Organic Chemistry articles for Japan

Time frame: 1 June 2025 - 30 May 2026

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Count: 438

Article ‘Count’ for Organic Chemistry.

Journal Count Share
1 1.00
Molecular-Scale Memory Generated by Liquid-Like Spins in On-Surface Synthesized Nanoclusters 1.00
1 0.40
Deep Eutectic Solvents Formed by Complex Hydrides: A New Class of Hydrogen‐Rich Liquid 0.40
1 1.00
Evaluation of Intermolecular Interactions in HPLC Using Deuterated Mobile Phases 1.00
59 45.51
Enantioselective Total Syntheses of Bisleuconothine A and Bousigonine B 1.00
A Mononuclear Ruthenium(V)-Imido Complex With Hydrogen Bonding in the Second Coordination Sphere Forming Aziridines Without N-Substituents From Alkenes in Water 1.00
Biobased Cyclic Enoate Monomers: Enabling Intrinsically Crystalline, Chemically Recyclable, Ultratough Polymers 0.13
Monoselective Mechanochemical Aromatic Nucleophilic Substitution Enabled by Crystal‐Engineering‐Guided Reaction Design 1.00
Azide‐to‐Diazo Transformation Facilitated by Michael Addition via Phosphazide Formation 1.00
Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin 1.00
Tandem Reactivity of Metal−Carbon and Carbon−Silicon Bonds in Mononuclear α-Silyl Organolithium or Organosodium Complexes Towards CO, CO2 and Heteroallenes 0.22
Aqueous Upcycling of Polyethylene Furanoate From Mixed Plastic Feeds Into Metal-Organic Frameworks 0.15
Regioselective Synthesis of Benzylsilanols from Kobayashi-Type Reagents via C(sp3)─H Bond Activating 1,4-Palladium Migration 1.00
RaPID Selection of Backbone Macrocyclic Peptides Targeting Akt2 1.00
Spin‐Correlated Luminescence of Mechanically Generated Radical Species 1.00
Azetidinylideneketenimines as a Multimodal Synthetic Platform: Coordination Chemistry and Cycloaddition-Triggered Transformations 1.00
Ligand-Intercalated MOFs Enable Reaction-Pathway Engineering in Biomass Electrooxidation via Steric and π-Electronic Microenvironment Control 0.19
Acetal[6]Arenes: Rigid Chirality-on-Annulus Macrocycles Promoting Charge-Transfer Co-Assembly With Exceptional (Chiro)Optical Properties 0.09
Pillar[6]arene Assemblies With Continuous Hydrophobic Grooves for Capture of π-Conjugated Molecules 1.00
Conformationally Driven Dual Fluorescence Properties of Higher Heteroacenes With Periodically Incorporated Boron Atoms 1.00
Domino Polymerization for the Synthesis of Reductively Degradable Poly(disulfide)s With Arbitrary Side-Chain Structures 1.00
Photoinduced Generation of (Boryl)Silyl and (Chloro)Silyl Radicals: Access to Trisubstituted Silylboranes and Chlorosilanes 1.00
Biosynthesis of Kaitocephalin: A Neuroprotective Natural Product Featuring a Peptide‐Like yet Nonpeptidic Scaffold 1.00
Magnesiation of Phenol Derivatives Catalyzed by a Rhodium─Aluminum Complex 1.00
Temperature‐Responsive Near‐Infrared Emission Enabled by Reversible π‐Umpolung with an Alkenyl‐Strapped Diarylboryl Unit 1.00
Long‐Wavelength Light‐Induced Group 13–15 Elementalization Reactions of Alkenes/Alkynes 1.00
Total Synthesis of (±)-Cristaxenicin A: Construction of Nine-Membered Ring by Eschenmoser–Claisen/Cope Rearrangement Cascade 1.00
Hybridized Host Functions in Polyaromatic Tube-in-Capsule Composites 1.00
Divergent Total Synthesis of Denudatine Alkaloids Cochlearenine, Macrocentrine, Dictizine, 15‐Veratroyl‐17‐Acetyl‐19‐Oxodictizine, and the Proposed Structure of Acochlearine 1.00
Electron‐Enriched Pt‐In Synergistic Sites for Highly Selective and Direct Photo‐Reforming of PET Plastic Wastes into Acetic Acid 0.25
Reaction of Blatter and Verdazyl Radicals with Arynes: Synthesis and Investigation of N‐Chiral, Antiaromatic Triazines, and Tetrazinones 0.25
Emergent Chemical Reactivity and Complexity of RNA Condensates 0.60
Iron/NHC-Catalyzed Regio- and Stereoselective 1,6-Additions of Aliphatic Grignard Reagents to α,β,γ,δ-Unsaturated Carbonyl Compounds: Asymmetric Variants with Chiral NHCs 1.00
Revealing Pathway Complexity in Host–Guest Binding: Allosteric Regulation and Temporal Chiral Inversion During Complexation of Naphtho[2,2]urils 0.13
Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling 0.05
[3]CycloBODIPY: A Highly Strained Cyclic BODIPY Trimer with Effective Macrocyclic Conjugation 1.00
Nor[7]circulenyl Neutral Radical and Its Charged Species: Synthesis, Structures, and Efficient NIR-II Photothermal Conversion for Imaging and Laser Ignition 0.20
Amine‐Ligated Boryl Radicals Enables Direct C─F Borylation and Cross‐Couplings of Polyfluoroarenes 0.78
Rapid Construction of a Tyr C6–Trp C5′ Linkage: Application in the Total Synthesis of Micitide 982, a Noncanonical Cyclic Peptide 0.20
Total Synthesis of Calyciphylline F 1.00
Photocatalyzed Synthesis of Unsymmetrical Alkylphosphorus(V) Compounds Using Imidazolium Phosphonites 1.00
Multipoint Coordinative Capture of Olefinic Substrates Utilizing Metal‐Carbon Bonds by Macrocyclic Complex 1.00
Twelvefold Dearomative Esterification of (6,6)Carbon Nanobelt 0.79
Radical Ring‐Opening Reaction of Non‐Activated Oximes Catalyzed by Aldoxime Dehydratases 1.00
Introducing Steric Bulk Into Silylboranes: Enhanced Bench Stability and Novel Chemical Reactivity 1.00
Regiodivergent Photocatalytic Annulation for the Synthesis of igem/i‐Difluorinated Cyclic Hydrocarbons 0.78
Mechanoactivated Celite as a Catalyst for C‒H Bond Perfluoroalkylation and Other Radical Reactions 1.00
Formal Cyclopropylation of Imines with Cyclopropanols: Stereocontrolled Access to Conformationally Constrained γ‐Amino Alcohols 1.00
Liquid Coordination Polymers with Anhydrous Proton Conductivity 0.88
Organophotoredox‐Catalyzed Postfunctionalization of Poly(methacrylate) Derivatives via Radical–Polar Crossover Phosphonylation 1.00
Total Synthesis of Isodaphlongamine H by Iridium‐Catalyzed Reductive [3 + 2] Cycloaddition of iN‐/iHydroxylactam 1.00
Phenacetin[3]Arenes: Mannich‐Type Macrocyclization, Unique Structure, Versatile Functionalization, and Strong Allosteric Binding 0.11
Rhodium/Indium Heterobimetallic Alloy as an Effective Catalyst for Reductive C(spsup3/sup)─O Silylation of Ethers with Chlorosilanes 1.00
On‐Surface Synthesis of Nanographenes Through Domino Cyclization Reactions 0.43
Hyperpolarization Modulation of the T‐Type hCasubv/sub3.2 Channel by Human Synenkephalin [1–53], a Shrew Neurotoxin Analogue without Paralytic Effects 1.00
Development of a Vinylated Cyclic Allene: A Fleeting Strained Diene for the Diels–Alder Reaction 1.00
A Polyaromatic Metallotube With a Dual Multi‐Functionalization Ability 1.00
Metal Synergistic Dual Activation Enables Efficient Transesterification by Multinuclear Titanium Catalyst: Recycling and Upcycling of Polyester Waste 0.17
Mixing and Matching of Hybrid Megasynthases is a Hub for the Evolution of Metabolic Diversity in Cyanobacteria 0.29
Mixed‐Metal Ce‐Zr‐Mn Clusters as Photo‐Catalysts for Decarboxylative Functionalization of Carboxylic Acids 1.00
Self‐Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C─F and C─O Bond Cleavage 0.83
Remote Silyl Groups Enhance Hydrolytic Stability and Photocleavage Efficiency in Carbamates for Protein Release 1.00
Asymmetric Synthesis of Noradamantane Scaffolds via Diphenylprolinol Silyl Ether‐Mediated Domino Michael/Epimerization/Michael (or Aldol)/1,2‐Addition Reactions 1.00
1 0.06
Pan-modification profiling facilitates a cross-evolutionary dissection of the thermoregulated ribosomal epitranscriptome 0.06
57 54.00
Supramolecular catalysis by the inside of a bowl-type dodecavanadate for cyanamide dimerization 0.83
Selective ammonia sensing through reversible vapochromism and luminescence ON–OFF switching of a chalcone-based Co(ii) complex 1.00
Upcycling disposed sunscreen waste into supported catalysts for environmental purification 1.00
Nitrogen editing of aromatic rings: from skeletal editing to fragment editing 1.00
Thiosulfonate synthesis via halothiolation of aryne intermediates followed by oxidative S-sulfonylation 1.00
Ring expansion of benzocyclobutenols toward benzo[b]furans 1.00
meso-Substitution controlled synthesis of BODIPY-DPM conjugates: a pathway to tailored photophysical properties 0.25
Regio- and diastereoselective synthesis of multi-substituted silacyclopentanes by catalytic cyclosilylborylation of styryl(vinyl)silanes 1.00
Desaturative arylaldehyde synthesis by synergistic carbocatalysis and organocatalysis 0.21
Nonenzymatic carbamoylation and phosphorylation via urea nitrosylation under mild aqueous conditions 1.00
Flow-driven non-covalent synthesis 1.00
Facile generation and reaction of densely trifluoromethylated alkyl radicals by dual photoredox and acid catalysis 1.00
π-Stacked dimerization of an antiaromatic homoHPHAC monocation 1.00
Opposite enantioselectivities displayed by supramolecular helical catalysts with non-enantiomeric “sergeants” 0.29
Unveiling a host–guest assembly composed of an emissive Ir(iii) complex salt and a concave aromatic host at a local minimum state 1.00
Cationic iridium-catalyzed enantioselective decarboxylative aryl addition of aromatic carboxylic acids to bicyclic alkenes 1.00
Visible-light-induced upcycling of perchloroethylene into trichloroacetamides using chlorine dioxide 1.00
Selective nucleophilic addition of aryllithium reagents to α-ketonitriles giving ketones under microflow conditions 1.00
Potassium-ion-responsive chiral supramolecular hydrogels exhibiting long-range chirality transfer from d- or l-alanine to achiral frameworks 1.00
Nitrogen-centred helical acridiniums with a 6–7–6–6 fused ring skeleton 1.00
Dual pharmacokinetic modifier strategy for synergistically enhanced tumor accumulation of PSMA-targeting radioligand 1.00
Gate-opening cooperative methanol binding to multi-bladed benzenes bearing 1,2-diboryl functionality 1.00
One-pot asymmetric sulfoxidation using in situ generated H2O2 from H2 and O2 catalyzed by rhodium and vanadium complexes 1.00
Dynamic regulation of nucleic acid replication beyond the Watson–Crick base-pairing rule 1.00
Chirality amplification step of temperature cycle-induced deracemization 1.00
Pd-catalyzed acceptorless dehydrogenative aromatization of cyclohexyl rings via benzylic C–H bond activation 1.00
Transition-metal–free borylative functionalization of aryl fluorides with boron alkoxide in the presence of sodium dispersion 1.00
A novel bivalent albumin binder for enhanced tumor retention of a fibroblast activation protein-targeted radioligand 1.00
Triplet nitrene-mediated photocatalytic azidation of tertiary C(sp3)–H bonds 1.00
Size-selective formation of metallonanobelts via tethering-template-directed self-assembly 1.00
The direct photochemical cross-esterification of alcohols via site-selective C–H bromination 1.00
Synthesis of [1,3]-thiasilolanes via rare-earth-catalysed intramolecular α-C(sp3)–H silylation of alkyl sulphides with hydrosilanes 0.42
Seeded control of symmetry-directed diverse chiral π-stacked benzothiadiazole assemblies with leucine-based diamide units 1.00
Generation of alkyl radicals via C(sp3)–C(sp3) bond cleavage of xanthene-based precursors for photocatalytic Giese-type reaction 1.00
Non-covalent interaction-controlled site-selective benzylic C(sp3)–H oxidation 1.00
Iminophosphonamido stannylenes enable quantitative CO2 conversion to isocyanates 1.00
Multistage control of near-infrared and magnetic properties via π-dimer modulation in TCNQ radical anion salts 1.00
Covalently linked triarylborane–iridium(iii) complex as a photocatalyst for CO2 reduction 1.00
Visible-light-driven borylation and phosphorylation of aryl halides by phosphonium ylide organophotoredox catalysis 1.00
Utilizing an elemental sulfur and molecular hydrogen combination: cobalt silicate-catalyzed thiol synthesis from carbonyls 1.00
Se-Aryl-N-phenylphenoselenazinium salts: aryl radical precursors incorporating a photosensitizer unit 1.00
Photocatalytic Shono-type oxidation of iN/i-alkylamides with hydrogen evolution 1.00
Redox-associated phase transition of a marginally stable synthetic polymer 1.00
Phthalimide: a potential warhead for switchable and bioorthogonal conjugation 1.00
Dimeric boron complexes bearing isoquinolyl-pyrrole ligands 1.00
Unveiled open-shell nature of an antiaromatic molecule by surface–molecule interaction: a concept suggestion by spin-projected density functional theory 1.00
Twisting of aryl groups affects thermal back reactivity of diarylbenzene photoswitches 1.00
Spiro-fluorene-indenoindenyl-Ir(scpi/scp) complex-catalyzed, 1,3-azole-directed C(spsup3/sup)–H borylation with pinacolborane 1.00
Revisiting 3-azidoindoles: overcoming the trade-off challenges between stability and reactivity of iin situ/i-generated azidoindoles 1.00
Macrocyclic skeletal modification approach to the anti-trypanosomal macrolides, actinoallolides 1.00
Pseudorotaxane monolayers of pillar[5]arene and linear fatty acids at the air–water interface 1.00
C–H bond activation of fluorene over a TiOsub2/sub photocatalyst by ligand-to-metal charge transfer under visible light irradiation 1.00
Visible-light-induced radical switching using benzothiazolyl sulfides for geminal carbon–carbon bond formation 1.00
Unexpected cyclization of β-(hydroxymethyl)phosphole into 1-phospha-1,6a-dihydrophosphapentalene: a fused 1,3-butadiene-based luminophore 1.00
Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions 1.00
Conversion of simple alkenes into 1H-1,2,3-triazolium salts by oxidative cycloaddition and subsequent dehydrogenation 1.00
Arylative double bond transposition of allylic alcohols ivia/i silicon-tethered intramolecular benzyne–ene reactions 1.00
35 30.31
Near-infrared (NIR)-responsive activation of Ru-benziphthalocyanine complexes via singlet–triplet transition 1.00
Tris((4-BMes2)phenyl)methanide: a carbanion with a delocalised triple quinoidal structure 0.17
Electrolyte-anion-controlled reactivity of aromatic radical cations 1.00
Peptide–based artificial cytoskeleton enhances colocalized cascade reactions in cell-like microreactors 0.10
Acridinium amidate as a hydrogen-bonding photocatalyst for direct decarboxylative alkylation of native carboxylic acids 1.00
High brightness in bis(tri-isopropylsilyl)ethynyl-functionalized polycyclic aromatic hydrocarbons: localized representation versus Clar's model 0.33
Self-induced charge transfer activation enables metal-free C–H coupling of polycyclic aromatic hydrocarbons under photo irradiation 1.00
Photocatalytic CO2 reduction using a diazabenzacenaphthenium photosensitizer and a Mn catalyst 1.00
Bead mill-driven acceleration in catalytic methanolysis reaction of poly(ethylene terephthalate) toward low-energy chemical recycling of polymers 1.00
L-region-selective annulative π-extension through dearomative activation of polycyclic aromatic hydrocarbons 1.00
Guest-induced emission enhancement in the permanent porous conjugated carboracycle crystal 1.00
Characterization of the ketoreductase domain of pikromycin module 2 1.00
Visible photon energy storage by [2+2] cycloaddition of Pd-oxazolones 0.13
Modular synthesis of benzothiophene-fused pentalenes reveals substituent-dependent antiaromaticity 1.00
Se-catalyzed enantioselective lactamization enabled by a N-fluorosulfonyl group: total synthesis of diaporisoindole A 1.00
Interfacial photocycloaddition polymerization: a synthetic approach for structurally functionalized degradable polymer particles from naturally derived monomers 1.00
Photoredox catalysed reductive cleavage of dibenzothiophene dioxides enabled by a temperature-controlled photoreactor 0.50
Compositional selection of phospholipid compartments in icy environments drives the enrichment of encapsulated genetic information 1.00
Synthesis of wave-shaped Cu(ii) porphyrin arrays and their electrocatalytic hydrogen evolution activity 0.23
A neutral homoaromatic heavy allene as a platform for selective conversion to a germylene-coordinated digermavinylidene 1.00
<atl>Nickel-catalyzed decarbonylative addition of acylsilanes across alkynes ivia/i the cleavage of a carbon–silicon bond</atl> 1.00
High-valent sulfur fluorides as reactivity switches for PFAS-free benzene–azepine skeletal editing 0.86
Synthesis of dibenzoarsole derivatives from biarylborates via the twofold formation of C–As bonds using arsenium dication equivalents 1.00
One-pot synthesis of sequence-controlled macromonomers via living anionic addition reaction and subsequent acyclic diene metathesis polymerization 1.00
Chemoselective Cu-catalyzed acylsilylation of vinyl arenes using silylboronates and acyl fluorides 1.00
Noncovalent immobilization of chiral Lewis acids on single-walled carbon nanotubes as a tool for synthetic organic aquachemistry 1.00
Versatile method for the synthesis of aminobenziodoxolones and its application to one-pot coupling of arylboronic acids with simple amines 1.00
Spontaneous chiral symmetry breaking in a single crystal 1.00
Dimerization of pillar[5]arene: length-adaptive encapsulation of long-chain guests 1.00
A unified approach to highly functionalized clovane-type terpenoids: enantiocontrolled total synthesis of rumphellclovane E and sarinfacetamides A and B 1.00
Difluoroenol phosphinates as difluoroenolate surrogates: synthesis and applications in defluorination and deoxygenative coupling 1.00
Copper-catalyzed direct regioselective C5–H alkylation reactions of functionalized indoles with α-diazomalonates 1.00
A mechanochemical [2+2+2] cycloaddition facilitated by a cobalt(scpii/scp) catalyst and piezoelectric materials 1.00
Metal-catalyzed methylthiolation of chloroarenes and diverse aryl electrophiles 1.00
iso-TEtraQuinoline (i-TEQ): an inherently chiral N4 macrocyclic quinoline tetramer 1.00
1 0.83
Performance Evaluation of Tetrabutylphosphonium Trifluoroacetate Ionic Liquid-Water Solution as Refrigerant for Adsorption Refrigeration in Chilled Storage Applications 0.83
9 6.07
Design, Synthesis, and Evaluation of an Ammonium-Terminated Superchaotropic Boron Cluster: Effects on the Transmembrane Delivery of Neutral and Charged Cargos 0.67
Stable Au(III) Benzohomoporphyrin: Synthesis, Structure, Near-Infrared Absorption, and Superoxide Radical Generation 0.23
Singlet–Triplet Transitions in the Dianionic Complex of Fullerene C60 with Iron Carbonyl: (TBA+)2{[Fe2(CO)6]-η2,η2-C60}2– 0.29
Figure-Eight Macrocyclic Salen Dimers Synthesized from ortho-Phenylene-Bridged Bissalicylaldehyde 1.00
Visible–NIR Photodynamic and Photothermal Mono- and Bis-Rhodium(I) Complexes of a Pyrrole-Appended N-Confused Porphyrin 0.14
Induction of Platinum(II) Coordination-Bonded Network Formation in Coacervates of Single-Stranded DNAs 1.00
Modification of Alkylpyridine Ligands in the Reactions of Osmium(III) Complexes with Anions 1.00
Ambident Reactivity of (Selenocarbamoyl)Phosphines: Transformation into a Crystalline (Phosphino)(Seleno)Iminium Salt and Transition-Metal Complexes 1.00
Activation of C(sp2)–X and C(sp3)–X σ-Bonds (X = F, Cl, Br, and OMe) by Rhodium Complex with Pincer-Type Aluminyl Ligands: Theoretical Insight into High Reactivity and Flexible Reaction Mechanism 0.75
1 1.00
Conceptual process design-based solvent selection: Optimization of solvent combinations with application to Suzuki–Miyaura coupling 1.00
1 1.00
CaMKII drives synaptic maturation by coordinating spine remodeling and receptor segregation via liquid-liquid phase separation 1.00
70 58.44
Beyond Passive Substituents: Tosyl-Directed Self-Templation Enables Selective Pillar[4 + 1]arene Formation and Topology Switching 0.22
Host–Guest Complexation through Geometric Self-Optimization in [12]Cycloparaphenylene 1.00
Breaking the Immiscibility Barrier: A Mechanochemical Approach to Enable the Direct Glycosylation of Native Sugars with Hydrophobic Aliphatic Alcohols 1.00
One-Shot Carbon Insertion Unlocks Polycyclic Frameworks and Near-Infrared Photocatalysts 1.00
Controlled Pyrolysis of Polystyrene Using Metal–Organic Frameworks 0.75
Visible-Light-Induced C–S Bond Cleavage Enables Alkyl Radical Generation from Redox-Inert Substrates 0.60
The Synthesis of Tertiary Alkylamines from Alkyl-Substituted Alkenes Using Amine Umpolung Strategy 1.00
Radical Copolymerization of Formaldehyde with Vinyl Acetate: Direct Incorporation of C–O Bonds in Vinyl Polymer Backbones 1.00
Singlet-Oxygen-Driven C(sp2)–P Bond Cleavage Enables Red-Light Uncaging of Phosphorus(V) Prodrugs on Gold Nanoclusters 1.00
Cavity Constriction and Chiralization of Polyaromatic Subnanotubes via Post-assembly Ligand/Metal Modification 1.00
Nitrogen Doping at the Periphery of a Quadruply-Fused Porphyrin and Its Multi-Step Proton-Coupled Electron Transfer to Form a 34π Aromatic Molecule 1.00
Cascade Radical Isomerization Polymerization to Engineer Polymer Backbones 1.00
Copper(I)-Mediated Direct C–H Functionalization of Carborane Anion: One-Pot Installation of Amino, Hydroxyl, Carbon, and Other Heteroatom Functional Groups at the C1 Vertex 1.00
Total Synthesis and Complete Stereochemical Assignment of the Marine Bromotriterpenoid (+)-Callicladol through a Combined Approach Using Model Syntheses and Nuclear Magnetic Resonance Calculations 1.00
Fused Rubrene Derivatives with Embedded Seven-Membered Rings: Curvature-Dependent Photophysical and Semiconductor Properties 1.00
Carbenes Embedded in Cyclic Paraphenylenes: Detection, Ground-State Spin Multiplicity, and Möbius Aromaticity 0.71
Iridium-Catalyzed meta-Selective C–H Silylation of Arenes Enabled by Remote Regiocontrol with a Spirobipyridine Ligand 1.00
Medium-Sized-Molecule Encapsulation in Coordination Cages via Solid-State Mechanochemistry 1.00
Elucidating Leader Peptide–Enzyme Dynamics in Lactazole Biosynthesis Using mRNA Display 1.00
Redox-Switchable Halogen Bonding in Haloanthracene Mediators Enables Efficient Electrocatalytic C–N Coupling 1.00
A Rational Design of Chiral Iron(III) Complexes for Photocatalytic Asymmetric Radical Cation (4 + 2) Cycloadditions and the Total Synthesis of (+)-Heitziamide A 1.00
Host–Guest Interaction-Controlled Site-Selective C–H Borylation of Aromatic Compounds 1.00
Asymmetric Carbonium Ion Catalysis: The Intramolecular Hydroalkoxylation of Cyclopropanes 0.21
Using Mechanochemistry to Activate Poly(vinyl chloride) as a Mechanotunable Brønsted-Acid-Releasing Reagent for Organic Synthesis 1.00
Collective Total Synthesis of 12 C4-Oxygenated Cladiellins and Structure Elucidation of Cladieunicellin D and Cladielloides A/C 1.00
Design of Phosphine-Heteroarenesulfonamide Ligands as Dinuclear Silver Catalysts for Enantioselective Construction of α,β-Diamino Acids 1.00
Carbonylative Ring Expansion of Cyclic Carboxylic Acids 1.00
Synthesis of Phenylenediamines via (4 + 1 + 1) Photocycloaddition of 1,3-Dienes and Isocyanides Enabled by a Gallium(I)/(III) Redox: The Key Role of a Phenalenyl-Based Ligand 1.00
Vinigrol Tricyclic Scaffold Biosynthesis Employs an Atypical Terpene Cyclase and a Multipotent Cyclization Cascade 1.00
Antiaromatic Nanographenes via a BODIPY-Fusion Strategy 0.83
Total Synthesis of Trigocherrins A and C 1.00
Supramolecular Ionic Polymerization: Cellulose-Based Supramolecular Plastics with Broadly Tunable Mechanical Properties 1.00
Enzymatic Anti-Baldwin Ring-Closure Cascade for Fused Bicyclic Ether Formation 0.67
Denitrogenative Carbon Skeleton Cleavage and Reorganization of Pyridines by a Trinuclear Titanium Polyhydride Complex 0.67
Deep-Red to Near-Infrared Light-Driven Radical Generation from Organoboron Compounds via Ligand-Induced Direct Excitation Catalysis 1.00
Azaanthraquinone PCET Catalysis Enables Chemoselective Decarboxylative Functionalization of Diverse Carboxylic Acids 1.00
Virtual Ligand-Assisted Screening for the Generation of Ketyl Radicals from Alkyl Ketones via Photoexcited Palladium Catalysis 1.00
Catalytic Enantioselective Diels–Alder Reaction of Dienes with Acyclic and α,β- and β,β-Disubstituted Enones 0.19
Programmable Artificial-Cellular Membrane Dynamics via Ring-Closing Metathesis 0.50
Strain-Induced Quinoidal Character in a Carbon Nanoring Embedding Anthracene Units 1.00
An Isolated Lithium ortho-Carboranyl Cuprate Complex for the Synthesis of Multiple-Carborane-Substituted Arenes from (Hetero)Aryl Bromides and Chlorides 1.00
Automated Reactivity Prediction of Complex Molecules and Its Application to Total Synthesis of Ageliferin 1.00
Flow Photo-Oxidative Dearomative Cyclization Enables Unified Asymmetric Synthesis of Trichodermamides A–F 1.00
Catalytic Asymmetric (ene–endo)-Carbonyl–Ene Type Cyclizations 0.33
Structural Basis for 3-Amino-3-carboxypropyl Transfer in Nocardicin Biosynthesis 0.83
A Versatile One-pot Strategy for Thiazolylazo Extensions: Visible Light-Driven Photoswitches 1.00
Controlled Molecular Orders in Layered Multiple Porphyrins 1.00
Direct Generation of Carboxyl Radicals from Carboxylic Acids Catalyzed by Photoactivated Ketones 1.00
Migrating Group Strategy for Remote Functionalization of Seven-Membered Rings 0.07
Carbon Reduction Powered by Natural Electrochemical Gradients under Submarine Hydrothermal Vent Conditions 0.15
Au-Catalyzed Aerobic Dehydrogenative Aromatization to m-Phenylenediamine Derivatives via Product Selectivity Control 1.00
C–H Amination of Arenes and Heteroarenes through a Dearomative (3 + 2) Cycloaddition 0.50
Induced Bioconjugation via On-Demand Isocyanate Formation 1.00
Diastereo- and Enantioselective Synthesis of Polycyclic Amines by Cascade Cyclization of Aromatic Aldimines with Tethered Alkenes via Scandium-Catalyzed C–H Activation 0.92
Correlated Reaction Coordinate Motion Produces Nonadditive Rate Enhancement for Electron and Energy Transfer in Multiacceptor Structures 0.25
Complete Structure of Delftibactin A and Its Function in Reductive Formation of Gold Nanoparticles 1.00
Ketosynthase Domain Catalyzes β-Lactonization in the Biosynthesis of the HMG-CoA Synthase Inhibitor Hymeglusin 1.00
Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates 0.90
A Visible-Light-Responsive Octahedral Cage for Efficient and Selective Cross-[2 + 2] Cycloadditions 1.00
Melt Rheology of Dendritic Hyperbranched Polyacrylates Synthesized by Controlled Radical Polymerization: Evidence of Self-Similar Branch Structure Formation 0.92
Sulfur[n]arenes: Synthesis and Solid-State Supramolecular Dimerization via Multiple Sulfur···Sulfur Interactions 1.00
Covalent Template-Guided Synthesis of iendo/i-Functionalized Oligophenylene Cages 1.00
Unraveling the Potential-Dependent Selectivity of Propylene Electrooxidation: The Role of Electrochemistry-Induced Reconstruction 0.33
Deoxygenative [3 + 2] Annulation of α,β-Unsaturated Carbonyl Compounds and Electron-Rich Olefins via Photocatalytic Umpolung of Triarylphosphine 1.00
Single-Molecule Reactor Based on the Excluded Volume Effect of Bottlebrush Polymers 1.00
Breaking the Strongest Organic Bonds by Water: Defluorosubstitutions at the Air–Water Interface of Microdroplets 0.25
Regioselective Hydropyridylation of Heteroatom-Functionalized Internal Alkenes by Half-Sandwich Rare-Earth Catalysts 0.50
Controlled/″Living″ Click Polymerization with Possible Bidirectional Chain-Growth Propagation during Polyaddition 1.00
Planarity Is Not Plain: Closed- vs Open-Shell Reactivity of a Structurally Constrained, Doubly Reduced Arylborane toward Fluorobenzenes 0.13
Direct Access to Benzofurans and Indoles from Ethylene with 2-Methylphenols/Anilines through Iridium-Catalyzed Dehydrogenative Annulation 1.00
26 24.17
Cationic Polymerization of Pendant-Reactive Styrene Derivatives Using Diaryliodonium Salts as Both a Lewis Acid Catalyst and a Photoreactive Reagent 1.00
Lower Critical Solution Temperature-Type Phase Behavior of Poly(N-isopropylacrylamide) in Nonaqueous Organic Solvents 1.00
Design of Pyrazole-Pendant Acrylamide Monomers Enabling Selective Postpolymerization Modification for Library Synthesis of Random/Block Copolymers 1.00
Organotellurium-Mediated Radical Polymerization of Chloroprene 1.00
Synthesis of Deuterated Multicyclic Polystyrenes for a SANS Study to Explore the Structural Characteristics of Multicyclic Architectures in the Bulk 0.96
Chemoselective Polymerization of 2-(Acryloyloxy)ethyl Methacrylate Enabled by B(C6F5)3-Stabilized s-cis and s-trans Monomer Conformations 1.00
Quantitative Evaluation of Cross-Linking Efficiency in Worm-like Nanoparticles Prepared via RAFT-Mediated Aqueous Emulsion PISA 0.40
SuFEx Chemistry Enables Sustainable Side-Chain Modification of Renewable Phenylpropanoid Polymers 1.00
Direct Fluorination of Ethylene–Tetrafluoroethylene Copolymer Films in Liquid Media 1.00
Controlled Thermoresponsive Aggregation of Core-Cross-Linked Multiarm Star Poly(N-isopropylacrylamide) for a Highly Dispersed Hydrophobic Nanospace in Water 1.00
Preparation of Polymer Gel with Homogeneous Network Structure Composed of Photoreactive Star-Shaped N-Isopropylacrylamide Polymers 1.00
A Library Synthesis of N-Alkylacrylamide-Hydroxyethyl Vinyl Ether Alternating Copolymers for Studies of Thermoresponsive Features in Water 1.00
Confined Polymerization in Microphase-Separated Liquid Crystalline Films: Alignment-Controlled Growth of Conjugated Poly(diacetylene) Nanostructures 1.00
Structure–Property Relationships in Multicyclic Polystyrenes: Synthesis, Physical Properties, and Comparison with Acyclic Counterparts 0.81
Electrochemical C–H Phosphonylation of Dissolved Conjugated Polymers via Direct Electron Transfer at the Electrode 1.00
Synthesis of Polyester-Polystyrene Hybrid Gel by PET-RAFT Polymerization in “RAFT Gel” and the Role of Dynamic Covalent Bonding in Its Self-Healing Properties 1.00
Cosolvency-Induced UCST/LCST Dual Phase Separation of Poly(2-hydroxyethyl methacrylate) in Nonaqueous Organic Solvent Mixtures 1.00
Kinetic Model of Radical Ring-Opening Polymerization of Asymmetric Five-Membered Cyclic Ketene Acetals 1.00
Synthesis and Structural/Physical Properties of Well-Defined Linear and Star-Shaped Polysulfides Constructed by Controlled Insertion Reaction of Thiirane and Carbamic Acid Thioester 1.00
Organocatalytic Group Transfer Polymerization of α-Methylene-N-methylpyrrolidone: Controlled/Living Property Applied to the Synthesis of Gradient and Block Copolymers with Acrylamide and Methacrylate Polymers 0.29
From Monomer Design to Multifunctional Polymers via Controlled ROMP: Novel Indole-Functionalized Norbornene Dicarboximide Copolymers with Enhanced Thermal, Optical, and Antibacterial Properties 0.71
RAFT Copolymerization of Glycerol-Derived Vinyl Ethers Possessing Acetal-Protected Diols for Biobased Hydrophilic and Thermoresponsive Polymers 1.00
Fluoroalkyl Chain End Groups Regulating Crystal/Amorphous Interfaces of Semicrystalline Polyethylene Films 1.00
Facile Synthesis of Graft Polymers with Poly(vinyl ether) Graft Chains Using Poly(cyclic acetal)s as Macroinitiators for Living Cationic Polymerization 1.00
Why Is the Trommsdorff Effect Weak for Styrene? An Investigation Using Small-Angle Neutron and Wide-Angle X-ray Scattering 1.00
Rauhut–Currier Polyaddition: Self-Polymerization of Divalent Aryl Vinyl Ketones for Unsaturated Polyketones 1.00
1 0.12
Pressure-Driven Solid-State Radical Polymerization toward Carbon Nanothread 0.12
3 0.35
Electronic origin of reorganization energy in interfacial electron transfer 0.18
The asymmetric synthesis of an acyclic N-stereogenic amine 0.13
Catalytic enantioselective synthesis of alkylidenecyclopropanes 0.05
4 3.67
Metal electrode potential diverges with ion additions 0.75
A system of paired polyether epoxide hydrolases enables a mouldable enzyme for consecutive ring cyclization cascades 0.92
Non-ribosomal peptide cyclase-directed chemoenzymatic synthesis of lariat lipopeptides 1.00
Mechanochemical pathway for converting fluoropolymers to fluorochemicals 1.00
19 14.64
Directed trilithiation enables entropically stabilized heavy-atom-centered triangulenes 1.00
Supramolecular protection of isocyanates from water by encapsulation within hydrophobic crystalline pillar[n]arene macrocycles 1.00
Superacid-resistant macrocyclic BODIPYs 1.00
Non-chelation control in allylations of α-oxy ketones using group-14 allylatranes 1.00
Photooxidative Copper(II) Catalysis for Promoting anti-Markovnikov Hydration of Alkenes 1.00
Expression of nano-engineered RNA organelles in bacteria 0.08
Electrochemical and photocatalytic generation of cis-olefin-bridged carbodication for umpolung [4+1] cycloaddition 1.00
Autonomous biogenesis of all thirty proteins of the Escherichia coli translation machinery 0.13
Sustainable purification-free synthesis of N–H ketimines by solid acid catalysi 1.00
Straightforward construction of functionalized γ-lactams via conjugated-engineered covalent organic framework photocatalysed cascade reactions 0.15
Essential oil-derived decomposable polymers via cycloaddition polymerization of silyl ether-linked phenylpropanoids 1.00
Light-driven radical copper-catalyzed allylic amination via allylic copper intermediates 0.10
Heteroaromatic swapping in aromatic ketones 1.00
Fe-electrocatalytic deoxygenative Giese reaction 0.25
Gram-scale selective telomerization of isoprene and CO toward 100% renewable materials 1.00
Simultaneous in vitro expression of minimal 21 transfer RNAs by tRNA array method 1.00
Catalytic diazene synthesis from sterically hindered amines for deaminative functionalization 1.00
Structural basis of transfer RNA processing by bacterial minimal RNase P 1.00
Electrochemical cascade access to hetero[8]circulenes as potent organophotocatalysts for diverse C–X bond formations 0.93
135 125.61
Direct-Excitation-Enabled Radical Hydrosilylation via a Silyl Radical Precursor 1.00
Clarifying the Unknown Mechanism of the Removal of the 4‑Nitrobenzyloxymethyl Group via a Benzyl Radical Intermediate Induced by Tetra‑n‑butylammonium Fluoride 1.00
Photocatalytic Oxidative Strecker-Type Reaction with Primary Amines, Tertiary Amines, and Cyanoarenes 1.00
Visible-Light-Driven Photocatalytic Utilization of Sulfur Hexafluoride (SF6) as an SF5 Radical Source 1.00
Nickel/Photoredox-Catalyzed Benzylation of Aryl Bromides Via Double Decarboxylation of Malonic Acid Derivatives 1.00
<atl>Synthesis of Functionalized [5]-Cyclo- im/i -phenylenes Enabled by Controlled Multihalogenation Using a Carborane Catalyst</atl> 1.00
Total Synthesis of (±)-Integerrines B–F via Bismuth-Catalyzed Oxidative Homo- and Cross-Couplings of 3-Hydroxycarbazoles 1.00
Co/Salox-Catalyzed Enantioselective C–H Annulation for One-Step Generation of C–N Axial and C Central Chirality 0.17
Covalent-Bond-Directed Synthesis of Rotaxanes from Macrocyclic Diaryliodonium Salts 1.00
α‑Diazo Masked Sulfinates for the Synthesis of Sulfonyl Fluorides and Their Application in the C(sp2)–H Functionalization of Aryl Sulfoximines 1.00
Skeletal Modification of Phenols into Benzo-Fused Seven-Membered N,O-Heterocycles via Catalytic Alkyl Nitrene C(sp2)–H Amination 1.00
Photocatalytic Oxidative Generation and Synthetic Application of Phosphine–Boryl Radicals 1.00
Benzo[1,2-b:3,4-b′:5,6-b″]trithieno[3,2-b:6,5-b′:9,8-b″]trithiophene: A Thiophene-Rich 3-Fold Symmetric Building Block for π-Extended Materials 1.00
Hypervalent Iodine(III)-Mediated Oxidative C–H Amination of Phenols and Anilines with Azoles 1.00
Supertrityl Radical and Cation: The Effect of a Large π-Surface for Intermolecular Interactions and Spin/Charge Delocalization 1.00
Synthesis of Multisubstituted Diazatricyclic Molecules Via Intramolecular Cycloaddition of Cyclic Azomethine Ylides 1.00
Multicomponent Synthesis of β-Boryl Ketones Triggered by Ketene-Induced Metallate Rearrangement of Alkenylboronic Esters 1.00
Syntheses of Bridged Fenestranes via Stepwise Intramolecular Diels–Alder Reaction and Nitrone Cycloaddition and Their Structural Analyses 1.00
Traceless Silicon-Tether Strategy for the Synthesis of a Tetraphenylammonium Salt 1.00
Cu-Catalyzed [1,3]-Fluorine Rearrangement Reactions of N-Fluoroanilines 1.00
ipso-Halogenation of Arylsilanes Using a Carborane Sulfide Catalyst 1.00
Discovery of Coracanols A and B, Two Biological Nitrification Inhibition Diterpenoids from Finger Millet 1.00
Selective Synthesis of 5-Nitroindoles through a Ag-Catalyzed Nitro Rearrangement/Cyclization Cascade of N-(o-Alkynylphenyl)nitramines 1.00
Computation-Enhanced Structure Elucidation of Cyclopropane-Containing Polyketides Ikeiamides A–M 1.00
Palladium(0)-Catalyzed Nucleophilic Cyclization of Conjugated Enyne-Carbonyls Leading to Cyclic Allenic Alcohols 1.00
Synthesis of α,β-Unsaturated Ketones from Aldehydes and Ketones Using 1,1-Di(boryl)alk-1-enes 1.00
Halide-Mediated Electrochemical Peptide Synthesis Applicable to Highly Sterically Hindered Amino Acids 1.00
Brønsted Base-Catalyzed Aminoxylation of Benzylic and Allylic Compounds with TEMPO 1.00
Enantioselective Total Synthesis of Citrifelin A via the Oxa-Pictet–Spengler Reaction and Acid-Promoted Dihydropyran Formation 1.00
Asymmetric Cycloaddition of 1,6-Diynes with Alkenes Enabled by Ligand-to-Metal Chirality Transfer in Cobalt/Photoredox Cooperative Catalysis 1.00
Shimojilide, a Potent and Selective Antiproliferative Cyclic Lipopeptide from a Marine Cyanobacterium Okeania sp. 1.00
Synthesis of an A/B-cis-Fused Cyclopenta[b]fluorene (6/5/6/5) Ring System for Embellicine A via the Eight-Membered Silylene-Tethered IMDA Reaction 1.00
Synthesis of Antiaromatic Ni(II) Norcorroles by Mn Powder 1.00
Dynamic Dual Role as Cationic Cu+ and Cu Alkoxide in Cu-Catalyzed Dearomative Cascade Reactions 1.00
Pd/Tl Bimetal-Catalyzed C3(5)–H Activation of Pyridine Derivatives Enables Access to Pyridine-Fused Benzophospholes and Their Transformation into Seven-Membered Phosphepines 1.00
Total Syntheses of (+)-Penicibilaenes A and B via Enantioselective Desymmetrization 1.00
Direct Ether Synthesis Utilizing the Carbonyl Umpolung Reaction 0.69
Michael-Addition-Triggered Release of Substituents from Tertiary Amines 1.00
A Recyclable Triangular Phenanthrenequinone (TPQ) Catalyst-in-a-Teabag System for Biomimetic Aerobic Oxidation of Benzylamines 0.50
Phosphoric-Acid-Catalyzed ortho-Selective Intramolecular Cyclodehydration Reaction of Phenols and Anilines 1.00
Mono- and Bisphosphonylation of Aryl Chlorides via Phenothiazine Organophotoredox Catalysis 1.00
Alkyl and Aryl Thioester Synthesis via N-Heterocyclic Carbene-Catalyzed α-Thio Aldehyde Rearrangement 1.00
Synthesis of Keto Hexafluoro Alkyl Sulfonyl Amides Via Radical Ring-Opening Polymerization of Aryl-Substituted Vinyl Cyclohexafluoropropane-1,3-bis(sulfonyl)amides Followed by Hydrolysis 1.00
Synthesis and Properties of Medium-Sized cis,trans-Cycloocta-1,3-diene–Pt(II) Complexes 1.00
Catalytic Asymmetric Benzoin Condensation for the Synthesis of Natural Products and Their Analogs 1.00
Synthesis of Benzarsoles by Arsenic Cation-Mediated Formal [3 + 2]-Cycloaddition with Alkynes 1.00
Visible-Light-Mediated Cyclization of Enynes toward Medium-Sized Carbocycles with Copper Catalyst 1.00
Radical Borylation of Aryl Sulfones with N-Heterocyclic Carbene Borane: A Modular Approach to Aryl Boranes 0.83
Iridium-Catalyzed γ-Hydro(hetero)arylation of α,β-Unsaturated Amides 1.00
Synthesis of Seven-Membered Nitriles by Formal Anionic Divinylcyclopropane Rearrangement 1.00
Organophotoredox-Catalyzed Alkene Functionalization Reactions Using α-Bromocarbonyl Compounds 1.00
Oxidative α-Amination and Aziridination of Cyclic β-Ketoesters Using Aminobenziodoxolones 1.00
Oxahelicene-Based Pd2L4 Cages: Synthesis, Optical Properties, and Guest Encapsulation 1.00
Iron-Catalyzed C–N Coupling Using Polycyclic Aromatic Hydrocarbon as a Redox Mediator 1.00
Total Synthesis of Racemic Benzosceptrins via an Electrocyclization Cascade 1.00
JBIR-160–166 Obtained from the Heterologous Expression of a Cryptic Gene Cluster in Kitasatospora setae 1.00
Native Amide-Directed C(sp3)–H Alkynylation Using an Electron-Deficient Iridium Catalyst with Pyridone Ligand Assistance 1.00
Visible-Light-Induced Comprehensive Carboxylation of Benzyl Halides with CO2 via Halogen Atom Transfer 1.00
Synthesis of Si-Bridgehead Polycyclic Aromatic Hydrocarbons via Ru-Catalyzed Double Annulation of Secondary Silanes with Internal Alkynes 1.00
Copper-Catalyzed β-Functionalization of Amino Acid Schiff Bases 1.00
Silyl Lewis Acid-Catalyzed 5-endo-trig Remote Aryl Rearrangement Enabling Dual Migration of Anisole and Amide Groups of N-Cinnamyl-N-alkoxybenzyl Sulfonamides 1.00
Synthesis of Silyl Dienol Ethers via Peterson Olefination of Siloxyallylpotassium Species 1.00
Diazacyclobutene Ring Cleavage Provides 1,2-Diazetidin-3-ones via Intramolecular Nucleophilic Cyclization 0.17
Single-Walled Carbon Nanotubes as a Support for Palladium-Catalyzed Aquachemical Cross-Coupling Reactions 1.00
N-Difluoroacetylation of Sulfoximines by TFEDMA 1.00
Electroreductive α-Aminoalkylation of Sulfonylazoles with Amines and Aldehydes 1.00
Divergent Synthesis of Tetrafluoroethylene-Containing Tetrahydrofuran (THF) and Dihydropyran (DHP) Derivatives 1.00
Benzophenone-Based Phenylogous Peptide Linkage via Friedel–Crafts Acylation 0.43
Enantioselective Construction of Fluorinated Tertiary Stereocenters by Rh-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Enynes with α-Fluoroacrylamides 1.00
Synthesis and Two-Dimensional Chiral Self-Assembly of Oxygen-Incorporated Dibenzo[hi,st]ovalene 0.93
Bioinspired Electrochemical Cyclization toward the Divergent Synthesis of Mavacurane- and Akuammiline-Type Alkaloids 1.00
Divergent Construction of Polycyclic Frameworks Enabled by Sequential Ru-Catalyzed [2 + 2 + 2] Cycloaddition of Iododiynes and Pd/Norbornene-Mediated Catellani-Type Annulation 1.00
Synthesis, Structures, and Properties of Polybenzo[n]spirenes with Carbon-Based Polyspiroconjugation 1.00
Cu-Catalyzed SF4-Alkynylation of Quinolones, Chromones and Cyclohexenones 1.00
From Refrigerant to Reagent: Repurposing HFC-125 into Inorganic and Organic Fluorinating Agents 1.00
Easily Separable Racemic and Meso Isomers of a Salen-Based Cryptophane for Selective Guest Binding 1.00
Synthesis and Photophysical Properties of Cyclic Homodimer of U-Shaped Dibenzophenazinylene 1.00
Construction of Pyridine-Fused Azacorroles through Multicomponent-Coupling Strategy 0.25
A Tsuji–Trost Reaction Using Free Carbenes as Nucleophiles: Palladium-Catalyzed Photoinduced Coupling of Acylsilanes with Allylic Alcohol Derivatives 1.00
Synthesis of Neokotalanol and Its Derivatives as Potent α-Glucosidase Inhibitors 0.22
Energy-Transfer Excitation of Dibenzothiophene S-Oxide Induces Oxomethylation of Styrenes 1.00
Photoirradiation-Promoted ipso-Azidation of 1-Aryltriazenes 1.00
Synthetic Studies of Spiroschincarins: Construction of 1-Oxaspiro[6.6]tridecanone Skeleton with All-cis Cyclopropane Moiety 1.00
DiazaChrysenes (DC): Nitrogen-Containing π-Extended Molecules for Photocatalytic C–H Amination 1.00
4-Nitrophenyl Sulfamates as Precursors Containing Acid-Labile Functional Groups for Sulfamidation with Weakly Nucleophilic Amines 1.00
Two Cationic Antiaromatic Free-Base Corroles 0.20
Synthesis of Diazatricyclic Molecules via Intramolecular Cycloaddition of Azomethine Ylides 1.00
Synthesis of N,O-Bidentate Difluoroboron Complexes via Iodide-Promoted Demethylative Borylation 1.00
Direct S-Azidomethylation of Thiols with N-Azidomethyldisulfonimides 1.00
Synthesis of a Face-to-Face Porphyrin Nanoring 0.15
Aldol Condensation of Bis(pentafluorophenyl)boron Enolates for the Synthesis of α-Pentafluorophenyl-Substituted α,β-Unsaturated Carbonyl Compounds 1.00
Lewis Acid-Catalyzed Direct Conversion of Carboxylic Acids into Primary Amides and Nitriles Using Bis(trimethylsilyl)amine 1.00
Pyrrole-Fused Aza-Nanographene with Two Gulf-Edge Regions as Flexible Sites 1.00
NiII and CuII Complexes of 5-Oxa-, 5-Sulfa-, 5-Selena-, and 5-Telluracorroles 0.13
Directed Secondary C(sp3)–H Borylation by a Phenoxyimine Iridium Catalyst at Room Temperature 1.00
Computationally Designed Dearomative Claisen-Type Rearrangement of a Benzyl Alkynyl Ether and Cascade Reaction To Provide a Dihydroindenone 1.00
Modulation of Koelsch Radical Stability and Aromaticity through Nonhexagonal Ring Fusion 1.00
Iodine(III)-Mediated Cyclization Cascade of Diynes to Benzofulvene Derivatives 1.00
Cobalt-Catalyzed Bicycloaddition of Alkynes with Conjugated Trienes Yielding Bicyclo[3.2.1]octadienes 1.00
Synthesis of a Highly Luminescent Pyrrole-Fused Dicorannulene as a Corrugated π-Extended Carbazole 1.00
Modular Construction of a Three-Layered π-System Using Cruciform Azaacene Dimers 1.00
Isolation of a Transition-State Geometry via Intermolecular Stabilization in the Solid State 1.00
Fold-in Synthesis of an Ovalene Analogue Composed of Four Peripheral Amide Linkages 1.00
Strategy for the Synthesis of Phenylalanine Derivatives through the Addition of Aryl Radicals to Dehydroamino Acid via Photoinduced Decarboxylation or Deboronation 1.00
Synthesis of Cyclobuta[cd]pentalenes via an Intramolecular Double Michael Addition Reaction of 1,3-Cyclopentanedione Derivatives 1.00
Stereoselective Synthesis of (E)-α-Bromo- and (E)-α-Iodoacrylates from Readily Available tert-Butyl Diphenylphosphonoacetate 1.00
Substantial Effects of Ring Size on the Structure and Properties of 2,9-Anthrylene Cyclic Oligomers 1.00
Thermolides D and E: Total Synthesis and Stereochemical Revision 0.25
Synthesis of Citrifurans A and D through Assembly of the Natural Products Citrinin and Gregatin A 1.00
One-Pot Synthesis of Iptycenes and Dissymmetric Triptycenes Using Ynolate-Benzyne Triple Cycloaddition 1.00
Synthesis of 2-Phosphorus-Substituted Indoles via Ring Expansion of Benzocyclobutenone Oxime Sulfonates 1.00
Total Syntheses of Ganodilactone and Related Ganoderma-Derived Meroterpenoid Dimers via Intramolecular Vinylogous Michael Addition 1.00
Light-Driven Dehydrogenative Construction of Thioester Linkages from Thiols and Aldehydes 1.00
Asymmetric Total Synthesis of (−)-Lemnalemnane C 1.00
Electron-Catalyzed Cross-Coupling Reaction of Arylzinc Reagents with Aryl Triflates Accelerated by Photoirradiation 1.00
Porphyrin AuIII Complexes Bearing Bulky Meso-Substituents as Building Blocks of Stacking-Frustrated Ion-Pairing Assemblies 1.00
Transformation of α,β-Unsaturated Aldehydes with a Small Amount of Electricity: Cyanosilylation, Isomerization, and Nucleophilic Addition 1.00
Anion-Mediated Synthesis of Diethynyl-Substituted Doubly N-Confused Dioxohexaphyrin Dyes That Exhibit Enhanced Photoacoustic Signals in the NIR-II Region 0.95
Synthesis and Characterization of Perhydroxy-asar[6]arene and Perhydroxy-asar[6]quinone 1.00
Photocatalytic Decyanative Radical Addition Based on Cyano Group Transfer Mediated by Amine-Ligated Boryl Radicals 1.00
Acceptorless Dehydrogenative Aminoalkylation of Allylic C(sp3 )−H Bonds via Reversible Hydrogen Atom Transfer 1.00
Selective Modification of Carboxylic Acids with Oximoyl Chlorides under Aqueous Conditions 1.00
Stereoselective Synthesis of Delgocitinib and Its Diastereomer Using Organocatalyzed Michael Addition 1.00
Isolation and Computer-Based Structural Determination of Madangolide B 0.83
Annulative π-Extension of Phospholes by Sequential Site-Selective C–H Iodination and Pd-Catalyzed C–H Coupling with Alkynes 1.00
Highly Active Catalyst for Suzuki–Miyaura Coupling to Form Sterically Demanding Biaryls: Electronic Control of Pd through the Secondary Interaction Using a Buchwald-Type Ligand Bearing a Fluorinated Aryl Ring 1.00
Rh-Catalyzed in Situ Generation of Phenanthrocyclobutadienes from Tetraaryl-Diynes and Their Cycloadditions with Cycloalkenediones and io/i-Chloranil 1.00
Copper-Catalyzed Stereoconvergent 1,4-Protosilylation of E/Z Dienes 0.20
1,6-Reduction-Type Hydride Shift/Cyclization Process without Adjacent Heteroatom: Stereoselective Synthesis of Hexahydrofluorene Derivatives via Internal Redox Reaction/Friedel–Crafts Reaction Sequence 1.00
Synthesis of Parent Peropyrene and Its Derivatization 1.00
Chiral Phosphoric Acid-Catalyzed Enantioselective Pictet–Spengler Reaction for Concise Synthesis of CF3-Substituted Tetrahydro-β-Carbolines 1.00
Stable Tribrominated Phenalenyl Radical Exhibiting Long-Lived Luminescence from a Monomer−π-Dimer Equilibrium 0.90
Mechanochemical Buchwald–Hartwig Cross-Coupling Reactions of Aromatic Primary Amines and Their Application to Two-Step One-Pot Rapid Synthesis of Unsymmetrical Triarylamines 1.00
Total Synthesis of (±)-Rhazinilam via Red-Light-Driven Zinc(II)porphyrin-Catalyzed Radical Cyclization of iN/i-Substituted Pyrrole 1.00
2-(Cyanomethyl)benzimidazole Derivatives as 1,3-Dicarbonyl Analogues for a Kinetically Controlled Diastereo- and Enantioselective Mannich-Type Reaction Catalyzed by Chiral Phosphoric Acid 0.81
2 0.63
Violation of Local Reciprocity in Charge-Orbital Interconversion 0.60
Universal Effective Charges in the 𝑠⁢𝑑 and 𝑓⁡𝑝 Shells 0.03
5 2.90
Compositional memory matters for early molecular systems 0.60
A rare glycoalkaloid biosynthetic pathway from wild potato unlocks genetic routes to Colorado potato beetle resistance 1.00
Mineral-facilitated aqueous synthesis of hydrogen cyanide from prebiotically abundant amino acids for chemical evolution 1.00
Interstep compatibility of a model for the prebiotic synthesis of RNA consistent with Hadean natural history 0.24
An Archean atmosphere rich in sulfur biomolecules 0.06
1 1.00
In-insect synthesis of oxygen-doped molecular nanocarbons 1.00
1 0.11
Electrochemical C4 alkylation of pyridine derivatives: Enhanced regioselectivity via silane assistance 0.11
1 0.67
Proton Irradiation of Primitive Atmospheres of Young Exoplanets and Early Earth: N2O Greenhouse Warming and Prebiotic Synthesis 0.67
2 2.00
Rational Design of a Metal-Free Organic Radical Cation Exhibiting Mid-IR π–π* Transition Based on the Exchange Interaction 1.00
Photochromic Phenoxyl–Imidazolyl Radical Complex via Homolytic C–O Bond Cleavage 1.00
1 0.04
Vepdegestrant, a PROTAC Estrogen Receptor Degrader, in Advanced Breast Cancer 0.04

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