Decolorization 0.58
Crystal Structure of Poly(α-methylene-δ-valerolactone) 0.15
Synthesis of Highly Syndiotactic Poly(8-Vinylquinoline) via Heteroatom-Assisted Coordination Polymerization 0.40
Electrostatic Mediation in Synthesis of Single-Chain Nanoparticles in Concentrated Solutions 0.19
Tailoring Branched Polyethylene with Polar Segments: A Strategic Approach to Multifunctional Polyolefin Materials 0.93
4 1.01
Proton Concentration Tunes the Double-Layer Characteristics of Lead Catalysts to Boost the Electrosynthesis of Glyoxylic Acid 0.08
Pressure-Driven Solid-State Radical Polymerization toward Carbon Nanothread 0.12
Molecular Stacking Patterns Enhance Organic Small-Molecule Electrochemical Stability and Enable Ion Separation 0.47
Temperature-Insensitive Electron Transfer in Quantum Dot–Molecule Hybrids Driven by Nuclear Quantum Tunneling 0.34
5 1.16
Carbonyl swapping converts cyclic ketones to saturated heterocycles 0.24
Direct conversion from alkenes to alkynes 0.02
Direct deaminative functionalization with N-nitroamines 0.05
Decoding the redox behaviour of copper in Ullmann-type coupling reactions 0.28
In-line NMR guided orthogonal transformation of real-life plastics 0.58
5 0.31
[2+2] Photocycloaddition reactions of sulfinylamines with alkenes to access β-sultam derivatives 0.04
Stepwise-controllable catalytic asymmetric Atherton–Todd reaction to access diverse P(V)-stereogenic compounds 0.02
Enantioconvergent radical addition of racemic alkyl halides to access vicinal stereocentres 0.03
Diastereo- and enantioselective 1,3-hydrofunctionalization of trisubstituted alkenes by a directing relay 0.07
Interfacial assembly of biomimetic MOF-based porous membranes on coacervates to build complex protocells and prototissues 0.17
52 14.34
Single-iron catalyst with heterogenized TEMPO for selective toluene electrooxidation to benzaldehyde at low potentials 0.10
Unveiling a flip-over retention mechanism in the gas-phase Cl− + (CH3)3CI SN2 reaction 0.18
Decorating titania with ultrasmall UiO-66-H crystallites enables quantitative photocatalytic oxidation of methane to oxygenates 0.18
Redox-mediated domino electrosynthesis of -dimethylformamide with industrial-relevant productivity and modularized cathodic integration 0.48
Unlocking the reactivity of difluoroketene and its synthetic applications 0.01
Electrochemical tyrosine-click bioconjugation enables multiplexed cytokine sensing and immunoprofiling in native serum 0.08
Concise synthesis of bufogargarizin B by a conformation-controlled skeletal reorganization approach 0.44
Electrochemically mediated disproportionation for selective formaldehyde upcycling in acid 0.05
Molecular mechanism underlying regulation of chalcone synthase by chalcone isomerase-like protein 0.75
Coenzyme-functionalized photo-redox catalysis for low-energy click labeling 0.44
Stereoselective depolymerization of chiral polyesters 0.69
Chemodivergent Coupling of 1,3-Enynes with Anilines to Access Dihydropyrrole Skeleton under Palladium Catalysis 0.60
Asymmetric synthesis of Heteroatom-bridged [3.2.1]Octane scaffolds via enantioselective β-H elimination reaction 0.04
Space ionizing radiation triggers the formation of peptides and organophosphates on olivine surfaces 0.10
Acid-base pair-mediated copolymerization of acid-sensitive epoxides and cyclic anhydride for synthesizing recyclable thermoplastics 0.63
Ultrafast solvent-modulated roaming mechanism in bromoform revealed by femtosecond X-ray solution scattering 0.01
Trifunctional flavoenzyme-catalyzed asymmetric 4-alkyl-butenolide assembly in avenolide biosynthesis 0.65
Abyssal hydrothermal alteration drives the evolution from simple alkanes to prebiotic molecular complexity 0.20
Solution-synthesized stable triaza[4]triangulene triradical with a quartet ground state 0.33
Recycling of polyolefins using recycled PVC under sunlight 0.75
Manganese catalyzed oximation of hydrocarbons to oximes 0.06
Photochromism of pyridine-substituted merocyanine through reversible C-N bond formation 0.38
Late-stage adenine N6-alkylation of nucleos(t)ides and oligonucleotides via photoredox and copper co-catalytic decarboxylative C(sp3)–N coupling 0.03
Enantioselective dearomative single-atom skeletal editing of benzofurans 0.03
Copper-catalyzed atroposelective hydroarylation of 1-alkynylindoles 0.07
Dual transition metal electrocatalysis for difluoromethylation of Aryl halides using potassium difluoroacetate 0.25
Abiotic N reduction in submarine hydrothermal systems could quickly fertilize prebiotic oceans 0.40
Light-driven radical copper-catalyzed allylic amination via allylic copper intermediates 0.10
Enzymatically reconfigurable liquid crystalline coacervate microdroplets as protocell models 0.17
Chiral macrocycles forming high-affinity host-guest homoternary complexes for chiral discrimination and amplified circularly polarized luminescence 0.09
Copper integrative catalytic pairs with mixed-valence Cu-Cu Species for selective alkyne conversion 0.07
Copper-catalyzed enantioselective synthesis of γ-butenolides via radical diversification of allenoic acid 0.75
Sustainable recycling of polyamides via C–N bond cleavage facilitated by methyl tosylate under mild conditions 0.07
Bioinspired transfer methylation enabled by a photoactive reagent 0.11
Dehydroxy-Perfluoro--butylation of alcohols with PhSOC(CF) and insights into the structure of the [C(CF)] anion 0.10
Gymnosperm-specific CYP90Js enable biflavonoid biosynthesis and microbial production of amentoflavone 0.33
Near-infrared photon-triggered CH-to-CHOH conversion over plasmonic oxyselenides 0.17
A general esterolysis strategy for upcycling waste polyesters into high-value esters 0.13
Coordinatively unsaturated bismuth sites accelerate in-situ hydrogen peroxide electrochemical formation for efficient butanone oxime synthesis 0.08
Cationic alkyl chain length and nanoaggregate form of ionic liquids dominate biocompatibility and toxicity 0.45
A SaBOX/Co catalyst designed for facile access to the challenging copolymers of vinyl ester and methacrylate 0.94
Enantioselective synthesis of chiral 2,3--disubstituted piperidines and C1-substituted tetrahydroisoquinolines by asymmetric Cu-catalyzed cyclizative aminoboration 0.63
Multi-component reactions via copper(I) difluorocarbene as carbonyl source for constructing α—aminoamide derivatives 0.41
Amines tuned controllable carbonylation for the synthesis of -lactones and 1,4-diones 0.33
LMCT-driven electron relay unlocks alcohols as tunable reductants for nickel-catalyzed cross-electrophilic couplings 0.47
Enantioselective aza-electrophilic dearomatization of naphthalene derivatives 0.06
Pathway-divergent coupling of alkynes and cyclobutenes through enantioselective cobalt catalysis 0.38
Syngas from waste plastics and water using Joule heating 0.10
Highly efficient catalytic propane dehydrogenation driven by MFI zeolite defect sites 0.09
symmetric chiral ligand dictating allyl-allyl coupling 0.17
Chemoselective dual functionalization of proteins via 1,6-addition of thiols to trifunctional -alkylpyridinium 0.06
Substrate-based discovery of α-hydroxycarboxylic acid derivatives as potential herbicides targeting dihydroxyacid dehydratase 0.17
2 0.60
Catalytic cascade depolymerization for sustainable recycling of waste polyvinyl chloride 0.10
Efficient glycerol electro-oxidation at an industrial-level current density 0.50
144 44.47
Copper-Catalyzed Functionalization of C(sp2)–H Bonds with Vinyl Cations: Synthesis of Polycyclic Pyrroles 0.04
Enantioselective Synthesis of Indole-Derived Atropisomers through Rh(I)-Catalyzed C–H Arylation with Aryl Bromides 0.50
Regiodivergent 1,3-Annulation of Valylene with 4‑Hydroxycoumarins 0.60
Photoinduced Defluorinative Alkylamination of Alkenes with Trifluoromethylated Arenes and Anilines 0.06
Visible-Light-Induced Dual Iron/Eosin Y Catalysis for Direct Dehydrogenation of Saturated Heterocycles, Alcohols, Esters and Amides 0.48
meta-Sulfonylation of Pyridines from Sulfur Dioxide with Dearomatized Pyridines as Redox-Active Substrates 0.07
How Silver Additives Promote Copper-Catalyzed Cyclization and Alkene Transposition: A Mechanistic Study 0.13
Asymmetric Reductive Cross-Coupling of Aldimines 0.47
Asymmetric Synthesis of Spirocyclic Sultams via Nickel-Catalyzed Arylative Cyclization 0.90
<atl>Sodium iS/i -(difluoromethyl) Sulfurothioate: A Readily Available (Deuterio)difluoromethylthiolating Reagent with SCF sub2/sub H sup+/sup , SCF sub2/sub H sup–/sup , and SCF sub2/sub H sup•/sup Reactivity</atl> 0.05
Bioinspired Alkyl Transfer Enabled by Ca(II)/HFIP Cooperative Catalysis: Modular Synthesis of Functionalized Isoindolinones 0.50
Nickel/Photoredox-Catalyzed Allylic Alkylation via C(sp3)–C(sp3) Cross-Coupling of Allyl Boronic Esters and Alkyl Halides 0.83
“Addition–Elimination” Transformations for Aminative Isomerization of Bicyclo[1.1.0]butanes (BCBs) 0.42
Spirocyclization-Enabled Remote Phosphorothiolation of Nonactivated Arenes via Dual Photoredox/Copper-Catalyzed Dearomatization 0.48
Copper-Catalyzed Divergent Rearrangement Reactions of Propargyl Ethers 0.07
Marundihomalkins A–J and Marundisphingalkin A: Triglyceride-Lowering Marine Fungal Alkaloids Featuring Non-amide C–N Linkages between Polyketide and Homoisoleucine or Phytosphingosine 0.22
Synthesis and Photophysical Properties of Azaarene-Substituted Hypocrellin B Derivatives 0.50
Photocatalyzed Radical Cross-Coupling of Allylic Esters with N-Aryl Glycinates and Benzyl Amines for sp3 C–C Bond Formation 0.55
Catalytic Enantioselective Formal (3 + 3) Cycloaddition of 3-Halooxindoles with Pyridinium 1,4-Zwitterionic Thiolates 0.10
NHC-Catalyzed Desymmetrizative Amidation for C–O Axially Chiral Imides 0.06
Visible-Light-Induced Carbonylative Synthesis of Aliphatic Thioesters 0.50
Nickel-Catalyzed Aminocarbonylation of Aryl Trifluoromethoxides 0.67
Construction of Functionalized 2,3-Dihydropyrroles via Visible-Light-Driven Formal [3 + 2] Cycloaddition 0.04
Jatropodagines A and B: Lathyrane Diterpenoid Dimers from Jatropha podagrica, Inducing Paraptosis-Like Cell Death 0.64
Artemverlotolides A and B, Two Sesquiterpenes from Artemisia verlotorum Lamotte: Structural Elucidation, Bioinspired Synthesis, and Antineuroinflammatory Activity 0.57
Photochemical Boronate Rearrangement Enables the One-Pot Synthesis of 2,4-Difunctionalized 2H-Chromenes 0.42
Chemoselective [2+1] Cycloaddition of Difluorocarbene with Conjugated Enynes: Synthesis of Alkenyl Difluorocyclopropenes 0.11
Photocatalytic Transfer of Trifluoromethylcarbenes for X–H Insertion, Oxetane Skeleton Editing, and Alkene Cyclopropanation 0.08
Et3SiOBpin as a Dual Reagent Enabled Photocatalytic Stereoselective Assembly of Multisubstituted Perfluoroalkyl-boryl Styrenes 0.05
A Pd-Catalyzed (6+2) Cycloaddition/Ring-Contraction Relay for Chemodivergent Access to Chiral Spirooxindoles 0.04
Copper-Catalyzed Amino-alkoxycarbonylation of Unactivated Alkenes: Synthesis of β-Amino Esters via Primary Tosyl Amidyl Radical 0.60
Hexafluoroisopropanol-Mediated Hydroaminoalkylation–Aza-Prins for Construction of α-Amino-butenolide 0.50
N,N′-Di-Boc-N″-fluorosulfonyl-guanidine: A SuFEx-Enabled Guanylating Reagent (SuFEx-G) with Enhanced Reactivity on Water 0.04
Zinc-Mediated Four-Component Carbonylation toward Direct Synthesis of α-Amino Ketones 0.50
Substituent-Promoted Thio-Belluš–Claisen Rearrangement with Difluoroketene 0.02
Direct Synthesis of Triarylethynylphosphines from White Phosphorus and Arylacetylidene Lithiums 0.32
Synthesis of (S)-Finerenone via Late-Stage Asymmetric Transfer Hydrogenation 0.50
Photoredox-Catalyzed Modular Synthesis of ε-Lactams via Acrylamides Cyclization Enabled by Radical-Polar Crossover-Mediated Carbanion Trapping 0.73
Biosynthesis of the l-Pyridylalanine Moiety in Antimycobacterial Pyridomycin via a PKS-NRPS Hybrid System 0.14
Cobalt-Catalyzed Intramolecular Dearomative Alkylation of Phenols with Alkenes 0.10
R3P/ICH2CH2I-Promoted Skeletal Editing of Cyclic Ethers via O/N Exchange 0.10
Construction of PROTAC Library via Liquid-Phase Synthesis Enabled by a Hydrophobic Tag 0.54
Cu-Catalyzed Atroposelective Protoboration of Allenes to Access Stereodefined Tetrasubstituted Axially Chiral Alkenylboronates 0.09
Biomimetic Iron-Catalyzed Oxidation of 3-Substituted Indoles to 2-Oxindoles 0.29
Asymmetric Synthesis of 2,2-Disubstituted Dihydroquinolines via Rhodium-Catalyzed Dearomative Arylation and Alkenylation of 2-Substituted Quinolinium Salts 0.72
Hyperacmoses A–C, Three Seco-Norpolyprenylated Acylphloroglucinols from Hypericum acmosepalum with Lipid-Lowering Activity 0.04
Chlorjaponoids A and B, Two Lindenane–Guaiane Sesquiterpenoid Dimers with a Cage-like Tetracyclo[8.5.0.02,7.03,13]pentadecane Scaffold from Chloranthus japonicus 0.58
Polycyclic Limonoids as Potential Nrf2 Inducers from Trichilia connaroides 0.05
Asymmetric Synthesis of cis-3α-Aryloctahydroindole Alkaloids by Ene-Reductase Dehydrocyclization 0.93
Copper-Catalyzed [3+3] Cycloaddition of Ethynyl Methylene Cyclic Carbamates with N,N′-Cyclic Azomethine Imines Enabled by an Extended C═C Bond 0.75
Divergent Access to α,β-Unsaturated Thiolated and Selenolated Lactams via a Unified Palladium-Catalyzed Carbonylative Transformation 0.17
Pentafluoroethyl Sulfoximine Reagent for the Photocatalytic Pentafluoroethylation–Difunctionalization of Styrene Derivatives 0.02
Cα-Umpolung of Amides Strategy for Enantioselective Propargylic Amination toward Cα-Tetrasubstituted α-Amino Acid Derivatives 0.12
Visible Light-Promoted Thiobenzoic Acid-Catalyzed Deuteration of Alkylamines and Alkylarenes 0.50
Minisci-Type C–H Methylation and Silylation of Heteroarenes with Visible Light and N-Fluorobenzenesulfonimide 0.10
Site-Selective Azidation of Arenes via Hypervalent Iodine-Mediated C–H Functionalization 0.19
Developing Nitrogen-Rich High-Energy Initiating Materials: Integration of Azidotetrazole into a Heterocycle via a Two-Step Approach 0.06
(CF3S)2C═S: Electrophilic Site at the Thiocarbonyl Sulfur for the Incorporation of Multiple CF3S Groups 0.11
Photoredox-Catalyzed Defluorinative [4 + 2] Cycloaddition of α-Fluoro-β-keto Esters and Alkynes by Single Photosensitizer 0.07
Phosphorothiolation of Benzylic C(sp3)–H via EnT-Mediated Radical–Radical Cross-Coupling 0.10
Radical-Polar Crossover Enabled Photoredox 1,2-Carbosulfinylation of Alkenes with N-Sulfinyltritylamine 0.05
Access to Five-Membered Silacycles via Pd-Catalyzed Heck-Type Coupling with Arylthianthrenium Salts 0.69
Cu-Catalyzed Highly Selective Ritter-Type Reaction of Enaminonitriles with Cycloketoxime Esters: A Direct Route to Diverse α-Tertiary Amines 0.52
Copper-Catalyzed Three-Component Radical 1,2-Carboazidation of 1,3-Dienes 0.17
Biomimetic Total Synthesis of Dispirocochlearoids A–C and Related Ganoderma Meroterpenoid Dimers 0.10
Copper-Mediated Oxidative Chloro- and Bromodifluoromethylation of Aliphatic Alcohols 0.13
Synthesis of (Hetero)aryl Fused 4H-Quinolizin-4-ones from N-Ts Substituted (Hetero)arylamides and Pyridotriazoles 0.14
Assembly of α-Aryl Sulfones and Allyl Sulfones and Their Amide Analogues via Copper-Catalyzed Coupling Reactions 0.25
Phosphine-Catalyzed Allylic Fluorides Addition to gem-Difluoroalkenes 0.10
Copper-Catalyzed Sulfinylation of Boronic Acids with Sulfinates 0.05
Synthesis of β-Amino-α-iminonitriles and α,β-Diiminonitriles Enabled by Lewis Acid-Catalyzed Double Isocyanide Insertion with Imines 0.13
Visible-Light-Driven C(sp3)–H Bond Carboxylation of Benzyl Amines with CO2 for the Synthesis of α-Amino Acids 0.17
Photoredox-Mediated C–N Bond Cleavage Enables Synthesis of Tetra-Substituted Olefins via Reductive Radical-Polar Crossover 0.32
Photocatalytic Cascade Reaction of Allylamines for the Synthesis of Ester-Containing Imidazolines and Oxazolidines 0.11
Pd-Catalyzed Fluorocarbonylation of Iodoarenes with Difluoromethyl Benzoates 0.13
Visible-Light-Induced Organobismuth(III)-Initiated Halogen-Atom Transfer for the Alkylation of Heterocycles with Unactivated Alkyl Iodides 0.06
Dual-Co/Ni-Catalyzed Radical Hydroarylation of 1,3-Enynes: Selective Access to Tetrasubstituted Allenes 0.08
Modular Amide Synthesis via Dual C–O and N–O Bond Cleavage: Palladium-Catalyzed Deoxygenative Carbonylation of Benzyl Alcohols with Nitroarenes 0.14
Photoredox Fe-Catalyzed Truce–Smiles Rearrangement of N-Arylsulfonyl Acrylamides with Aliphatic Carboxylic Acids 0.13
Cobalt-Catalyzed Chemo-, Regio-, Diastereo-, and Enantioselective Cascade Coupling of 1,1-Disubstituted Allenes and Aldehydes 0.66
HPLC–UV-Guided Discovery of Eurotamines A–F: Six Pairs of Isoquinoline Derivative Enantiomers from Marine-Derived Fungus Eurotium sp. SCSIO F452 0.42
Palladium-Catalyzed Cyclization of N-(2-Iodoaryl)-N-methylbenzenesulfonamide with Aryl Iodides to Access Phenanthridine Derivatives 0.11
A Macrocyclic Arene Derived from Pagoda[4]arene: Cavity Reshaping, Complexation with Neutral Guests, and CPL Property 0.20
Palladium-Catalyzed Ring Opening of Vinyl Oxetanes Enables Asymmetric Dearomative [6 + 2] Cycloaddition of 3-Nitroindoles to Access Indoline-Fused Oxa-Eight-Membered Rings 0.10
Copper-Catalyzed Diastereoselective Defluoroborylation of Pentafluoroethyl Alkenes Using (pin)B–B(dan) 0.08
Cobalt-Catalyzed Methylselenation of Boronic Reagents with PhSO2SeCH3 0.03
Synthesis of α-Substituted β,γ-Unsaturated Cyclobutanecarboxamides via Palladium-Catalyzed Aminocarbonylation of Vinylcyclobutanols 0.25
Deaminative Functionalization of Olefins and Dienes with Katritzky Salts: A Highly Selective Route to Diverse Deuterium-Labeled Molecules 0.41
Synthesis of 3-Alkenyl Isoquinolines through Redox-Neutral C–H Annulation of Oximes with Alkylacetylenes followed by Dehydrogenation 0.43
Dual-Copper-Catalyzed Enantioselective Decarboxylative [2 + 3] Cycloaddition of Ethynyl Cyclic Carbamates/Carbonates with 4-Hydroxycoumarins 0.06
Chemoenzymatic Decarboxylative Bromination of Acetylenic Acids Using Vanadium-Dependent Chloroperoxidase 0.33
Distahlianins A–C: Architecturally Diverse Cadinane-Type Sesquiterpenoid Dimers from Stahlianthus involucratus 0.63
Palladium-Catalyzed Suzuki–Miyaura Couplings of Glycal Boronates with Aryl Thianthrenium Salts for the Synthesis of C-Aryl Glycals 0.24
Copper-Catalyzed Coupling of N-Acyl-N′-Substituted Hydrazines with (Hetero)aryl Chlorides/Bromides 0.50
Enantioselective Total Synthesis of (+)-Lucidumone via Organocatalytic Double Michael Addition 0.75
A Design for Achieving Robustness in Molecular Machines Based on Self-Assembled Pyrene Cavitands 0.05
Manganese-Catalyzed Asymmetric Hydrogenation of Multi-Nitrogen Heteroaromatic Compounds 0.92
Effects of π-Extended Aromatic Fragments on Tris(hexa-peri-hexabenzocoronenyl)methyl Radical and Cation: Synthesis, Radical Transformation, and Reactivity Insights 0.45
Palladium-Catalyzed Allylic C–F Bond Functionalization of Pentafluoroethyl Alkenes with Heteroatom Nucleophiles 0.08
Nickel-Catalyzed Carbonylative Cyclization of Bromodifluoroacetamides with Arylboronic Acids toward δ-Lactams 0.10
Iron-Catalyzed Radical Addition Reaction of Dehydroglycine with Aliphatic Carboxylic Acids 0.07
Oxidative Chloro- and Bromodifluoromethylation of Thiophenols 0.13
Copper-Catalyzed Enantioselective Reduction of Biaryl Dialdehydes via Bora-Brook Rearrangement 0.73
Radical 1,2-Boron Shift-Enabled Synthesis of β-Thioalkylboronic Esters from β-Boryl NHPI Esters 0.03
On-DNA Synthesis of Privileged Dihydropteridinones via Diboron-Mediated Cyclizations 0.39
Palladium-Catalyzed Carbonylative Fluoroalkylation of 1,3-Enynes to Access Allenyl Primary Amides 0.46
Formal α-Nucleophilic Addition to Electron-Deficient Alkenes by Photoredox and Copper Dual Catalysis 0.07
Rhodium-Catalyzed [3 + 1 + 2] Cycloaddition of Type II Diene-Vinylcyclopropanes and Carbon Monoxide for the Synthesis of 5/6 Skeletons with Two Adjacent Bridgehead Quaternary Centers 0.50
Nickel-Catalyzed Umpolung Allylation of Imines with Allylic Alcohols 0.47
An iS/isub4/sub-Symmetrical Multi-Macrocyclic Nanohoop Derived from a 1,3-Alternate Calix[4]arene Core 0.50
Rh(III)-Catalyzed Direct C–H Selenylation/Cyclization of Benzylamines with Elemental Selenium for the Rapid Construction of Benzoisoselenazole Frameworks 0.50
Palladium-Catalyzed Intermolecular Tandem Difunctional Carbonylation of 1,3-Enynes: Synthesis of Fluoroalkylated Butenolides 0.46
Synthesis of Azuleno[1,2,3-cd]phenalene and Its π-Extended Buckybowl Derivative 0.03
Ligand-Controlled Acyl and Decarbonylative Sonogashira Cross-Coupling of α,β-Unsaturated Thioesters 0.63
Rh(III)-Catalyzed Atroposelective C–H Cyanation of 1-Aryl benzo[h]isoquinolines 1.00
Telescoping Synthesis of γ-Lactone-Fused Indanones via C–H Activation and Rearrangement-Cyclization 1.00
Elucidation of Acetyl-Branched Sugar Pathway in Type II Polyketide Biosynthesis via One-Pot Enzymatic Synthesis 0.88
Palladium-Catalyzed Selenylative Alkoxycarbonylation of Alkynes toward β-Selenated Cinnamic Acid Esters 0.17
Late-Stage Aryl C–H Bond Carboxylation with CO2 via Combining Metal-Free C–H Bond Borylation and ZnEt2-Promoted C–B Bond Carboxylation 0.08
Isodesmic C(sp2)–H Iodination of 2-Phenethylamines Directed by Native Primary Amino Groups 0.50
Copper-Catalyzed Formal C(sp3)–H Insertions via 1,5-Diyne Cyclization Triggered by a 1,6-Hydride Shift 0.03
Hupserrine A, a Caged Lycopodium Alkaloid with a 6/6/5/6/7 Pentacyclic Skeleton from Huperzia serrata 0.86
Catalytic Quantities of Inorganic Salt Promote an Electron Donor–Acceptor Complex to Achieve Defluorinated Cycloaddition 0.04
Iron-Catalyzed Reductive Carboxylation of Arenes with CO2 via Thianthrenium Salts 0.10
Site-Selective α-Alkoxylation of Iodonium Ylides with Alcohols via Ruthenium Catalysis 0.53
Visible Light-Promoted Construction of Cage-Like Frameworks by Sequential [2 + 2] Cycloaddition 0.07
Iron Photocatalysis Enabling Decarboxylative Bromination of (Hetero)Aryl Carboxylic Acids 0.50
Photocatalytic Functionalization of Olefins with Triaryl Phosphine and Dibenzyl Sulfoxide: Preparation of Tertiary Phosphine Oxide 0.79
Copper-Promoted Reductive Cross-Coupling for Cyanodifluoromethylation of (Hetero)aryl Iodides with BrCFsub2/subCN 0.12
Synthesis of Perfluoro-itert/i-butyl Triazoles via Decarboxylative CuAAC of (Perfluoro-itert/i-butyl)propiolic Acid with Azides 0.10
Chromium(II)-Catalyzed Decarboxylative Alkyl Acylation under Visible Light Irradiation 0.25
Catalyst- and Base-Free Synthesis of Pyridine-Fused Uracils from 6-Methyluracils, Aldehydes, and Ammonium Iodide via a One-Pot Multicomponent Reaction 0.03
Palladium-Catalyzed Regio- and Monoselective B(2)–H Alkylation of Zwitterionic nido-Carboranes at Room Temperature in Water 0.05
Triconnarins A–D: Four Secophragmalin-Type Limonoids from the Twigs and Leaves of iTrichilia connaroides/i 0.06
Late-Stage Oxime iO/i-Glycosylation with Unprotected Glycosyl Fluorides 0.17
Ascomycotols A–C: Rare Sulfur/Sulfone-Containing Scaffolds from Mushroom Endophytes with Dual Anti-inflammatory and Antirenal Fibrosis Effects 0.08
Electrochemical Synthesis of β-Keto Phosphorodithioates via Difunctionalization of Alkenes under Metal-Free Conditions 0.02
Mild Lewis-Acid-Promoted Cysteine–Tryptophan Conjugation Involving a Radical Process 0.07
Sorbicillalanines A and B, Two [6,5,6] Hybrid-Sorbicillinoid Alkaloids from Deep-Sea-Derived Penicillium sp. Co-Cultured with Sponge-Derived Setosphaeria sp. 0.78
Traceless Aminoalkyl Radical-Induced Halogen-Atom Transfer for Minisci Reactions 0.50
A Unified Strategy for Transition-Metal-Free Synthesis of Benzothienopyridines, Benzoselenopyridines, and Benzotelluropyridines and Related Analogues 0.19
Identification of a Privileged Scaffold for Induction of Lysosomal Biogenesis through Synthesis of the Scaffold of Cipadonoid A 0.33
Steric Gating of Excited-State Channel: Controllable AIE/RTP Switching through Tuning π-Bond Twisting 0.56
Dipolar Cycloaddition Approach toward Harmicine-Type Alkaloids: Synthesis and Stereochemical Determination 0.33
2 0.61
<atl>Multi‐Omics Insights Into Anthraquinone Biosynthesis in iRheum tanguticum/i</atl> 0.48
Unveiling the catalytical roles of three glycosyltransferases in triterpenoid saponins in quinoa 0.13
5 1.45
A ribosomally synthesized and posttranslationally modified peptide with ADP-ribosylation 0.10
A balance between glycitein and glyceollins governed by isoflavone 6-hydroxylase confers soybean resistance to Phytophthora sojae 0.57
Living/controlled supramolecular protein polymerization 0.09
Characterization of SrUGT76G4 reveals a key residue for regioselectivity and efficient Reb M synthesis 0.61
Thioether editing generally increases the photostability of rhodamine dyes on self-labeling tags 0.08
3 0.38
Divergent and consecutive skeletal editing of saturated primary amines 0.13
Engineered aldehyde dehydrogenases for amide bond formation 0.23
Integrated low-temperature PVC and polyolefin upgrading 0.03
4 1.67
Synergy of liberated anions and intense electric field in frustrated ion pairs for enhancing CO2 cycloaddition 0.20
A dual role of Arabidopsis PAL nuclear localization in fine tuning flavonoid biosynthesis 0.69
Photoredox-controlled chemo-divergent, regio-, and stereoselective difunctionalization of olefins via switchable SO2 reintegration 0.06
Molecular basis of very-long-chain fatty acid elongation by the CER6-GL2 enzyme complex in plant wax biosynthesis 0.71
2 0.53
Vibrational Control of Spin–Orbit Coupling Enhances Triplet–Triplet Annihilation Upconversion Efficiency 0.50
Intrinsic Spin Effect beyond Aqueous Systems: Selectivity Control in Organic Electrochemistry via Spin-Polarized Radical Intermediates 0.03
1 0.71
The deubiquitinase UBP15 and the E3 ubiquitin ligase PUB17 coordinate GLK1 stability in apple anthocyanin deposition 0.71
3 1.39
Unraveling the phototransformation of 2,4,6-tribromophenol: Aqueous mechanisms involving ·OH and the emergence of hydroxylated PBDEs 0.78
Thermal Stimulation Unlocks Ligand-Dependent Selective Pathways in Cu(II)/PMS Oxidation of Recalcitrant Phosphonates 0.14
Photoinduced thiol formation in dissolved organic matter: The role of sulfur-containing precursor and source of electron 0.47

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