Organic Chemistry articles for China

Time frame: 1 June 2025 - 30 May 2026

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Count: 3268

Article ‘Count’ for Organic Chemistry.

Journal Count Share
12 11.92
Carbene-Mediated Photoconversion of Cellulose Diacetate 1.00
Chlorine Ion-Enhanced Efficient Photocatalysis of Polyethylene Plastics 1.00
Chiral Covalent Organic Frameworks Trigger Tumor-Specific Mitophagy via Notch/Mitogen-Activated Protein Kinase Pathways and Enantiomer-Dependent Photodynamic Therapy 1.00
Weakening Chaotropic Effect of Li+ in Two-Dimensional Confined Channels via Coulomb Interactions for Efficient Li+/Mg2+ Separation 1.00
Reconfigurable Mechanically Interlocked Metal–Organic Nanocages for Adaptive Guest Recognition and Allosteric Regulation 1.00
Iridium Nanoantidotes Attenuate Jellyfish Toxin-Induced Hepatotoxicity by Inhibiting Gasdermin D Palmitoylation 1.00
Self-Assembly of P22 Virus-like Particles in Liquid–Liquid Phase-Separated Condensates for Enhanced Enzyme Catalysis 1.00
A Cyclic Photosensitizer Nanoplatform for Effective Pyroptosis and Enhanced Photoimmunotherapy 1.00
Autonomous Self-Pulsation of Protein Vesicles via Substrate-Induced Protein Allosteric Cycle 1.00
Highly Exposed Subnanometric Palladium Ensembles on Yttrium Oxide Enable Boosted Catalytic Performance for Heck Cross-Coupling Reactions 0.92
High-Entropy Metallene Arrays with a Turing Structure for Electrocatalytic Upcycling of Polyethylene Terephthalate Plastics Coupled with Electrosynthesis of Ammonia 1.00
Anion Immobilization from Quasi-Icosahedron to Cubo-Octahedron Enhances the Lithium Ion Transference Number in Solid-State Electrolytes 1.00
25 23.81
Aggregation-Induced Stabilization of Boron-Containing Organic Diradicaliods via π-Bridge toward Highly Efficient Light-to-Thermal-Electric Conversion 1.00
ATP‐Activated Tumor Targeting Therapy via Bioorthogonal Alkyne‐Calixarene Host–Guest Assembly 1.00
Electronic Engineering of Lyophobic Surface Shield in Boron Nitride for Stabilizing Propane Oxidative Dehydrogenation 0.75
Bifunctional Direct and Oxidative Dehydrogenation of Propane by Balanced Electronic Coupling and Surface States in Pt-M@Silicalite-1 1.00
A Computational Framework to Efficiently Screen Antioxidants for Cross-Linked Polyethylene Insulation 1.00
Retractable Cages with Continual Change of Cavity Size and High Iodine Capture 1.00
Coral-Like Pd3Pb Nanoarchitectures Enable Poisoning-Resistant Electrosynthesis of Glycolic Acid From PET-Derived Ethylene Glycol 1.00
Construction of Fluorenone-Functionalized Porous Organic Polymers for Visible-Light-Driven Oxidative Cleavage of Polystyrene to Acid 1.00
Redefining Gold-Ligand Chemistry for Biosensing: Au─C≡C Probe Enable High-Sensitivity and Low-False-Positive Furin Imaging 1.00
Oxidation Engineering Activates Ni─Fe Nitrides for Efficient Mechanocatalytic Thiol Coupling 1.00
Substrate‐Triggered Surface Activation for Efficient Electrosynthesis of Potassium Formate 1.00
Intensifying Internal Electric Field on ZnO Nanoplates with Polar Surface Exposure and Cu Doping for Efficient Photocatalytic Methane Oxidation to Oxygenates 1.00
Polyferrocene-Based Cubosomes: Conversion to Magnetic Mesoporous Microparticles, Supramolecular Modification, and Oxidation Response 0.20
CuO@TiO2 Hollow Cubes Enable Highly Selective and Stable Photocatalytic Non-Oxidative Methane Coupling to Ethylene 1.00
A Biomimetic Self‐Reinforcing Recyclable Multifunctional Sustainable Material Harnessing π‐Conjugated Cinnamene Units 1.00
Precisely Controlled Relationship between Sulfur Vacancy and Ni Site for Boosting Photocatalytic Conversion of Polyester into Formate 1.00
Laser‐Driven Superfast‐Heating and Quenching Approach to Selectively Upcycle Waste Polyolefin into Long‐Chain Terminal Alkenes and Functionalization 1.00
Charge‐Directed Ionic Frameworks Based on Pillar[6]arene for Iodine Capture: Synergistic Confinement and Polyiodide Stabilization 1.00
Functional Upcycling Discarded Poly(Ethylene Terephthalate) Bottles for Ultralong Organic Phosphorescence Polymer Elements 1.00
Bridging Uranium Uptake and PET Plastics Degradation Within an All‐Inorganic Polyoxoniobate Framework 1.00
Alternating Pulse Driven Periodic Reactivation of High-Entropy Mesoporous Film Boosts Continuous Membrane-Free PET Waste Upcycling Coupled with H2 Production 1.00
Boosting Electrochemiluminescence in Ring‐Contracted Porphyrins via Central‐Coordination Modulation 1.00
Metastable Sn-O-Pd Sites Modulating the Seesaw Effect Specifically Activate H2O2 for the Identification of Plasticizers 1.00
Dual‐Site Synergistic Electrocatalysis Enables Highly Selective Upcycling of Real‐World Plastic Waste to Glycolic Acid 1.00
Discrete Chiral Metallacycle-Based Membrane for Highly Efficient Enantioseparation 0.86
15 13.09
Upcycling Waste PET Into Ionic Liquid-Derived Small-Molecule Adhesives 1.00
A Bipolar Integrated Electro‐Chemocatalysis System for Continuous‐Flow Paired Synthesis of Cyclohexanone Oxime at Industrial‐Relevant Current Density 1.00
Pairs of Zirconium Site and Hydroxyl in MOFs Enable Generating Peroxo Species for Efficiently Tandem Oxidative Condensation of Aromatic Amines 1.00
Single‐Atom Photocatalyst as Floatable Artificial Leaf for Upcycling Oceanic Plastic Waste 0.14
High-Performance, Recyclable Thermosets Enabled by Thiosemicarbazone Dynamic Bonds via Synergistic Dynamic Covalent and Supramolecular Networks 1.00
Bioinspired Quinone Redox Cycling Enables Highly Selective Photocatalytic Hydrogen Peroxide Production via Electron–Proton Relay 1.00
Suppressing Hydrogen Transfer and Aromatization Reactions Enables Efficient Photothermal Recycling of Polyethylene into Platform Olefins 0.94
Reversible Metal Coordination Switch Enables Activatable Sonodynamic Therapy via Dual-Death and Immune Synergy 1.00
Dynamic Geminal-Atom Coordination for Highly Efficient Photo-Fenton Catalysis 0.88
Electrical Catalysis of Forbidden Transitions in Single‐Molecule Devices 0.13
Synergistic Cu2 and Polyoxometalate Clusters in Metal–Organic Layers Enable Oxidant-Free CH4 Photooxidation 1.00
Copper-Driven Allosteric and Self-Encapsulating Polymers for Tumor-Specific Fluorescence Imaging and Dual-Enzymatic Cancer Therapy 1.00
Upgrading Natural Ores for Efficient Photothermal Polyester Recycling 1.00
A Broad Range of Aromatic Carboxylic Acids for Photocatalytic Methane Oxidation 1.00
Modular Molecular Editing of End‐of‐Life PBT for High‐Performance Sustainable and 3D‐Printable Platforms 1.00
22 21.29
Effect and Mechanism of Deep Eutectic Solvents as Mobile-Phase Additives on Retention Behavior of G‑Quadruplexes in Reversed-Phase High-Performance Liquid Chromatography 1.00
Cucurbit[n]uril (n = 6 and 7)-Based High Affinity Enrichment of Basic Peptides Containing Multiple K/R Residues via Supramolecular Affinity Chromatography 1.00
Active Ruthenium-Based High-Entropy Nanozyme Through a “Chemical Tongue” for Recognizing Bioactive Components in Honeysuckle 1.00
Detection and Identification of Alkenes and Alkynes Using a 19F‑Labeled NMR Probe 1.00
A Live-Cell Analytical Platform by Using Strigolactones-Induced Dimerization System 1.00
Epitope-Directed Antibody Development and Enhancement for Broad-Spectrum Fentanyl-Class Substance Detection: From Rational Hapten Design to On-Site Analysis 1.00
An Effective Method for Evaluating Antioxidant Capacity: Integrating Chemical Kinetics and Stoichiometry Based on the Study of the Antioxidant Behavior in the Mixture 1.00
Efficient and Selective Arsine Evolution Reaction on the VS4–x-Modified Electrode for Atomic Spectroscopic Quantification of Sub-ppb Level AsIII 1.00
A Fluorescent Palladium–Ligand Platform for In Situ Monitoring and Bayesian Optimization of Sonogashira Coupling Reactions 1.00
Universal Enrichment and Sequencing of DNA Modifications Using a Click-Coupled IgG-Protein A/G System 1.00
Host–Guest Doping Room-Temperature Phosphorescence Sensing Strategy for the Detection of Related Substances in Naproxen APls and in the Production of Dosage Forms 1.00
Framework Doping Enhances COF-DNA Nanoplatforms for Dual RNA Imaging and Phototherapy 1.00
Protein Labeling and Intramolecular Cross-Arylation via Rational Tuning of Bis-Halogenated Pyridiniums 1.00
Conformation-Locked Near-Infrared Probes for Real-Time Visualization of G Protein-Coupled Receptor Dimers in Living Systems 1.00
Efficient Photochemical Generation of Germanium and Arsenic Hydrides in a Sulfite and Iodide Medium 1.00
Spatiotemporal Control of RNA Functions via Bioorthogonal Chemistry for Activatable Biosensing 1.00
Novel Near-Infrared Cyanine Dyes for DNA Sequencing 1.00
Photochemical Vapor Generation of Platinum: Mechanism and Analytical Application 1.00
A General Strategy for Triggerable Donors and Analyte-Replacement Fluorescent Probes of Hydrogen Selenide 1.00
Principal Component Analysis Followed by Mahalanobis Distance Classification for Authentication of iVaccinium/i Berry Ingredients and Supplements via LC-MS/MS-based Anthocyanin Fingerprinting 0.29
ArticleJune 11, 2025 Microdroplet Accelerating C(sp2)–H Halogenation in Organic, Pharmaceutical, Analytical, and Environmental Use 1.00
In-Column Click Chemistry for the Preparation of Chromatographic Stationary Phase Materials and Online Evaluation of the Reaction by Chromatographic Behaviors 1.00
485 452.08
Nickel/Photoredox Dual-Catalyzed Migratory Reductive C(sp2)–H/Si–Cl Cross-Coupling 1.00
Single-Atom Iron-Catalyzed Oxidative Esterification: From Methylarenes to the Upcycling of Polystyrene and Lignin-Derived Feedstocks 0.54
Photocatalytic Synthesis of Aromatic Nitriles Using TiO2 Nanotubes Decorated With Bismuth Halide Perovskite Nanodots 1.00
Asymmetric Reductive Three‐Component Annulation Reaction for Constructing Fused N‐Heterocycles With Contiguous Stereogenic Centers 0.80
Oxidative PCET-Triggered Benzylic C─H Iminolactonization via 1,5-HAT/Cyclization Enabled by Cage-Confined Photocatalysis 1.00
Palladium-Catalyzed Regiodivergent Telomerization of Isoprene With Oxindoles 1.00
Meso-Strap Engineering of Aromaticity Redistribution in Porphyrinoids 1.00
Br-Mediated Pd Catalysis Promotes Intermediates Stabilization and Coupling for Anodic Electrosynthesis of Dimethyl Carbonate 1.00
A Highly Strained All‐BODIPY‐Based Nanohoop 1.00
W1/TiO2−x Enabled Photoelectrochemical Tandem Upgrading of Glycerol to Nucleoside Precursors 1.00
Nickel–Boryl-Catalyzed Modular Alkyl Difluoromethylation Enabled by an NMP-Stabilized ICF2H Reagent 1.00
Nickel‐Catalyzed Boron‐Mediated Saturative Trifunctionalization of Alkynes 1.00
Biobased Cyclic Enoate Monomers: Enabling Intrinsically Crystalline, Chemically Recyclable, Ultratough Polymers 0.88
Diastereomeric Configuration Modulates Liquid–Liquid Phase Separation and Catalysis in Minimalist Dipeptide Coacervates 1.00
Photoredox‐Catalyzed Chem‐ and Stereoselective Thiosulfonylation of Cyclopropylamides 1.00
Benzodithiolane-Enabled C─O Bond Activation for Deoxygenative Functionalization of Carbohydrates and Nucleosides 1.00
Steric‐Engineered Thermodynamic Gating: Metastable Assemblies for Chemical‐Class Discrimination of Synthetic Cannabinoids 1.00
Beyond para- and meta-Substitution: Synthesis and Biological Validation of Chalcogen-Rich Thiabicyclo[3.1.1]heptanes as Bioisosteres of Aryl Thioether Derivatives 1.00
Synthesis of Chonemorphol A, Chonemorphol C, and Ecdysantheroside A Aglycone From Simple Steroids 1.00
Palladium-Catalyzed Three-Component Coupling Through Carbene Migratory Insertion: Access to Allenes and 1,5-Enynes 1.00
Nearly 100% Valorization in Seconds: Transforming PET-Metal Oxide Mixtures Into M1Ox Clusters on rGO and Premium Syngas/Aromatics Products 1.00
Near-100% Selective Photocatalytic Methane-to-Methanol Conversion Enabled by Synergistic Chlorine Radicals and Oxygen Vacancies 1.00
Supramolecular Near‐Infrared Photocatalysts for Efficient and Oxygen‐Tolerant Aqueous RAFT Polymerization 0.86
Skeletal Rearrangement of Indazoles to Indoles With α-Trifluoromethyl Diazosilanes 1.00
Accelerating SuFEx Reactions via Aryl Fluorosulfate Structural Engineering for Enhanced Covalent Targeted Cancer Therapy 1.00
Formation of an Amorphous LaAlBOx Overlayer on Crystalline LaAlO3 Perovskite for Highly Efficient and Stable Propane Oxidative Dehydrogenation 1.00
Visible-Light Unlocked Carbene Insertion and Radical Release in a Structurally Constrained Pincer Phosphorus Compound 0.38
Electrophotocatalysis Enables Birch‐Type Dearomative Alkylation 1.00
Ligand‐Controlled Chemoselective and Enantioselective Cyclization of Enynes With Aroyl Chlorides 1.00
Intermolecular Interactions Regulating Exciton Behavior in Hydrogen‐Bonded Organic Framework for Photocatalytic Aerobic Oxidation 1.00
Unassisted Electrocatalytic Hydrogenation Coupled With Aldehydes Oxidation on Bifunctional Pd–Cu Synergistic Sites 1.00
Polyethylene as a Hydrogen Source for C─O Bond Cleavage Via Transfer Hydrogenation 1.00
A Bioinspired Approach toward the Complex Cyclotaxane Taxpropellane 1.00
BIBOP-Catalyzed Asymmetric Staudinger/aza-Wittig Reaction: Unified Syntheses of (–)-Minfiensine and (+)-Aspidophylline A 1.00
Photocatalyzed Hydro-acrylonitrilation of Alkenes 1.00
A Unified Radical C–SuFEx Platform via Catalytic EDA Complex‐Mediated S(VI)─F Bond Activation 1.00
High‐Entropy Catalyst Activated Molecular Oxygen for Oxidative Coupling Under Ambient Conditions 1.00
Regulating π–π Stacking Interactions to Boost Near-Infrared Light-Driven CO2 Reduction 1.00
Threading an Aluminum Molecular Ring Onto a Chemically Growing Copper-Directed Polyrotaxane 0.86
Proteolysis‐Assisted Cyclization Facilitates Site‐Centric Target Deconvolution of Isothiocyanates 1.00
From Mechanism to Catalyst: Integrated Catalysts for Direct Electrosynthesis of Glycine Through an Oxime Pathway 1.00
Hierarchical Mesoscale Trapping Controls Pathway Selection in Supramolecular Polymerization 1.00
Cooperative Sulfate Binding Drives Hierarchical Assembly of Supramolecular Trimers 1.00
Precisely Constructing Ag1/C3N4 Dual-Site for Highly Efficient Chlorine-Mediated Electrocatalytic Methane Valorization 1.00
Highly Regioselective Trifluoromethylation of Unprotected Phenols and Anilines Enabled by an Engineered P450 Peroxizyme System 1.00
A Stable Open‐Shell Polycyclic Hydrocarbon With Schlenk‐Chichibabin Hybrid Conjugation 1.00
Enzymatic Redox Gating Directs Oxidative Divergence in Acyclic Peroxides Biosynthesis 1.00
Catalytic Asymmetric Construction of Si‐Chiral Silabicyclo[3.3.1]Nonanes Using Functionalized Prochiral Silacyclohexanones 1.00
Photoactivated Signaling Networks using DNA-Based Synthetic Organelles as Biomimetic Protocells 0.57
Selective Para-Functionalization of Aromatic C(sp2)─H Bonds via Atomically Dispersed Photocatalysis 0.06
Multicomponent C−H Activation/Annulation Polymerizations Toward Structurally Regular Polyelectrolytes With Light-Boosted Antibacterial Potency 1.00
Enantioselective Synthesis of Inherently Chiral Tetraphenylene Analogues Enabled by NHC‐Catalyzed Benzoin Condensation 1.00
Catalyst‐Free, Divergent Cysteine Modification via Indole Isocyanide Photochemistry 1.00
Integrated CO2 Capture and Conversion Induced by Amines for Effective Electrocatalytic N-Methylation 1.00
Integrative, Orientational Self‐Sorting at the Four‐Crossing Level in Molecular Knots and Links 1.00
Photo‐click Proteolysis‐Targeting Chimeras Enable Intracellular Generation of PROTACs for Precise Dual Protein Degradation 1.00
Solar-Driven Photocatalytic C─S Coupling for Organosulfur Synthesis Via Upcycling SO2 and Plastic Waste 1.00
10.1002/anie.8135901 1.00
Light-Induced Chiral Aldehyde/Palladium Catalysis-Enabled Asymmetric Allylic C─H Alkylation of Alkenes With NH2-Unprotected Amino Acid Derivatives 1.00
Hydroxylamine Hydrochloride as Bifunctional Reagent for Aminochlorination of Alkenes via Iron Catalysis 1.00
Ligand-Switched Regiodivergent Fluoroallylic Alkylation of Secondary Nitroalkanes via an Unusual Inner-Sphere Pathway 0.91
Electrochemically Driven Enzymatic Oxidative Desymmetrization for the Enantioselective Construction of Silicon Stereocenter 1.00
Room-Temperature Gas-Phase CO2-to-C3 Coupling by a 4f-Aromatic Cluster 0.88
Palladium/Photoredox-Catalyzed Three-Component Coupling for Glycoconjugation 1.00
Study of form factors and observables in B− c → ¯D(∗)0ℓ−¯νℓ and B− c → D(∗)−ℓ+ℓ− decays 1.00
Electrochemical Biomimetic Iron-Catalyzed Benzylic C─H Bonds Hydroxylation 1.00
Anion Size‐Dependent Conformational Folding of Guanidinopropionate: Enabling Tunable Birefringence and Balanced Second‐Harmonic Generation Performance 1.00
Strain‐Sequenced Synthesis of a Quadruply Twisted Cycloarene With Alternating [4]/[5]Helicenes 1.00
Formal Allylic C(sp3)−H Carboxylation With CO2 via Copper Metallaphotoredox Catalysis 1.00
Selective π‑Metalation of Nut[6]Arene With Large and Chiral Cavity for Recognition Toward Bulky Anions in Water 1.00
Suppressing Metallic Co0 Formation in Co-Based Catalyst by In-Situ Selective H2 Oxidation for Efficient Ethane Dehydrogenation 1.00
Replacing Metabolically Unstable Amides With Stable α‐Trifluoromethylamines via Decarboxylative Synthesis 1.00
A 12‐Crossing Vertex‐Fused Double‐Triangle [5]Catenane with Programmed Topological Handedness 1.00
Electrode “Cocktail Effect” Enables Charge Selective C─C Bond Cleavage of Acetonitrile for Aryl Halide Methylation 1.00
Enantioselective Total Synthesis of Breviones Utilizing a Bio‐Inspired Skeletal Editing Strategy 1.00
Selective Oxidation of Tertiary Silanes Enabled by Tandem Single Atom Cerium Catalyzed Water Splitting/Non‐Bonding Phosphorus Site Promoted Nucleophilic Substitution 1.00
Selective Glycine Electrosynthesis via C‐N Coupling Enabled by Synergistic Mott–Schottky Heterojunction and Oxygen Vacancies 1.00
Enantioselective Synthesis of Isoquinuclidine Analogs by Synergistic Copper/Amine-Catalyzed Sequential [3 + 3]/[4 + 2] Cycloaddition 1.00
Migration at Boron Cage for Selective B–H Functionalization of nido-Carboranes 0.64
Organoboron Cycloarenes: Boron‐Carbon Annulated Macrocyclic π‐Systems 1.00
Ligand-Intercalated MOFs Enable Reaction-Pathway Engineering in Biomass Electrooxidation via Steric and π-Electronic Microenvironment Control 0.81
Enantioselective Synthesis of Polycyclic Spiroheterocycles by Chiral Phosphoric Acid Catalyzed Dearomative Cyclization of γ-Hydroxy Ynamides 1.00
Cyclooctatetraenyl Metal−Organic Octahedra and Their 3D Cage to 2D Nanosheet Transformations 1.00
Acetal[6]Arenes: Rigid Chirality-on-Annulus Macrocycles Promoting Charge-Transfer Co-Assembly With Exceptional (Chiro)Optical Properties 0.91
Molecular-Gate Strategy for Solid-State Selective Recognition of Dioxane Isomers via Reversible Host–Guest and Charge-Transfer Modulation 1.00
Bioinspired Design of F–Zn Sites in Layered Double Hydroxides for Photothermal Catalytic Upcycling of Polyethylene Terephthalate 1.00
Enantioselective Intermolecular Photocycloaddition of Indoles 1.00
Boracycle-Annulation Stabilizes Antiaromaticity and Enhances Diradical Character in s-Indacene/Dicyclopenta[b,g]Naphthalene-Cored Organoboron Polycyclic Hydrocarbons 1.00
Iron-Catalyzed Anti-Markovnikov Hydroxyazidation of Unactivated Alkenes 1.00
Unlocking Efficient Spontaneous Deracemization: A MOF‐Mediated Heterogeneous System Overcomes Catalytic Incompatibility in Cocrystallization 1.00
Redox-Neutral Electrochemical Cis-Cyclopropanation of Alkenes With Sulfoxonium Ylides 1.00
Captodative Radicals Coupling Into Homochiral Molecular Nanotubes With Conglomerate Crystallization 1.00
Dissipatively Fueled Unidirectionally Communicating DNA Circuits That Control Biocatalysis 0.14
Nickel-Catalyzed Enantioselective Direct Addition of 1,3-Dienes to Aldehydes Enabled by Chiral Monodentate Diamidophosphite Ligands 1.00
Ambient One-Pot Electrocatalytic Synthesis of Caprolactam From Cyclohexanone and Nitrate Over Ag-Ag4Sn-SnO2 Nanoparticles 1.00
Asymmetric Dearomative Dual‐Functionalization via Rearomatization‐Blocked Sulfonium Claisen Rearrangement 1.00
Cu/La Cocatalysis Enables 1,4-Aminative Difunctionalization of 1,3-Dienes 1.00
Skeleton Editing of Indenes With Metal Carbenes to Access 1,2-Dihydronaphthalenes 1.00
Enantioselective Synthesis of Axially Chiral Anthracenes via [4+2] Cycloaddition and Cycloreversion of Cyclopentadienones 1.00
Tailored Pyridine Enables Diverse Electrochemical Benzylic C–H Functionalization 1.00
α-Trifluoromethyl Substituted α-Hydroxyhydrazides as Dianionic Ligands Enable Cu-Catalyzed Aryl Amination With Higher Turnovers 1.00
Single-Atom La Promoter Breaks the Activity–Stability Trade-Off on Al2O3-Supported Pt Catalysts for Propane Dehydrogenation 1.00
Viologen Covalent Organic Frameworks Integrating Synergistic Singlet and Triplet Excitation for Efficient Photosynthesis of Benzazole Pharmaceuticals 1.00
Photomediated Controlled Radical Homopolymerization of Sulfonated α-Olefins and Vinyl Ethers with Propagating Sulfonyl Radicals 1.00
1,3‐Dicarbonyl Rhodamines for Live‐Cell Single‐Molecule Super‐Resolution Imaging 1.00
Electrosynthesis of Chlorohydrins From Alkenes in Seawater Enabled by On‐Site Generated Active Surface Chlorine Intermediate 0.88
Chemical Primary Color Pixels for Full-Color Image Encoding and Decoding 1.00
Isolable Monocyclic N-Heterocyclic Radicals Supported by Rare-Earth Organometallics 1.00
Modular and Direct Synthesis of γ-Sultines From Simple Unactivated Alkenes 1.00
Lewis Base-Catalyzed DYKAT of Racemic Chlorohydrosilanes With Grignard Reagents En Route to Si-Stereogenic Hydrosilanes 1.00
Enantioselective S-Alkylation of Sulfenamides With Copper-Catalyzed Amino-Radical-Transfer Deboronation 0.67
Enhancing Memory of Chirality in Phosphorus‐Centered Radicals by Inductive Deceleration of Pyramidal Inversion 1.00
Aqua-Oxidation of Polyethylene Into Carboxylic Acids Under Mild Conditions: A Catalyst-Free Upcycling Strategy for Nonpolar Plastics 1.00
A Modular Approach to N-Fluoroalkyl Amides via Nitrene Insertion Into Fluoroalkylcopper(I) 1.00
Photoswitch Mediated Electron Highway Driving Direct Pollutant‐to‐Oxidant Electron Transfer in Ultrafast Fenton‐Like Reactions 1.00
Millisecond Aliphatic Iodonium-Claisen Rearrangement Enabling Dual Functionalization of Alkenyl Iodanes 1.00
Synergistic Ion‐Pair/Lewis Acid Catalysis Enables Enantioselective Synthesis of Helically Chiral Oxa[6]Helicenes 1.00
Catalyst-Free Ammonia Formation at the Gas-Liquid Interface Enables Selective Nitrogen-Saccharide Association Under Abiotic Conditions 1.00
Mild Generation of Highly Nucleophilic N-Heterocyclic Carbene Boryl Anion From Neutral sp2–sp3 Diboron Reagents and Its Applications in Nucleophilic Borylation 1.00
A Monkey-Saddle-Shaped Nanographene Embedding a Dicyclohepta[cd,fg]-as-Indacene Core and Two Additional Heptagons, and Its Paddle-Wheel Co-Assembly With Fullerenes 0.71
Bioinspired Total Synthesis of Curtachalasin B and Biosynthetically Related Cytochalasans 1.00
Mechanically Triggered Chemical Recyclable Polyethylene‐Like Materials 0.50
Palladium‐Catalyzed Enantioselective Four‐Component Carbonylative Dicarbofunctionalization of Internal Alkenes With 1 Atm CO 1.00
Ligand‐Engineered Metal–Organic Cages Boost Charge Separation for Efficient Photocatalytic Synthesis of Hydrogen Peroxide in Pure Water 1.00
Copper‐Catalyzed Regio‐ and Diastereoselective Dearomative Carbosilylation of Unactivated Arenes by Intercepting the Dienyl Radical 1.00
Minimizing H2O2 Loss in Industrial Electrosynthesis via Asymmetric Main-Group Sn Single-Atom Catalysts 1.00
Sequential Radical‐Anionic Polymerizations via Consecutive Photo‐Reduction 1.00
Charge‐Regulated Pyridinic Nitrogen in Covalent Organic Frameworks for Metal‐Free Heterogeneous Photocatalytic C─H Arylation of Pyrroles 1.00
Predictive, Data‐Driven Design of Red‐Light Photoredox Catalysts for C─Heteroatom Bond Formation 0.14
Phosphine-Catalyzed Enantioselective [2 + 2] Annulations of α-Allyl γ-Benzyl Allenoates via a Transannular Cyclization Approach 1.00
Access to Axially Chiral Vinyl Sulfilimines via Copper-Catalyzed Enantioselective Radical Relay Trifluoromethyl-Sulfilimination of Terminal Alkynes 1.00
Synthesis of Axially Chiral Phenanthryl–Aryl Phosphines via Nickel-Catalyzed Atroposelective [4 + 2] Cycloaddition with Broad Ligand Applications 1.00
Pickering Emulsion Interfaces Enhance Photocatalytic Selective Oxidation of Aromatic C─H Bonds 1.00
Stereospecific Transition‐Metal‐Free Alkylation of Chiral Non‐Racemic Secondary Tosylates with Cyanohydrins: Convenient Access to Enantiomerically Enriched α‐Tertiary Ketones 0.25
Nanocrystalline Sn for Photoelectrocatalytic Synthesis of Stereocontrolled Oxime 1.00
Energy‐Transfer‐Enabled Skeletal Rearrangement of Cyclic Ketones into Strained Cyclopropane‐Fused Medium Rings 1.00
Selective Singlet Oxygen Generation over a Silver–Porphyrin Single‐Atom‐Site Catalyst for Ultrafast Sulfide Photooxidation 1.00
Conjugation Engineering Boosts Alkynyl‐Copper Photocatalysis for Efficient Selective Aerobic Oxidation 1.00
Energy‐Transfer‐Enabled Copper‐Catalyzed Direct Site‐Selective Cycloaddition of Unprotected Oximes with Alkenes 1.00
Halide Bond Assisted Double Desymmetrization of Meso-Dicarboxylic Acids with Symmetrical Olefins via Asymmetric Halogenation 1.00
<atl>Photoredox/Cobalt‐Catalyzed Asymmetric Radical Addition to Imines with Furanosyl 1,4‐Dihydropyridines to Access iC/i ‐Glycosyl Amino Esters</atl> 1.00
Nickel-Catalyzed Chemo- and Diastereoselective Dearomative Dialkylation of Indoles with Two Different Alkyl Halides 1.00
Controlled Radical Copolymerization of Hydrofluoroolefin 2,3,3,3-Tetrafluroropropene (R1234yf) via Thermally Activated Delayed Fluorescence Catalysis 1.00
Late-stage Tyrosine ortho-C(sp2)-H Alkenylation for Macrocyclic Peptide SuFEx Proximity Labeling and Targeted Degradation 1.00
Iron-Catalyzed Enantioselective Deoxygenative Addition of Propargyl, Allyl, and Benzyl Alcohols to Cyclic N-Sulfonyl α-Ketiminoesters Mediated by Visible Light 1.00
Skeletal Editing of Hydroxyl Oxindoles via Organoiodine-Catalyzed Oxygen Atom Insertion Reaction 1.00
Single‐Atom‐Modulated Reactive Oxygen Species Generation and Network Crosslinking in Porphyrin‐Based Metallacages for Selective Photocatalysis 1.00
Formal [4+3] Bridged Cyclization of Pyridines/Isoquinolines with Vinylcarbenes via Dearomatized Oxazinopyridine Intermediates 1.00
A Photoelectrocatalytic Platform for Sequence-Unrestricted Modification of Oligonucleotide Backbones 1.00
Dynamic Metal-Organic Tube Isomers 1.00
Brominated Pd-on-Au Nanostructures Enable Reductive Relay Isomerization of Alkynes to E-alkenes 1.00
Bidirectional Photoregulated Chromism in Pyridinium Derivatives via Secondary Excitation‐Driven Electron Transfer 1.00
Practical Synthesis of Allylic Heteroaromatic Amines via Pd‐Catalyzed Oxidative Amination of Olefins 1.00
A Stable Triindenobenzotrithiophene Triradical with Equilateral Ferromagnetic Spin Coupling 1.00
Pulse-Constructed Cuδ+/CuOx Reduces the C─Cl Dipole Moment to Enable Complete Deuterodechlorination of Trichloroacetic Acid 1.00
Dispersion‐Enhanced Nitrogen‐Centered Photocatalysis of the Direct Hydrogen Atom Transfer 0.65
Networked Porous Organic Cage Membranes for Precision Separation of Pharmaceutical Ingredients 1.00
Temperature-Controlled Synthesis of Corannulene-Based Multi-Helicenes: Highly Integrated Curvature/Planarity for Enhanced CPL Brightness and Solid-State Luminescence 1.00
A Boron-Doped Buckybowl with a C42B2 Core: Synthesis, Crystal Structure, and Optoelectronic Properties 1.00
Minimalist Molecules Drive Liquid–Liquid Phase Separation to Modularly Assemble Functional Coacervate Protocells 1.00
Stereochemical Dissection of the Strobilurin PKS Reveals the Complex Biosynthetic Logic of Iterative EZE Triene Construction 0.08
Confined Chiral Center Stacking Induced Twisted Silica Nanoribbons for Tumor Cell Proliferation Regulation 0.79
A Para‐Selective Kolbe–Schmitt Reaction 0.67
Hydroxyl Radicals Unlock Strong C(sp3)─Si Bonds: Photocatalytic Alkylation and Silacycle Engineering 0.88
Enantioselective Synthesis of Chiral Sulfinamidines via Asymmetric Amination of Sulfenamides Using a Chiral Phosphoric Acid Catalyst 1.00
A Modularly Integrated Chiral Cavitand 1.00
Bifunctional Photoactive Chiral Ligands Enable Visible-Light-Induced Nickel-Catalyzed Enantioselective C−O Coupling 1.00
Biomarker-Gated Photocatalysis Uncaging in Live System 1.00
Total Syntheses of Diketopiperazine Alkaloids via Divergent C3–N1' and C3–C5' Bond Anchor 1.00
Regiodivergent Chain-Growth Polymerization of Aza-π-Allylpalladium Zwitterions via Proton Transfer 1.00
Electrocatalytic Migratory Carboxylation of Unactivated Olefins or Halides with CO2 1.00
Ligand-Promoted Site-Selective Regiodivergent Lactamization of Activated δ- versus Inert γ-Methylene C(sp3)–H Bonds via Open-Shell Copper(II) Nitrenoid Catalysis 1.00
Engineering a Thermally Activatable SpyCatcher/SpyTag Protein Ligation for Injectable and In Situ‐Forming Hydrogels 1.00
Hydrophobic NIR Photocatalysts for High-Throughput RAFT Aqueous Solution Polymerization: Achieving Ultrahigh Molecular Weights with 4-ppm Dye Colloids 0.67
Synergistic Pd/Cu-Catalyzed Stereodivergent Controlling of the Z/E and R/S Configurations: Synthesis of Non-Natural α-Amino Acids Containing Trisubstituted Olefin 1.00
Nanoconfined Photocatalytic Cascade Reaction in Vinylene‐Linked Covalent Organic Frameworks 0.91
Construction of Biaryl Skeletons Initiated with Benzyne Insertion into C═S Double Bond of Pyridine-2(1H)-thiones 1.00
Streamlined Sugar Diversification via Photoredox-Catalyzed Regio- and Stereoselective 1,2-Alkylarylation of Glycals 1.00
Copper-Catalyzed Enantioselective Radical Desymmetrizing Cyclization of Cyclopentenes: Access to Chiral 2-Azabicyclo[2.2.1]Heptan-3-ones 1.00
Highly Diastereo‐ and Enantioselective Pd‐Catalyzed Spiroaminoalkylation: One‐Step Construction of Multifunctional Angular Polycyclic Amines 1.00
Highly Efficient Construction and in Situ Post‐Assembly Modification of Multifunctional Metal–Organic Cages in Microdroplets 1.00
Stereodivergent Construction of Spiropyrrolidine-γ-Butyrolactones Enabled by Cu/Ru Sequential Catalysis and Stereoselective Reduction 1.00
Enantioselective Synthesis of H-Phosphinamidates 1.00
Crystalline 90°‐Twisted Carbon‐Centered Non‐Kekulé Diradical Derived from N‐Heterocyclic Carbene 1.00
Radiation-Responsive Coacervates Through Controlled Self-Immolative Demembranization 1.00
Inner-Axial Chlorine Engineering Enables Efficient and Selective Phenol Electrocatalytic Upcycling to Benzoquinone on Noble-Metal-Free Catalysts 1.00
Synthesis and Upcycling of All‐Carbon‐Backbone Degradable Polyethylene with Dispersed On‐Chain Ketones 1.00
Highly Selective Electrosynthesis of Glycine from Glyoxylic Acid and Nitrate via Stabilizing the NH2OH Intermediates 1.00
Electrochemical Controllable Divergent Carboxylation and Hydrocarboxylation of Alkynes with CO2 1.00
Copper-Catalyzed Phosphorus Radical Transformations for the Assembly of P-Stereogenic Architectures 1.00
Carbonyl-to-Silicon Exchange of Aromatic Lactones via Decarbonylation 1.00
Construction of Artificial Cells with Urea Cycle Pathway for Ammonia Detoxification 1.00
Ring Expansion of Oximes via Photochemical Aza‐di‐π‐methane Rearrangement 0.75
Compressed Co–O Bonds Resist Chlorine Corrosion to Enhance the Stability of Chlorine‐Involved Anodic Reactions 1.00
Hyalucidin A: A Bacterial RiPP Featuring a Benzofuranoindoline Motif Biosynthesized by Tandem P450 Catalysis 1.00
Switchable Phenanthroline‐Cu Catalysts for Enantioselective Alkynylation and Amination of Cyclic Diaryliodonium Salts 1.00
Hierarchical, Template-Controlled Self-Assembly of Two Different Organometallic Capsules from a Tetrakisimidazolium Salt 0.83
Enhanced Selectivity of Chalcogen Bonding over Halogen Bonding Catalyzed C-glycosylation Through Differentiated Intermediate Activation 0.50
Noble Metal-Free Photosensitive Terpyridine Coordination Assemblies for Efficient Single-Molecule H2O2 Photocatalysis 0.91
Electron‐Enriched Pt‐In Synergistic Sites for Highly Selective and Direct Photo‐Reforming of PET Plastic Wastes into Acetic Acid 0.75
Environment-Responsive Self-Assembly and Coupled-Network Effect in Dynamic Replicating Nucleopeptide Networks 1.00
Synergistic Enhancement of Photoredox Catalysis Beyond the Singlet Bottleneck Through Triplet Charge Recombination and Magnetic Field Effects 1.00
Nickel-Catalyzed Enantioselective Reductive Cyclization of 1,3-Dienes Toward α-Chiral Six-Membered Silacycles 1.00
Thiol–Ene Photoclick Chemistry for Efficient Bicyclic Peptide Synthesis and Genetically Encoded Peptide Library 1.00
Graphitic C6N6-Supported Dual Cu/Zn Single-Atom Nanozyme Mimicking Allosteric Regulation for Intelligent Switching Biosensing 1.00
Cationic‐Catalyst Strategy Enabling Ultrafast and Controlled Polymerization and Efficient Depolymerization Toward a Circular Polymer Economy 1.00
Miniature Photoenzyme Enables Organelle-Specific Cellular Control via Deboronative Hydroxylation 1.00
Decarboxylative Arene Ring-Opening of Benzoic Acids 1.00
Revealing Pathway Complexity in Host–Guest Binding: Allosteric Regulation and Temporal Chiral Inversion During Complexation of Naphtho[2,2]urils 0.88
Integrating the Substituent Effect into the Wade–Mingos Rules for Dicarboranes 0.57
A Photo- and Cobalt-Catalyzed Enantioselective Hydroamination of Unactivated Alkenes with Amines 1.00
Stereodivergent Access to C-N Atropisomers via Phosphonium Salt-Enabled Desymmetrizing Remote Cyclization/Aromatization Cascade 1.00
Ultrafast Single Electron Transfer Enables General Visible Light C─X (S, SS, Se) Coupling via Carbonyl Activation 1.00
Stereoselective Synthesis of 2-Deoxy-β-O-Aryl Glycosides by a One-Pot Strategy Involving C─O Coupling and Catecholborane Reduction 1.00
Integrated Conversion of Polyesters, CO2, and Glycerol via Ethylene Oxide-Mediated Tandem Process 1.00
All-Nido-Carborane-Protected Copper Clusters 1.00
Iridium Porphyrin-Catalyzed Asymmetric Rearrangement of Oxindoles with Aryl Diazoesters: Enantioselective Synthesis of Chiral Tertiary 2-Indolyl Alcohols 1.00
Anionic Hofmeister Effect Differentiated Subcellular Distributions of pH-Responsive Metal–Organic Cages for Tumor Photodynamic Immunotherapy 1.00
Successive Sulfur Oxidation Directs Topological Transformation From 4 1 Knot to 62 3 Link 1.00
Anion-Assisted Copper/Chiral Diamine-Catalyzed Aerobic Oxidation for the Kinetic Dearomative Spirocyclization of Arenols 1.00
Cooperative Brønsted Acid and Photo‐Promoted Stereoselective Synthesis of Substituted Piperidones 0.08
One‐ and Two‐Electron Carbon–Halide Bond Activation at a Phosphorus Center 1.00
Efficient Electrosynthesis of Dinitrile from Nylon-66-Derived Diamine Enabled by Highly Active Mn–O–Co Motifs in Spinel Oxides 0.82
Divergent Ring‐Opening Functionalization and Reductive Coupling of Pyridines via Zirconium Alkylidene Complexes 1.00
Tailoring Spin–Spin Dipolar Interactions by Conformational Locking Toward Room-Temperature Molecular Qubits 1.00
Diversity-Oriented Post-Polymerization Modifications by Developing gem-Diboryl Polyolefin as a Platform Polymer 1.00
“Noninnate” Ring-Opening Polymerization: Palladium-Catalyzed Stereoselective 1,4-Polymerization of Alkynylcyclopropanes 1.00
C─H Silylation of Unactivated Arenes Catalyzed by a Borenium/Pyridine Lewis Pair 1.00
Asymmetric N‐alkylation of Carbazoles by Cooperative Potassium‐Hydrogen‐Bond‐Aryloxide Catalysis 1.00
Synthesis of 2‐Chlorocyclopropene‐Tethered Diazocarbonyl Compounds and Their Cyclization to Form Poly‐Substituted Phenols 1.00
Directing the Electrochemical C─N Coupling Toward Efficient Amide Synthesis via Ammonia Activation‐Mediated Pathway 1.00
Complete Recycling of Polyester Wastes with Dialkyl Carbonates 1.00
Access to Inherently and Centrally Chiral Calix[4]Arenes via Rhodium-Catalyzed C─H Activation and Insertion into Diverse Olefins and Alkynes 1.00
Catalytic Asymmetric Aza-[2+2] Cyclization Reaction of Simple Ketoimine 1.00
Construction of Tetrasubstituted α-Amino- and α-Alkoxy Phosphine Oxides via Pd-Catalyzed Regio- and Enantioselective Hydrophosphinylation of Dienes 0.90
Controlled Dual Activation of Rhenium(I) Photosensitizers and Profluorophores/Prodrugs via a Dissociative Bioorthogonal Tetrazine–Isonitrile Reaction 1.00
Catalytic Asymmetric Synthesis of Chiral Allenylic Fluorides Enabled by Multiple Radical Sorting 1.00
A General Strategy to Develop Intramolecular Spirocyclic Boron Dipyrromethene Fluorophores for Self‐Blinking Super‐Resolution Imaging 1.00
Atroposelective Synthesis of Ultrarigid Chiral Styrenes via Pd-Catalyzed Unconventional 5-exo-dig Cyclization/Carbonylation of 1,5-Enynes 1.00
Reductive Cross-Coupling of Alcohol Derivatives with Chlorosilanes via Pyridines-Promoted Si─Cl Activation 1.00
Machine Learning‐Driven Automated Synthesis of Polysubstituted Gentisaldehydes 0.67
Remote Enantioselective Redox ε-Alkylation of Copper Allylic Allenylidenes with Enals 1.00
Unravelling the Dynamic Modulation of Copper (Oxy)Hydroxides for Electrocatalytic Organic Nucleophile Oxidation 1.00
Iridium Photosensitizers Immobilized on Metal–Organic Layers Lead to Enhanced Enantioselectivity in Ni/Ir Dual Photocatalysis 1.00
One-Step Assembly of α-Aryl-Substituted DOTAs as Superior and Universal Platforms for Multifunctional Theranostics 0.94
Achiral Catalyst‐Induced Stereoselectivity Switch at Quaternary Stereocenter: Diastereodivergent Ring‐Opening Alkylation and Enantiodivergent Arylation of Oxindoles 0.92
Palladium-Catalyzed Enantioselective Three-Component Dearomative Coupling of Bromoarenes: Modular Construction of Terpenoid Scaffolds 1.00
Ruthenium-Catalyzed Diversified Kinetic Resolutions of Diaryl-Substituted Cyclobutenones via Asymmetric Transfer Hydrogenation 1.00
Dynamic Kinetic Resolution Approach to Chiral Sulfur-Containing Aza-[5]helicenes via Chiral Lewis Base Catalyzed C─H Sulfenylation 1.00
Mannich Cyclization of Bifunctional Hydroxylamines by Aza-Kornblum–DeLaMare Rearrangement to Form Cyclopentyl β-Amino Esters 1.00
Nor[7]circulenyl Neutral Radical and Its Charged Species: Synthesis, Structures, and Efficient NIR-II Photothermal Conversion for Imaging and Laser Ignition 0.80
Enantioselective Synthesis of α‐Arylated Allene Ketones Through Sequential Bismuth(V)‐mediated Arylation and Organocatalytic Protonation 0.20
Total Synthesis of Clerodin 1.00
Nickel-Catalyzed O-Alkylisourea-Enabled Electrochemical Radical C(sp3)−C(sp2) Cross-Coupling 1.00
Visible-Light-Induced [2π+2σ] Cycloaddition Enabled by Cage-Confined Photocatalysis for Precise Bicyclo[2.1.1]Hexane Construction 1.00
Synthesis of Degradable Polyimines Through Deborylative Polycondensation 1.00
Regio-, Stereo-, and Enantioselective Copper-Catalyzed Allylation of Sulfinylamines with Allenes 1.00
Direct Boron-10 Access: Nickel-Catalyzed Reductive C(sp2)─10B Coupling Utilizing 10BF3 1.00
Observation of Near‐Infrared Photothermal and Photoacoustic Effects in a Metallosupramolecular Trefoil Knot 0.83
Catalytic Enantioselective Synthesis of Axially Chiral Tetraarylethenes 1.00
Bis(azuleno)pentalenes with Six Consecutive Odd‐Membered Rings 0.50
Facile One-Step Synthesis of mathematical equation Link Cages by Coordination-Driven Self-Assembly 1.00
Synthesis, Structures, and CPL Property of Inner-Wall Modified Pagoda[5]Arenes Driven by Cavity Microenvironment 1.00
Photoredox/Nickel-Cocatalyzed Asymmetric C–O and C–S Couplings for Atroposelective Synthesis of N-Heterobiaryls 1.00
N‐Doped Nonalternant Molecular Bowl/Saddle Hybrids 1.00
Engineering Artificial Mitochondria with Self-Amplifying Proton Generation for Autonomous Energy Supply and Metabolic Coupling in Artificial Cells 0.75
Plasma-Electrocatalysis Cascade Synthesis of Deuterated Ammonia 1.00
Molecular Recognition Driven Organelle Cross‐Linking Induces Endoplasmic Reticulum Stress and Mitochondrial Dysfunction to Potentiate Cancer Immunotherapy 1.00
Visible-Light-Driven α-C(sp3)−H Carboxylation of Primary Benzylamines with CO2 to Access α-Amino Acids 1.00
Polycyclic Heteroaromatics with Planar‐Curved Hybrid Skeletons for High‐Performance Photocatalytic Hydrogen Peroxide Evolution 0.94
From Solvent to Catalyst: In Situ Amino Acid‐Like Species Enable PET Upcycling Without Added Catalysts 1.00
Site-Selective α─C─H Functionalization of Saturated Heterocycles via Copper-Photoredox Catalysis 1.00
Stable Iminium Singlet and Triplet Diradical(oid)s with Intense NIR-II Absorptions 0.50
Bioinspired Peptide‐Phosphonium Salt Catalysis Unlocks Asymmetric Desymmetrization of Phosphoryl Acids: Programmable Synthesis of P(V)‐Stereogenic Molecules 1.00
Unlocking DAST‐Type Reagents for Modular Synthesis of Sulfur‐Containing Motifs 1.00
Air‐Stable Allyl Radicals and Heterocoupled Dimer: Synthesis, Characterization, and Near‐Infrared Emissions 1.00
Atroposelective Synthesis of Enamine‐Based Axially Chiral Styrenes via CuH‐Catalyzed Hydroamination of Internal Alkynes 0.83
Transition‐Metal‐Free Carbonyl Redox: A Ketene in Three Oxidation States 0.67
Rapid Construction of a Tyr C6–Trp C5′ Linkage: Application in the Total Synthesis of Micitide 982, a Noncanonical Cyclic Peptide 0.80
Engineering Cavity and Aperture Binding Sites Within a Metal–Organic Cage for Up‐ and Down‐Regulation of Catalysis 0.63
Chemo- and Regiodivergent Allyl-Propargyl Cross-Coupling Reactions for the Construction of 1,4-Enallenes and 1,5-Enynes 0.63
A Highly Selective Nucleophilic and Radical Relay Difluorination of Cyclopropanes and Alkenes 1.00
Formal C─H Functionalization of Quinolines at the C7 Position Through a Traceless Directing Strategy 1.00
Steering Amide Synthesis from Acetonitrile by Electrochemically Derived Active Superoxide 1.00
Ni‐Mediated High‐Spin Iron(III) for Boosting Electrocatalytic NO to Oxime Conversion 1.00
Temperature-Driven Conformational Switching of Binaphthalene-Based Tetraimidazolium Macrocycles to Enhance Sequence-Selective Recognition of Dinucleotides in Water 1.00
Single‐Atom Ligation of Four Different Alcohols at One Silicon Center: Methodology Development and Proof of Concept 1.00
Nondestructive Patterning of Upconverting and Down‐Shifting Luminescent Nanoparticles for Information Encryption 1.00
1,4-Dearomatization of Pyridines and Quinolines Enabled by the Carbodication Lewis Acid 1.00
Electrochemical Alkyl Displacement of Thioethers for Streamlined Trideuteromethylation 1.00
Programmable Vertical Expansion of Bilayer 2D Supramolecular Frameworks via Molecular Pillar Engineering 1.00
Accessing N-Unprotected Unnatural α-Amino Acid Esters by Half-Sandwich Chiral-at-Ruthenium Aldehyde Catalysis: Scope and Mechanistic Study 0.71
In Situ Sulfur Modification Enables Electrochemical Selective Deuterated Thiol–Yne Reactions 1.00
Efficient Hydrogen Sulfide Separation from Carbon Dioxide Achieved by Carbonyl‐Functionalized Ionic Liquids for Natural Gas Upgrading 1.00
Enantioselective Synthesis of ε-Lactams via Rh(I)-Catalyzed C─C Bond Activation 1.00
Intercalation Chemistry Awakens Transition Metal Hydroxide for Boosted and Sustained Electrocatalytic Sulfion Oxidation 1.00
Photo-Induced Catalytic Dearomative Coupling of N-Heteroarenes 1.00
Catalysis of Radical Coupling Reaction via Synergistic Action of Oriented External Electric Field and Light Irradiation 1.00
A Facile and Efficient Route to Achieve Polythiophene‐Based Nanoparticles With Various Morphologies 0.92
Enantioselective Incorporation of Amine Fragments onto Quaternary Carbons via Metallaphotoredox Catalysis 1.00
Iron-Catalyzed Asymmetric [4+2]/Cheletropic Retro-[4+1] Cycloadditions of Thiophene S,S-Dioxides with 3-Substituted Indoles 1.00
Photo‐Mediated Silacyclization by Wavelength‐Dependent Selective C─F or C─H Functionalization 0.29
Alkali Metal Cations Impact the Selectivity of Radical‐Mediated Electrochemical C─H Chlorination 0.22
Regulation of Relay Catalytic Mechanism for Efficient Methanol Oxidation Reaction 1.00
Stereoselective Self-Assembly of a Topologically Chiral [6]Catenane with 18 Crossings 1.00
Tertiary Phosphine Diversification via Photochemical P─C Chemoselective Cleavage of Phosphonium Salts 1.00
Photocatalytic Formamide Synthesis from Plastic Waste and Ammonia via C─N Bond Construction Under Mild Conditions 1.00
Enantioselective Synthesis of Cyclobutane‐fused Heterocycles via Lewis Acid‐Catalyzed Dearomative [2+2] Photocycloaddition of Indoles, Benzofurans, and Benzothiophenes with Alkenes 0.71
Isolable Arylphosphinidene Chalcogenides and their Radical Anions 1.00
In Situ Cation-Switched Organometallic Cage Reconfiguration Enables Highly Selective Li+ Recognition and Extraction 1.00
Transsulfurase‐Catalyzed Reversible Modification of C‐Terminal Cysteine and Application for Orthogonal Dual Labeling of Proteins 1.00
A Tertiary Amine‐Based Electrolyte with Methylation‐Mediated Steric and Electronic Synergy for High‐Performance Lithium Metal Batteries 0.92
Degradable Polyketone Thermoplastic Elastomers with Biomass Sourced Composition 1.00
From Corrosion to Creation: Interfacial De‐Electronation Drives Hydrogenation‐Energy Symbiosis 1.00
A Bioinspired Diazafluorenone Catalytic System for Aerobic Oxidative Deamination of Primary Amines 1.00
Acetone Derivatives for Nickel-Catalyzed Methylation, Trideuteromethylation, and 13C-Methylation of (Hetero)Aryl Chlorides 1.00
Chiral Cryptographic Key‐Based Fluorescence Encryption Enabled by Stimuli‐Responsive Metal–Organic Frameworks 1.00
Nickel‐Catalyzed Sila‐Cycloaddition of Dichlorodisilanes: Selective Si─Cl Activation for Cyclic Disilanes and Enantioenriched Synthesis 1.00
A Phenomenological Symmetry Rule for Chemical Reactivity Under Vibrational Strong Coupling 0.11
Regio‐, Diastereo‐, and Enantioselective Hydrosilylation of Alkyl igem/i‐Difluoroalkenes to Construct Carbon and Silicon Stereogenic Centers 1.00
Construction of Fused–Bridged Tricycles by Molecular Reorganization Involving Prins Cyclization/Dicycloexpansion 1.00
A Self‐Assembled Protein Platform for Plug‐and‐Play Customization of Multivalent Artificial Antibodies and Antibody‐Drug Conjugates 1.00
A Modular Three‐Component Asymmetric Tsuji–Trost Reaction Enabled by Cooperative Palladium/Lewis Acid Catalysis 1.00
Asymmetric Radical Coupling to Form βsup2,2,3/sup‐Amino Acid Esters by Synergistic Chiral Phosphoric Acid and Photocatalysis 1.00
Dual‐Site Modulation of Mgsup2+/sup Desolvation Beyond the Primary Solvation Shell in Magnesium Battery Electrolytes 1.00
iN,O/i‐Alternant Belt[3]arene Utilized for Construction of Multi‐Color Supramolecular TADF Materials and Highly Selective Detection of 2‐Cyanopyrazine 1.00
Corral[in/i]Bicarbazoles: Redox‐Active Chiral Macrocycles for Air‐Stable Radical Cations Formation and Guest Capture/Release 1.00
Hydrophilic Iridium Bis‐iN/i‐Heterocyclic Carbene Complexes Catalyze Linear‐Selective, Additive‐Free Hydroaminomethylation of Long‐Chain Olefins in Water 1.00
Enantioselective Synthesis of Chiral Azepines: A Cascade Strategy Featuring 1‐Aza‐Cope Rearrangement 1.00
Stereoselective Synthesis of Glycomimetics by Photocatalytic One-Pot C(sp3)─H Acylation and Ring Contraction 1.00
Asymmetric Catalytic 1,2‐Azaarene Migration to α‐Azaaryl‐α‐Hydroxy Esters Enabled by a Tailored Ligand 1.00
SuFEx‐Enabled Polypeptide: Creating Diversified Properties with Minimal Preset Conditions 1.00
Visible-Light-Driven Iron-Catalyzed Atom Transfer Radical Addition of CH2Br2 to Alkenes: Facile Access to 1,3-Dibromo Compounds 1.00
Length Ratio-Driven Configurational Modulation of Heteroleptic Pd6L6L’6 Cages 1.00
Sustainable Closed‐Loop Recycling of Polyester Waste Using Reconstructed Defective‐Metal–Organic Frameworks 0.86
Photoredox‐Catalyzed Radical Relay for C─N Cleavage and Ring Expansion: Accessing Medium‐Sized Lactams From Unstrained Cyclic Amines 1.00
Direct Asymmetric α‐C Addition of Glycinate to Nitroalkenes by Pyridoxal/Nd Dual Catalysis 1.00
Regioselective C─H Functionalization by the Combination of Enzymatic and Chemocatalytic Reactions in Water 0.25
Multicomponent Assembly of High‐Component Covalent Organic Cages 1.00
A Streamlined Approach to Indoles, Pyrroles, and Benzimidazoles via Redox-Neutral Aromatization and CO Reduction Mediated by Cs2CO3 1.00
Continuous Flow Electrochemistry Unlocks Broadly Applicable Arene C─H Amination 1.00
Light-Induced Radical C(sp2)−H Trifluorovinylation of (Hetero)arenes with a Trifluorovinyl Iodine(III) Reagent (TrFVI) 1.00
Efficient Glycine Electrosynthesis via CO2-Recyclable Hydrogen Donation on Pb/Pb7Bi3 Heterointerfaces 1.00
Node Flexibility Unlocks Structural Adaptability and Guest Versatility of Anionocages 1.00
Social Chiral Self‐Sorting Synthesis of [9]Cycloparaphenylene‐Pillar[5]arene Heterochiral Multicavity Macrocyclic Trimers with Circularly Polarized Luminescence 1.00
An Atomically Dispersed Photocatalyst for Undirected para-Selective C─H Bond Functionalizations 0.03
Unveiling an Alternative Mechanism for Lewis Basic Selenium as a C─H Hydrogen Bond Catalyst and Its Application in the Halogenation of Arenes 1.00
Biocatalytic Olefin Difunctionalization for Synthesis of Chiral 2‐Azidoamines Using Nonheme Iron Enzymes 0.17
Deep Eutectic Solvent Binder Facilitating Reaction Kinetics of Lithium Sulfur Batteries 1.00
Crown Ether–Peptide Rotaxanes 0.60
Ruthenium‐Catalyzed Cycloaddition of Azides and Selenoalkynes with Built‐in “Catch‐and‐Release” Functionality 1.00
Electrochemical Upgrading Plastic to Organosulfurs Through Fe-N3 Single Atom Catalyst Under Ambient Conditions 1.00
Central Dynamic Conversion of Dicyanomethyl Radicals via Intermolecular Charge Transfer for Ultrabright NIR‐II Fluorescence Imaging‐Guided Mild Photothermal Therapy 1.00
Exo-Selective Intramolecular (4+3) Cycloadditions to Trans-Fused Perhydroazulenes: An Asymmetric Formal Synthesis of (−)-Pseudolaric Acid B 0.75
Adjustable Upcycling of Polyethylene Terephthalate to Biodegradable Polymer Monomers by Mn‐Catalyzed Solvent Switching Strategy 1.00
Carbene Insertion and Furyl Migration Cascade Toward Benzofurans 1.00
Ligand-Controlled Chromium Catalysis for Tunable Z/E Selectivity in Asymmetric Homoallylic Alcohol Synthesis 1.00
Ligand-Controlled Stereodivergent Manganese-Catalyzed Hydroalkoxylation of Alkynylnitriles to Access (E)- and (Z)-3-Alkoxyvinylnitriles 1.00
Semiconductor Cluster with High Reduction Potential and Efficient Charge Transfer Enables Visible‐Light‐Driven Activation of Inert Organic Substrates 1.00
The Role of Reducibility of PtGaOisubx/sub/i‐Based Catalysts for Efficient and Durable Propane Dehydrogenation 0.49
Metal‐Free Electrochemistry‐Driven Decarboxylative Primary Alkyl‐Alkoxylation of Olefins 1.00
Splicing Them Together: Construction of Polyoxovanadate–Organic Polyhedra‐Based Pyrgoscages and Catenanes 1.00
Hetero‐Selective Cross‐Linking of Primary and Secondary Alkyl Amines with CSsub2/sub Under Ambient Aerobic Oxidation for Bioconjugation 1.00
Selective Aerobic Oxidation of Toluene to Benzaldehyde by Parallel Photoinduced Proton‐Coupled Electron Transfer and Energy Transfer Through Multiphoton Excitation 1.00
Methanol‐Facilitated Cascaded Polyolefin Upcycling Enabling the Efficient Generation of High‐Value Csub9+/sub Alkylaromatics 1.00
Titanium‐Catalyzed C─X and C─H Borylation of Aryl Halides for the Synthesis of Bis(boronate)benzenes 0.75
Rhodium‐Catalyzed 1,5‐Sigma Migratory Ring Expansion of igem/i‐Difluorodienyl Cyclopropanes and Cyclobutanes 1.00
HFIP-Promoted E-selective Asymmetric Crotylboration of Quaternary α-Silyl Crotylboronate with Aldehydes 1.00
Atomic Cu–O–Zr Sites for Highly Selective Production of p-xylene from Tandem Upcycling of PET and CO2 1.00
Lignin Dissolution and Direct Ultrasmall‐Lignin‐Nanoparticle Formation in Acidic and Alkaline Deep Eutectic Solvents: A Molecular‐Level Insight 0.21
Rapid Access to an Enantioenriched Spiro Bisindole Directly from Indole and Acetone 1.00
Enantioconvergent Synthesis of α‐Fluoroalkyl Alcohols Enabled by Photocatalytic Radical Brook Rearrangement 1.00
Enantioselective Divergent Total Syntheses of Cycloaurenones and Dysiherbols 1.00
Dynamic Hydrogen Bonding Tuned Enantioselectivity Control in Cobaloxime‐Chiral Amine Cooperative Catalysis 1.00
Breaking Symmetry of Active Sites in Metal‐Organic Frameworks for Efficient Photocatalytic Valorization of Polyester Plastics 1.00
Organocatalytic Asymmetric Cycloaddition for the Construction of Chiral Indole‐Fused Medium‐ and Large‐Sized Rings 1.00
Nonconjugated Structural Distortion Promoting the Formation of NIR Triplet States in Phenothiazine Dyes for Cancer Photoimmunotherapy 1.00
Organocatalyzed Copolymerization of CO, Se, and Oxetane: O/Se Exchange Reaction Determining Chain Structure 1.00
Crystallization/Precipitation Driven Nonequilibrium Ring‐Opening Polymerization of Thiovalerolactone Toward Closed‐Loop Recyclable Polythioester with Excellent Barrier Properties 1.00
Nickel‐Catalyzed Cross‐Electrophile Coupling to Access Polysubstituted Cyclobutenes 1.00
Identifying the Role of Solvation Entropy for the Solvation Chemistry in Nonaqueous Electrolytes 1.00
Insight into Lysine Selection via Controlled Degradation of 2,4‐Diaminobutyric Acid and Ornithine Polypeptides 1.00
Hyperbranched Polymer‐Based Multipath Proton Transmembrane Transport System with Redox‐Switchable Characteristics for Cancer Cell Apoptosis 1.00
Modular Access to Fluorinated Quaternary Stereocenters via Palladium/Lewis Base Synergistic Catalysis 0.80
Intracellular Polymerization Induced Self‐Assembly and Gold Nanocomposite Synthesis in Living Bacteria 1.00
Electrochemical Benzylic C─H Sulfation beyond the iO/i‐Sulfonation Limitation 1.00
Divergent Construction of Cyclobutane‐Fused Pentacyclic Scaffolds via Double Dearomative Photocycloaddition 1.00
Decavanadate‐Catalyzed Oxidative Cross‐Dehydrogenative Coupling: an Efficient and Sustainable Approach toward P(O)─S Bond Formation 1.00
Photocatalytic Boron Insertion into Thiaarenes via Boryl Radicals 1.00
Fluoride Enhances Alcohol Binding Within a Trigonal‐Prismatic Metal‐Organic Capsule 0.10
Biomimetic Hydrogen‐Bonded Base Pairing of Nucleoside Triphosphates in Water by a Tetraphenylethene‐Based Octaimidazolium Cage 1.00
Ternary Aldehyde–Copper–Iridium Catalysis Enables Stereodivergent Allylation via α‐C‐H Functionalization of Primary Amines 1.00
Chiral Spirobipyridine Synthesis by Cobalt‐Catalyzed Enantioselective Double [2 + 2 + 2] Cycloaddition 1.00
Phenacetin[3]Arenes: Mannich‐Type Macrocyclization, Unique Structure, Versatile Functionalization, and Strong Allosteric Binding 0.89
Hierarchically Self‐Assembled Anion‐Coordination‐Driven Gels for Guest Segregation and Electrical Sensing 0.86
Stereocontrol in Conformationally Stable C(sp2)─C(sp3) Atropisomers 0.18
Iron‐Catalyzed Radical Allylic Substitution of Unprotected Allylic Alcohols 1.00
Iridium‐Catalyzed Asymmetric β‐Selective Hydroamination of Enamides for the Synthesis of 1,2‐Diamines 1.00
Modular Access to Arylethylamines Enabled by Ni‐Catalyzed iMarkovnikov/i‐Selective Hydroarylation of Allylic Amines 0.75
Valence Tautomerism and Alkaline Properties of Global Aromatic Imine‐ and Methine‐Bridged all‐Benzenoid Macrocyclic Superpyrazine and Supertriazine 0.57
Enantioselective Divergent Cyclization of Amide‐Type 1,6‐Enynes Enabled by H–[Pd]–CN Catalysis 1.00
Cost‐Effective and Low‐Carbon Scalable Recycling of Waste Polyethylene Terephthalate Through Bio‐Based Guaiacol‐Enhanced Methanolysis 1.00
Tri‐Coordinated Boron Species in Confined Boron Oxide Catalysts for Enhanced Low‐Temperature Oxidative Dehydrogenation of Propane 1.00
Enantioselective Palladium‐Catalyzed α‐Arylation of Acyclic Esters 1.00
Preparation of Cyclic Olefin Polymers via Group Transfer Radical Cyclopolymerization for High Performance in Anode‐Free Batteries 1.00
On‐Surface Synthesis of Nanographenes Through Domino Cyclization Reactions 0.57
Metal-Controlled Enantiodivergent Tandem Rearrangement to Synthesize 2H-Azirines 1.00
Clsub3/subAl‐PHsub3/sub Is a Weak Lewis Pair Allowing the Synthesis of Sterically Highly Hindered Primary and Secondary Alkyl Phosphanes 0.06
Biomass‐Derived Functional Polyacetals via Controlled Cascade Enyne Metathesis Polymerization: Tunable Degradability, Postpolymerization Modification, and Self‐Assembly 1.00
Phosphorescent Iridium(III) Phenanthrolinedione Complexes as Lifetime‐Responsive Bioorthogonal Probes for Wash‐Free Time‐Resolved Bioimaging of Cellular Labeling 1.00
Palladium‐Catalyzed Enantioselective Arylative Dearomatization of Naphthols and Phenols for Constructing Quinazoline‐Containing Spirocycles 1.00
Natural Sunlight‐Driven Activation of Inert Aryl Halides Using Plasmonic Cu@CdS with Polysulfide Active Sites 1.00
Generation, Capture, Storage, and Release of Singlet Oxygen from a Perylene Diimide‐Based Metallacage for Oxygen Sensing 1.00
Design, Synthesis, and Application of a Family of Chiral Non-C2-Symmetric NHCs with a Fused Sidechain 1.00
Direct Synthesis of Poly(adipate)Esters via Catalytic Isomerizing Dual Hydroesterificative Polymerization of 1,3‐Butadiene 1.00
Electrochemically Promoted Activation of Light Alkanes at Ambient Conditions 0.63
Visible Light‐Driven Deracemization of Cyclic Sulfonamides by Quinuclidine and Chiral Arylthiol Catalysis 1.00
Modular Access to P(V)‐Stereogenic Compounds via Cu‐Catalyzed Desymmetrization of (Thio)Phosphonic Dichlorides 1.00
Electrocatalytic C─S Cross‐Coupling via Engineered Frustrated Lewis Acid‐Base Pairs for High‐Efficiency Methanesulfonate Synthesis 1.00
Polyolefin‐based Multiblock Copolymers from Cascade ROMP‐RAFT Polymerization 1.00
An Atomically Precise Copper Cluster Nanoreactor for Efficient Catalysis in Chemical Fixation of Low‐Concentration COsub2/sub 1.00
Chiral Self‐Sorting of Flexible Covalent Organic Pillars for Adaptive Molecular Recognition 1.00
Regioreversed Carbosulfenylation of Fluoroalkenes via Nickel‐Mediated Radical Sorting 0.88
Proteome‐Wide Ligand and Target Discovery by Using iβ/i‐Nitrostyrene Electrophiles: Supporting Targeted Protein Degradation 1.00
Synthesis of a Linear Tetraboron Cation via Deprotonation of a Nonsupported Dimeric Hydroborylborenium Ion 1.00
Merging Photocatalysis with Chiral Lewis Acid Catalysis for Enantioselective Hydrosilylation/Hydrogermylation of Electron‐Deficient Alkenes 1.00
Divergent Asymmetric Synthesis of Bonnadiene and ient/i‐Polytrichastrene B 1.00
Highly Efficient Suzuki–Miyaura Polymerization Enabled by Direct Transmetalation with Boronic Esters 0.94
A General Strategy for Enhanced Single‐Molecule Imaging Through Intramolecular Energy Transfer 1.00
Unnatural Triggers Converted From Tetrazine‐Attached Sialic Acid for Activation of Optoacoustic Imaging‐Guided Cancer Theranostics 0.31
Catalytic Enantioselective α‐Ethynylation of Oxindoles: Total Synthesis of (‐)‐Corynoxine, (‐)‐Isorhynchophylline, (‐)‐Aspidospermidine, and (‐)‐Limaspermidine 1.00
Enantiomerically Enriched Aziridine‐2‐carboxylates via Copper‐Catalyzed Reductive Kinetic Resolution of 2iH/i‐Azirines 1.00
Divergent Upcycling of Polystyrene into Phenol and Hydroquinone Derivatives by Photocatalysis and Electrocatalysis 1.00
Modulating Electron Transfer via Cerium Photocatalysis for Alkoxy Radical‐Mediated Selective Hydroetherification 1.00
Constructions of Biaryl‐Bridged Macrocycles Through Phosphine‐Ligand‐Controlled Switch of Selectivity Between Intra‐ and Intermolecular Cyclizations 1.00
Modular Synchronous Synthesis of Amides and α‐Ketoamides Realized by Matching Electrolysis‐Paired Tandems 1.00
Catalytic Enantioselective Reductive Arylation and Alkenylation of Sulfinylamines to Access Sulfinamides Enabled by Cobalt Catalysis 1.00
Iron(III)‐Catalyzed C─H Hydroxylation of Low‐Density Polyethylene Coupled with Short Chain Branching Growth 1.00
Ruthenium Catalyzed Ortho-Arylation Reaction of Benzoic Acids with Arylthianthrenium Salts 0.90
Bio‐Sourced 4‐Aryl‐1,2‐Dithiolanes for Recyclable Poly(disulfide)s with High Performance 1.00
Enantioselective Abiotic Synthesis of Ribose on Chiral Mesostructured Hydroxyapatite 1.00
Probing the Catalytic Degradation of Unsaturated Polyolefin Materials via Fe‐Based Lewis Acids‐Initiated Carbonyl–Olefin Metathesis 1.00
Copper‐Catalyzed Asymmetric Cyanation of Propargylic Radicals Derived From Silyl‐Substituted Allenes and Alkynes 1.00
Metal Synergistic Dual Activation Enables Efficient Transesterification by Multinuclear Titanium Catalyst: Recycling and Upcycling of Polyester Waste 0.83
Synergistic Mechanism for Unconventional Anodic Reaction of Aldehyde Oxidation for Hydrogen Production 0.85
Internally BN‐Doped Coronene 1.00
A Nitrogen‐Containing Graphenic Buckybowl for Photocatalysis and Assembly With Fullerenes 1.00
Catalytic α‐Site‐Selective Hydrogen‐Deuterium Exchange of Benzylic Alcohols by Palladium Single‐Atom Catalyst 1.00
Selective Functionalization of Benzene Ring via Carbene‐Initiated [4,5]‐Rearrangement 1.00
Copper‐Catalyzed Radical Enantioconvergent C─O Bond Formation for Asymmetric Cross‐Coupling of Allylamines and COsub2/sub 1.00
Catalytic Activation of Acceptor–Acceptor Bicyclobutanes Enabled by Lewis Base Catalysis 1.00
Efficient Electro-Oxidation of Ethylene to 2-Chloroethanol on SnO2 Through Dual-Adsorbate Pathway 1.00
Electrochemical Enantioselective Oxidation of Indoles via Chiral Phosphoric Acid Catalysis in Cooperation with H3PO4 in Aqueous Media 1.00
Synthesis of Porous Carbon‐Based Network Containing Ultranarrow Nonplanar Nanopores on Surfaces 0.85
Chlorine Radical‐Mediated Photocatalytic C─C Coupling of Methanol to Ethylene Glycol with Near‐Unity Selectivity 1.00
Redox-Driven In Situ Formation of Bimetallic Catalysts via Sn2+/Sn4+ Interconversion 1.00
Visible‐Light‐Driven Photocatalytic Methanol Activation on Hexagonal CdS for Triggering C─H Methylation 1.00
Reactive Cysteines in Proteins are the Dominant Reductants for Platinum(IV) Prodrug Activation in Live Cells 1.00
Facile Synthesis of Polyorganosiloxanes via Photo‐Induced Anionic Ring‐Opening Polymerization Using a Latent Catalyst 1.00
Indole‐Quinoline Transmutation Enabled by a Formal Rhodium Carbynoid 1.00
An Enzymatic Platform for Asymmetric Synthesis of Si-Stereogenic Silanols 1.00
Iron‐Catalyzed Reductive Allylic C─H Amination of Olefin with Nitroarenes via Intermolecular Nitroso Ene Reaction 1.00
Synthesis of Versatile DNA‐Conjugated Aldehydes by Controlled Oxidation of Amines 1.00
Scalable and Practical Electrooxidation of Electron‐Deficient Methylarenes to Access Aromatic Aldehydes 1.00
Visible Light‐Driven Benzaldoxime Synthesis by Glutathione‐Modified CdS Quantum Dots 1.00
Diastereoselective Synthesis of Cyclopropyl Diboronates via 1,2‐Boronate Rearrangement 1.00
Synthesis and Characterization of Circumtetracene: Unraveling Structure‐Property Relationships of Circumacenes 0.90
N-(Acyldithio)Saccharin: Design, Synthesis and Applications in Catalytic Enantioselective Disulfuration/Amination of Alkenes 1.00
Cobalt-Catalyzed Enantioselective Hydrotrifluoromethoxylation of Aromatic Alkenes 1.00
Cobalt-Metalated 1D Perylene Diimide Carbon-Organic Framework for Enhanced Photocatalytic α-C(sp3)─H Activation and CO2 Reduction 1.00
Acyclic Quaternary Stereocenters via Catalytic Asymmetric Cross‐Couplings with Unactivated Alkyl iN/i‐Hydroxyphthalimide Esters 1.00
Ionized Water Facilitates the Sustainable Radical-Mediated Reduction of CO2 to Multi-Carbon Hydrocarbons and Oxygenates 1.00
Remote Spin-Center Shift Enables Activation of Distal Benzylic C─O and C─N Bonds 1.00
Oxidative Rearrangements of the Alkaloid Intermediate Geissoschizine 0.07
Nickel‐Catalyzed Umpolung Difluoroalkylation of Imines Enables General Access to β‐Difluoroalkylated Amines 1.00
Rhodium‐Catalyzed Atroposelective Synthesis of Axially Chiral 1‐Aryl Isoquinolines via De Novo Isoquinoline Formation 1.00
Ligand‐Controlled Regiodivergent Carbosilylation of 1,3‐Dienes via Nickel‐Catalyzed Three‐Component Coupling Reactions 1.00
Electrochemical Amination of Aryl Halides with NH3 1.00
Thio-Tetracosulene: A Highly Twisted Molecular Plectoneme 1.00
Bio-Inspired Self-Activating Polydimethylsiloxane-Modified CrOx/Al2O3 Catalyst for Acetylene Semihydrogenation 1.00
Controlling the Chirality of Metallo‐Cages by Manipulating the Stereochemistry of the Metal Centers 1.00
Regiospecific 2,3‐Dialkylindole Synthesis Enabled by Alkylpalladium 1,2‐Migration to In Situ Formed Aldimine 1.00
Interfacial Lithium Cations Catalyze Biomimetic Aerobic Oxygenation via Short‐Range Electrostatic Interaction 1.00
Hydrogenation of “Readily Activated Molecule” for Glycine Electrosynthesis 0.56
Stereocontrolled Phenol‐Yne Click Polymerization Toward High‐Performance Bioplastics with Closed‐Loop Recyclability 1.00
2 1.10
From waste plastic to hydrogen fuel: selective conversion through advanced catalytic technologies 1.00
Advanced monometallic and bimetallic catalysts for energy efficient propylene production via propane dehydrogenation pathways–A review 0.10
1 1.00
Orbital inversion mechanisms hidden in strongly correlated radical systems 1.00
1 0.02
Pan-modification profiling facilitates a cross-evolutionary dissection of the thermoregulated ribosomal epitranscriptome 0.02
313 304.71
Fluorinated Zr-MOF supported Cu(i) for synergistic four-component CO2 reaction 1.00
Iodine-photoredox dual catalysis unlocks bifunctional reactivity of α-diazoesters in radical cascade cyclization reactions via remote C–I bond dissociation 1.00
Ruthenium catalyzed selective deacryloyl silylation of aromatic acrylates 1.00
Mechanochemical NH4Cl-mediated hydrogen-bonding network reconstruction of HFIP: enabling yne-allylic substitutions 1.00
HFIP-promoted strain-release rearrangement/N-functionalization of azabicyclo[1.1.0]butanes with para-quinone methides for the synthesis of azetidines 1.00
Preactivation-free direct decarboxylative alkynylation of indoleacetic acids: access to alkynyl-functionalized indoles 1.00
Rapid synthesis of nucleoside diphosphates accelerated by water 0.86
Efficient access to α-substituted β-keto phosphonates via NHC-catalyzed dehaloacylation of α-bromo phosphonates 0.80
Supramolecular network-based artificial light-harvesting system employing an AIE-active metallacycle for aqueous-phase photocatalytic oxidation 1.00
Ligand rigidity as a design principle for planar pentacoordinate fluorine 0.50
Plasmonic TiN-supported CuPd alloy for highly selective and base-free photocatalytic Glaser homocoupling 1.00
I2-mediated oxidative dearomatization for the synthesis of spirooxindole-lactones in water 1.00
Anti-Markovnikov radical hydroxychlorination of alkenes enabled by amine-promoted chlorine radical generation 1.00
Fe(0)-catalyzed alkyne carboxylation with CO2 involving spin crossover 0.25
peri-Selective C–H activation-initiated spiroannulation leading to spiropolycyclic compounds with unique photophysical properties and strong anticancer activity 1.00
A photo-induced three-component reaction of N-aryl piperidines, sulfur dioxide, and cycloketone oxime esters 1.00
A catalyst and base-free electrochemical ortho-amination of phenols 1.00
Highly diastereoselective synthesis of borylcyclopropanes by copper-catalyzed borylcyclopropanation of alkenes with enynones 1.00
Stabilizing CuTCNQ cathodes in sulfide-based all-solid-state organic lithium batteries via a fluoroiodinated molecular modifier 1.00
Protonation regulates the triplet state decay of 6-thioguanosine 1.00
Visible-light-driven bioorthogonal photoclick reaction of o-diones with vinyl amides 1.00
Oxygen-directed, copper-catalyzed, diastereoselective protosilylation of cyclopropenes 1.00
Photoinduced HCl-catalyzed acylation of N-heterocycles 1.00
Catalyst-controlled regio- and chemodivergent C–H functionalization of imidazopyridines with TIPS-protected terminal alkynes 1.00
α-Trifluoromethyl alkenes as fluorinated linchpins in photochemical C–H/C–C functionalization 1.00
Copper-catalysed radical cyclization from phenylboronic acid and N-acryloyl indole or benzimidazole derivatives with air as an oxidant 1.00
Silver-catalysed asymmetric [3+2] cycloaddition for the construction of 5–5-membered 1,3′-indolyl pyrrole atropisomers 1.00
Fabrication of lithium phenoxide complexes for hydrogen storage evaluation 0.60
Imine linkers enable the formation of robust single-molecule junctions 1.00
Correction: Iridium-catalyzed intramolecular asymmetric allylic amination of anthranilic acid derivatives: enantioselective construction of chiral benzodiazepinones 1.00
Copper-catalyzed three-component radical relay alkenylation of sulfenamides 1.00
Phosphine-catalyzed sequential [4+1]/[2+3] annulation of o-amino arylaldimines with Morita–Baylis–Hillman (MBH) carbonates 1.00
Electrophilic substitution reaction of benzeneselenyl bromide (chloride) for the selective modification of the tryptophan side chain in peptides 1.00
Copper-catalyzed three-component thiocyanosulfonylation of allenes 1.00
Recent advances in α-oxo nitrenes: from fundamental properties to reactivity 1.00
Iridium-catalyzed intramolecular asymmetric allylic amination of anthranilic acid derivatives: enantioselective construction of chiral benzodiazepinones 1.00
Electrooxidative C–N coupling of seven-membered cyclic sulfonylimines with piperazines 1.00
Palladium-catalyzed denitrative C–N coupling of amides with nitroarenes enabled by Al(OTf)3 1.00
Enantioselective construction of chiral quinoline scaffold via a Michael addition/O-alkylation sequence 0.89
D˙–A radicals fabricated from polychlorinated trityl and pyridinium featuring a SOMO–LUMO electronic transition 1.00
Catalyst-free synthesis of pyrazolo[5,1-a]isoquinolines from hydrazine hydrate 1.00
Chemical emulation of the biosynthesis of (±)-arnebidin 1.00
Constructing dual-redox polyimides for enhanced hybrid capacitive deionization performance 1.00
Catalytic electron donor–acceptor complex triggered cascade radical trifluoromethylation/cyclization of N-isopentenyl aldehyde hydrazones 1.00
Enantioselective reductive cyclization of alkynals via cobalt catalysis 1.00
Nickel-catalyzed intramolecular defluorinative [4+2] cycloaddition for the construction of monofluoroarenes with gem-difluoroalkenes 1.00
Photocatalytic coupling of silyl enol ethers with oxime phosphonates for streamlined β-ketophosphonate synthesis 1.00
Pd-catalyzed enantio- and diastereoselective synthesis of N–N atropisomeric indoles via N-alkylation reaction 1.00
Enantioselective synthesis of chiral cyclic hydroxylamine ethers via NiH-catalyzed cyclization of alkyne-oxime ethers 1.00
Copper-mediated photoinduced perfluoroalkylation of arylsulfonium salts 1.00
Direct C–H magnesiation of thiophenes with an Mg–Mg-bonded compound 1.00
Silver-catalyzed fragmentation of all-carbon quaternary centers from sp3 to sp2 carbon via C–C bond cleavage 1.00
Stibine-catalyzed selective conversion of nitroarenes to hydroxylanilines through deoxygenation and hydroboration processes 1.00
Copper-catalyzed stereodefined synthesis of halogenated spirodihydrofurans 1.00
Direct carbonylative amidation of benzylic alcohols with alkylamines via palladium catalyzed C–O bond activation 1.00
Copper-catalyzed spirocyclization–oxytrifluoromethylation of alkynyl-bicyclo[1.1.0]butanes for spirobutyl quinolone synthesis 1.00
Photocatalyzed generation of acyl radicals from aryl/alkyl acyl halides via nucleophilic substitution 1.00
Cu–guanidine-catalysed asymmetric protoboration of internal 1,3-dienes for one-pot access to chiral homoallylic alcohols 1.00
A mechanochemical construction of C–P bonds through radical–radical coupling 1.00
From molecular tweezers to pliers: a significant enhancement of fullerene grasping capability 0.80
Late-stage diversification of pharmaceuticals and natural products via a direct electrochemical decarboxylative platform 1.00
Recent advances in silanecarboxylic acids as versatile reagents for modern organic synthesis 1.00
Fast-track discovery of MOF-derived M@NC catalysts for HMF-to-FDCA oxidation via DFT prescreening and Box–Behnken optimization 0.60
Tunable regioselectivity for C–H alkynylation of weakly coordinating amides that tolerated strongly coordinating heterocycles 1.00
Mantis-shaped bifunctional tridentate HoMPy-PI-NO ligands capable of cooperatively activating nucleophiles and electrophiles: empowering asymmetric addition reactions 1.00
Enantioselective Pd&Cu-catalyzed coupling of imine esters with gem-difluorinated cyclopropanes 1.00
Photoredox-catalysed arylamination of non-anomeric exoglycals with aryl sulfinamides via radical Smiles rearrangement 1.00
Chiral bowl-shaped thiazole-embedded B(iii)-azatriphyrins(2.1.1): a nonaromatic platform via triple core-modification 1.00
Visible light-induced sulfonylation reaction of copper-catalyzed thianthrenium salts 1.00
Efficient spin-doublet near-infrared emission beyond 800 nm via intramolecular charge transfer in a quasi-planar donor–acceptor structure 1.00
A direct route to ynones: Pd-catalyzed Sonogashira carbonylative coupling of ethers with alkynes via C–O cleavage 1.00
Enantioselective access to chiral phosphonothioates via iridium-catalyzed asymmetric allylic substitution 1.00
Tuning the reactivity of an osmium–peroxo unit by modulating metallacycle aromaticity 1.00
Photoinduced transformations of oxime derivatives via electron donor–acceptor complex activation 1.00
Light-induced controlled synthesis of arylsulfonyl oxindoles and arylsulfonyl amides under catalyst- and oxidant-free conditions 1.00
Stable radical cations based on indolo[3,2,1-jk]carbazole: synthesis, characterization, and theoretical calculation 1.00
A novel photochemical vapor generation medium: diketone as a medium for the determination of tellurium(iv) and bismuth by ICP-MS 1.00
Red CPL from water insoluble achiral carbon dots assisted by cyclodextrin MOF templating 1.00
Oxidant-controlled divergent construction of sulfenylsuccinimides and sulfonylsuccinimides via Mo-catalyzed C–S cross-coupling 1.00
Photocatalytic Heck-type coupling reactions of alkyl chlorides mediated by halide-exchange of CsPbBr3 nanocrystals 1.00
Alternating current polarity for electrochemical de novo synthesis of 3,3′-bisoxindoles 1.00
Enantioselective photoredox- and Cu-catalyzed alkoxycyanation of styrenes to synthesize chiral β-cyanoethers 1.00
Oxetanes in heterocycle synthesis: recent advances 1.00
Iridium-catalyzed P(iii)-directed ortho-C–H silylation of arylphosphines with hydrosilanes 1.00
Purple-light-induced synthesis of spiro-oxindole oximes from BCBs and TBN via strain release 1.00
Photocatalytic bifunctionalization of indole to access multi-substituted benzopyrrolizidinones 1.00
Synthesis of S-alkyl sulfilimines via ring-opening sulfilimination of sulfonium salts 1.00
Cathodic oxygen-reduction-reaction-mediated active peroxide for oxidizing cyclohexanone to ε-caprolactone 1.00
Palladium-catalysed imidoylative difunctionalization of allenes: access to quinolines and indeno[1,2-b]quinolines 1.00
Tandem [2+4] annulation/aromatization reaction of yne–enones with o-sulfonamidobenzaldehydes 1.00
Trimercarbazole-based aggregation-induced fluorescence-to-phosphorescence-active gold(i) complexes: isomeric engineering of an auxiliary ligand for high-contrast hypsochromic phosphorescent mechanochromism 1.00
Visible-light-induced perfluoroalkylation cyclization to access perfluoroalkylated benzazepines and benzoxepines by EDA complexes 1.00
Construction of oxindole spiro medium-sized S-heterocycles via ring expansion [2,3]-sigmatropic rearrangement 1.00
Metal and additive-free synthesis of 2,4-disubstituted oxazoles via thiourea-mediated cyclization reaction 1.00
Regioselective electrochemical 7-endo-dig selenocyclization of N-benzyl propiolamides to access selenated benzo[c]azepinones 1.00
Controlled ROS generation in pyridinium-functionalized nanocatalysts for selective photooxidation 1.00
Silver nanoparticle-immobilized benzimidazole-linked porphyrin polymers for efficient carboxylation of terminal alkynes with CO2 1.00
Oxime-modified pillar[5]arene-based hybrid supramolecular polymers: construction and antibacterial performance 1.00
Unveiling a novel GC-globulin host for supramolecular recognition 1.00
Iridium-catalyzed [5+1] cyclization of terminal alkynes with CF3-imidoyl sulfoxonium ylides to construct 2-trifluoroquinolines 1.00
Synthesis of multifunctional lactam-substituted alkyl sulfones using rongalite as an electron donor, sulfone source, and C1 synthon 1.00
Synthesis of isoquinolin-1,4-diones via photocatalytic C(sp2)–C(sp3)-scission/oxidation of 4-(hydroxy(aryl)methyl)-isoquinolin-1(2H)-ones 1.00
Photoinduced three-component alkylpyridination of alkenes via spiro-dihydroquinazolinone fragmentation 1.00
Carbene-catalyzed [2+2] cycloaddition of chloroaldehydes and isatin-derived ketimines for enantioselective synthesis of spirocyclic β-lactams 1.00
Visible light-mediated cyclopropylamide [3+2] cycloaddition with maleimides to synthesize cyclopentylamide derivatives 1.00
Exploration of heteroatom doping in modulating the two-electron selectivity of M–N–C catalysts for the oxygen reduction reaction 1.00
Upcycling thermosetting polysiloxanes into thermoplastics via UV-induced surface photopolymerization of acrylates 1.00
Visible-light-driven N[double bond, length as m-dash]N bond functionalization of azobenzenes 1.00
Aryldiazonium ion-initiated C–N bond cleavage for regioselective ring-opening of N-sulfonylazetidines with thiol nucleophiles 1.00
A face-regulated tetrahedral cage for selective and efficient encapsulation of perylene dimers 0.75
A facile strategy for π-extended BOPYINs: transformation into six-membered BODIPY analogues and their optical properties 1.00
Photoinduced benzylic C–H thiocyanation enabled by triphenylphosphine oxide and N-thiocyanophthalimide 1.00
Facile synthesis of multisubstituted 2,3-dihydrofurans via intermolecular cyclization of enals or alkyl/aryl aldehydes with acyl-stabilized sulfur ylides 1.00
Photocatalyst-free access to α-arylethanone oximes enabled by sequential HAT/SET of aryl iodides with TBN and alkenes 1.00
Stable acidic H2O2 electrosynthesis via in situ Ti–N bridging sites 1.00
Cu-catalyzed tandem cross-coupling/cyclization of aryl diazophosphonates with phenylacetylene derivatives 1.00
Metal-free oxidative all-halogen–compatible halogenation of methylenecyclopropane for accessing benzoxazines 1.00
One-step synthesis of porous ionic liquids via proton transfer for natural gas purification 1.00
The one-step formation of four chemical bonds toward dithiophosphinates via a multicomponent reaction 1.00
Palladium-catalyzed ring-opening defluorination of gem-difluorocyclopropanes: expedient synthesis of fluorinated 1,3-dienes and arenes 1.00
Visible-light-induced generation of alkenyl radicals from alkenyl sulfonium salts: direct synthesis of 11-alkenyl-substituted dibenzodiazepines 1.00
Photo-induced and azide anion-facilitated atom transfer cyclization of N-allyl-2-bromoamides 1.00
1,4-Dihydropyridine compounds as versatile dehalogenation reagents under visible-light irradiation 1.00
Chloride-incorporating cascade dearomatization of isoquinolines with chloroformate and DMAD achieving 100% atom economy 1.00
Supramolecular light-harvesting systems enabled by amphiphiles 1.00
Metal-free halogen atom transfer for carbocyclization of N-arylacrylamides enabled by visible light-excited ligated boryl radicals 1.00
Edge-centred chirality-induced enantiopure square-like sulfonylcalix[4]arene-{Coii16} cages for selective (+)-/(−)-α-pinene adsorption 0.07
Efficient synthesis of benzo(hetero)aryl-5-yl(2-hydroxyphenyl)methanones via mechanochemical benzannulation 1.00
Turn left and turn right: recent advances in selectivity controlled carbonylation 0.83
Amine-based anion receptor enables an improved magnesium plating/stripping reversibility 1.00
Efficient Pd/AntPhos-catalyzed α-arylation of benzyl aryl ketones with aryl thianthrenium salts 1.00
Enantioselective synthesis of N-arylpyrrole aldehydes via NHC-organocatalytic atroposelective desymmetrization followed by kinetic resolution 1.00
Pre-targeted delivery of a tetrazinylated albumin–zinc(ii) porphyrin complex for tumor photodynamic therapy 1.00
Base-controlled divergent synthesis of cyclopropyl aryl methanones from homopropargylic alcohols with DMTST 1.00
Electro-oxidative [3+2] cycloaddition for the synthesis of 5-selenyltetrazoles 1.00
Metal- and photocatalyst-free CF3-modification of N-containing fusion skeletons in photo-flow chemistry 1.00
EnT-catalysis-enabled, radical-relay cascade cyclization to access multisubstituted cyclohexane/cyclohexene 1.00
Biosynthesis inspired asymmetric total synthesis of camptothecin 1.00
G-quadruplex DNA/iron cationic porphyrin catalyzes enantioselective carbon–silicon bond formation 1.00
Integration of perylene diimide into a two-dimensional cobalt–organic framework for enhanced photocatalysis 1.00
Strong ligand-modified polyaniline decorated with cobalt nanoparticles optimizes surface electron density for efficient oxygen evolution 1.00
Regioselective synthesis of allylic/propargylic alcohols from conjugated dienes/enynes catalyzed by CuCl under aerobic conditions 1.00
Radical-triggered annulation-haloazidation of alkynyl-bicyclo[1.1.0]butanes: an efficient route for the construction of spiro-cyclobutyl quinolinones 1.00
Bridged chemistry of macrocyclic arenes: from sp3-carbon bridges to π-conjugation and heteroatom bridging 1.00
Cavity-size-directed supramolecular assembly of AIEgen networks for aqueous white-light emission 1.00
Metal-free regioselective B–O coupling in carboranes for constructing aggregation-induced emission luminogens 1.00
Electrochemical hydro- and seleno-amination of 2,3-dihydrofurans 1.00
Controlling Lewis acid-catalysed bicyclobutane cycloadditions: carbonyl substituents dictate electrophilic vs. nucleophilic addition pathways 1.00
Stable Zr-based polyoxometalate as a green catalyst for selective oxidation of aniline 1.00
Ru-catalyzed C–H annulation: accessing quinazolinone–BCP hybrids from stable precursors 1.00
Functionalized pillar[5]arenes with pH-responsive fluorescence and chiroptical properties 1.00
D2h HZn4S4−: an elongated planar tetracoordinate hydrogen star 0.75
Design, synthesis and structural investigation of a novel class of aggregation-induced emission (AIE) molecular scaffolds 1.00
Cu-catalyzed selective coupling of alkynes with danB–Bpai 1.00
Catalytic asymmetric reactions of indolylmethanols for the synthesis of chiral indole derivatives 1.00
Palladium-catalysed asymmetric allylic alkylation of hydantoins using bench-stable chiral palladium precatalysts 0.15
A homemade and simple solid-state photoreactor for solvent-free benzylic oxidation 1.00
Chiral amplification of prebiotic peptide synthesis induced by chemical–physical interactions on calcite surfaces 1.00
Molybdenum-catalyzed synthesis of 2,3-disubstituted indoles via imine condensation and C(sp2)–H insertion 1.00
Chalcogenylation of 4-hydroxycoumarins and 4-hydroxyquinolinones in water at room temperature 1.00
Atroposelective synthesis of isoquinolinone bearing two distinct C–N axes via cobalt-catalyzed enantioselective C–H activation/annulation 1.00
Regioselective functionalization of sulfenamides: S-arylation with cyclic diaryl λ3-bromanes and λ3-chloranes 1.00
Regioselective postmodification of aryl sulfonyl fluorides via iridium(i)-catalysed C–H borylation 1.00
Metal- and photocatalyst-free benzylic C–H halogenation via an electron donor–acceptor complex 1.00
Ru(ii)-catalyzed stereoselective C(7)–H α-fluoroalkenylation of indolines 1.00
Electrochemical upcycling biomass-derived methyl 2-furoate and CO2 into monomers for recyclable polyesters 1.00
Recent advances in photochemical diradical hydrogen atom transfer (DHAT) reactions of C–H bonds 1.00
EDA complex-directed streamlined synthesis of isoxazolidines from nitroarenes 1.00
Biochar-supported Cu catalyst for low-temperature base-free oxidative N-formylation of amines with paraformaldehyde in green solvent 1.00
Rh(iii)-catalyzed C–H activation/β-F elimination/Michael addition: diastereoselective access to dihydroisoquinolinones featuring β-amino α-fluorocarbonyl motif 1.00
Aryl semicarbazides as aryl sources for mechanochemical oxidative Heck coupling by C–N bond activation 1.00
Carbon monoxide as the key: carbonylation triggered (hetero)aryl migration transformations 0.50
Iridium-catalyzed [3+2] cyclization of terminal alkynes with sulfoxonium ylides to construct 2,5-disubstituted furans 1.00
Photocatalytic (3+3) cycloaddition of arylaminocyclopropanes with nitrones: highly diastereoselective synthesis of 1,2-oxazinan-6-amine derivatives 1.00
Recent advances in transition-metal-free deconstructive functionalization of saturated N-, O-, P-, and S-heterocycles 1.00
Halide-free deep eutectic solvents with low viscosity and corrosion for efficient SO2 capture and conversion under environmental conditions 1.00
Enzymatic trifluoropropylation by a trifluoropropyl S-adenosylmethionine analogue 1.00
A study of 1-(hydroxymethyl)isoquinoline as a new member of the photoremovable protecting groups 1.00
Diversity-oriented transformation of methyl triazine via sulfur-mediated pathways: access to 2,4-disubstituted triazines functionalized with thioamides and amides 1.00
Palladium-catalyzed aminoalkynylation/alleneamination of urea-tethered alkenes: access to imidazolidinones bearing alkynes and allenes 1.00
Size-matched supramolecular assembly between an asymmetric Anderson-type polyoxometalate hybrid and α-/γ-cyclodextrins 1.00
Visible-light-promoted synthesis of imidazo[1,5-a]indole-3-ones via cascade carbene N–H insertion and oxidative cyclization 1.00
Nickel-catalysed Suzuki-type cross-coupling of α-iodosilanes with arylboronic acids: direct and efficient access to benzylic silanes and gem-silylboronate esters 1.00
Electrosynthetic access to allyl sulfones via sulfonylation of allyl bromides 1.00
Synthesis of [1,3]-thiasilolanes via rare-earth-catalysed intramolecular α-C(sp3)–H silylation of alkyl sulphides with hydrosilanes 0.58
Photosensitizer-free synthesis of benzochalcogenophenes via photoinduced cascade cyclization 1.00
Divergent late stage functionalisation of luminescent europium(iii) complexes for targeting and imaging applications 1.00
Pore-confined trimerization of terephthalonitrile in MAF-5 1.00
Chiral pool-engineered homochiral covalent organic frameworks for catalytic asymmetric synthesis of drug intermediate 1.00
An ultra-simple construction strategy for uncommon 3,4-diaryl-modified maleimide luminophores and their unique aggregation-induced asymmetric effect (AIAE) on conformation 1.00
Remote asymmetric conjugate addition of naphthoquinone methides: constructing adjacent tertiary-quaternary carbon stereocenters 1.00
meta-NTf2 substituted diaryliodonium salts: novel nitrogen-substituted aryne precursors for trapping reactions and rearrangements 1.00
Electrochemically driven bromochlorination of alkenes 1.00
TMSCl-promoted allylic phosphorothiolation and intermolecular difunctionalization of alkenes 1.00
Photo-induced tandem cyclization of unsaturated amides with thiocyanates to access thiocyanated heterocycles 1.00
Photoinduced iron-catalyzed reduction of nitroarenes for multicomponent synthesis of α-branched secondary amines 1.00
Direct and affordable alcohol phosphorylation through ambient electrochemical oxidation of phosphorous acid 1.00
Photoelectrocatalytic XAT strategy for the generation of alkyl radicals to synthesize alkylated 3-CF3-2-oxindoles 1.00
Fe(iii)/NaBD4-mediated regioselective deuteration/cyclization of 1,7-enynes and 1,7-dienes 1.00
An EDA complex-driven multicomponent reaction of Br–Rf with alkenes via radical-polar crossover 1.00
A tetraphenylethylene-based dicyclophane with an o-carborane framework exhibiting dual-state emission 1.00
Photocatalytic cyclization reaction of 2-vinylarylamines with CF3SO2Na and arylaldehydes to access 3-(2,2,2-trifluoroethyl)-3H-indoles 0.95
Visible-light-induced stereoselective trifluoromethylselenolation of arylalkenyl iodides with [Me4N][SeCF3] 1.00
Additive-controlled chemodivergent multi-component domino reaction between salicylaldehydes and Morita–Baylis–Hillman (MBH) carbonates 1.00
Catechol-facilitated Sn2+ transport enables ultrahigh utilization rate of aqueous metallic tin anodes 1.00
Ir(iii)-catalyzed selective C–H acylmethylation and dicarbonylation of indolizines with β-ketosulfoxonium ylides 1.00
Dehalogenation hydrolysis of CF2Br2 enables four-component aminocarbonylation via photocatalytic radical-polar crossover 1.00
Trace water-induced anomalous diffusion in chlorinated imidazolium ionic liquids 1.00
Sulfonium salt-mediated phosphorodithioation of alkynes with P4S10 and alcohols to access Z-vinyl phosphorodithioates 1.00
Palladium-catalyzed cyanation and alkynylation of allylic gem-difluorides via Hiyama-type coupling 1.00
Additive-free synthesis of α-keton thiol esters via oxyacylthiolation of vinyl azides with thioacids and water 1.00
Rh(iii)-catalyzed cyclization of 5-amino-pyrazoles with maleimides to pyrazoloquinazolines 1.00
Auto-oxidation-driven vicinal C(sp3)–H desaturative cyclization of tertiary alkylamines for the synthesis of pyrido[3,2-c]coumarins 1.00
Pd-catalyzed electrophilic cross-coupling of pyridylphosphonium salts with arylthianthrenium salts to access C4-arylated pyridines 1.00
Electrochemical dehydrogenative α-vinylation and α-allylation of cyclic β-ketoesters 1.00
Copper-catalyzed 1,4-alkylcyanation of CF3-containing 1,3-enynes: alkoxy radical-mediated selective cleavage of fused azabicycles 1.00
Visible-light photoredox catalyzed thioesterification of sulfoxonium ylides with elemental sulfur and α-ketoacids 1.00
Indole ring expansion into quinolines with TMSCCl3/TMSCBr3 1.00
Cu(ii)-catalyzed synthesis of 3-functionalized benzofurans via sequential nucleophilic cyclization and C–C bond activation 1.00
Concise synthesis of phosphonylated heteroarenes from nitroheteroarenes by dearomatization/elimination 1.00
Palladium-catalyzed Heck/polyfluoroarylation of alkene-tethered carbamoyl chlorides with polyfluoroarenes 1.00
Constructing stable solid electrolyte interfaces and facilitating Li transport via an electrolyte additive for lithium metal batteries 1.00
Photo-triggered tandem cyclization of arylethynyl quinazolin-4(3H)-one for difluoroalkylated quinolino[2,1-b]quinazolines 1.00
Iridium-catalyzed [(5+1)−1] annulation of pyridinium 1,4-zwitterionic thiolates and sulfoxonium ylides: a versatile platform to indolizines 1.00
Visible-light-induced energy-transfer-mediated hydroacylation of alkenes with alcohol-derived oximes 1.00
B2Pin2-enabled reductive thioesterification of aryl triflates with thiocarbonates 1.00
Regioselective C7 sulfinylation of 4-aminoindoles with sulfinates 1.00
Nickel-catalyzed hydroacylation of acrylates with carboxylic acids 1.00
Solvent-regulated electro-oxidation of iodide and its electrocatalytic performance towards acetylacetone oxidation 1.00
Accessing diverse fluorinated organic molecules by fluoro-functionalization reactions of enaminones 1.00
Aggregation-induced emission in synthetic macrocycle-based supramolecular systems 1.00
Construction of dibenzo[1,4]oxazocines via palladium-catalysed arylalkylation of allenamides 1.00
Enhanced N-terminal glycine modification with electron deficient o-oxyacetate aromatic aldehydes 1.00
Copper-mediated intramolecular C(spsup3/sup)–H amination of alicyclic amines: regio- and site-selective access to imidazolidin-4-one 1.00
Catalytic asymmetric construction of planarly and centrally chiral [2.2]paracyclophanes by combining photochemical and cobalt-catalyzed desymmetrization 1.00
Sulfoxonium ylides as carbon radical precursors in three-component carbohalogenation of alkenes 1.00
Pillar[5]arene-based crosslinked covalent network for efficient heavy metal ion adsorption 1.00
One-pot electrochemical synthesis of N-trifluoromethylthio sulfoximines from sulfoximines via N-SCN intermediates 1.00
General and versatile electrochemical α-C(sp3)–H amidation for N-Mannich base synthesis 1.00
Dithiane-initiated cascade to eight-membered sulfur-containing pyrazoles via decarboxylative aromatization 1.00
Visible-light–enabled reduction of arylsulfonyl and benzoyl azides to access primary arylsulfonamides and benzoyl amides 1.00
Nickel-catalyzed Barbier-type reaction of carbonyl derivatives with unactivated alkyl halides 1.00
Electrochemical seleno-/tellurocyclization of propargyl carboxylic acids 1.00
Thermolysis of bismuth(III) dithiolates toward cyclic disulfides with tunable ring size and near-unity conversion 1.00
Unconventional diastereoselectivity and mechanism of Cp*Co(iii)-catalyzed C–H functionalization of asymmetric dienes: a DFT perspective 0.93
Achieving a dramatic blue colour stability in anthocyanins bearing acylated sugars in position 3′,5′ 0.08
Cobalt(scpiii/scp)-catalyzed C–H functionalization of 2-arylthiazoles with maleimides or allyl acetate 1.00
Sulfonium triggered one-pot synthesis of dihydrofurans via [3+2] annulation of alkenes and active methylene compounds 1.00
Switchable synthesis of benzimidazole/quinoxaline C-glycosides with o-phenylenediamines and sulfoxonium ylide glyco-reagents 1.00
Light/copper catalysis in 1,2-alkylarylation of allylic alcohols with sulfonium salts involving radical 1,2-aryl migrations 1.00
Zn3BSi5+: a two-layer molecular rotor with a planar pentacoordinate boron 1.00
Hydroaminoalkylation of 1,3-dienes by dual photoredox and nickel catalysis 0.86
Biphen[3]arenes based on V-shaped units: synthesis and macrocyclization-enhanced thermally activated delayed fluorescence 1.00
Pd-catalyzed asymmetric (6+2) dipolar cyclization for medium-sized spirooxindoles 0.90
Organophotocatalytic acyltrifluoromethylation of unactivated alkenes enabled the efficient synthesis of CF3-substituted chroman-4-ones 1.00
Diastereoselective synthesis of 1,4-diaryl piperazines through the dimerization of 3-aminooxetanes with cooperative indium–diphenyl phosphate catalysis 1.00
Three-component reaction of isocyanates and 3-aminoacrylates: selective synthesis of N-2-aryl-1,2,3-triazoles and hydrazones 1.00
Divergent synthesis of alkylphosphonate-containing indanes and indenes via norbornene derivative-controlled palladium-catalyzed three-component systems 1.00
A sulfonic acid-functionalized donor–acceptor conjugated organic polymer for enhanced photocatalytic hydrogen peroxide production 1.00
Palladium-catalyzed tandem cyclization reaction: access to isoxazoline-benzofuran bis-heterocycles 1.00
C(sp3)–H functionalization of N-protected dialkylpyrrole derivatives with azodicarboxylates 0.57
Palladium-catalyzed aromatic C–H alkylation of 1-naphthylamines with dichloroalkanes and its application in fused polycyclic amine synthesis 1.00
Electrochemical oxidative cleavage of C(OH)–C bonds for sustainable synthesis of esters 1.00
C–H functionalisation of [2.2]paracyclophane under copper catalysis 1.00
Light-switchable divergent C–H activation and cross-coupling of cyclic ethers with aromatic aldehydes 1.00
Decarboxylative sulfinamidation of N-sulfinylamines with carboxylic acids via a photochemical iron-mediated ligand-to-metal charge transfer process 1.00
Nickel-catalyzed sequential 1,2-iN/i-migration/BCBs ring-opening to access spirocyclobutyl β-amino acid esters 1.00
Diphanes: cage-like compounds featuring two cavities 1.00
Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle 1.00
Electrochemically driven direct C–H difluoroethylation of (hetero)arenes under metal/catalyst-free conditions 1.00
Kinetics and thermodynamics of CO2 binding to a metal centre promotes CO2 reduction 1.00
Photoredox radical Truce–Smiles rearrangement of N-sulfinyl acrylamides with sulfoxonium ylides 1.00
Electron donor–acceptor complex of aryl sulfonium salt enabling hydrogen/halogen atom transfer: C(sp3)–H alkylation of glycine derivatives and late-stage modification of peptides 1.00
Electrosynthesis of a cyclo-N5− anion via TEMPO-mediated selective C–N bond cleavage in aryl-pentazole 1.00
Rhodium(iii)-catalyzed oxidative [3+2] annulation of arylboron reagents and 7-azabenzonorbornadienes via transmetalation-initiated C–H activation 1.00
Visible-light-induced radical 1,2-aryl migration in diaryl allyl alcohols for efficient synthesis of 1,5-dicarbonyl compounds 1.00
Dearomatization [4+2] cycloaddition for constructing bridged polycyclic lactams 1.00
Electrochemical site-selective C(sp3)–H amination of alkyl substituted indoles and pyrroles 1.00
Switching between type I/II photosensitization processes for of an unconventional dye as modulated by the tumor microenvironment for inducing immunogenic death 1.00
Asymmetric synthesis of venezuelaene's core with a trans-fused [5-5] ring system 1.00
Synthesis of cyclopropanes ivia/i palladium-catalyzed [2+1] annulations of sulfoxonium ylides and norbornenes 1.00
Synthesis and isolation of less stable cyclopropene-1-carboxylates 1.00
Electrochemical synthesis of PhSe/CF3-containing dibenzazepines via radical cascade cyclization of alkynes 1.00
Diastereoselective synthesis of succinimide-fused polycycles ivia/i intermolecular interception of indanone–allene intermediates with maleimides 1.00
Efficient photocatalytic C-3 thiocyanation of indoles over tetraphenylsilane-based porous aromatic frameworks 1.00
A Pd-tannic acid-loaded ceramic catalytic membrane for the flow-through Sonogashira reaction 1.00
Visible-light-induced radical 1,3-hydrosulfonylation of allylketones with sulfonyl chlorides 1.00
Efficient supramolecular artificial light-harvesting systems based on an AIE-active calix[4]arene derivative for cross-dehydrogenative coupling reaction 1.00
Alkylaluminium-catalyzed regioselective hydrophosphinylation of α,β-unsaturated ketones into γ-ketophosphine oxides 1.00
Visible-light-driven oxidative coupling of arylhydrazines with sulfinates catalyzed by polyoxometalates for aryl sulfone synthesis 0.95
Photoredox catalyzed three-component tandem cyclization of 1,5-dienes with α-keto acids and water to access pyrrolidinones 0.93
Reduction of nitrobenzene to phenylhydroxylamine with anthraquinone-2-sulfonic sodium as an electron mediator 1.00
Copper-catalyzed three-component radical aminoazolation of vinylarenes with N-fluorobenzenesulfonimide and trimethylsilylazole derivatives 1.00
Oxidative N-functionalization of primary sulfonamides with aliphatic aldehydes: a green synthesis of α-sulfonamido acetals 1.00
Oxidative [3+2] annulation of activated pyridines for the synthesis of indolizinyl sulfonyl fluorides: a class of important pharmacophores 0.60
Nickel-catalyzed reductive coupling of α-haloboronates to access internal vicinal bis(boronate) esters 1.00
Radical [3+2] Cycloaddition Enables Polysubstituted Pyrrole Synthesis via Visible-Light-Mediated 1.00
Visible-light induced 1,2-dicarbofunctionalization of alkenes with quinoxalin-2(1H)-ones and malonic esters 1.00
Pillar[5]arene-based ionic single crystals formed by dual self-assemblies through host–guest and ionic interactions for iodine capture 1.00
Dual-nickel/photoredox-catalyzed acylation of spiro-dihydroquinazolinones with carboxylic acids via an aromatization-driven deconstructive strategy 1.00
Transition metal/photocatalyst-free skeletal editing of indene with iodonium difluorodiazo reagent to access 2-(difluoromethyl)naphthalene 1.00
Direct N-methyl C–H esterification of O-tosyl hydroxamates to enable facile synthesis of hemiaminal esters 1.00
Coupling Dy3 toroics in macrocycles 1.00
Visible-light-driven decarboxylative C(sp3)–H alkylation of glycine derivatives via in situ formation of NHPI esters 1.00
Visible-light-driven photocatalyst-free deoxygenative homologation of alcohols to access tertiary alcohols 1.00
Carbene-organocatalyzed enantioselective [5+5] annulation of dienols and dienals towards tetrahydroisochromen-1-ones 1.00
Organocatalytic asymmetric electrophilic tandem selenylation semipinacol rearrangement of 1-(1-arylvinyl)cyclobutanols 1.00
An Ir(ppy)3 encapsulated metal–organic tetrahedral cage for photocatalytic dehydrogenation cross-couplings 1.00
Modifications of terpenoids via inert aliphatic C–H bond heteroarylation with heteroarenes 1.00
Site-selective alkylation of electron-deficient aromatic cycles: visible-light photoredox-catalyzed radical di-functionalization of [1.1.1]propellane 1.00
Dearomatizative aminoetherification and diamination of indoles enabled by photochemical nitrene transfer reactions 1.00
Asymmetric synthesis of quinolinone-based polycyclic indoles through [1,3]-rearrangement/cyclization reaction 1.00
Stereoselective construction of 5-6-5 aza-tricyclic scaffolds ivia/i catalytic asymmetric aza-Piancatelli/Diels–Alder reactions 1.00
151 132.73
Conversion of trifluoromethyls into esters along with polyether upcycling via cation-transfer-catalyzed C–O/C–F metathesis 1.00
Photochemical skeletal editing: one-step transformation of diaryl dithiophenes into regiodefined helicenes 1.00
Phosphine-catalyzed β-C(sp3)–H functionalization of cyclic amines via a halogen based frustrated radical pairs approach 1.00
Electrochemically cooperative halogen-cation delivery enables modular electrophilic haloesterification of both activated and unactivated alkenes 1.00
Tris((4-BMes2)phenyl)methanide: a carbanion with a delocalised triple quinoidal structure 0.17
Selenol-containing two-dimensional perovskite promotes visible-light-driven selective reduction of unsaturated ketones 0.85
Enantioselective synthesis of calix[4]arenes with C–C axial and inherent chirality via palladium/chiral norbornene cooperative catalysis 1.00
Site-selective bromination of anthracene–maleimide Diels–Alder crystals for tunable afterglow and white light emission 1.00
Sterically controlled 5-exo-dig cyclization enables synthesis of non-benzenoid polycyclic aromatic hydrocarbons with intriguing (anti)aromaticity and diradical properties 1.00
Modular assembly of chiral biaryl phosphoramidite (BPA) libraries by nickel catalysis 1.00
Computational study of the effect of Lewis base additives and molecular spin state in SmI2-chemistry 0.13
Lipid-donor-anchored genome mining uncovers dioxanopeptins, antibacterial lipopeptides with a 1,3-dioxane functionalized polyunsaturated lipid tail 0.90
Polarization-induced reversible electron–hole migration and redox reaction switching in ferroelectric single-atom photocatalysts 1.00
Non-covalent assembly-enabled selectivity in aqueous microdroplets 0.83
Asymmetric synthesis of planar-chiral metacyclophanes via aromatic amination enabled enantioselective desymmetrization 1.00
Peptide–based artificial cytoskeleton enhances colocalized cascade reactions in cell-like microreactors 0.10
Electrochemical control enables high-concentration, one-pot macrolactonization 1.00
Photoinduced deacylative epoxidation of ketone derivatives with allylic peroxides 1.00
Deoxygenative phosphonation of ketones by titanium 1.00
Stereospecific alkenylation of carboranes: copper-catalyzed access to pyridylcarboranyl alkenes 1.00
Stepwise B≡N bond cleavage by isocyanides: access to the 3-azaborole structural motif 0.63
Reductive desymmetric silylation of biaryl bis(triflates) enabled by a chiral nickel/picolinamide complex 1.00
From alkynes to spiroindole δ-lactams via a copper-nitrenoid intermediate featuring unusual 1,1-addition and high Z-selectivity 1.00
Nickel-catalyzed hydroxymethylation with α-silicon N-methoxyphthalimides via radical Brook rearrangement 1.00
Heterogeneous photocatalytic C4 remote fluorosulfonamidation of pyridines 1.00
Neutral anion-detecting organic cages based on anion–π interactions 1.00
Undirected ruthenium-catalyzed C–H activation using arylsulfonium salts: direct arylation without ruthenacycle intermediates revealed by computation and data science 0.10
Enantioselective electrophilic α-fluorination catalyzed by an artificial metalloenzyme 1.00
Non-innocent behaviour of aromatic isocyanides under visible light: a pathway to thioformimidates and dehydroalanine 0.11
A dicationic ionic liquid strategy to enhance the thermal stability of manganese bromide scintillators 1.00
Expanding the chemical space of peptides via biocompatible tryptophan C7-arylation 1.00
Water-enhanced electrochemical hydrogenolysis of aryl C–O bonds 1.00
Photoinduced intramolecular S-α-C(sp3)–H functionalization enabled by an electron donor–acceptor complex-Mediated radical relay 1.00
Rh(iii)-catalyzed heteroannular-selective heteroarylation of biaryls: facile access to heteroacenes with sulfur-embedded 5–7 ring topology 1.00
Controllable copper-catalysed photo-induced carbonylative cyclization to access dihydroquinolinones and oxindoles 0.33
A difluorocarbene-triggered annulation/ring expansion cascade via sequential single-atom-insertions: direct assembly of 2-fluoroquinazolinones from azo compounds 1.00
Stereodivergent access to α- and β-azanucleosides via catalyst-free, achiral modulator-controlled iodocyclization: a concise synthesis of forodesine 1.00
A Polycondensation–depolymerization strategy enables closed-loop recyclable polyoxalates via ring-opening polymerization of six-membered cyclic oxalates 1.00
Visible light-induced 1,2-alkoxy shift of α-diazoacetates for Wolff rearrangements – access to oxyketenes 0.80
Intramolecular exciton coupling modulates the convergent singlet-triplet energy gap toward NIR-emissive heavy-atom-free Oligo-BODIPY photosensitizers 1.00
Directing robust built-in electric fields via imine linkage orientation in COFs for efficient dehydrogenative organic transformation coupled with H2O2 photosynthesis 1.00
HCl-mediated silylation of C–H bonds in (hetero)arenes with trialkylsilanes 0.71
Diastereoselective synthesis of cyclopropyl sulfoxides via hydrosulfenation 1.00
Uncovering outer-sphere mechanisms governing chemoselectivity in copper-photocatalyzed ATRA reactions of CF3SO2Cl with alkenes 0.20
Chiral Lewis base/Lewis acid/Brønsted acid cooperative catalysis enabled regio- and enantioselective electrophilic sulfenylation/semipinacol rearrangement of allenols 1.00
Pyrene-based conjugated porous polymers as photocatalysts for oxidative cycloaddition of phenols 1.00
Biomimetic sulfur-catalyzed carbonyl transfer enables the carbonylative difunctionalization of unactivated alkenes 0.83
Ag-triggered Co4+ active sites enable OH* nucleophilic attack for efficient electrocatalytic oxidation of alcohols to acids 1.00
Asymmetric vicinal C(sp3)–H difunctionalization of saturated cyclic amines via synergistic photoredox, copper and chiral phosphoric acid catalysis 0.80
Chemo- and atroposelective Boc protection for asymmetric synthesis of NH2-free axially chiral biaryl amino phenols 1.00
Efficient and rapid cell surface functionalization: a sub-minute selenol-yne click reaction for bioconjugation 1.00
Thiyl radical reversible-deactivation polymerization via degenerative transfer with vinyl sulfides 1.00
Cu-catalyzed enantioconvergent oxygen-centered radical cyclization 1.00
Acetic anhydride as a versatile carbon source in carbonylation reactions 1.00
Palladium-catalyzed amidocarbonylation of thioethers: access to α-amide-substituted thioether derivatives 0.50
Synthesis of wave-shaped Cu(ii) porphyrin arrays and their electrocatalytic hydrogen evolution activity 0.77
Regioselective C(sp3)–H borylation via a diarylboryl anion surrogate in sp2–sp3 diboranes(5) 1.00
Narrowing emission spectra based on indolocarbazole molecular model system: an experimental and theoretical study 1.00
Photogenerated-radical cyclopropylation of in situ generated iminiums mediated by NaI/PPh3: direct access to α-cyclopropyl tertiary alkylamines 1.00
Sequential oxidative dearomatization/asymmetric homologation: from simple naphthols to chiral benzocycloheptanes 1.00
Palladium-catalysed asymmetric annulations of Morita–Baylis–Hillman carbonates with allenes or alkenes via migratory insertion 1.00
Synthesis and separation of two stereoisomers of deuterated tetrasubstituted allylic alcohols via consecutive dual 1,2-metallate shifts 1.00
Interfacial polarization enables dual pathways for electrosynthesis of propyl acetate 0.78
Enantioselective synthesis of vicinal amino alcohols promoted by fluorine-containing counteranions 1.00
A 4,4′,4″-nitrilotriphenoxyl radical derived from Yang's biradical 1.00
Palladium-catalyzed carbonylative synthesis of acrylamides from alkenyl thianthrenium salts 0.50
Carboxylate positional isomerism in metallacycles governs hierarchical assembly pathways 0.83
Single atom-bridged Au nanozymes boost glucose oxidase-like activity in acidic media 0.90
Enantioselective copper-catalysed defluorinative alkylation of polyfluoroarenes with alkenes and 1,3-dienes 1.00
Acyl-oxyallenes as α,β-unsaturated ketone surrogates for Giese radical addition 1.00
Genetically encoded green-light-responsive photocaged lysine for sequential control of protein function 1.00
Spatially confined single-molecule folding achieves multicolor phosphorescence 1.00
Borate intercalation optimizes the electro-oxidation kinetics of α-Ni(OH)2 nanosheets for selective electrochemical conversion of benzylamine to benzonitrile 1.00
Photocatalytic generation of alkoxysulfonium ions for selective oxidation of benzylic/allylic halides to carbonyls under base-free conditions 1.00
Inherently chiral homo-heteracalixarenes: design and synthesis via an enantioselective intramolecular Sonogashira cross-coupling reaction 0.80
Unraveling the role of counter-cations in Pd-catalyzed carboxylic acid C–H activation 1.00
Catalytic asymmetric synthesis of indole-based atropisomers bearing silicon-stereogenic centers 1.00
Organic–inorganic perovskite ferroelectric catalytic selective alkyne coupling under ultrasound sonication 1.00
Droplet-mediated kinetic-to-thermodynamic transition for the fabrication of uniform 1D and 2D nanostructures from conjugated homopolymers 1.00
Activatable self-reporting cyclization reaction for in-cell synthesis of cyclocyanines 1.00
A self-assembled macrocycle with a non-closed structure for hierarchically upgraded self-assembly 1.00
Cis-difluoromethyl hetarylative dearomatization by a radical docking-migration cascade 1.00
Nickel-catalyzed aminocarbonylation of aryl chlorides enabled by a newly designed CO source 0.63
Chelation-assisted multiple and relay C–H functionalization of unactivated aliphatic E-alkenes 1.00
1,2-Hydrogen atom transfer of aminyl radicals under photoredox catalysis for the synthesis of α-amino phosphine oxides 0.67
Catalytic asymmetric construction of remote P or other heteroatom (Si/S) stereogenic axially chiral scaffolds 1.00
Highly selective and AI-predictable Se–N exchange chemistry between benzoselenazolones and boronic acids for programmable, parallel, and DNA-encoded library synthesis 1.00
Surface dynamic engineering of discontinuous cobalt dopants on copper sulfide for enhanced electrosynthesis of hydrogen peroxide 0.83
Elucidating the reaction kernel and probing the effect of anharmonicity in the ring-closing reaction of fulgide single crystals 0.38
Desulfurative modification of cysteine residues in peptides and proteins via the installation and photoexcitation of thieno[2,3-c]-pyrroles 1.00
Cobalt-catalyzed direct carbonylative 3-acylation of (N–H)Indoles with alkyl halides 0.67
Cyclopropylmethyl S-adenosyl-l-methionine: an enzymatic cyclopropylmethyl donor 1.00
Switchable supramolecular polycationic assemblies for tunable antibacterial strategies against antibiotic resistance 0.85
Catalytic asymmetric isomerization/hydroboration of silyl enol ethers 1.00
Asymmetric ring contraction of 2-hydroxypyranones by borrowing hydrogen biocatalysis 0.17
A dual-engineered covalent organic framework with charge-oxygen synergy promotes photocatalytic dipolar [3 + 2] cycloaddition 1.00
Molecular functionalization of Ni(OH)2 promotes electrosynthesis of adipic acid 0.89
Construction of α-quinonyl-α-hydroxy/amino acid esters through the redox chain reaction 1.00
Modular and diverse synthesis of oxaheterocycles via Pd-catalyzed migratory 1,n-cycloannulation of alkenes 1.00
Gram-scale synthesis of (+)-elacestrant streamlined by iridium-catalyzed dynamic kinetic asymmetric hydrogenation of α-substituted tetralones 1.00
Remote generation of N–N axial chirality through asymmetric hydrophosphinylation/hydroamination of maleimides 0.21
Enhancing photoredox catalysis by suppressing back electron transfer with the aid of a spin catalyst 1.00
Catalytic enantioselective construction of two N-stereogenic centers of ethano- and propano-Tröger's bases 1.00
Rigid cationic ligands enable high-efficiency NIR-II photoluminescence in copper(i) iodide hybrid semiconductors 0.79
Theory-guided multifunctional Zn-Salen molecular catalyst for sustainable polyester plastic recycling 0.80
Dynamic surface radical confinement in a compact CdS–CdIn2S4 semi-coherent heterojunction for highly efficient synergetic photocatalytic selective oxidation of toluene and enhanced hydrogen production 1.00
Copper-catalysed oxy-alkylation of styrenes enabled by halogen-atom transfer 1.00
Enantioselective synthesis of C–C and C–N axially chiral pyrazole-based heterobiaryls 1.00
Synthesis of N-CD3 aryl amines via iron-catalysed site-selective aromatic C–H amination 1.00
Atroposelective synthesis of sterically hindered stereochemically complex BINOL derivatives via central-to-axial chirality induction 0.78
Chiral benzo[2.2.1] α-hydroxyketones from a dirhodium(ii)/bisphosphine-catalyzed desymmetrization addition reaction 1.00
Unveiling the migration reactivity of bicyclic diaziridines: enantioselective synthesis of chiral pyrazolines 1.00
Thiol-free arene C–H thioesterification enabled by a photoactive electron donor–acceptor complex 1.00
Revisiting aromaticity and stability in the diboron actinide compound Pa2B2 0.22
A biomimetic supramolecular platform enables sequential four-step energy transfer and reactive oxygen species modulation for selective photocatalytic oxidations 1.00
Two-step coupled photoelectrochemical chlorination and oxygenation of C(sp3)–H bonds mediated by chlorine radicals over a modified BiVO4 photoanode 0.89
Regulating enol–keto tautomerism at the single-molecule level with a confined optical field 1.00
Tailoring multi-dimensional hierarchical self-assembly of metallacages through balancing non-covalent interactions 0.59
Photoactive monofunctional Pt(scpii/scp)–cyanine complex for nucleus and mitochondria dual-targeted antitumor therapy 1.00
Photosensitized diradical rearrangement of alkenyl oxime ethers towards amino-featured oxiranes: reaction, mechanism, and structural prediction 1.00
Construction of helicates based on six-coordinated silicon centres 1.00
Lateral π-extended helical nanographenes with large spin polarization 0.17
BiVO4/BiOCl heterostructure photoanodes for highly selective photoelectrochemical oxidation of benzylic C(sp3)–H bonds 1.00
Palladium-catalyzed redox diversified entry to axially chiral styrenes via asymmetric olefination with alkynes 0.83
Electrochemically promoted defluorinative sulfoximination and fluorosulfonylation of non-activated aryl fluorides at room temperature 1.00
ThDP-dependent Enzymes Catalyzed Oxidation of Aldehydes 1.00
Manganese-mediated C(sp)–Si cross-electrophile coupling of alkynyl halides with chlorosilanes 1.00
A practical photocatalytic strategy for radical (deuterio)difluoromethylation using imidazolium reagents 1.00
Modulating ion migration realizes both enhanced and long-term-stable nanozyme activity for efficient microplastic degradation 1.00
Photocatalytic regioselective four-component radical relay carbonylation for α-aminoketones synthesis 0.25
Sunlight-driven photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer polymerization at a large scale 1.00
Hydroxy-pendant tetrazole as the cage group for photoactivatable push–pull fluorophores 1.00
Single solvent molecule effect over SN2 and E2 competition in the hydroperoxide anion reaction with ethyl-iodide 0.75
Asymmetric intramolecular reductive coupling of bisimines templated by chiral diborons 1.00
A pair of strongly reductive and oxidative photocatalysts for the general upcycling of biomass derivatives and plastic wastes 1.00
Photoactivated solid-state self-assembly: a mechanochemistry-free route to high-purity aromatic amine crystals 1.00
Crown ether–cycloparaphenylene hybrid multimacrocycles: insights into supramolecular gas sensing and biological potential 1.00
Machine learning photodynamics reveal intersystem-crossing-driven ladderdiene ring opening 0.75
Single electron/energy transfer photocatalysis: α-/β-switchable synthesis of 3-deoxy-scpd/scp-manno-oct-2-ulosonic acid iO/i-glycosides 1.00
Carbene-stabilized 6,12-diboraanthanthrenes: unveiling the multistage redox properties of polycyclic aromatic hydrocarbons featuring electron-rich boron centers 1.00
Ppm level palladium catalyzed regioselective remote arylation of alkenyl alcohols 0.33
Rh-catalyzed enantioselective hydrosilylation of unactivated alkenes 1.00
Achieving highly efficient carbon radical-mediated cross-coupling reaction in a confined radical microenvironment within a metal–organic framework 1.00
Convergent and divergent synthesis of dihydroisoquinoline-1,4-diones enabled by a photocatalytic skeleton-editing [4 + 2] strategy 1.00
Photoaffinity SAM analogues for the identification of SAM-binding proteins 1.00
Decarboxylative sulfation by persulfates 1.00
A conformationally adaptable tetrahedral cage with different guest encapsulation models 1.00
N-Heterocyclic carbene-catalyzed enantioselective (dynamic) kinetic resolution for the assembly of inherently chiral macrocycles 1.00
Precise construction of spiro stereocenters ivia/i enantioselective radical addition through modulating photocatalysis from redox to energy transfer 1.00
Synthesis of gem-di(boryl)cyclopropanes from non-activated olefins via Mn-photocatalyzed atom transfer radical addition 0.71
Access to spirocyclic vinyl sulfones via radical cyclization and functional group migration 1.00
1 1.00
Photocatalytic energy driven building sustainable power, air purification and air dehumidification 1.00
3 2.63
<atl>Unravelling the anion-dominated interfacial structure of hybrid solid electrolytes ivia/i ssNMR</atl> 0.93
Molecular engineering of an ether–nitrile constructs robust dual-interphases for ultra-stable 4.5 V lithium metal batteries 1.00
Continuous-flow organic electrosynthesis of a conjugated bipolar polymer cathode for high-performance low-temperature aqueous aluminum-ion batteries 0.70
7 7.00
Cyanidin-3-O-glucoside alleviates aflatoxin B1-induced splenic immunotoxicity via gut microbiota remodeling 1.00
6-acetyl-1,1,2,4,4,7-hexamethyltetraline (AHTN) induces abnormal macrophage polarization and nuclear lamina remodeling under low-dosage and long-term exposure 1.00
Evolution of environmentally persistent free radicals on tire wear particles under UV irradiation: Contributions of relative humidity and ozone concentration 1.00
Enhancing Effects of Glycine on Methanesulfonic Acid-driven New Particle Formation: Mechanistic Insights and Implications for Atmospheric Pollution 1.00
Formation and stability of environmental persistent free radicals (EPFRs) from the reaction between phenolic compounds and Fe(III)-loaded particles 1.00
Terrestrial inputs of synthetic musks from Chinese mainland to the East China Sea 1.00
Assessing the toxicological impact of DEGDB plasticizer exposure on glioblastoma multiforme via network toxicology, machine learning and in vitro methods 1.00
3 3.00
Bimetallic isotypic heterojunction Mn-CN/Co-CN for enhanced PMS activation: Unraveling the synergistic Co(III)/Mn(II) catalytic redox cycle 1.00
Naphthenic Acid Exposure Disrupts Mitochondrial Function and Locomotor Behavior in Marine Medaka (Oryzias melastigma) via G Protein–Coupled Receptor Signaling: A Multi-Omics Perspective 1.00
Tuning Fe-P covalency via regenerative phosphorus vacancies for efficient aqueous cyclohexanone degradation 1.00
14 13.08
Synergistic Mechanisms of Formaldehyde-Induced Radicals Enhancing Photothermal Catalytic Oxidation of Toluene 1.00
Efficient Cleavage of C–F Bond via Bridging Hydroxyl Group for FVOCs Hydrolysis–Oxidation 1.00
Selective Photocatalytic Upcycling of Polystyrene Plastic to High-Value Chemicals by a Single-Atom Fe Catalyst 1.00
Oxygen Vacancy Defects in Hematite Enhance Maillard Reactions and Promote Recalcitrant Organic Carbon Formation 1.00
Comprehensive Mapping of Ionic Liquid Degradation Pathways and Toxicity Risks in UV/NaClO Treatment via Integrated Molecular Networking and In Silico Toxicology 1.00
Mechanisms Underlying Tralopyril-Induced Olfactory Dysfunction in Marine Medaka: Disruption of the Dopaminergic System and the Complement Alternative Pathway 1.00
Enhanced Fluorine Resistance and Catalytic Performance of the Zirconia-Supported Ru Single-Atom and WOx Cluster Catalysts for Elimination of the Typical Hydrofluorocarbon (HFC-134a) 1.00
Oxygen-Independent Mineralization of Acetaldehyde by a Cyclodextrin-Anchored WO3 Photocatalyst under Visible Light 0.25
Deciphering the Role of Heavy Metals in Zero-Valent Iron-Driven Dechlorination of PVC Microplastics under Mild Condition 1.00
Iron- and Manganese-Catalyzed Maillard Chemistry: Molecular Characteristics, Evolution Pathways, and Implications for Soil Organic Carbon Formation 1.00
Air-Exposed Nano-TiO2 for Rapid and Sustainable Hydrolysis of Gaseous Phthalate Ester: The Remarkable Facet and Humidity Effects 1.00
Net-Zero Upcycling of Mixed Polyolefins by Spatially Homogeneous Joule Heating 1.00
Environmentally Persistent Free Radicals on Black Carbon Induce Rapid Degradation of Phenolic Acids 0.83
Enhancing Photocatalytic Decarboxylation by Frustrated Lewis Acid–Base Pairs for Efficient Degradation of Perfluorooctanoic Acid 1.00
2 1.21
Investigating terrestrial ethane sources with molecular-average and clumped isotopes 0.21
Atomic-level insights into nanoclay for prebiotic nucleoside phosphorylation 1.00
1 0.92
Dietary anthocyanins alleviate age-dependent hepatic steatosis by expanding Limosilactobacillus reuteri and modulating gut microbiota-bile acid-hepatic FXR signaling. 0.92
73 66.55
Ambient Organocatalytic Synthesis of Salphen-Embedded Chiral COFs for Aqueous Enantioselective Sulfoxidation 1.00
Chemoselective Semihydrogenation of Azoarenes to Hydrazoarenes under Atmospheric Pressure Catalyzed by a Metal–Ligand Bifunctional Iridium Catalyst 1.00
Visible-Light-Driven E → Z Isomerization of Olefins Catalyzed by Atomically Precise Copper Clusters 1.00
Oxidative Addition as the Selectivity-Determining Step in Gold(I)-Catalyzed Cross-Dehydrogenative Coupling of Arenes 0.17
A Helical Hydrogen-Bonded Aramide Macrocycle with a “Closed” Cavity: Dinuclear Ag(I) Coordination Assembly and Switchable Chirality Sensing 1.00
Constructing Metallo-Supramolecular Cuboctahedra Incorporating Flexible Alkyl-Diamines via Postassembly Ligand Exchange 1.00
Cucurbit[8]uril-Directed Facet Engineering of Zn-Based Catalysts for PET Methanolysis 1.00
Potassium tert-Butoxide Promoted Proton Transfer-Electron Transfer in Aerobic C(sp3)–H Hydroxylations 1.00
Designing Copper(I) Iodide Clusters with Tunable D−π–A Ligands for Photocatalytic Thiocyanation 1.00
A Nitrogen-Enriched Pd3L6 Cage Assembled from Hydrogen-Bonded Triazole Foldamers for Chemisorption-Driven Methyl Iodide Capture 1.00
A Multivalent Supramolecular Assembly for the Detection and Removal of Pd2+ 1.00
Two-Dimensional Hybrid Framework Based on Weakley-Type POM as a Heterogeneous Catalyst for Glycolysis of PET and Various Polyesters 1.00
Ligand Effects on the Mechanism and Regio- and Stereoselectivity of the Pd-Catalyzed Cascade Allylation of ortho-TsNH Arylimines with 2,4-Dienyl Carbonates 1.00
Synthesis of Carborane-Containing Esters of Natural l-Amino Acids via Construction of a Carborane Cage Using Alkyne-Insertion Reactions 1.00
Rational Design and Development of an Acyclic Chelator H4pyox for Theranostic Radiometal Labeling under Mild Conditions 1.00
Stable Au(III) Benzohomoporphyrin: Synthesis, Structure, Near-Infrared Absorption, and Superoxide Radical Generation 0.59
Tailoring a Polyoxometalate-Based Metal–Organic Framework for Photocatalytic Oxidative Cross-Coupling Reactions to Synthesize Benzo(naphtho)thiazoles 1.00
Gradient Construction of High-Efficiency Lanthanide Polynuclear Nanocages for Three-Component Ugi Reactions 1.00
Hemin Molecular Catalyst with Axial Cl–Fe Coordination for Selective and Stable Acidic Chlorine Evolution 0.88
Dual-Site Molecular Recognition in a Truncated-Octahedral Pd6L8 Cage via Symmetry-Selective Endo and Peripheral Binding 1.00
N-Heterocyclic Carbene-Based Tetradentate Platinum(II) Complexes for Deep-Blue Phosphorescent Emitters: Safe Synthesis and Photophysical Study 1.00
An Fe(II)-Based Hexagon-Fused Wheel Constructed via Post-Synthetic Transmetalation 1.00
Adaptive Self-Assembly of Lanthanide-Covalent Organic Polyhedra: from Triangular Prism to Octahedron 1.00
Copper Halide Hybrids Driven by Irreversible Structural Transitions for Anti-Counterfeiting and Traceability 1.00
Mechanistic Insights into Scandium-Catalyzed Cascade Cyclization of Aromatic Aldimines with Tethered Alkenes via C–H Activation 1.00
Three-Component CO2 Conversion to Carbonyl Carboxylates Catalyzed by a Copper-Based Metal–Organic Framework under Mild Conditions 1.00
Mechanistic Revision of Ir(III)-Catalyzed Allylic C–H Alkynylation through DFT Calculations: An Ir(III)-Only Pathway via Alkyne Insertion and Ag-Assisted Debromination 1.00
Stereocontrolled Synthesis of Chiral [2]Catenanes by Coordination-Driven Self-Assembly 1.00
Noncovalent Bonding of Group 4 Metals 0.67
Study on the Quenching Mechanism of Radicals by Fullerenes (C60 and C70) 1.00
Anion- and Conjugated Building Block-Driven Construction of Handcuffs and Cages, Featuring In Situ Topological Transformation from Handcuff to Double-Z Cage 1.00
Au-Mediated Enhanced Charge Separation in Cs2AgBiBr6/Au/UiO-66 for Photocatalytic Synthesis of Thiosulfonates 1.00
More is Different: Theoretical Investigation on the Origin of Ligand Loading-Dependent Switching Regioselectivity in Ir-Catalyzed C–H Borylation 1.00
Unveiling Cooperative Effects of Two Bidentate Pyridone-Pyrazole Ligands in the Regioselective C–H Activation: A Theoretical Study 1.00
Mechanistic Insights into E(II)-Catalyzed (E = Si, Ge, Sn, Pb) C–F Activation/C–C Cross Coupling Reactions 1.00
Visible–NIR Photodynamic and Photothermal Mono- and Bis-Rhodium(I) Complexes of a Pyrrole-Appended N-Confused Porphyrin 0.86
Arene-Fused o-Carboranes via C–B(3) Bond Formation: Synthesis and Properties 1.00
Steric Bulk Controls Δ/Λ Handedness Enabling Stereodivergent Self-Assembly of FeII2L3 Cages 0.89
Reaction of Diazo Compounds with Borenium Ions: C–H Bond Activation/Annulation vs 1,1-Carboboration 1.00
In Situ Synthesis of Cu-CP by Cleavage of the C–N Bond for CO2 Fixation into Oxazolidinones through Aziridine/Propargylamine under Ambient Conditions 1.00
Anionic Supramolecular Cluster with [Cu4Br7O]2– Core: Self-Assembly and Photocatalysis for Organic Transformations 1.00
Quinoxaline-Based Cationic Cyclometalated Iridium Complexes for Deep-Red Light-Emitting Electrochemical Cells 0.17
DFT Calculations Reveal the Origins of Chemo-, Regio-, and Stereoselectivities in Nickel-Catalyzed Synthesis of Chiral Tetrasubstituted Allenes with Simultaneous Construction of Central and Axial Chirality 1.00
N-Indolylsilylene Cobalt(I) Chloride: A Base Metal Catalyst for Alkene Hydrosilylation 0.80
The Mechanism of Photocatalytic C(sp3)-H Activation by Decatungstate Anion: CPET or HAT? 1.00
Cavity-Mediated Global Thermodynamic Control in Heteroleptic Coordination Cage Assembly via Endohedral Noncovalent Interactions 1.00
Hexavalent/Tetravalent Tellurium-Based Chalcogen Bond Catalysis on the Cyclization of 1,6-Diyne: Mechanistic Insights and Computational Design 1.00
Carbocation-Coupled Electron Transfer: An α-Ferrocenylmethylium as a Masked Primary Alkyl Radical 1.00
Mechanistic Discovery of a Nucleophile–Electrophile Coupling Mechanism in Binuclear Gold(I)-Catalyzed Photoredox Alkynylation of Tertiary Aliphatic Amines with 1-Iodoalkynes 0.17
Designing a Photoactive Polyoxometalate-Based Metal–Organic Framework for Solar-Powered Hantzsch Reactions in a Divergent and Mild Pathway to Thermal Methods 1.00
Recognition and Detection of Phenylmercapturic Acid and a Pair of Stereoisomers Based on a Cucurbit[6]uril Supramolecular Assembly 1.00
Synthesis and Reactivity of an Iminoborane-Boraalkene Adduct via the Complete Cleavage of the Carbon–Nitrogen Triple Bond of Isonitrile 1.00
Selective B(9)–H Bond Oxidation of o/m-Carboranes with mCPBA 1.00
Two Imidazole-Functionalized Mixed-Valence Oxidovanadium Clusters for Catalytic Oxidation of Sulfides 1.00
Polytantalotungstates Stabilized Iron Catalysts for Carbonylation of Benzylic C–H Bonds 1.00
Octahedral Cs2AgBiBr6 Double Perovskite Microcrystals for C–C Coupling Reactions under Visible-Light Irradiation 0.86
Coordination Polymers Driven by Urea-Diisophthalate Linkers: From Hydrothermal Assembly and Structural Diversity to Catalytic Applications 0.67
Structural Chemistry of AlCl3–N-Methylformamide Deep Eutectic Solvent: Study on Spectroscopy Techniques and Quantum Chemical Calculations 1.00
Supramolecular Assembly of Chiral Lanthanide Triple-Decker Metallocyclophanes Ln3(Lmeta)3(LR/S)3 or Tetrahedral Cages Ln4(Lpara)4(LR/S)4 and Their Chiroptical Properties 1.00
Diverse Reactivity of a Pincer-Type Dialuminum Complex 1.00
Selenolated Copper Hydride Clusters for Visible-Light Photocatalytic Iodofluoroalkylation of Alkynes 1.00
Luminescent Cyclometalated Iridium(III) Polypyridine Complexes Modified with a Dendritic Guanidinium Moiety as Molecular Glues for Combined Chemo-Photodynamic Therapy 1.00
Unveiling Unusual Reactivity of SOsub2/sub and Unusual Type of S–X Long Bonds 0.88
Synthesis of NH3·B9H13 and Its N-Alkyl Analogues: Toward the Polyhedral Azaboranes, M[NH2B9H11] (M = Na, K) 1.00
Structure and Bond Dissociation Variations in Dialumenes: A Comparative DFT Study on N,P- versus N,N-Bidentate Ligand Effects 1.00
Sequential Separation of Metal Cations Using Nor-seco-cucurbit[10]uril as a Supramolecular Material 1.00
Synergistic Photoredox and High-Spin Cobalt Cluster Dual Heterogeneous Catalysis: Visible-Light-Driven C(sp2)–H Bond Functionalization 1.00
Ga5Li12+: A Doubly Aromatic Ga511– Ring Stabilized by Lithium Cations 0.60
Controlled Mono- and Double-Insertion of Sulfonamide Fragments into Ni–S Bonds of Nickel(II) Dithiocarbamate Complexes via Sulfonyl Azide Reactivity 0.13
A Pd(II) → Pd(0) → Pd(II) Catalytic Cycle Enables the Generation of Bis(o-carborane)s: Confirmed by Reproduced Yields and Ratios, Regioselectivities, Additive and Substituent Effects 1.00
Rhodium-Catalyzed Selective Chalcogenation of B(4)-H of o-Carboranes 1.00
Activation of C(sp2)–X and C(sp3)–X σ-Bonds (X = F, Cl, Br, and OMe) by Rhodium Complex with Pincer-Type Aluminyl Ligands: Theoretical Insight into High Reactivity and Flexible Reaction Mechanism 0.25
Palladium-Catalyzed Regioselective B(3,4,5,6)–H Tetra-Arylation of io/i-Carboranes 1.00
10 9.79
Generation of nitrogen-containing compounds by cellulose nitrogen-rich pyrolysis under CO2/N2 atmosphere: Influence mechanism of different catalysts 1.00
Low-cost slow-release fertilizers fabricated by hot-melt encapsulation from biomass waxes 1.00
Deep eutectic solvent-enzyme complex system for green extraction of essential oil, flavonoids and pectin from citrus peels: Optimization, composition and mechanism 1.00
From mechanism to design: The mechanism of π bond effect and molecular flexibility synergistically regulating the reaction of coal oxidation 1.00
Enhanced and sustainable extraction of acetic acid from wastewater using a novel ternary deep eutectic solvent 1.00
Comparative analysis of ethylene-vinyl acetate debonding with D-limonene and Trichloroethylene in a life cycle perspective: Towards the directional separation of end-of-life photovoltaic panels 0.92
Towards cleaner production of methyl glycolate: Techno-economic-environmental optimization via hybrid physics-machine learning modeling 1.00
Electrostatic interaction-driven surface engineering for fabrication of uniform and size-controllable polymer microspheres in green solvent 1.00
Amino acid mediated hydration of caustic calcined magnesia: dual-function for efficient conversion and purification 0.88
Data-driven design of ionic liquids for targeted desulfurization: Integrating machine learning prediction with structure-performance analysis 1.00
1 1.00
Epigenetic and metabolic reprogramming support plasma cell differentiation in germinal centers 1.00
1 0.88
Construction of general N-body lattice operators with arbitrary momenta 0.88
444 406.80
Unlocking Multi–Product Selectivity in Olefin Electro-oxidation through Cooperative Cation/Oxygen Species Modulation 1.00
Chiral Phosphoric Acid Catalyzed Asymmetric Ring Contraction of Isoxazoles under Dye-Free Photodriven Conditions 1.00
Enantioselective Synthesis of Sulfilimines Enabled by Photoinduced Copper-Catalyzed C(sp3)‑H Sulfimidation 1.00
Catalytic Enantioselective Dearomatizing [2,3]-Wittig Rearrangements Allow Divergent [2,3]-, [1,2]-, and Sommelet–Hauser-Type Products 0.07
Dynamic Kinetic Asymmetric Allylation of Ketones: Stereodivergent Synthesis of E- or Z‑Substituted α,β-Stereogenic Tertiary Alcohols 1.00
Solar-Driven Dehalogenation and Upcycling of Brominated Plastic Waste 1.00
Ketal-Bridged Rhodamines as a New Scaffold for Near-Infrared Chemigenetic Indicators with Enhanced Fluorogenicity 1.00
Low-valent Iridium Enables “Outer-Sphere” Radical–Radical Coupling in Photoinduced Asymmetric Allylic Alkylation 1.00
Conformationally Switchable Molecular Trefoil Knot Assembled From 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Building Blocks 0.25
Benzo-Fused Medium-Sized Heterocycles with a Chiral C–N Axis from Asymmetric Cycloaddition and Skeletal Rearrangement 0.56
Enantioconvergent Decarboxylative Arylation of Serine and Isoserine Derivatives with Aryl Halides: Modular Access to Chiral 1,2-Amino Alcohols 0.78
Asymmetric Dearomative [4 + 2] Photocycloadditions of Quinolines with Alkenes Enabled by Organocatalytic Activation 1.00
A Methyltransferase Catalyzing Reactions More Than Methylation 1.00
Pd-Catalyzed Geminal Coupling for the Construction of Fused Polycycles and Natural Product Synthesis 1.00
Synthesis of Distal 1,4-Diaxial Atropisomers: CPA-Catalyzed Atroposelective (3 + 3)-Annulation via a Desymmetrization Strategy 1.00
Iron-Catalyzed Selective C(sp2)–C(sp3) Coupling of Nitro(hetero)arenes and Alkyl Bromides by Paired Electrolysis 1.00
Nickel-Catalyzed Regioselective Dihydrosilylation of Allenes 1.00
Spontaneous and Efficient Oxime Synthesis by Al-Catalyst Assembly 1.00
Discovery of a Potent Antisarcopenia Drug Molecular Scaffold Derived from Ligusticum chuanxiong and Its Photochemical Synthesis 1.00
Asymmetric Radical Allylic Cyanation of Electron-Deficient Alkenes with a Low Copper Catalyst Loading: Development and Mechanism 1.00
A Palladium(IV) Amido Alkyl System Relevant to C(sp3)–N Bond Formation 1.00
Condensation Center Regulation in Donor–Acceptor Polymers Enables Dynamic Proton Reservoirs for Efficient H2O2 Photosynthesis 1.00
Stereoreversed C–O Activation Unlocks All-Carbon Tetrasubstituted Z‑Alkene Synthesis 1.00
Divergent Skeletal Editing of Pyridinium Salts to Azepinones and Pyrrolidinones via Formal Carbonyl Insertion 1.00
Ligand Control Overrides Intrinsic Site Selectivity in C–H Borylation of Phenol and Aniline Derivatives 0.91
Characterization of UDP-Sugar 3‑Dehydrase KsgR in the Biosynthesis of a Distinctive Multideoxy Diamino-Sugar Kasugamine of Kasugamycin 1.00
Enhancing the Tsuji–Trost Reaction via 1,3-Diene Formation 1.00
Coordination Chemistry of a Star of David [2]Catenand 0.39
Unexpected Chemoselectivity in Radical Aryl Translocation via Photosensitization 0.94
Cage-on-Cage Evolution toward Rigid Metallo-Organic Giant for Enhanced Fluorescence 1.00
Enantioselective Synthesis of Boron-Stereogenic Compounds with Multiple Chiral Elements via Cobalt-Catalyzed Desymmetric Annulation 1.00
Nickel-Catalyzed Selective Defluorinative Deuteration of Polyfluoroarenes 1.00
Visible-Light-Promoted Continuous-Flow Iodination of Primary C(sp3)–H Bonds: An Undirected and Regioselective Approach 1.00
Ultrafast Formation of Aza-Quinone Methides from Suitably Substituted o-Hydroxymethylanilines Involves Higher Excited States 0.29
Bringing Silicon to Drugs: Modular Construction of Sila-Pharmacophores for the Development of Target Protein Degraders 1.00
Controllable Difluorocarbene Elongation via Copper Catalysis 1.00
Distorted Nanographenes by Embedding a Cyclopenta[a]heptalene Core and Multiple Additional Heptagons: Chiral Supramolecular π-Dodecamer and Co-crystal with Fullerenes 0.71
Electroenzymatic C1 Fixation to Glycine via Dithiothreitol Regeneration on Functionalized 1T′-MoS2 1.00
Selective Construction of Pseudo-Mortise-and-Tenon-Type Molecules 1.00
Hexacoordinate Ti-Anchored Single-Atom Pd Catalyst for High-Efficiency Cyclohexanone Ammoximation with H2 and O2 1.00
Thiol-Retaining N-Terminal Cysteine Chemistry for Dual Modification and Bicyclic Peptide Construction 0.78
Chlorosyl Nitrite (OClNO): An Elusive Intermediate in the Photochemistry of Nitryl Chloride 0.78
Copper(I)–NHC-Catalyzed Enantioselective Borylation and Silylation of Ketimines 1.00
Access to Planar- and P-Chiral Macrocyclophane-Based Phosphines via Palladium-Catalyzed Asymmetric Hirao Reaction 1.00
Enantioselective Palladium-Catalyzed Intermolecular Four-Component Acylcarbonylation of Alkenes: A Modular Approach to Chiral γ-Keto Esters 1.00
The Salting-Out Effect Enables Highly Selective Electrochemical Ammoxidation of Aldehydes to Nitriles 0.86
Direct Synthesis of Pure Aqueous H2O2 Solutions Catalyzed by C60-Buffered Proton–Electron Transfer on Palladium Adatoms 0.91
Fast and Selective Labeling of Serine and Threonine in HFIP for Facile Editing of Peptide Alcohol Side Chains 1.00
Total Synthesis of Euphopia B and Discovery of a Selective Inhibitor of Potassium Efflux-Independent NLRP3 Inflammasome Activation 1.00
Enantioselective Total Syntheses of Grayanoid (−)-Mollfoliagein A and (−)-Rhodomollein XXV 1.00
Rhodium-Catalyzed Desymmetric Addition of Boronic Acids to Malononitriles 1.00
Electrochemical Synthesis of Boron-Centered Carboranyl Radical for Modular Carboranyl N-Heterocycles 1.00
Facile Synthesis of Gem-Difluoroalkene-Based Bis(silanes) via Copper-Catalyzed Disilylative Defluorination of 1-Chloro-1-trifluoromethylalkenes 1.00
Stereo-Switchable Electrochemical Glycosylation 1.00
Enantioselective Synthesis of Quaternary Stereocenter Aldehydes by Palladium-Catalyzed Intermolecular Propargylation Reaction 1.00
Interior Editing via Dynamic Molecular Recognition 0.50
Enantioselective Iridium-Catalyzed C–H Bond Alkylation for the Synthesis of N–N Atropisomeric Phosphines 1.00
Chiral Pyridoxals Enabled Efficient Enantioselective Synthesis of α-Substituted Tryptophan Derivatives 1.00
Dynamic Double Carbaporphyrin-Fused Nanographene: Facile Monolayer and Persistent Bilayer Switching 0.60
Asymmetric Alkene Boration and Z-Retentive Allylic Substitution Reactions under Cu/Pd Relay Catalysis 1.00
Diastereo- and Enantioselective Construction of Vicinal Stereocenters through Tandem Electrochemical Dearomatization and Allylic Alkylation 1.00
Photoinduced Palladium Catalysis Enables Dynamic Kinetic Asymmetric Allylic Imidation 1.00
Excited-State SNAr Reactions of Nitroarenes 1.00
Photo-Induced Aliphatic C–H Amination Mediated by Hydrogen Atom Transfer of an Alkoxycarbonyloxyl Radical and Its Utilization for Diastereoselective Modification of Proline Residues in Peptides 1.00
Selective Deoxygenative Electroreduction of Amides 1.00
Linker Torsional Angle Engineering in Metal–Organic Frameworks Enables Boosted O2 Photoactivation for Organic Synthesis 0.92
Cu-Catalyzed Stereoconvergent and Enantioselective C–S Cross-Coupling of Alkenyl Halides with Sulfenamides via Alkenyl Radicals 1.00
Adsorption-Biased, Halide-Tuned Perovskite Photocatalysts for Aerobic Oxidation of Primary Alcohols to Benzimidazoles 0.93
Enantioselective [2π+2σ] Cycloaddition to Bicyclo[2.1.1]hexanes Enabled by an Artificial Photoenzyme 1.00
Highly Efficient Alkene Radical Difunctionalization toward Alkyl Azide and Nitrile Achieved by Copper Single-Atom Catalysts 1.00
Boryl Homolytic Aromatic Substitution Enables Radical Borylation via Inverted B–H Polarity of Hydroborane 0.78
Programmed Oxidation-Guided Divergent Total Syntheses of (±)-Anisatin, (±)-Neoanisatin, (±)-Majusanols A and B 1.00
Spin Alignment in Cr–W–Cr Motif Promotes N, N-Dimethylformamide Electrosynthesis from Dimethylamine Self-Coupling 1.00
Tandem Auxochrome Design Enables Ready Access to Deep Shortwave Infrared Dyes 1.00
One-Step-Three-Ring Propellanation Reaction of Yne-Vinylcyclobutanones Catalyzed by Nickel: Reaction Development, Mechanism, and Formal Synthesis of Modhephene 1.00
Unraveling the Single-Site Origin of Strong Brønsted Acidity in Fluorinated γ-Al2O3 1.00
Methylene Cycloalkene as a Reactive 1,3-Diene for Enantioselective Hydroamination 1.00
Synthesis and Isolation of α-Diazophosphonium Ylides 0.63
SPSiP-Enabled Pd-Catalyzed Enantioselective Alkynylamination of Alkenes 1.00
Reductive Cyclopentamerization of Carbon Monoxide to the Elusive Croconate Radical Trianion 0.17
Divergent Radical and Ionic Electroreductive Regulation for Disulfuration 1.00
Single-Electron Reactivity of Thianthrene S-Oxide and Its Synthetic Application in Late-Stage Thiocyanation and Selenocyanation 1.00
Surface Coordination-Promoted Electrosynthesis of 1,4-Butanediol from Ethylene and Water via 2-Bromoethanol 1.00
Catalytic Asymmetric cis-Dihydroxylation of Quinones Enabled by a Functional Mimic of Rieske Dioxygenases 0.93
Chiral Binaphthyldimethyl η6-Benzene Ligands: Design, Synthesis, and Application in Ruthenium-Catalyzed Asymmetric C–H Activation 1.00
Deciphering the Stepwise N–O Activation of Nitroarenes: Electronic Structure and Reactivity of Iron-Nitrosoarene Intermediates 1.00
Facile Synthesis of Nonalternant π-Conjugated Azaborines via Boron-Deleting Annulation 1.00
Perfectly Alternating Copolymerizations of Methacrylates and Coumarin to Robust C–C Main-Chain Polymers with Full Degradability and Depolymerizability 0.50
Polymerization Chaperone for the Controlled, Homogeneous Synthesis of Proline-Based Homo- and Copolypeptides 1.00
Inverse Al-ZrO2/Cu Catalysts Enable the On-Purpose Production of Separable Para-Xylene and Ethylene Glycol from PET Wastes 1.00
Aminyl Radical-Enabled Photoredox/Nickel-Catalyzed C(sp3)–C(sp3) Suzuki–Miyaura Cross-Coupling via Halogen-Atom Transfer Strategy 1.00
Unveiling Orthogonal Mechanochemical Pathways via 19F NMR under a Three-Arm Pulling Strategy 1.00
Anion-Suppression Strategy Enables Palladium Metallaphotoredox-Catalyzed Desymmetric Carboxylation with CO2 1.00
Electrocatalytic Oxidative Coupling of CO with Amines toward Symmetrical and Asymmetrical Urea Derivatives 1.00
Ring Expansion of Benzofurans by Single-Silicon Insertion 1.00
Deciphering Mechanistic Pathways and Selectivity in Electrochemical Oxidative C–N Bond Formation between Olefins and Sulfonamides 1.00
Lateral Boron-Doping Intensifies Diradical State and Stabilizes Spins of peri-Acenoacene: A Nanographene Diradicaloid with Absorption beyond 1300 nm 1.00
Efficient and Selective Hydroxyl-Mediated Photocatalytic Ethane Oxidation to Acetic Acid 1.00
Potassium N-Borylisocyanamide: Synthesis, Structure, and Its Utilization as an Amino and Cyano Transfer Reagent 1.00
Biomolecular Condensates Power Nitrogen Cycling via Concurrent Redox Activities 0.07
Catalytic C(sp3)–F Bond Activation at Low-Valent Germanium and Tin Redox Platforms 1.00
Photoinitiated Enantioselective Cycloisomerization/Addition Cascades of 2-Acyl Benzaldehydes with α,β-Unsaturated Carbonyl Compounds 1.00
Upcycling of Vulcanized Rubber via Controlled Backbone Cleavage and Functionalization 0.88
Steric Engineering of Phenanthrenequinone for Ultrafast and Tunable Visible Light-Induced Photoclick Reaction 0.60
A Universal Platform for One-Pot Synthesis of Block Copolymers via Organoborane-Mediated Aerobic Tandem Polymerization 1.00
Enzyme-Catalyzed Intramolecular C–C Coupling Transformation of Nitriles 0.95
Divergent Asymmetric Synthesis of Four Pentacyclic Homoproaporphine Alkaloids via C–H Elaboration 1.00
Ionic Liquid Gating Enol–Keto Tautomerism 1.00
Copper-Catalyzed Asymmetric Vinylation of α-Cyano Substituted Carbonyl Compounds 1.00
Iron-Catalyzed anti-Markovnikov Allylzincation of Terminal Alkynes 1.00
Solar-Driven Upcycling of Polystyrene Enabled by Elemental Sulfur 1.00
Catalytic Remote Dihalogenation of Alkenes Induced by Transposition of Esters 1.00
All-Hydrocarbon Polymers with Chemical Recyclability via a Catalyst-Free and Solvent-Free Method 1.00
C–H Nucleophilic Substitution for the Diversity-Oriented Modification of Polycyclic Aromatic Hydrocarbons 0.85
Photocatalytic Direct Deoxytrifluoromethoxylation of Phenols 1.00
Transformation of Dewar Metallabenzenes: Valence Bond Isomerization to Metallabenzenes and Beyond 1.00
Synthesis of α-Deuterated Trifluoromethylated Amines through Isomerization-Deuteration Reaction of Imines 1.00
Artificial Spherical Chromatophore Mimicking LH2 and LH1–RC for Highly Efficient Photocatalytic Hydrogen Production with Turnover Number >667,000 1.00
Chemoenzymatic Synthesis of Arisugacins and Terreulactones via Directed Evolution of a Privileged Sclareolide Dioxygenase 1.00
Strategy for the Synthesis of Inverse Sandwich 1,4-Diarylbutadiene Dianionic Rare-Earth Metal Complexes via Directing Coupling of β-Aryl Vinyl Boron Reagents 1.00
Enantioselective C–H Arylation for Axially Chiral Tetra-ortho-Substituted Heterobiaryl N-Oxides 1.00
The Catalytic Asymmetric Mukaiyama–Michael Reaction of Silyl Ketene Acetals with Cyclic Enones: Short Routes to Jasmonates 0.11
Taming Sulfate Radical for Anti-Markovnikov Alkene Hydrosulfation 1.00
Palladium-Catalyzed Autotandem Hydrogenolysis/Hydrogenation for the Synthesis of Hexahydro-β-carbolines Containing Three Contiguous Stereocenters 1.00
Harnessing Cooperative Hydrogen-Atom Transfer and Nitrene-Primed Radical–Polar Crossover for Asymmetric C–H Amidation of α-Amino Carbonyls 1.00
A Rational Desymmetrization Approach for Enantioselective Synthesis of Inherently Chiral C1-Symmetric Metal–Organic Cages 1.00
Craig Excited-State Aromaticity in Metallabenzenes: How, When, and Why? 0.67
In Situ Heterochiral Helix Coupling Triggered Supramolecular Evolution 1.00
The Radical SAM Enzyme BlsE Can Operate as a Dehydratase, Dehydrogenase, or Epimerase upon Mutation of a Single Active Site Serine Residue 0.29
Enantioconvergent Indole Alkylation Using Diols via Oxocarbenium Intermediate by Borrowing Hydrogen To Access γ-/δ-Chiral Ketones 0.33
Expanding Ullmann Homocoupling to Cross-Coupling: Electrochemical Copper-Catalyzed Cross-Electrophile Coupling of Alkyl and Aryl Halides 1.00
Copper-Catalyzed Enantioconvergent Radical Deborylative Coupling of Racemic Benzylboronic Esters with Alkynes and Alkenylboronic Esters 1.00
Surface Halogen Passivation Enables Ultra-Stable Metal Sulfide for Efficient Methanol Photoactivation 1.00
Total Synthesis of (±)- and (+)-Euphohyrisnoid A 1.00
Visible-Light-Mediated Lewis Acid-Catalyzed Diradical Hydrogen Atom Transfer Reaction of Bicyclo[1.1.0]butanes 0.83
Co-Catalyzed Asymmetric Carbamoyl Radical Addition of Imines 1.00
Photodriven Enantioselective 6-endo Hydroaminative Cyclization to Chiral 4-Substituted 3,4-Dihydroisoquinolones 1.00
De Novo Labile C–N Bonds Enable Dynamic Covalent Chemistry and Reversible Bioimaging 1.00
Waveform-Enhanced Alternating Current Electrocatalysis Enables Cu-Catalyzed Carbon–Oxygenation of β-Keto Carbonyls with Alkenes and Alkynes 1.00
Intermolecular Cyclization of Alkyl Chains of Ketones for Constructing ortho-Diacylbenzenes 1.00
Copper(I)-N-Heterocyclic Carbene-Catalyzed Enantioselective Conjugate Allylation of α,β-Unsaturated Esters 1.00
Ring Constraint Strategy Enabled Cycloaddition of Oxazolones and Alkenes via Photoinduced Energy Transfer 0.17
Asymmetric Ketone Diene Coupling via Stereodivergent Copper Catalysis 0.25
Room-Temperature Methane Oxidation to Formaldehyde Mediated by CoMoO+ Gas-Phase Cations 0.86
Antiaromaticity Relief-Mediated Intramolecular Charge Transfer Enables Efficient and Stable Radical Emission in Polar Solvents 1.00
Diazulenopentalene: Facile Synthesis of Linear Non-Alternant Molecular Carbons through Pt-Mediated Rearrangement 1.00
Enantioselective Functionalization of Light Alkanes and C(sp3)–H Bonds via Photoinduced Palladium Catalysis 0.86
Iridium-Catalyzed Borylation of Strong Alkyl C(sp3)–H Bonds of Sulfonamides Enabled by Triflyl Activation 0.25
Concise Synthesis of Deoxylimonin 1.00
Confined Chiral Pd(II) Catalyst-Enabled Enantioselective Intramolecular Aminoalkylation of Alkenes: One-Step Construction of Chiral N-Fused Bicyclic Skeletons 1.00
Transient Compartmentalization in Coacervates Driven by Chemically Fueled Autocatalysis and Interfacial Remodeling 1.00
Regulating π-Stacked Micelle-Like Assembly via Anion Coordination to Achieve Frank–Kasper C15 Phases 1.00
Ambimodal (2 + 1)/(4 + 1) Pseudopericyclic Transition States in Reactions between Dihalocarbenes and Olefins 1.00
Construction of Heteroleptic Copper Complexes in Perylene Diimide-Based COFs for Heterogeneous Metallaphotoredox Catalysis 1.00
Photocatalytic Upcycling of Polyethylene Terephthalate via Formate-Mediated Non-Hydrogen Deoxygenative Reduction 1.00
The Effect of Allosteric Conformational Regulation on the Crystal Packing of Aromatic Amide Metallomacrocycles via Ligand-Modulated Remote Intramolecular Hydrogen Bonds 0.89
An Organoborate Monoxide Radical 1.00
Doping a Nanographene with a Formal NiIV Center 1.00
Photo- and Copper Dual-Catalyzed Z-Selective Chlorosulfonylation of Allenes for Tetrasubstituted Alkenes 1.00
Iridium-Catalyzed B–H/C–H Dehydrogenative Coupling to Enable Boron–Nitrogen-Embedded Polycyclic Aromatic Hydrocarbons 1.00
Palladium-Catalyzed Asymmetric Oxidative Amination of Internal α,β-Unsaturated Esters with Lewis Basic Amines 1.00
Enantioselective Radical Addition of Carboxylic Acids to Imines through Cooperative Copper/Acridine Catalysis 1.00
Electrochemical Indole Skeletal Editing via Single-Carbon Atom Insertion 1.00
Catalyst Metamorphosis: In Situ Oxidation of Diphosphines in Palladium-Catalyzed Regioselective and Enantioselective Heck Reactions 1.00
Total Synthesis of (+)-Melicolone K Enabled by a Late-Stage Programmed C–H Functionalization 1.00
Integrating High-Density Frustrated Lewis Pairs with Switchable Pt–O–In Motifs to Break the Activity–Selectivity Trade-Off of Methane Photooxidation 1.00
Iron-Catalyzed Synthesis of Unsymmetrical Disilanes 1.00
Asymmetric Total Synthesis of Vilmotenitine A and Structural Revision of Hemsleyaconitine F 1.00
Mechanistic Study of Cycloisomerization of 1,7-Allenenes and Guidance to Develop a [2 + 1 + 2] Reaction of 1,7-Allenenes with CO for Accessing cis- and trans-5/5 Skeletons 1.00
Modular Synthesis of Chiral Multi-Substituted Cyclohexanes via Cobalt-Catalyzed Enantioselective Desymmetrizing Hydroalkylation 1.00
Phosphonium Ionic Imine Cage with an Uncommon Tri24Di6 Topology for Selective Capture of Propyne in Propyne/Propylene Separation 1.00
Thiol-Regulated Rhodium Nanocatalyst for Electrochemical Reductive Perdeuteration of Alkenes 1.00
Enabling Proteins with Photocatalytic Functions via HisTag–Iridium Coordination 1.00
Ligand-Relay Strategy Enabling Copper-Catalyzed C–C/C–O/C–N Cascade Trifunctionalization of Internal Alkynes and Propargylic Sites: Synthesis of Benzofuran-β-Lactams 1.00
Dynamic Kinetic Control Enables Nickel-Catalyzed Enantioconvergent C(sp3)–O Coupling 1.00
Stereoselective Dihalogenation of Alkynes to Access Enantioenriched Z-Vicinal Dihaloalkene Atropisomers 1.00
Stereocontrol on Helical Bimetallic DNA Catalysts with Switchable Enantioselectivity via Dynamic Reaction Distance Regulation 0.44
Electrocatalytic Semi-Hydrogenation of Pyridine Derivatives over an In Situ Assembled Cu Cathode 1.00
Coordination Cage-Confined Chirality of Non-precious Metals for Enantioselective C–C and C–N Bond Formation 1.00
Crystalline Neutral Boraolympicenyl Radicals with Electronic Regulation through Boron-Doping Sites 1.00
Enantioselective Construction of 1,3-Stereogenic Centers via 1,3-Borylamination of Conjugated Dienes 1.00
Reversible Interconversion between a Carbon–Carbon Double Bond and Diradical beyond External Stimulus 1.00
Visible-Light-Induced Nitrogen-Atom Deletion of Unactivated Secondary Amines 1.00
Automated Rapid Synthesis of High-Purity Head-to-Tail Cyclic Peptides via a Diaminonicotinic Acid Scaffold 1.00
Dual Cation/Anion Binding in Crown Ether-Based Coordination Cages 0.08
Cu-Catalyzed Enantioselective and Divergent Synthesis of 5–5-Membered Atropisomers via Direct Atroposelective C–C/C–N Axial Bond Formation 1.00
Asymmetric Catalytic Construction of 1,1-Diheteroquaternary Tetrahydro-β-carbolines Enables Collective Syntheses of Polycyclic Alkaloids 1.00
Efficient Electrosynthesis of Adipic Acid via a Cascade Reaction at Pickering Droplet Interfaces 0.86
Direct Catalytic Enantioselective C(sp2)–H Allylation of Acrylic Acids: Modular Access to Chiral 1,4-Skipped Dienes 1.00
Cascade Dearomative Hydride Transfer/Enantioselective Semipinacol Rearrangement of Quinolines by a Chiral Brønsted Acid 1.00
O2-Mediated Reactivity of Confined Carbenium Ions in Zeolites 1.00
Aza Analogs of Arene Oxygenase Metabolization via Iron Catalysis 1.00
Total Synthesis of Acoapetaludine A Enabled by a Rhodium-Catalyzed Domino Cyclization 1.00
Rhodium-Catalyzed Atroposelective Alkyne Oxyamidation Using Non-Nitrene NH Acyloxyamide Reagents 1.00
Boron Nitride-Confined Nanographene as a Metal-Free Catalyst for Acetylene Hydrochlorination 1.00
Electrochemical Dehydroxymethylative Functionalization of Unactivated Alcohols via Criegee–Kolbe Radical Relay 1.00
Enantioselective Ni–Al Bimetal-Catalyzed Cycloaddition of Cyclopropyl Ketones with Alkynes under Mild Conditions 1.00
Electrosynthesis of High-Valent Iridium-Oxo Species for Efficient Oxygen Transfer Defluorination 1.00
Proton-Regulated C–N Coupling for Efficient Amino Acid Electrosynthesis 1.00
Synergizing Structure-Guided Photocaged Linear Diubiquitin-Dha with Biotinylated Linear-Fab for Time-Resolved Profiling of Interactors in Living Cells 1.00
Copper-Catalyzed Asymmetric Alkynylation of sp2 Allenic C–H Bonds for the Synthesis of Skipped Diynes 1.00
Unifying Dearomatization and Rearomatization via Stereoselective Chlorination/Dechlorination: Resolution of Axially Chiral 1-Aryl-2-naphthols 1.00
Conformationally Adaptive Molecular Cages Enabled by Metal Cluster-Mediated Assembly 1.00
Constructing a Built-In Electric Field via Polymer Modification to Boost D2O Reorientation and Electron Transfer for Deuteroacetic Acid Electrosynthesis 1.00
Electrocatalytic Proton Borrowing N-Alkylation of Pure Alcohols and Amines 1.00
Protocells with ATP-Fueled Dissipative Behaviors as Functional Regulators 1.00
Harnessing the Potent Excited-State Reductive Power of Pyrene-Modified N-Heterocyclic Carbene-Stabilized Au13 Nanoclusters for Four-Electron Nitroarene Reduction with Unity Selectivity 0.90
Catalytic Enantioselective Synthesis of Planar-Chiral Cyclophanes via a Chiral Octahedral Cobalt(III)-Templated C–H Macrocyclization 1.00
Bioorthogonal Photocatalytic Protein Labeling and Cross-Linking Enabled by Stabilized Ketyl Radicals 1.00
Facile Access to Tricyclic Molecular Architectures through Photo-Reversible Dearomative 6π-Desymmetrizations: Scope, Applications, Bioactivity Study, and Mechanistic Nuances 0.82
Hydrogen-Bond-Donor Coupled Electron Transfer Enabled Copper-Catalyzed Asymmetric Radical Alkynylation with a Planar Chiral Ligand 1.00
Enantioselective Radical Sulfonylation of 2-Naphthols and β-Ketoamides with Sodium Sulfinates 1.00
Taming Halogen Radicals via Electrophotocatalysis: Direct Access to Alkenyl Halides 1.00
Convergent Total Synthesis of Papililone A via Pd-Catalyzed Alkenylation/Cyclization Cascade 1.00
Catenanes of Twin-Cavity Cages 1.00
Isolation and Reactivity of a Silylene-Stabilized Borasilylidene 1.00
Pd/SadPhos Enabled Modular and Enantioselective Assembly of Triarylmethanes 1.00
Protocell Survival Networks in Spatially Modulated Chemical Gradients 0.50
Water-Promoted Molar-Level Photocatalysis and Spontaneous Product Separation with Near-Unity Quantum Efficiency 0.89
Asymmetric Synthesis of Diverse P(V) Compounds Bearing a C–P Bond via Desymmetrization of Phosphonic Dichlorides Catalyzed by a Chiral Bicyclic Imidazole 1.00
Entropy-Driven Amino Acid-Based Coacervates with Enzyme-Free Metabolism and Prebiotic Robustness 0.83
Steric Control over Heteroleptic Trigonal Prisms: From Integrative Self-Sorting to Programmable Spin-State Modulation through Cage Transformations 1.00
Solar-Driven C–N Coupling over Pd/TiO2 Enables High-Yield Synthesis of Methylamine Hydrochlorides from Methanol and Ammonium Chloride 0.78
Copper-Catalyzed Enantioselective Intra- and Intermolecular Desymmetrization of Azetidiniums by Carbon Nucleophiles 1.00
Fast and Site-Specific Covalent Targeting of Proteins by Arylfluorosulfate-Modified Aptamers 1.00
Solar-Driven Upcycling of Polylactic Acid to Alanine over Pt/CdS–TiO2 Heterojunction Single-Atom Photocatalyst 1.00
Catalytic Asymmetric Synthesis of 3-Hydroxyindolenines Using Achiral Oxaziridines 1.00
Photoenzymatic C(sp3)–H Functionalization of 1,3-Dicarbonyls Enables Enantioselective Hydroalkylation of Styrenes 1.00
Synthesis of Collinoketones via Biomimetic [6 + 4] Cycloaddition 0.43
Bimetallic Relay Catalysis for Radical Hydrofunctionalization of Alkenes with Diverse Nucleophiles 1.00
Selective Electrochemical C–N Coupling via Synergetic Chemical and Electrochemical Microenvironment Regulation Strategies 1.00
Stereoconvergent Polymerization Driven by Catalytic Racemization 1.00
General Photo-Driven Chemoselective and Rapid Hydropentafluorosulfanylation of Alkenes via an Orchestrated Radical Chain Process 1.00
Cucurbit[8]uril-Induced Self-Sorting Heterodimer for Aqueous Red/NIR Delayed Emission 1.00
Electroreduction of Aromatic Carboxylic Derivatives to Aldehydes 1.00
Palladium-Catalyzed Site– and Enantiodifferentiating Allylic C–H Alkylation of Internal Alkenes 1.00
Direct B–H Bond Activation Polymerization of Boron Clusters 1.00
Stereoselective De Novo Construction of Cyclopropane by a Multifunctional Class I Aldolase 1.00
Snap-Trapping Strategy for Amine-Specific Bioconjugation with Pyridotriazole Carbaldehydes 1.00
Total Synthesis of (+)-Resiniferatoxin via a Pyridinium Salt Photorearrangement 1.00
Electrophotocatalytic Oxygenation of Unactivated Aliphatic C–H Bonds Using Water as a Sustainable Oxygen Source 1.00
Precise Synthesis of Pyrene-Based Molecular Nanocarbons Driven by Dehydro-Diels–Alder Reactions 1.00
Denitrogenative Carbon Skeleton Cleavage and Reorganization of Pyridines by a Trinuclear Titanium Polyhydride Complex 0.33
From Conjugated to Enantioenriched Skipped Dienes: Co-Catalyzed Asymmetric Cross-Hydrodimerization of 1,3-Dienes and Alkynes 1.00
Catalytic Enantioselective C(sp3)–C(sp3) Cross-Coupling of Tertiary Nitriles with Allyl Halides to Quaternary Stereocenters 1.00
A Persistent Open-Shell m-QDM-Type Diindenoanthracene Diradicaloid with a Large Diradical Character 1.00
Conjugated Networked Poly(ionic liquid)-Accommodating Organic Cages: A Matter of Interhost Electron Communications 1.00
Atropisomeric Indene (AtroInd) Libraries: Design, Catalytic Synthesis, and Applications 1.00
From Alkylarenes to α-Amino Acid Derivatives via C-Difunctionalization 1.00
Enantioselective Redox-Neutral Radical Addition of α-Imino Esters with Sulfonyl Hydrazides 1.00
Borane/Transition Metal–Catalyzed Allenylic and Allylic Alkylation of Unactivated 2-Alkylbenzoxazoles 1.00
Neutral Aromatic 2,3-Diboranaphthalenes 1.00
Bioinspired Total Syntheses of Skeletally Diverse Lycopodium Alkaloids 1.00
Divergent Total Synthesis of Pleurotinoid Natural Products 1.00
Curvature-Directed Selective C–C Bond Cleavage Driven by Electric Fields 1.00
Photocatalyst-Regulated Trifluoromethoxylation of Aryl Halides under Silver Promotion 1.00
Skeletal Editing of Quinolines by Single-Atom Carbon Insertion–Deletion 1.00
Deciphering Spin-Governed Dual Emissions in TTM Diradicaloids: Unraveling the Interplay of Singlet and Triplet Fluorescence Pathways 1.00
Ligand Evolution-Enabled Enantioselective C(spsup3/sup)–H Azidation 1.00
Photoetching-Generated Redox Pairs in Confined Layered Structure Boost Single-Electron-Transfer-Mediated Photocatalysis 1.00
Efficient Assembly of Functional RNA by in Situ Phosphate Activation and Loop-Closing Ligation 0.17
Synthesis of Acyclic All-Carbon Quaternary Stereocenters through Nickel-Catalyzed Enantioselective C(sp3)–H Amination 1.00
Rare-Earth-Catalyzed Selective Hydrosilylation of Iminocyclopropanes: Efficient Access to Azasilacyclopentanes 1.00
Two Flavoenzymes Convert Fungal Polyketide-Nonribosomal Peptide to cis-2-Butene-1,4-dial-Type Carcinogen via Olefin Dihydroxylation and C–C Bond Cleavage 1.00
Catalytic Enantioselective Perezone-Type [5 + 2] Cycloaddition 1.00
Biocatalytic Stereodivergent Construction of Axially Chiral Tri- and Tetrasubstituted Allenols via Desymmetric Hydroxylation 1.00
A Highly Selective Cobalt Catalyst for Primary Amine Synthesis from Carboxylic Acids, Esters, and Vegetable Oils 0.06
Direct Deaminative Halogenation at Hindered Tertiary Centers 1.00
Alternating Current-Driven Diol Epimerization via a Deplete–Regenerate Strategy 1.00
Asymmetric Total Syntheses of Hetidine-Type C20-Diterpenoid Alkaloids: Spirasines V and VI, Spiradine D, and the Proposed Structures of Spirafines II and III 1.00
Single-Crystalline Poly(disulfide)s Enabled by PhotoTriggered Topochemical Ring-Opening Polymerization of 1,2-Dithiolane 1.00
Ultradurable Regenerative Propane Dehydrogenation Catalyst by Fluorination-Induced Confining and Positioning 0.80
Kinetic Resolution for 1,4-Spin-Center Shift-Based Reduction of Azaarene-Functionalized Secondary and Tertiary Allylic Alcohols 1.00
Ir(III) Pincer Complex with Solo Coordinatively Active Site as a Surrogate for Half-Sandwich Catalysts: Enabling Asymmetric Acylnitrenoid Transfer and Structure–Activity Relationship Studies 0.83
A Crystalline Monomeric Diboryl Diazene 1.00
Regiodivergent Access to α- and β-Amino Acids via Solvent-Controlled Rh-Catalyzed Carboamidation of β,γ-Unsaturated Carboxylic Acids 1.00
Bridged-Backbone Strategy Enables Asymmetric Synthesis of Highly Functionalized Oxabicyclo[3.3.1]nonanes with Anti-Osimertinib-Resistant NSCLC Activity 1.00
In Situ Probing Two Radicals in Halogenation Couplings from Photoanodic Single-Atom Catalysis 1.00
Atomically Precise Copper Cluster for Highly Chemoselective Carbenoid Insertion into the N–H Bond of Aliphatic Amine 1.00
Photobiocatalytic Radical Hydroalkylation with C(sp3)–H Bonds Enabled by Engineered Imine Reductase and Redox Buffering 1.00
Design, Synthesis, and Application of a Type of Chiral Spirocyclic Naphthylamines 1.00
Ligand-Controlled Stereodivergent α-Vinylation and α-Arylation of Peptide Backbones 1.00
A Biomimetic Procedure for the Synthesis of 1,2-cis C-Vinyl Furanosides from Unprotected Aldoses 1.00
Photoelectrochemical Catalyzed Site-Selective Tryptophan β-Position Functionalization 1.00
Inhibiting Isomerization via Confinement in Ice–Water Interfaces Enhances Stereoselectivity in [2 + 2] Cycloaddition 1.00
Copper-Catalyzed Asymmetric C–H Sulfilimination of Arenes via HAT-Primed C–S Radical–Radical Coupling 1.00
Unlocking Difluorocarbene as a Fluorocarbanion and a Fluorocarbon Radical Precursor for Sequential Catalytic Coupling 1.00
Rapid Activation of Amino Acids with Cyanide and Hypochlorite 0.25
Enantioselective Synthesis of Atropisomeric 3-Arylindoles via Cobalt-Catalyzed Electroreductive Cross-Coupling 1.00
Total Syntheses of Giraldine I and Heterophyllisine 1.00
Pretzelanes with Planar Chirality and Guest Recognition Capabilities 1.00
Asymmetric Coordination Designed Heterocrown Ether Host–Guest Ferroelectrics with Ultrahigh Tc 1.00
Ligand Architecture Control Geometry, Self-Sorting, and Postsynthetic Modification in Anthracene-Based Organometallic Assemblies 1.00
Methylation and Alkylation of Pyridines at the meta Position Using Aldehydes or Aldehyde Surrogates 1.00
Cobalt-Catalyzed Enantioselective Hydroalkylation of Oxa- or Azabicyclic Alkenes 1.00
Palladium-Catalyzed Asymmetric Carbonylation of Alkynes to Axially Chiral Carbothioate Esters 0.90
Bio-Photo Dual Action of Intracellular Radical Polymerization 1.00
A General Copper-Catalyzed Radical Cross-Coupling of Unactivated Alkyl Halides 1.00
Nickel-Catalyzed Enantioselective Direct Addition of Styrenes to Imines Enabled by Chiral Spiro Phosphine Ligands 1.00
Cyclic BODIPY Arrays: A Class of Macrocycle-Based Molecular Solids for Hydrogen Isotope Separation and Iodine Capture 1.00
Methyl Radical Dominated Highly Selective Methane Oxidation to Liquid Oxygenates 1.00
Ligand-Induced Self-Complementing Tag (LiSC-Tag) as an Epitope Tag for Live-Cell Super-Resolution Imaging and Functional Manipulation of Cellular Proteins 1.00
Asymmetric Dearomative [2 + 2] Photocycloaddition of Quinoline and Indole Derivatives with Bicyclo[1.1.0]butanes 1.00
Late-Stage Tryptophan Modification of Native Peptides through Photochemical Indole-to-Quinazoline Editing 1.00
Highly Selective Photo-Oxidation of Methane to Methanol by Fe–Au Site-Supported SrTiO3 Hollow Nanotubes with Oxygen Vacancies 1.00
Molecularly Tuned Carbon Dots for Visible-Light-Driven Boryl Radical Generation via Enhanced Hole Transfer 1.00
Harnessing Chromium(V) Hydrazido Intermediates for N2 Functionalization to Multisubstituted Hydrazines through Ligand Migration 1.00
Stereodivergent Synthesis of Allylic All-Carbon Quaternary Centers by Bimetallic Iridium/Magnesium-Catalyzed Allylic Alkylation 1.00
Development of Cyclooctyne-Nitrone Based Click Release Chemistry for Bioorthogonal Prodrug Activation both In Vitro and In Vivo 1.00
Construction of Zeolite Framework-Anchored Rh–(O–Zn)x Sites for Ethylene Hydroformylation 1.00
A Uniquely Structured Heteronuclear Cluster Cage with Anion-Templated Pentagons and Hexagons 1.00
Ultrastable Copper Cluster Enables Highly Site-Selective and Chemoselective Carbocation C(sp3)–H and C(sp2)–H Bonds Functionalization 1.00
A Bifunctional Chiral Disulfide Catalyst for Highly Enantioselective Anti-Markovnikov Hydrophosphinylation 1.00
Enantioselective Assembly of (Hetero)aryl Alkyl Sulfilimines via Copper-Catalyzed S-Arylation of S-Alkyl Sulfenamides with (Hetero)aryl Iodides 1.00
Structural Basis for 3-Amino-3-carboxypropyl Transfer in Nocardicin Biosynthesis 0.06
Ruthenium-Catalyzed Intermolecular [2 + 2] Cycloaddition of Unactivated Allenes and Alkynes with Unusual Regioselectivity 1.00
Photocatalytic C–X Bond Cleavage Facilitates Peptide Synthesis 1.00
Water as an Electron Donor for Cross-Electrophile Coupling Reactions 1.00
Pillar-like Macrocycle Reversibly Self-Assembled from a Molecular Thermally Activated Delayed Fluorescence Emitter Based on B ← N Dative Bonds with Intriguing Fluorescence 0.91
Divergent Synthesis of 1-Azabicyclo[n.1.1]alkane Bioisosteres via Photoinduced Palladium Catalysis 0.83
Targeted Synthesis and Development of Neotype Antiviral Agents with a Radical-Mediated Deoxyphosphoamination Strategy 1.00
Cu/Ru Relay Catalysis Enables Functionalization of Allenic Alcohols with Stereodivergence and Skeleton Diversity 1.00
Ultralow Content of Chromium Species in Zeolite for Efficient Catalytic Propane Dehydrogenation 0.87
Modular Access to Medium-to-Large Sized Lactams through Alkyne-Bridging C–C Bond Activation of Unstrained Carbonyls 1.00
Asymmetric Total Synthesis of (−)-Psychotriadine Featuring [3,3]-Rearrangement and Stereo-Controllable Ring-Contraction 1.00
Divergent Total Syntheses of Elisapterane and Relevant Diterpenoids Assisted by iIn Silico/i Structure Reassignment 1.00
Photocatalyzed Decarboxylative B–C Couplings for the Synthesis of Carboranyl Amino Acids and Peptides 1.00
Near-Infrared Photoenzymatic Catalysis at ppb Levels Enables Ultrahigh-Molecular-Weight Polymers 0.67
Highly Selective Carbonylation of Olefins Using CO2 and H2 0.07
Site-Specific Chemoselective Cyclization and Fluorogenic Modification of Protein Cysteine Residues: From Side-Chain to Backbone 0.86
Enhanced Single-Molecule Imaging via Intersystem Crossing Suppression 1.00
Recyclable Inorganic Subnanowire Plastics 1.00
Multiple Template Site Nitrogen Atom Deletions from Rotaxanes, Catenanes, and a Molecular Knot 0.07
Trisilylation of a Formal Cr(−I) Bis-dinitrogen Complex 1.00
Porous Gold Nanoumbrellas with Adjustable Apical Angles for Selective Electrosynthesis of Styrene Epoxide from Styrene 1.00
Stereodivergent Synthesis of Enantioenriched Organoboron Compounds with Carbon/Boron Dual Stereocenters via Rh(I)/Cu(I)-Catalyzed Enantioselective Desymmetrization of B–H Insertions 1.00
Radical Ring Expansion Catalyzed by an α-Ketoglutarate-Dependent Dioxygenase in the Biosynthesis of Tropolones 1.00
Bench-Stable Carbamoylzinc Pivalates for Modular Access to Amides, Ureas, and Thiocarbamates 1.00
Carbon-Caged-Yttria Catalysts for Stable Electrosynthesis of H2O2 in Concentrated Acid 0.93
Enantioselective Synthesis of α-Oxygenated Ketones via Organocatalytic Formal O–H Bond Insertion of Sulfonium Ylides 1.00
Iron-Catalyzed Asymmetric Reductive Cross-Coupling of Ketimines with Alkyl Iodides 1.00
Construction of a Chiral Click Chemistry Platform via Enantioselective F/Cl Exchange at S(VI) Centers 1.00
Photocatalytic Asymmetric Oxidation of Phosphines with Water 1.00
Isolation and Reactivity of a BN-Embedded Heterocumulene 1.00
Catalytic Oxidation of Carbon–Halogen Bonds by Water with H2 Liberation 0.17
Nickel-Catalyzed Regio- and Enantioselective Hydroalkenylation of Aldehydes with 2-Azadienes 0.88
Diversity-Oriented Synthesis of Diaza-Polycyclic Aromatic Hydrocarbons Coupled with Virtual Screening for OLED Applications 1.00
Organocatalytic imeta/i-C–H Hydroxylation of Azaarene iN/i-Oxides 1.00
Photoelectrochemical Asymmetric Epoxidation of Alkenes with Water as an Oxygen Source in a Biphasic System 0.97
Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols via Tandem Etherification/Claisen Rearrangement 1.00
Late-Stage Aromatic C–H Bond Functionalization for Cysteine/Selenocysteine Bioconjugation 0.31
Enantioselective Construction of β-Substituted γ-Lactone through Catalytic Asymmetric Oshima–Utimoto Reaction: Divergent Total Syntheses of (−)-Podophyllotoxin and Its Eleven Congeners 1.00
A Bifunctional Sulfone Reagent for Asymmetric Aminomethylative Sulfonylation of Dienes 1.00
Ultraconjugated Electron–Proton Transfer Mechanism in the Product Selectivity-Controllable Electrocatalytic Oxidation of Binary Primary Alcohols 1.00
Enantioselective Construction of Aza-bicyclo[3.2.1]octane Skeletons via Substituted π-Allyl Palladium Dipoles Originated from Neutral η3-Propargyl Palladium Species 1.00
π–π Stacking and Structural Configurations in Aromatic Thiophene and Fluorobenzene Dimers Revealed by Rotational Spectroscopy 1.00
Electrochemical Oxygen Reduction Reaction-Coupled Dechlorination Promoting Acylation Reaction for Aromatic Ester Synthesis 1.00
Tunable Formal Photocycloaddition of 1-Naphthol Derivatives 1.00
Preparation of 1,4-Diamines by Enantio- and Diastereoselective Cu–Josiphos-Catalyzed Reductive Couplings of Azatrienes and Imines: Regiodivergence Enabled by Catalyst Structure and Reagent Tailoring 0.20
Nanographene-Oxy Radical Stabilized by a Carbaporphyrin Framework 0.33
Reversible Electron Transfer in the Formation of Radical Anionic and Dianionic 1,4-Diborabutatrienes 1.00
Bimolecular Nucleophilic Substitution (SN2) Reaction Catalyzed by l-Threonine Aldolase 1.00
Binuclear Metal-Based Covalent Organic Framework Mimicking Metallohydrolases for Direct Photoreforming of PET Plastic 1.00
Chiral Porous Sheet Assembly for Multiple Chirality Induction in Macrocycle Formation 0.80
Systematic Synthesis of Large Porous Organic Cages Driven by Steric Hindrance 1.00
Construction of a De Novo Nucleotide Biosynthesis Pathway in Artificial Cells for RNA Transcription 1.00
Cobalt-Catalyzed Asymmetric Reductive Coupling of Isocyanates with Tertiary Alkyl Halides for Sterically Bulky Chiral Amide Synthesis 1.00
Cooperative Bimetallic Radical Catalysis Enables Asymmetric Hydrogen-Atom Transfer 1.00
Johnson Solid Gold Nanoclusters as Heterogeneous Visible-Light Photocatalysts for Fukuyama Indole Synthesis 1.00
Mono or Di? A Potential-Controlled Electrochemical Halogenation of Anilines 1.00
Enantioselective Total Synthesis of Bipolarolides A and B 1.00
Total Synthesis of Paxdaphnine A and Daphlongamine B via an Aza-Prins Cyclization Strategy 1.00
Electron Donors in the Intertwined Interface Restore Oxy-Substituted Selenides 1.00
Sustainable Imine Production Using Alkanes as Substrates via a Plasma-Microdroplet Approach 1.00
Interfacial Electric Fields Modulate Redox Reactions in Abiological Coacervates 0.22
Concise Syntheses of Harziane Diterpenoids by Merging Local Desymmetrization and Radical Retrosynthesis 1.00
Nucleophilic α- and β-Additions Enable Redox-Neutral Aziridination of Conjugated Hydroxamates 1.00
Diastereo- and Enantioselective Synthesis of Polycyclic Amines by Cascade Cyclization of Aromatic Aldimines with Tethered Alkenes via Scandium-Catalyzed C–H Activation 0.08
α-Ketoglutarate-Dependent Dioxygenase-Catalyzed Macrocyclization in RiPPs 1.00
Chiral Phosphoric Acid-Catalyzed Enantioselective Higher-Order Cycloadditions: Temperature-Dependent Periselectivity 0.13
Scaffold Hopping of α,β-Unsaturated Ketones via Divergent Alkyl Amine Insertion 1.00
8-Quinox Cobalt Catalyst Enables the Reductive Alkylative Addition of Sulfinylamines with Unactivated Alkyl Halides 1.00
Asymmetric Access to δ-Hydroxy α-Amino Acids Bearing Two Adjacent Stereocenters from Inert Allylic Alcohols Via Cu/Ru Relay Catalysis 1.00
Controlled Solid-State Ring-Opening Polymerization of Cyclic Carbonates via Mechanochemical H-Bonding Organocatalysis 0.88
Disordered Ru–O6 Octahedrons for Efficient and Selective Electro-oxidation of Sulfide to Sulfoxide via Boosted Surface Oxygen Kinetics 1.00
Precise Distal B–H Bond Activation of nido-Carboranes by Copper Catalysis: Synthesis of Benzene Bioisosteres from Boron Clusters 1.00
Warhead Strategy for Targeted Protein S-Nitrosation 1.00
Radical 1,3-Difunctionalization of β,γ-Unsaturated Ketones via Concomitant 1,2-Carbonyl Migration: An Entrance to β-SF5-/β-CF3SF4 Ketones 1.00
Modular One-Pot Access to Boron-Carboxylated Dipyrromethene Dyes as Visible-Light and Two-Photon Activatable Photocages 1.00
Melt Rheology of Dendritic Hyperbranched Polyacrylates Synthesized by Controlled Radical Polymerization: Evidence of Self-Similar Branch Structure Formation 0.08
Stereoconvergent Aminoboration of (Z/E)-Mixed Alkenes via Bimetallic Asymmetric Relay Catalysis 1.00
Unveiling Janus Chemical Processes in Contact-Electro-Chemistry through Oxygen Reduction Reactions 0.82
Spin Delocalization of Nitrile-Ligated Diarylboryl Radicals Enables Photochemical Boracycle Synthesis via N-Borylimidoyl Radicals 1.00
Taming Enolate Regioselectivity: Catalyst-Guided Divergent Synthesis of Atropisomeric Pyridones via Switchable C- and O-Acylation 1.00
Triplet Energy Transfer-Based Deracemization of Axially Chiral Alkenes Enabled by a Dual Catalyst System 1.00
Cu/Ir Relay Catalysis for Regio- and Enantioselective Alkene Borylation/Allylic Alkylation 1.00
Enantioconvergent Radical–Radical Cross-Coupling via Magnesium-Mediated Charge-Transfer Photocatalysis 1.00
On-Demand Nonalternating Copolymerization Enables Upcycling of Mixed Polyethylene and Nylon Plastics 1.00
Unraveling the Potential-Dependent Selectivity of Propylene Electrooxidation: The Role of Electrochemistry-Induced Reconstruction 0.67
Platinum-Catalyzed C–F Bond Reconstruction via the Multi-unit Insertion for Remote Fluorine Migration 1.00
Room Temperature Ring Opening of Benzene by Four-Electron Reduction and Carbonylation 1.00
Mechanical Recycling of Mixed Plastics by Supramolecular Dynamic Cross-Linking Strategy 1.00
DACH-ZYC-Phos/Pd-Catalyzed Enantioselective Allenylation of Secondary Phosphine Oxides via Ligand Relay 1.00
Diastereo- and Enantioselective Pd-Catalyzed C–P Coupling for Axially and P-Chiral Phosphine Oxides via Simultaneous Dynamic Kinetic Asymmetric Transformation and Kinetic Resolution 1.00
A Concise Total Synthesis of Glycinoeclepin A 1.00
Design and Semisynthesis of Ubiquitin Extension Probes for Structural Analysis of Cullin1-Mediated Substrate Polyubiquitination 0.93
Photocatalytic 1,2-Dicarboxylation of Unactivated Alkynes with CO2 1.00
Unlocking a Nano-Aluminum Oxide Lewis Acid Layer as the Electrocatalyst for Hydrogenation of Thiophene and Other Arenes 1.00
Gram-Scale Total Synthesis of Illisimonin A 1.00
Enantioselective Synthesis of 2,3-Disubstituted Azetidines via Copper-Catalyzed Boryl Allylation of Azetines 1.00
Sulfur Vacancy Boosts Light-Driven C–N Coupling in Upcycling of Polylactic Acid to Alanine 0.75
Catalytic Asymmetric P-Site Dearomatization Enables Kinetic Resolution 1.00
In Situ Synthesis of Multifunctional 3D Polymeric Artificial Organelles in Living Cells 1.00
Copper-Catalyzed Highly Efficient and Asymmetric Allylic C–H Oxidation of 3-Aryl-Substituted Terminal Alkenes 1.00
Catalytic Asymmetric Reactions of Alkyl Alkynyl Ketimines: A Versatile Approach to Chiral α-Trialkyl Amines 0.63
Tuning Covalent Organic Frameworks for Nucleic Acid Loading: Toward Creating a Hierarchical Artificial Cell 1.00
Photoinduced Copper-Catalyzed Enantioselective Alkylalkynylation of Alkenes via Polarity-Matched Hydrogen Atom Transfer 1.00
Regioselective Hydropyridylation of Heteroatom-Functionalized Internal Alkenes by Half-Sandwich Rare-Earth Catalysts 0.50
Collective Biosynthesis of Plant Spirooxindole Alkaloids through Enzyme Discovery and Engineering 1.00
Biomimetic Metal–Organic Nanotubular Host for Straight-Chain Fatty Acids Recognition 1.00
Iridium-Catalyzed Z-Selective Asymmetric Allylic Substitution Reaction via Z/E Kinetic Resolution 1.00
A Tailored Quinoline-Locked Covalent Organic Framework for Metal-Free Photocatalytic α-Amino C–H Annulation 1.00
Carbene-Catalyzed Intramolecular Cyclization to Access Inherently Chiral Saddle-Shaped Lactones: Achiral Bases Alternate Product Chirality 0.94
Cobalt-Catalyzed Enantioconvergent Decarboxylative N-Alkylation 0.61
Photoinduced Copper-Catalyzed Enantioselective Allylic C(sp3)–H Oxygenation of Acyclic Terminal Olefins Enabled by SphenBOX 1.00
Phosphorus(III)-Compatible Asymmetric Suzuki–Miyaura Cross-Coupling (P-ASMC) Reaction 1.00
Silicon Rhodamine-Catalyzed Near-Infrared Light-Induced Photodecaging of Ortho-Nitrobenzyl Groups In Vitro and In Vivo 1.00
Divergent Total Syntheses of Rearranged Steroids Swinhoeisterols A–C 0.75
Rapid C–S+ Bond Cleavage via 1,6-Benzyl Elimination for Traceless Modification of Bioactive Peptides 0.71
Insights into the Mechanisms of Sugar Acceptor Selectivity of Plant Flavonoid Apiosyltransferases 1.00
Near-Infrared Light-Driven Condensation Using Branched Two-Photon-Absorbing Organic Photocatalysts with Viscosity-Dependent Properties 0.07
Iridium-Catalyzed Nitrene-Mediated Enantioselective 1,2-Hydride Shift Enabled by Attractive Noncovalent Interactions for Chiral δ-Lactam Synthesis 1.00
Iridium-Catalyzed Asymmetric Hydrogenation of Aryl(4-hydroxyphenyl)ketones 1.00
Reagent-Regulated Organocatalytic Enantiodivergent Synthesis of Chiral Sulfinimidate Esters 1.00
Formation Mechanism of Polycatenane by Direct Catenation 1.00
Piercing Molecular Graphenes: Precision Synthesis and Photophysics of NBN-Edged Porous Molecular Carbons 0.22
Unlocking Epoxide Radical Anion Reactivity for Asymmetric Cross-Coupling by Copper Metallaphotoredox 1.00
Photocatalytic Phosphine-Mediated Deoxygenative [3 + 2] Cycloaddition of α,β-Unsaturated Carbonyls and Alkenes 1.00
Copper-Catalyzed Formal Aldehydic C–H Borylation Enabled by an sp2–sp3 Diboron Reagent 1.00
Photo- and Copper-Catalyzed Enantioselective Oxidation of Benzylic C(sp3)–H Bonds 1.00
Multiple Secondary Bond-Mediated C–N Coupling over N-Doped Carbon Electrocatalysts 1.00
Aza-Michael Addition–Fragmentation Ring-Opening Polymerization 1.00
Concise Total Synthesis of Ambiguine P 1.00
Stereoselective 1,3-Cyclotelomerization of Butadiene with Dienophiles under Nickel Catalysis 1.00
75 68.19
Synthesis of Recyclable Polyesters via Catalytic Transfer Hydrogenation–Dehydrogenative Polymerization of Diketones and Diols 1.00
From Flory Theory to Real Systems: Decoding Polymerization Deviations in Poly(β-amino ester)s (PAEs) 0.17
Self-Assembly of Functionalized Cyclooctene-Based Homopolymers and Photo-Triggered Morphology Transformation Driven by Shackling Photoisomerization 1.00
Thermally Irreversible Y-Junction-Bearing Polyacrylamides Comprising Dialkylamino and Imidazolyl Heterosubstituents 1.00
Revisiting Multiphase Coexistence in Symmetric Ternary Polymer Mixtures 1.00
Enhanced Accessibility and Stability of Worm-like Micelles via Ring-Opening Metathesis Polymerization-Induced Self-Assembly 1.00
Scalable Upcycling of Mixed Plastics into High-Performance Covalent Adaptable Networks 1.00
Isolation of ROMP-Generated Macrocyclic Polyalkenamers via Polar Monomer Incorporation and Chain-End Modification 0.21
Diverse Functionalization of Nonpolar Polyolefins through Late-Stage Incorporation of Alkyl Bromides 1.00
Aqueous Slurry Polymerization of Ethylene by Phosphinephenolato Nickel(II) Complexes: Catalyst Tailoring and Synthesis of Bimodal Polyethylene 1.00
Living Carbanionic Chain-Shuttling Polymerization 1.00
Self-Sacrificing Photocatalyst Enables Polymer Synthesis and In Situ Decolorization 1.00
Polyacrylic Acid-Mediated Supramolecular Light-Harvesting Platform Enables Reactive Oxygen Species Boosting and Photocatalytic Oxidations 1.00
Controlled Synthesis of Degradable Lipoate-Vinyl Copolymers via Xanthate-Mediated Reversible Addition–Fragmentation Chain Transfer Polymerization 1.00
One-Pot Orthogonal Synthesis of Branched Polymers Enabled by Dual-Functional Copper(I)–Organic Frameworks Integrating Photo-ATRP and CuAAC 1.00
Crystal Structure of Poly(α-methylene-δ-valerolactone) 1.00
Structural Switching between Binary Alternating and Ternary Periodic with Reversible Lock–Unlock Carbanionic Polymerization Method 1.00
Segmental Mobility of Polymer Chains under Molecular Confinement: Insights from Precision Molecular Bottlebrushes 1.00
Exclusion-to-Adsorption Transition of Hyperbranched Polymers in Liquid Chromatography: Governed by Configurational Diversity and High Fractal Dimension 1.00
Steric Effect in Kinetic Monte Carlo Simulation of Arm-First Synthesis of Star Polymers 0.83
Hierarchical Dynamic Network Reconfiguration for Co-Rrecycling of Mixed Biodegradable Polyesters 1.00
Determinants of π-π Stacking Motifs in Polymers with Different Aromatic Side Groups 0.67
Synthesis of Highly Syndiotactic Poly(8-Vinylquinoline) via Heteroatom-Assisted Coordination Polymerization 1.00
Interlocked Polymerization inside Cocrystal versus Interfacial Polymerization at Solid of Racemic Leucine N-Thiocarboxyanhydride 1.00
Selective Upcycling of Mixed Polyesters into Valuable Polysulfone 0.86
Fabrication of a Multifunctional Fluorescent Supramolecular Assembly via Cucurbituril-Based Host–Guest Interactions in Aqueous Solution 1.00
Mechanocatalytic Oxidation Using Alkoxyamine Mechanophores: Ultrasonication-Triggered Release of TEMPO Catalysts 1.00
On-Demand CO Delivery and Incorporation from Solid Surrogate Enable Compatible Slurry-Phase Ethylene Polymerization 1.00
Selectivity in Unireactor Oligomerization within a Multiple Tethered-Monomer Reactor 1.00
Step Toward Cationic RAFT Polymerization of Less Reactive Monomers: Dithiobenzoates Bearing Electron-Withdrawing Groups as Chain-Transfer Agents 0.11
Electrostatic Mediation in Synthesis of Single-Chain Nanoparticles in Concentrated Solutions 1.00
Ternary Acrylamide–Aldehyde–Thiol Photopolymerization toward Side Chain-Functionalized Degradable Polyamides 1.00
Stereoselective Control of Crystalline Alternating Copolymers Synthesized with an Anion-Migrated Ring-Opening Polymerization Method 1.00
Tailoring Branched Polyethylene with Polar Segments: A Strategic Approach to Multifunctional Polyolefin Materials 1.00
Radical Cascade Polymerization Involving Dual Cyano Group Migration to Synthesize Periodic Polymers 1.00
Thermally Programmable Off-Equilibrium Pathways in Salt-Doped Polyelectrolyte Hydrogels 1.00
Kinetic Study of Self-Condensing Vinyl Polymerization via ATRP: A Stochastic Model Coupled with Ab Initio Calculations 1.00
Efficient Intermolecular Electron Transfer-Mediated Radical Photopolymerization via Controlled Accessibility of Triplet Excited States in Donor–Acceptor Sensitizers 1.00
Thermo-Driven Dynamic Reversible Self-Assembly of Crystalline Polymersomes and Worms for Active Polymerization Safety Sensors 1.00
Modular Synthesis of ABAC-Type Periodic Terpolymers via RAFT Single-Unit Monomer Insertion and RAFT Step-Growth Polymerization 0.67
Ionized H-Donors as Simple and Diverse Organobase Catalysts for Selective and Versatile Ethoxylation 1.00
Fluorinated Phthalocyanine as a Catalyst for NIR-Photocontrolled PET-RAFT Polymerization: From Submicron Dispersion to Surface Immobilization 1.00
AIEgen Functionalized Polymer Ring 1.00
Structure–Property–Performance Relationships of Tetra-Alkylated Phenazine Photoredox Catalysts in Organocatalyzed Atom Transfer Radical Polymerization 0.09
Flow RAFT Step-Growth Polymerization 1.00
Rationally Designed Poly(heptazine imide) for Highly Efficient Photoinduced Reversible Deactivation Radical Polymerization 0.92
Phenolic Formaldehyde Resin-Based Nano-objects via a Modification-Induced Cooperative Assembly Process Using Poly(4-hydroxystyrene) as the Core-Forming Block 1.00
Mechanically Accelerated Chemical Deconstruction for Nondeteriorative Recycling of Industrial Unsaturated Thermosets and Rubbers 1.00
Stereospecific Hydroxyl–Yne Click Polymerization to Selectively Construct High-Performance Plastics and Elastomers 1.00
Direct Comparative Study of Ring-Opening Polymerization between Propylene Oxide and Cyclohexene Oxide: Geometric Control of Epoxide Polymerization Behaviors 1.00
Organocatalytic Precision Synthesis of Poly(ester amide)s with Enhanced Thermal Performance and Programmable Microarchitectures 1.00
Isolated In Situ Cross-Linking-Assisted Polymerization-Induced Self-Assembly to Polymer Cubosomes with Enhanced Stability 1.00
Morphology Regulation and Quenching Mechanism of AIE Nanobowls by Side Chain Engineering of Azobenzene Homopolymers 1.00
Synthesis of ABC-Type Periodic Terpolymers through a Reversible Lock–Unlock Mechanism in Living Carbanionic Polymerization 1.00
Recyclable Biomass-Derived Polyethylene-like Plastics 1.00
Cyclization in Linear Step-Growth Polymerizations 0.17
Incorporation of Oxime Functionality into Polyolefins via Iron-Catalyzed C–H Imidoylation 1.00
Enlightening the Depolymerization Kinetic Mechanism in Reversed Atom Transfer Radical Polymerization via In Silico Modeling 1.00
Streamlined Synthesis of Sequence-Defined Oligomers and In-Chain Multifunctionalized Polymers via Sequential Dual Monomer Insertion 1.00
Molecular Bottlebrushes with Programmable Grafting Densities 1.00
Initiator Activation and Active Chain End Stabilization Strategy via the Dual Hydrogen Bond for the Controlled Synthesis of Poly(fluorosiloxane) 1.00
Rapid Copper-Catalyzed Aqueous Polymerization of Cyclic Propargylic Carbonates 1.00
Green-Light-Driven PET-RAFT Polymerization Catalyzed by Pyrazino[2,3-f][1,10]phenanthroline Derivatives and Their Mediated Polymerization-Induced Self-Assembly 1.00
Bioinspired Dual-Stimulus-Responsive Macromolecular Engineering Enables Chemically Recyclable, High-Performance and Fire-Retardant Plastic 1.00
Organocatalytic Group Transfer Polymerization of α-Methylene-N-methylpyrrolidone: Controlled/Living Property Applied to the Synthesis of Gradient and Block Copolymers with Acrylamide and Methacrylate Polymers 0.71
Functional Nano-Objects Prepared via Living Anionic Polymerization-Induced Self-Assembly (LAPISA) of Polar Vinyl Monomers 1.00
Iron-Catalyzed C–H Amination of Polyethylenes 0.67
Crystallization Regulation Through Monomer Sequence Control in the Carbanionic Copolymerization-Induced Crystallization Method 1.00
1,4-Cyano Group Migration Involved Radical Cascade Polymerization 1.00
N-Sulfonyl Aziridine-Derived Trithiocarbonates: Functional RAFT Agents for the Synthesis of Architectural Polymers 1.00
Retrograde Depolymerization in Living Anionic Polymerization of α-Methylstyrene 1.00
Cationic Dithiocarbamate for Efficient Blue Light-Controlled Photoiniferter Polymerization 1.00
Synthesis of Compact Single-Chain Nanoparticles in Concentrated Solutions 1.00
Microfluidic Reactor for Studying Aqueous Phase Polymerization Events of Relevance to Emulsion Polymerization: Methyl Methacrylate 0.13
Simultaneous Click Coupling Reaction and Declick Cyclization Reaction in the Synthesis of Degradable Polymers 1.00
12 10.67
Bromine-Mediated Electrochemical Cascade Valorization of Styrene 1.00
Proton Concentration Tunes the Double-Layer Characteristics of Lead Catalysts to Boost the Electrosynthesis of Glyoxylic Acid 1.00
Biotic–Abiotic Hybrid System for Efficient Soluble Plastic Degradation 0.56
Discrete Patterned Functional Polymeric Nanostructures via Controlled Biaxial Iterative Synthesis 1.00
Nanoclay–Peptide Interfaces Mediate Prebiotic Chemical Evolution in the Origin of Life 1.00
Pressure-Driven Solid-State Radical Polymerization toward Carbon Nanothread 0.88
Molecular Stacking Patterns Enhance Organic Small-Molecule Electrochemical Stability and Enable Ion Separation 1.00
Bioinspired Flavin-Based Supramolecular Materials for Catalyzing Baeyer–Villiger Oxidation 1.00
Temperature-Insensitive Electron Transfer in Quantum Dot–Molecule Hybrids Driven by Nuclear Quantum Tunneling 1.00
Sub-Nano Copper Sites on SiO2 with Downshifted d-Band Centers Dominate Non-Radical Selective Oxidation of Benzene to Phenol 1.00
Electrocatalytic Upcycling of Plastic Waste to Organonitrogen Chemicals via Intercepting Carbon Intermediates 0.22
Gram-Scale Synthesis of an Ultrastable 38-Nuclei Copper(I) Alkynide Nanocluster for Unraveling Bifunctional Photocatalysis 1.00
12 8.89
Molecular skeleton programming of premediators in sulfur electrochemistry 1.00
Carbonyl swapping converts cyclic ketones to saturated heterocycles 1.00
Direct conversion from alkenes to alkynes 1.00
Alcohol group migration by proximity-enhanced H atom abstraction 0.05
Electrochemical defluorinative Matteson-type homologation 1.00
Controlling pyramidal nitrogen chirality by asymmetric organocatalysis 0.63
Direct deaminative functionalization with N-nitroamines 1.00
Photocatalytic oxygen-atom transmutation of oxetanes 0.25
Decoding the redox behaviour of copper in Ullmann-type coupling reactions 0.75
Stabilizing effect of amino acids on protein and colloidal dispersions 0.21
Synthesis of deuterated acids and bases using bipolar membranes 1.00
In-line NMR guided orthogonal transformation of real-life plastics 1.00
1 1.00
Self-splicing and cyclization mechanisms of the full-length Anabaena pre-tRNA 1.00
30 26.32
[2+2] Photocycloaddition reactions of sulfinylamines with alkenes to access β-sultam derivatives 1.00
Diverse radical C–F functionalizations of hexa- to difluoroarenes using boryl radicals as link-and-lose mediators 1.00
A system of paired polyether epoxide hydrolases enables a mouldable enzyme for consecutive ring cyclization cascades 0.06
Programmable divergent electrochemical ring-opening multifunctionalization of strained rings 1.00
Biocatalytic site- and stereoselective carbonyl desaturation for late-stage functionalization of cyclic ketones 0.67
Organocatalytic enantioselective synthesis of S(IV)-stereogenic sulfinamides enabled by an air-stable chiral phosphine 1.00
Mineral-to-molecule arsenic transfer via photoredox catalysis 0.75
Catalytic asymmetric sulfonimidoyl transfer to access chiral sulfonimidoyl fluorides and related derivatives 1.00
Thermal [2+2] cycloaddition as a route to -difluoro heterobicyclo[.1.1]alkanes 0.82
The catalytic enantioselective [1,2]-Wittig rearrangement cascade of allylic ethers 0.05
Direct enantioselective C(sp3)−H coupling of N-alkyl anilines via metallaphotoredox catalysis 1.00
Stepwise-controllable catalytic asymmetric Atherton–Todd reaction to access diverse P(V)-stereogenic compounds 1.00
Dearomative syn-1,4-hydroalkylation and C(sp2)−H alkylation of arenes controlled by chemoselective electrolysis 0.83
Stereodivergent construction of non-adjacent stereocentres via migratory functionalization of alkenes 1.00
Copper-catalysed asymmetric cross-coupling reactions tolerant of highly reactive radicals 1.00
Enantioconvergent radical addition of racemic alkyl halides to access vicinal stereocentres 1.00
Selective arylation of atypical C–F bonds in polyfluoroarenes with aryl chlorides 1.00
Leveraging electron donor–acceptor complexes for kinetic resolution in catalytic asymmetric photochemical synthesis 1.00
Divergent access to E- or Z-trisubstituted medium-sized cycloalkenes by Pd-catalysed cycloaddition 0.75
A two-metalloenzyme cascade constructs the azetidine-containing pharmacophore 1.00
Tunable cobalt-catalysed hydrogenation of allenes enabled by multiple metal–ligand cooperative functionalities 1.00
Bulk water redox chemistry enables radical-mediated C–C coupling in CO2 electroreduction 1.00
Diastereo- and enantioselective 1,3-hydrofunctionalization of trisubstituted alkenes by a directing relay 1.00
Diastereodivergent synthesis of multi-substituted cycloalkanes 1.00
Deaminative Giese-type reaction 1.00
Synthesis of highly strained -cyclophanes via ring-expansion [5,5]-sigmatropic rearrangement reaction 1.00
Adaptive dynamic kinetic resolution enables alteration of chiral induction with ring sizes 1.00
Synthesis of diverse terpenoid frameworks via enzyme-enabled abiotic scaffold hop 0.40
Modular alkyl growth in amines via the selective insertion of alkynes into C–C bonds 1.00
Interfacial assembly of biomimetic MOF-based porous membranes on coacervates to build complex protocells and prototissues 1.00
237 211.54
Mechanochemical Single-Carbon Insertion into (Iso)quinolines 1.00
Template-assisted [6+6] cycloaddition for the construction of photothermally responsive functional materials 1.00
Atomically dispersed iron on carbon nitride with enhanced oxygen adsorption for efficient and scalable photooxidation 1.00
Photocatalytic reductive carboxylation of unactivated hydrazones with CO2 1.00
Total syntheses of (+)-dalesconols A and B enabled by triple-relayed remote chirality transfer 1.00
Accelerating molecular dynamics simulations using fast Ewald summation with prolates 0.10
Bridged scaffold editing of carbocycles and heterocycles 0.88
Catalytic Markovnikov hydrophosphorylation of unactivated olefins via a radical-polar crossover rearrangement 1.00
Heterogeneous photocatalyst enables large-scale broadband light-driven atom transfer radical polymerization with high oxygen and inhibitor tolerance 1.00
Organocatalytic atom transfer radical polymerization with light and pH dual-gated regulation 1.00
Chiral hafnium phosphate catalyzed asymmetric de Mayo reaction via visible-light-induced dearomatization 1.00
Chemo-divergent and regioselective branched cross-hydroalkenylation of electron-deficient olefins and vinylarenes directed by (NHC)Ni(II) catalysts 1.00
Construction of boron-stereogenic BODIPYs through organo-catalyzed enantioselective formal C(sp2)–O/O–H metathesis 1.00
Single-iron catalyst with heterogenized TEMPO for selective toluene electrooxidation to benzaldehyde at low potentials 1.00
Coordination orientation isomerism boosting concerted hydrogen peroxide photosynthesis 0.86
Electrosynthesis of 1,3-butadiene from dilute acetylene over coordination-modulated dicopper molecular catalysts 1.00
Pulsed electrosynthesis orthogonally optimizes C‒N coupling and hydrogenation for amine production with a molecular catalyst 0.06
Chiral Brønsted acid-catalyzed kinetic resolution of radical additions 1.00
Synergistic Fe/Ni catalysis for electrochemical 1,1-difunctionalization of alkenes 1.00
A membrane-modulated chemoenzymatic dynamic kinetic resolution for the synthesis of chiral phthalidyl esters 1.00
Unveiling a flip-over retention mechanism in the gas-phase Cl− + (CH3)3CI SN2 reaction 0.44
Decorating titania with ultrasmall UiO-66-H crystallites enables quantitative photocatalytic oxidation of methane to oxygenates 0.18
Mechanochemically functionalized waste plastics for NO sensing 1.00
Merging photocatalysis with C-H insertions enabled switchable synthesis of indoles and indolines 1.00
Electrostatic-confinement-induced regioselective C-H functionalization of polyolefins 1.00
Sn catalyst reconstruction and microenvironment modulation for efficient amino acid electrosynthesis via C–N coupling 0.57
Kinetics-controlled radical coupling on dual redox-active sites for selective formamide production 1.00
Redox-mediated domino electrosynthesis of -dimethylformamide with industrial-relevant productivity and modularized cathodic integration 1.00
Piezocatalytic reforming of plastics into high-value chemicals 1.00
Kinetic resolution of amino acids by phosphine oxide catalyzed enantioselective esterification 1.00
Room-temperature electrochemical hydroxyalkylation of pyridines 0.75
Repurposing trifluoromethyl copper (III) complexes for difluoromethylation of saccharides and complex alcohols 0.94
Skeletal editing of tetrahydrofurans to pyrrolidines through O-to-N single atom swap 1.00
Sustainable recycling of polyester wastes using a coordinatively unsaturated Zn catalyst 0.90
Gallium in liquid state shows nuclease-mimicking activity 0.10
Enantioselective Synthesis of 2-Oxabicyclo[2.1.1]hexanes and Bicyclo[2.1.1]hexanes via Catalytic Asymmetric Intramolecular Photocycloadditions 1.00
Photochemical synthesis of oxiranes using DABSO-activated sulfinates and allylic peroxides 1.00
Differentiating interfacial water structures via alkali metal cation promotor for HO electrosynthesis in acid 1.00
Bioinspired total synthesis of (+)-pleuromutilin 1.00
Disulfide modification and thiol protection via tris(trimethylsilyl)silane-mediated hydrosilylation of disulfides 1.00
Pillar[]arene-catalyzed anti-Markovnikov halogenations through cationic intermediates stabilization in confined spaces 0.60
Hydrogen transfer-triggered C(sp3)−C(sp3) cleavage of 1,3-diols for mono-N-methylation of primary amines 1.00
Metal-dependent and metal-free mechanisms of peptide condensate catalysts 0.43
Unlocking the reactivity of difluoroketene and its synthetic applications 1.00
Photoinduced Mn catalysis for efficient platform for C-heteroatom bond coupling of aryl halides 1.00
Electrochemical tyrosine-click bioconjugation enables multiplexed cytokine sensing and immunoprofiling in native serum 1.00
Concise synthesis of bufogargarizin B by a conformation-controlled skeletal reorganization approach 1.00
Large-scale multi-omics profiling reveals environmental and evolutionary drivers of fungal phylogeographic and metabolic diversity 0.57
Paired electrolysis enables para-C–H amination of phenols with nitroarenes and mechanistic visualization via multifunctional electrochemical mass spectrometry 1.00
Unlocking the reducing power of metal nitrides by mechanochemical hydrodefluorination of fluorinated compounds 1.00
Electrochemically mediated disproportionation for selective formaldehyde upcycling in acid 0.80
Ynimines as versatile precursors to 2-imido- and 2-amido-1,3-dienes for stereodivergent diels–alder reactions 0.17
Coenzyme-functionalized photo-redox catalysis for low-energy click labeling 1.00
Chlorine radical-mediated electrochemical propylene epoxidation from seawater 1.00
Molecular mechanism underlying regulation of chalcone synthase by chalcone isomerase-like protein 1.00
Insights into the activation patterns of 1,2-dithiolane unit in biofunctional molecules 1.00
Discovery and engineering of bacterial P450s for C-14 hydroxylation in ent-kaurane diterpenoids 1.00
Carbonylolysis of waste polyesters into high-value organic acids 1.00
Stereodivergent synthesis of chiral amines bearing vicinal stereocenters via hydroamination of trisubstituted alkenes 1.00
Chemodivergent Coupling of 1,3-Enynes with Anilines to Access Dihydropyrrole Skeleton under Palladium Catalysis 1.00
Stereoselective depolymerization of chiral polyesters 1.00
Upcycling of atmospheric CO2 to self-healing recyclable polymers under ambient conditions 1.00
Topology-controlled dynamic conjugated oligomers from tetra-arylsubstituted alkene building blocks 1.00
Asymmetric synthesis of Heteroatom-bridged [3.2.1]Octane scaffolds via enantioselective β-H elimination reaction 1.00
Crystallization-driven template autocatalysis induces mirror symmetry breaking and amplification 1.00
Ketone displacement and migration enabled by trifunctionalization of vinyl triflates 1.00
Copper-catalysed dynamic kinetic (4+1) cyclization of 1,3-enynes for atroposelective arylpyrrole synthesis 1.00
Space ionizing radiation triggers the formation of peptides and organophosphates on olivine surfaces 1.00
Ligand-enabled next-generation glycosyl Stille cross-coupling for the stereospecific synthesis of sterically hindered aryl -glycosides 0.88
Guest-induced porous gating of a fluorescent nonporous adaptive crystal for efficient radioactive iodine sorption 1.00
COMPASS subunit Bre2 regulates chromatin remodeler Arp9 to control Aspergillus flavus aflatoxin synthesis and virulence 1.00
Tuning aromatic cage occupancy in prenyltransferases enables selective and efficient production of rare -prenylated flavonoids 1.00
Electrocatalytic C(sp)-H bond functionalization using biomass-derived electrodes 0.80
Asymmetric biomimetic transamination of α-keto phosphonates enabled by chiral pyridoxamines and synergistic solvent 1.00
Mechanistic insights into the non-equilibrium thermodynamics of nitrogen fixation via acoustic cavitation 0.13
Acid-base pair-mediated copolymerization of acid-sensitive epoxides and cyclic anhydride for synthesizing recyclable thermoplastics 1.00
Radical defluoroallylation of polyfluoroalkyl compounds with alkenes via synergistic photoredox/cobalt catalysis 1.00
Reactive oxygen species-activated bioorthogonal chemistry in living systems enabled by boronate-caged dihydrotetrazines 1.00
Chemoenzymatic synthesis of pentalenolactones via stereoselective Riley oxidation by engineered P450 0.80
Photoinduced polarity-mismatched transformations of isoquinolines into naphthalenes 1.00
Ultrafast solvent-modulated roaming mechanism in bromoform revealed by femtosecond X-ray solution scattering 0.37
Trifunctional flavoenzyme-catalyzed asymmetric 4-alkyl-butenolide assembly in avenolide biosynthesis 0.90
Metallic molybdenum sulfide catalyses protometabolic carbon dioxide reaction networks under extreme conditions 0.80
Abyssal hydrothermal alteration drives the evolution from simple alkanes to prebiotic molecular complexity 1.00
An isolable phosphaalumene(3) capable of small molecule via 1.00
Solution-synthesized stable triaza[4]triangulene triradical with a quartet ground state 1.00
Recycling of polyolefins using recycled PVC under sunlight 1.00
Coacervate droplets as pH-regionalized protocells 1.00
Enhanced methane chlorination via RuO-gas convection electrode with in-situ generated dynamical three-phase boundaries 1.00
Engineered alcohol oxidases catalyse transesterification in aqueous media without competing hydrolysis 0.41
Stereoselective cyano translocation reaction enabled by photoenzymatic catalysis 1.00
Divergent photochemical ring-replacement of isoxazoles 0.08
Copper-catalysed enantioconvergent -alkylation of hydrazines with racemic α-haloamides to access enantioenriched hydrazines 1.00
Unlocking enzymatic deracemization of structurally diverse allenes by designed photoenzymes 1.00
Photo-induced selective N-N bond construction via harnessing nitrene release and transfer 1.00
Evolution of manganese low-energy photoredox catalysis from high-energy visible light photocatalysis 1.00
Atroposelective interrupted CuAAC reaction using cyclic diaryliodoniums 1.00
Managing electrolyte flow boosts the efficiency of continuous oxime electrosynthesis to over 95% 1.00
Harnessing P-oxirene for the modular synthesis of α-Oxy carbonyls 1.00
Glycine photosynthesis via C−N coupling of waste plastic and nitrate over diatomic Pd−B catalyst 1.00
Nickel-catalyzed divergent sulfonations of propargylic carbonate 1.00
Ligand-controlled regiodivergent and enantioselective C–H cyanation of secondary amines 1.00
Spatiotemporally controlled drug release via a click-release system utilizing mono-alkyl-hydroxylamine and cyclooctyne chemistry 1.00
An artificial cell capable of signal transduction mediated by ADRB2 for the regulation of glycogenolysis 1.00
Manganese catalyzed oximation of hydrocarbons to oximes 0.82
Efficient synthesis of chiral vicinal diamines with four contiguous stereocenters via sequential dynamic kinetic resolution of 2,3-diamino-1,4-diketones 1.00
Photo-driven bifunctional iron-catalyzed one-pot assembling of indoles from arylamines and alkanes/carboxylic acids 1.00
Tetrachloromethane as an editable all-carbon quaternary source 1.00
Formal anti-Markovnikov hydration of alkenes via paired electrolysis intercepting water-splitting 1.00
Mechanochemical upcycling of poly (vinyl chloride) for alcohol halogenation 1.00
Coupling nitrate electrochemical reduction and nitrite oxidation of ethanol for acetamide synthesis 0.22
Photochromism of pyridine-substituted merocyanine through reversible C-N bond formation 1.00
Steric and hydrophilic/hydrophobic effects of organic cations on electrochemical CO reduction 1.00
Photoenzymatic catalysis enables enantioselective radical dearomative spirocyclization 1.00
Unveiling mechanistic patterns of copper-catalyzed radical bond formation through linear free energy relationship 1.00
Late-stage adenine N6-alkylation of nucleos(t)ides and oligonucleotides via photoredox and copper co-catalytic decarboxylative C(sp3)–N coupling 1.00
Oxyanions stabilized low-coordinated nickel species for efficient and durable nucleophilic electrooxidation 1.00
Enantioselective dearomative single-atom skeletal editing of benzofurans 1.00
Reconstituting transcription–translation-coupled DNA replication within complex in vitro biological systems 1.00
Divergent synthesis of Haplomitrium diterpenoids via a late-stage biomimetic skeletal reorganization approach 1.00
Catalytic asymmetric tandem Heck/Sonogashira reaction enabling access to versatile chiral bridged ring scaffolds 1.00
Photoredox-controlled alternating copolymerization enables highly crystalline structures and block copolymers from thermoplastic to elastomer 1.00
Copper-catalyzed atroposelective hydroarylation of 1-alkynylindoles 1.00
Engineering microbial consortia for mixed plastic upcycling 0.10
Vinyloxy radicals unveiled as critical intermediates in Ni/La2O3-catalyzed ethanol steam reforming for hydrogen production 1.00
Concise synthesis of chiral tricyclic γ-lactams via synergistic isothiourea/Ir catalyzed asymmetric [3 + 2] annulation 1.00
Direct deoxygenative arylation of saccharides via phosphorus-assisted C−OH bond activation 0.33
Iridium catalyzed regiodivergent functionalization of all three C–H bonds of arenes by a single ligand 0.33
Iron-catalyzed three-component amino(radio)fluorination of alkenes to unprotected β-(radio)fluoroamines 0.64
Chiral hypervalent iodine catalyzed stereoselective skeletal editing of pyrimidine fused heterocycles 1.00
Isolated Ni atoms enable alkali-free photoreforming of waste polylactic acid plastic 0.08
Confirmation-dependent organic phosphor reveals amino acid nanoaggregates in ice with insight for prebiotic chemistry 1.00
Straightforward construction of functionalized γ-lactams via conjugated-engineered covalent organic framework photocatalysed cascade reactions 0.67
Dual transition metal electrocatalysis for difluoromethylation of Aryl halides using potassium difluoroacetate 1.00
Installation of d3-methyl group to drugs by continuous-flow solid-phase synthesis 1.00
Abiotic N reduction in submarine hydrothermal systems could quickly fertilize prebiotic oceans 0.50
Asymmetric formal [1 + 2 + 2]-cycloaddition of diazoamides with enamines and carbonyl compounds 1.00
Catalytic photoinduced deoxygenation via B(C6F5)3-enabled oxygen atom transfer for aromatic C–H amination of alkylarenes 1.00
Direct asymmetric α C(sp3)‒H alkylation of benzylamines with MBH acetates enabled by bifunctional pyridoxal catalysts 1.00
Light-driven radical copper-catalyzed allylic amination via allylic copper intermediates 0.90
Enzymatically reconfigurable liquid crystalline coacervate microdroplets as protocell models 1.00
Rapid amide ligation between α-halo acylsilanes and amines under aqueous conditions 1.00
A virtual platform for automated hybrid organic-enzymatic synthesis planning 1.00
A DMAP-enabled strategy for C(sp2)-Si coupling of halosilanes with organic halides 1.00
Regioselective and site-divergent synthesis of tetrahydropyridines by controlled reductive-oxidative dearomative hydroarylation of pyridinium salts 1.00
Organocatalytic iminium-assisted asymmetric B(sp²)-to-B(sp³) transformation 0.80
Biocompatible decarboxylative coupling enabled by N-hydroxynaphthalimide esters 1.00
Surfactant-enhanced Cuδ+ and induced electrostatic forces promote the electrocatalytic deuteron-dechlorination of trichloroacetic acid 1.00
Homogeneous silver catalyst for propylene electrooxidation to propylene glycol 1.00
Nickel-catalyzed highly diastereo- and enantioselective hydroaminocarbonylation and hydrocarboxylation of cyclopropenes 1.00
Photocatalytic generation of amidine carbon radicals for aminodihydroquinoline synthesis 1.00
Palladium-catalyzed enantioselective dienylation of propargylic carbonates via sulfonimidamide desymmetrization 1.00
Scalable reductive deuteration of (Hetero)Aryl chlorides with D2O 0.83
Iron/phosphine-catalyzed reductive cross-coupling to construct quaternary carbon centers 1.00
A catalyst-free bioorthogonal reaction for malononitrile addition to azodicarboxylates 1.00
Rhodium-catalyzed construction of boron-based point and axial chirality via asymmetric annulation of alkynylborons 1.00
Chiral macrocycles forming high-affinity host-guest homoternary complexes for chiral discrimination and amplified circularly polarized luminescence 1.00
Copper integrative catalytic pairs with mixed-valence Cu-Cu Species for selective alkyne conversion 0.86
Electro-induced C-H/S-H cross-coupling for the functionalization/macrocyclization of cysteine-containing peptides 1.00
Catalytic asymmetric synthesis of (N, N)- spiroketal via Pd-catalyzed enantioconvergent aminocarbonylation and dearomative nucleophilic aza-addition 1.00
Dynamic radical recombination enabling stereodivergent construction of spirocycles with nonadjacent stereocenters 0.92
Photochemical rearrangement of isonitriles via energy transfer catalysis 0.80
Copper-catalyzed enantioselective synthesis of γ-butenolides via radical diversification of allenoic acid 1.00
Photocatalytic non-oxidative dehydrogenation of ethane to ethene with near unit selectivity 1.00
A planar chiral organoselenium enabled enantioselective intramolecular oxidation of trisubstituted olefins 1.00
Overcoming limitations in Chan-Lam amination with alkylboronic esters via aminyl radical substitution 1.00
Photocatalytic streamlined dual-functional group transfer from cyanopyridine to internal alkynes 0.55
Stereoselective diversification of α-amino acids enabled by N-heterocyclic carbene catalysis 1.00
Accessing acyclic vicinal tetrasubstituted stereocenters via biomimetic Cu/squaramide cooperative catalysed asymmetric Mannich reactions 1.00
Harnessing platinum(IV) prodrugs as versatile photoinitiators and photocrosslinkers for multifunctional hydrogels and protein labeling 1.00
Dinickel-catalyzed enantioselective reductive addition of imines with vinyl halides 1.00
Sustainable recycling of polyamides via C–N bond cleavage facilitated by methyl tosylate under mild conditions 1.00
Direct and efficient synthesis of nucleosides through the ortho-(tert-butylethynyl)phenyl thioglycosides (BEPTs) protocol 1.00
Regulation of lattice oxygen reactivity of ZrO2 to promote efficient chemical looping oxidative dehydrogenation of ethane 0.10
Fe-electrocatalytic deoxygenative Giese reaction 0.75
Metal-free para-selective C-H amination and azidation of N-arylhydroxylamines 1.00
Enantioselective intramolecular cyclopropanation via a cationic sulfoxonium-Rh-carbene 1.00
Modular synthesis of PAHs from aryl halides and terminal alkynes via photoinduced palladium catalysis 1.00
Constructing an auto triplet excitons supply system for photogenerated radicals in the solid state 1.00
Bioinspired transfer methylation enabled by a photoactive reagent 0.78
Salt-templated transformation of waste plastics into single-atom catalysts for environmental and energy applications 0.04
Catalytic aromatic C−H borylation via strained Si and Ge metallacycles 1.00
Modular multi-enzyme cascades enable green and sustainable synthesis of non-canonical amino acids from glycerol 0.88
Dehydroxy-Perfluoro--butylation of alcohols with PhSOC(CF) and insights into the structure of the [C(CF)] anion 1.00
Harnessing artificial intelligence to identify Bufalin as a molecular glue degrader of estrogen receptor alpha 1.00
Gymnosperm-specific CYP90Js enable biflavonoid biosynthesis and microbial production of amentoflavone 1.00
Internally hollow CuO nanoframes with the abundance of {110} facets enhance direct propylene epoxidation 1.00
Near-infrared photon-triggered CH-to-CHOH conversion over plasmonic oxyselenides 0.97
Photoredox catalytic asymmetric dearomative [3 + 2] cycloaddition of isoquinolines with enones 1.00
A general esterolysis strategy for upcycling waste polyesters into high-value esters 1.00
Catalyst-free Ullmann coupling in aqueous microdroplets 1.00
Highly selective synthesis of interlocked carbazole-based cages and their applications in photothermal seawater desalination 1.00
Development of a versatile chassis for the efficient production of diverse type II polyketides 1.00
Cyano group translocation to alkenyl C(sp)–H site by radical cation catalysis 1.00
Switchable electrochemical pathways for the selective C(sp)-Ge bond formation 0.40
Asymmetric synthesis of -amino acid derivatives by stereocontrolled C(sp)-C(sp) cross-electrophile coupling via radical 1,2-nitrogen migration 1.00
Skeletal editing of pyridines to aryldialdehydes 1.00
Electroreductive amination of carboxylic acids by cobalt catalysis 1.00
Skeletal editing of 4-arylpyrimidines into diverse nitrogen heteroaromatics via four-atom synthons 1.00
Catalytic synthesis of chiral sulfinimidate esters via oxidative esterification of sulfenamides 1.00
Coordinatively unsaturated bismuth sites accelerate in-situ hydrogen peroxide electrochemical formation for efficient butanone oxime synthesis 0.92
A SaBOX/Co catalyst designed for facile access to the challenging copolymers of vinyl ester and methacrylate 1.00
Cationic alkyl chain length and nanoaggregate form of ionic liquids dominate biocompatibility and toxicity 1.00
Late-stage -sulfation with a bioinspired sulfuryl donor 1.00
Electrochemical coupling of carbon monoxide and amine on iodide coordination stabilized Cu site 1.00
Enantioselective synthesis of chiral 2,3--disubstituted piperidines and C1-substituted tetrahydroisoquinolines by asymmetric Cu-catalyzed cyclizative aminoboration 1.00
Dispersity-controlled ring-opening polymerization of epoxide 1.00
Photocatalyst-free photochemical deuteration via H/D exchange with D2O 0.90
Precise control of selective nitrogen atom insertion into five-membered cyclic β-ketoesters 1.00
Cobalt catalyst with exclusive metal-centered chirality for asymmetric photocatalysis 0.06
Multi-component reactions via copper(I) difluorocarbene as carbonyl source for constructing α—aminoamide derivatives 1.00
Atroposelective construction of axially chiral alkenylindole-fused nine-membered rings via catalytic asymmetric formal (4 + 5) cycloaddition 1.00
A zinc boryl compound unlocks diverse reactivity pathways beyond nucleophilic borylation 1.00
Organocatalytic asymmetric synthesis of Tröger’s bases 1.00
Organocatalytic kinetic resolution of sulfinamides by N/O exchange 1.00
Amines tuned controllable carbonylation for the synthesis of -lactones and 1,4-diones 0.88
Electro-oxidative amination of benzylic C(sp³)–C(sp³) bonds in aromatic hydrocarbons 1.00
LMCT-driven electron relay unlocks alcohols as tunable reductants for nickel-catalyzed cross-electrophilic couplings 1.00
Chemoselective synthesis of 1,3,4-thiadiazoles from acyl hydrazines and nitroalkanes using elemental sulfur 0.86
Hydroxyl and nitrate co-upgrading to oxime via anode-cathode cascade electrolyzer 0.33
SPA-PNN ligand for the kinetic resolution of carbocyclic and heterocyclic spiranes by asymmetric hydrogenation 1.00
Waste polystyrene upcycling via the Birch reduction with ball-mill grinding 0.17
Highly efficient catalytic propane dehydrogenation driven by MFI zeolite defect sites 0.58
Organometallic-type reactivity of stable organoboronates for selective (hetero)arene C−H/C-halogen borylation and beyond 1.00
-alkylated polydithiocarbamates derived from thiocarbonyl fluoride as macro-photoiniferters for living 3D printing 1.00
Enantioselective aza-electrophilic dearomatization of naphthalene derivatives 1.00
Catalytic asymmetric intermolecular [4 + 2] annulation of benzocyclobutenones with Alkynes and activated carbonyls via C—C activation 1.00
Syngas from waste plastics and water using Joule heating 1.00
Pathway-divergent coupling of alkynes and cyclobutenes through enantioselective cobalt catalysis 1.00
Stereodivergent synthesis of benzylic alcohol derivatives enabled by Pd/Cu co-catalyzed asymmetric benzylic substitution reaction 1.00
Photoenzymatic enantioselective synthesis of fluorinated amides with remote stereocenter 1.00
symmetric chiral ligand dictating allyl-allyl coupling 1.00
Tailored amination enables switchable synthesis of α- and γ-amino acid derivatives from extended quinone methides 1.00
Chemoselective dual functionalization of proteins via 1,6-addition of thiols to trifunctional -alkylpyridinium 0.06
Substrate-based discovery of α-hydroxycarboxylic acid derivatives as potential herbicides targeting dihydroxyacid dehydratase 1.00
Consecutive mechanical-force-induced electron transfer for reduction of aryl halides with high reduction potentials 1.00
Copper-catalyzed C(sp3)−H amination and etherification of unactivated hydrocarbons via photoelectrochemical pathway 1.00
1 0.79
Supramolecular chemical recycling of dynamic polymers 0.79
4 4.00
Low-temperature polyethylene terephthalate upcycling by phenolic ionic liquids 1.00
Catalytic bromine recycling from waste 1.00
Catalytic cascade depolymerization for sustainable recycling of waste polyvinyl chloride 1.00
Efficient glycerol electro-oxidation at an industrial-level current density 1.00
1201 1171.06
Nickel-Catalyzed Enantioselective Hydroboration of Enamides 1.00
Copper-Catalyzed Functionalization of C(sp2)–H Bonds with Vinyl Cations: Synthesis of Polycyclic Pyrroles 0.71
Synthesis of Fully Substituted Alkynyl N,N′-Bicyclic Pyrazolidinones via a Cu(I)-Catalyzed Interrupted CuAIAC/Alkynylation Cascade Reaction 1.00
Neutral Aqueous, Visible-Light-Accelerated Rh(III)-Catalyzed C–H Bond Activation/Cyclization Applicable to Peptide Modification 1.00
Enantioselective Construction of Cyclopentene Spiroindene Scaffolds via Phosphine-Catalyzed Annulation of Benzofulvene with MBH Carbonates 1.00
Nitrogen-Doped 5–7–7 Ring-Fused Hexa-peri-hexabenzocoronene: A Saddle-Planar Hybrid Nanographene for Fullerene Recognition 1.00
Nickel-Catalyzed Asymmetric Reductive Allenylation of Aldehydes with Propargyl Carbonates 1.00
Synthesis of 1,2,4-Triazole Derivatives Via Three-Component Tandem Cyclization Reactions Based on N–N Bond Formation 1.00
Microdroplets Co-catalyze Nitro Hydrogenation in Organic and Pharmaceutical Application 1.00
Fluoride-Initiated Annulation of Alkynoates and Trifluoromethyl Alkenes 1.00
A Mild and DNA-Compatible Cyclization Strategy for the Construction of [1,2,4]Triazolo[1,5‑a]pyridine Scaffolds 1.00
Aryne Relay-Triggered Three-Component Cascade via In Situo‑QDM Generation: Synthesis of N,O-Spiroheterocycles and Benzo[f]isoindole-1,3(2H)‑diones 1.00
Amide-Based Polyene Cyclization: Stereoselective Construction of cis- or trans-Octahydrobenzo[f]isoquinolines 1.00
Palladium-Catalyzed Hiyama Cross-Coupling of Aryl Fluorosulfates 1.00
Asymmetric Semisynthesis of Ovatodiolide 1.00
Enantioselective Synthesis of Indole-Derived Atropisomers through Rh(I)-Catalyzed C–H Arylation with Aryl Bromides 1.00
Collective Total Synthesis of Isocoumarin Natural Products via Copper-Catalyzed Annulations of Diaryliodonium Salts 1.00
2‑(2-Pyridyl)ethyl (Pet): An Electroresponsive Protecting Group for O/N Functionalities 1.00
Divergent Site-Selective Coupling of Benzothiophenes via a Dearomative Halogenation Platform 1.00
Regiodivergent 1,3-Annulation of Valylene with 4‑Hydroxycoumarins 1.00
Enantioselective Synthesis of Chiral Dihydroisobenzofurans via Tandem Asymmetric Hydrogenation and Selective Oxo-cyclization 1.00
Catalyst-Controlled Asymmetric Chemodivergent Reaction of C,N-Cyclic Azomethine Imines with 2‑Indolylacetates 1.00
Diaryl-Pyrazole Phosphine Ligand Design Enables Palladium-Catalyzed Denitrative C–H Arylation of N‑Fused Azaheterocycles with Nitroarenes 1.00
Mechanochemical Rhodium(I)-Catalyzed C–H Functionalization of Indoles via Decarbonylative N–C(O) Bond Activation of Amides 0.86
Stereoselective Diazenylation of β,β-Disubstituted Enesulfinamides with Aryldiazonium Cations 1.00
Photoinduced Defluorinative Alkylamination of Alkenes with Trifluoromethylated Arenes and Anilines 1.00
Rh-Catalyzed Denitrogenative Formal (3 + 2) Cycloaddition for the Synthesis of Remote Chiral C–N and N–N Atropisomers 1.00
Light-Enabled C–F Bond Functionalization of α‑Trifluoromethyl Alkenes toward gem-Difluoroallyl Organogermanium Herbicides 1.00
Copper-Catalyzed Remote Asymmetric Three-Component Sulfonylation Using SO2 as the Sulfur Source to Access Chiral Allylic Sulfones 1.00
Csp3–H Bond Carbynoid Functionalization by Photoredox Catalysis 1.00
Asymmetric Synthesis of Fluorinated Quaternary Stereogenic Centers Enabled by a Bispyrrolidine-Diboronate-Catalyzed exo-Selective Diels–Alder Reaction 1.00
Tyrosine-Selective Polyfluoroaryl Modification Enables Bioactive Peptides with Enhanced Membrane Permeability and Ligation Capability 1.00
Transient Directing Group-Enabled Palladium-Catalyzed Axially Chiral C–H Alkynylation 1.00
Enantioselective Addition of Thiols to Pyrazolone Ketimines by Cinchona Alkaloid-Derived C‑2′ Amino Organocatalyst 1.00
Skeletal Editing of Isoquinolines Via CN/CC Atom-Pair Swap Enables the Synthesis of 3‑Arylthio-2-O-acylated Naphthols and DFT Studies 1.00
Solvent-Regulated Enantiodivergent Construction of Secondary Phosphine Oxides with P‑Stereogenicity 1.00
Visible-Light-Induced Dual Iron/Eosin Y Catalysis for Direct Dehydrogenation of Saturated Heterocycles, Alcohols, Esters and Amides 1.00
Construction of β‑Heteroarylated Aliphatic Aldehydes via Pd-Catalyzed and Ag-Mediated Redox-Relay Oxidative Heck Reactions 1.00
Cu-Catalyzed Selective 1,5-Hydrophosphoro(di)thiolation of Vinyl Cyclopropanes 1.00
Carbene-Catalyzed Enantioselective Atherton-Todd Reaction for Kinetic Resolution of 1,1’-Biaryl-2,2’-diols and Derivatives 1.00
gem-Difluoroallylation of Unactivated Alkanes Enabled by Core-Fluorinated Acridine d‑HAT Catalysis 1.00
Nitrogen-Atom Insertion of Indolyl Phosphonium Salts through C–P and C–C Bond Functionalization 1.00
Pd/NBE Cocatalyzed Modular Synthesis of 3‑Alkenyl-2,3′-bisindoles and Applications in Access to Racemosin B 1.00
Palladium-Catalyzed (Asymmetric) B(9)-Alkylation of o/m-Carboranes with α‑Aryl-α-diazoesters 1.00
meta-Sulfonylation of Pyridines from Sulfur Dioxide with Dearomatized Pyridines as Redox-Active Substrates 1.00
Organophotocatalytic Radical Chloro-fluorosulfonylation of Alkynyl Cyclohexadienones 1.00
3D Probe-Based Chemoproteomic Profiling Enables the Discovery of a Polyphenol Oxidase Catalyzing Oxidative Lactonization of Salvianolic Acid B 1.00
Iodine-Mediated Multicomponent Deaminative Cyclization for Direct Transformation of Inert Amides into Aromatic Lactones 1.00
Copper-Mediated Bis(trifluoromethyl)carbinolation of Arylboronic Acids Enabled by Iodobis(trifluoromethyl)carbinol Ester 1.00
Diverse Transformations Involving Sulfamoyl Fluorides (RNHSO2F) as Fluorosulfonamide Radical Precursors 1.00
Photoexcited Intramolecular Annulative Cross-Coupling via an EDA Complex Mechanism 1.00
Copper(II)-Catalyzed ortho-Selective C–H Allylation of Tertiary Anilines with Unprotected Allyl Alcohols 1.00
Electrochemical Synthesis of Selenated Isochromene-1-carbonitriles via the Cyanation and Selenocyclization of 2‑Ethynylbenzaldehydes 1.00
Chemoselective Azidation of Cysteine Coupled with Traceless Staudinger Ligation Enables Site-Specific Acylation of Recombinant Proteins 1.00
Assembly of Chiral Helical Quinones via Enantioselective Organocatalytic [4+2] Annulation 1.00
Enantioselective Total Synthesis of Verrucosamide 1.00
Photochemical Redox Buffering in Copper-Catalyzed Benzylic C–H Phosphatation 1.00
Ynamide-Mediated Ketone Synthesis 1.00
Cobalt-Catalyzed Reductive Carboxylation of Aldehydes/Ketones for the Synthesis of α‑Arylalkanoic Acids 1.00
Mg-Catalyzed Nucleophilic Cage B–H Amination of o‑Carborane 1.00
Asymmetric Sulfa-Michael/Mannich Cascade Reaction of β,γ-Unsaturated α‑Keto Esters for the Construction of γ‑Mercapto-γ-amino-α-keto Esters Bearing Multiple Chiral Centers 1.00
Heterogeneous Photocatalytic Carbonylation of Iodoalkanes Using Mesoporous Graphitic Carbon Nitride 1.00
Ni-Catalyzed Cross-Coupling Reaction of Aryl Halides with O‑Alkyl-Substituted Hydroxylamines to Obtain Aniline Derivatives 1.00
Diastereo- and Enantioselective Synthesis of Hexa-1,5-diene-3,4-diamines by Cobalt-Catalyzed Asymmetric Double Allylic Amination 1.00
Palladium-Catalyzed Cross-Electrophile Couplings of Aryl Thianthrenium Salts with Alkyl Bromides and Chlorides 1.00
How Silver Additives Promote Copper-Catalyzed Cyclization and Alkene Transposition: A Mechanistic Study 1.00
Copper-Catalyzed Regioselective [4 + 1 + 1] Annulation to 1,2-Oxazines Using Dioxazolones and H2O as the Heteroatom Sources 1.00
Palladium-Catalyzed Domino Reaction of 2‑Alkynylanilines with 2‑EthynylaziridinesAccess to Indole and Carbazole Derivatives 1.00
Photocatalytic Regioselective Alkylation of 4‑Alkenylpyridines via Delocalized Pyridinyl Radicals 1.00
Chiral Phosphine Oxide-Catalyzed Enantioselective Transannular Bromoaminocyclization for the Synthesis of Tropanes 1.00
Catalyst-Free Photoinduced ortho C–H Heteroarylation of Phenols 0.83
Ligand-Controlled Regioselective Deuteration of Indoles: Anti-C3 Selectivity and Mechanistic Insights 1.00
X‑Type Silyl Ligand-Controlled Regiodivergent C–H Borylation of Isoquinolines 1.00
Nucleophiles as Reaction Switches: Dearomative Multifunctionalization of Isoquinoliniums to Rigid Bridged-Ring Architectures 1.00
Synthesis of Aggregation-Induced Emission (AIE)-Tetraarylpyrazines via Ni(II)-Catalyzed Dimerization of 2,3-Diaryl‑2H‑Azirines 1.00
Photoinduced Synthesis of γ‑Amino Alcohols via [2,3]-Acyloxy Migration 1.00
Phosphine-Catalyzed [3+3] Annulation of Electron-Deficient Enyne-Type Propargylic Carbonates with α‑Cyano Ketones 1.00
Theoretical Study and Rational Design of Noncovalent Interactions Enable Organocatalytic Divergent [2+2] and [4+2] Annulations 1.00
Divergent Synthesis of Thioethers and Thioesters from Arenes and Carboxylic Acids 1.00
Benzoxazine-Promoted Copper Catalyst for the Activation of the Benzylic C–O Bond: A Homolytic Cleavage without Light 1.00
Synthesis of Vinyl Sulfoxides and Subsequent Construction of C,S Contiguous Stereocenters Via Thia-Stevens Rearrangement of IIII/SVI-Hybrid Ylides 1.00
Electrochemically Driven, pKa‑Controlled Regioselective Selenocyclization: Synthesis of Isocoumarin-1-imines with Structural Validation 1.00
Friedel–Crafts Reaction of Arenes by Oxidatively Generated Metal Carbene: Divergent Synthesis of Polycyclic Aromatic Hydrocarbons via Controllable Cyclization of Ynones 1.00
Visible-Light-Induced NaI-Catalyzed α‑C–H Sulfenylation Enables the Synthesis of o‑Sulfanylarylamines 1.00
Mechanoredox Enables Sulfonylation of Alkenes in a Heterogeneous System 1.00
Selective Construction of 1,1-Disubstituted Cyclopropyl Ketones, 2‑Arylacetophenones, and 2‑Aryl-3,4-dihydronaphthalen-1(2H)‑ones via Palladium-Catalyzed Cross-Coupling of Cyclopropyl Aryl Ketones with Aryl Bromides 1.00
Strain-Release-Driven Ring Opening of 3‑Alkylideneazetidines To Access β‑Halomethyl Allylamines 1.00
Direct Deaminative C(sp3)–N Cross-Coupling via Copper Catalysis 1.00
Palladium-Catalyzed Direct Dehydroxylative Cross-Electrophile Couplings of Unactivated Carboxylic Acids with Aryl Bromides for Accessing Ketones 1.00
Molecular Editing of Bilobalide: Regioselective C-Ring Lactam Formation 1.00
Photocatalytic C(sp2)–O Bond Cleavage and Dearomatization of Anisoles toward Epoxyquinols/para-Quinols 1.00
Photoinduced Sulfur Hexafluoride-Promoted Site-Selective Phosphonylation of Amino Acids and Peptide Derivatives 1.00
Copper-Catalyzed Cascade Cross-Coupling/Cyclization of Silyl Enol Ethers for Synthesis of Polysubstituted Furans 0.67
Synthesis of Spironitrodihydroacridines via Formal [5 + 1] Spiroannulation and Nitroso Group Oxidative Migration 1.00
Chemodivergent C–H Activation and C–C Coupling between Indoles and Alkyne-Tethered N‑Cyanosulfonamides via Substrate-Controlled Group Migration 1.00
Dual Photoredox/Nickel-Catalyzed Atroposelective C–N Coupling with Carbazoles and Indoles as N-Nucleophiles 1.00
Stereospecific N-Glycosylation Strategy for β-N-Glycoside Synthesis via Base Catalysis 1.00
tBuONO as the Co-catalyst in Palladium-Catalyzed Aerobic α,β-Dehydrogenation of Ketones 1.00
Copper-Catalyzed Decarboxylative Alkynylation of Arylacetic Acids via an Electrophotochemical Approach 1.00
Stereoselective Synthesis of (E)-Allylic Sulfones by Photocatalytic Desilyloxylative Sulfonylation of Allyl Silyl Ethers with Thiosulfonates 1.00
DFT-Guided Photocatalytic C5-Selective Hydrodechlorination of 4,5-Dichloropyridazinones 1.00
Copper-Catalyzed Petasis-Type Reaction Enables Efficient Synthesis of C1-Substituted Tetrahydro-β-carbolines 1.00
Asymmetric Reductive Cross-Coupling of Aldimines 1.00
Modular Synthesis, Properties, and Fluoride Response of Azaborine-Based Bidentate Boron Complexes Featuring Tri- and Tetracoordinate Centers 1.00
Photoredox-Catalyzed N-Centered Radical-Mediated Cascade Annulation/Dearomatization of ortho-Sulfonamide-Tethered Alkylidenecyclopropanes 1.00
Silyl-Triflate-Catalyzed Divergent Annulation of Isoquinolines with Ynamides: Direct Access to 2-Aminonaphthalenes and 2-Amino-1-naphthonitriles 1.00
Pd-Catalyzed β‑H Elimination of Alkenyl Thianthrenium Salts for the Synthesis of Disubstituted Allenes 1.00
Photocatalytic Functionalization of Perfluoroalkyl Alkenyl Iodides via Vinyl Radicals: Synthesis of Perfluoroalkylated Naphthalenes 1.00
Visible-Light-Induced Copper-Catalyzed Coupling Reaction of Aryl Halides with Phenols at Room Temperature 1.00
Multicomponent Reactions in Open-Air Metal-Free Aqueous Visible-Light Catalysis: Radical–Polar Crossover toward γ-Lactams and γ-Aminobutyric Acids 1.00
Rh(II)-Catalyzed Access to [4.3.1]Propellanes via a Formal Dicarbene Cascade Annulation 1.00
Asymmetric Synthesis of Spirocyclic Sultams via Nickel-Catalyzed Arylative Cyclization 1.00
Photocatalytic Regioselective Four-Component 1,4-Aryl Migration of N-Allylbenzamides To Access β-Arylethylamines 1.00
Cu-Catalyzed Z-Selective Carboboration of Acetylene with Hindered Michael Acceptors Enabled by a Buffering Borinate Additive 1.00
Electrochemical Decarboxylative Coupling for C(sp3)–N Bond Formation of Triazoles and Carboxylic Acids 1.00
En Route to N-α-Silylated Thioureas via Iridium-Catalyzed C(sp3)–H Silylation 1.00
Total Synthesis of Eucalyptusdimers A–C 1.00
Visible-Light-Driven [3 + 2] Annulation of N-Substituted Aromatic Amines with Nitriles: An Approach to Benzimidazoles 1.00
Visible-Light-Driven Manganese-Catalyzed Bromination Reactions with Dibromomethane 1.00
Visible-Light-Driven Self-Sensitized Photocatalysis: TBAI-Assisted Dioxygenation of 3-Salicyloylindoles 1.00
2,3-Diaryl Indanone Construction via the Neophyl Rearrangement 1.00
Easy Access to N,N-Disubstituted 2-Imidazolidinones from Weinreb-Type Amides and Enamides via Visible-Light-Mediated Radical Smiles Rearrangement 1.00
Pd(II)-Catalyzed Site-Selective [2 + 2 + 1] Spiroannulation of 2-Pyridone with Alkyne 1.00
Boronic Acid-Assisted Site-Selective Benzylation of Unprotected Saccharides 0.64
Enantioselective Synthesis of an Indenopyrrole Scaffold Containing an All-Carbon Quaternary Stereocenter via a Visible-Light-Mediated Organocatalytic Carbene Transfer Reaction 1.00
ortho-Selective C–H Alkenylation of Pyridines Enabled by a Heterometallic Mg–Ni–Mg Complex 1.00
Povarov-type Reaction of Anilines, Aqueous Acetaldehyde, and tBuONO for Access to N-Nitroso-1,2,3,4-tetrahydroquinolines 1.00
Photoactivation of Electron Donor–Acceptor Complexes via Quinolinium Salts and 4-Carboxamide-1,4-dihydropyridines: Synthesis of N-Heteroaryl-2-carboxamides 0.88
Norbornadiene Serves as a Tolyl Group Precursor for Constructing Biphenyl Derivatives by Palladium Catalysis 1.00
Energy-Transfer-Mediated Radical-Relay Brook Rearrangement of Electron-Deficient Ketones 0.95
SmI2-Mediated 4-Exo-Trig Cyclization of Trifluoromethyl Alkenyl Aldehydes 1.00
Asymmetric α-C–H Allylic Alkylation of α-Amino Acid Esters by Synergistic Carbonyl/Iridium Catalysis 1.00
<atl>Sodium iS/i -(difluoromethyl) Sulfurothioate: A Readily Available (Deuterio)difluoromethylthiolating Reagent with SCF sub2/sub H sup+/sup , SCF sub2/sub H sup–/sup , and SCF sub2/sub H sup•/sup Reactivity</atl> 1.00
Pd/WingPhos-Catalyzed Synthesis of γ-Amino Alcohol Derivatives with β-Axial Stereogenicity via Desymmetrization of Allenylic Cyclic Carbonates 1.00
Ir-Catalyzed Asymmetric Synthesis of 3-Allylic Spirotetramic Acid Derivatives with Insecticidal Activities 1.00
Hyperconjugation-Driven Ester Migration Enabled Aerobic 1,3-Iodohydroxylation with Iodoform: A Triple Functionalization of Allyl Carboxylates 1.00
Electrochemical Methylarene Oxidation via Electrolyte Anion Control: Access to 18O-Labeled Aromatic Aldehydes 1.00
A General Platform for Aryl/Alkyl Radical Functionalization Enabled by Photoinduced Electron Donor–Acceptor Complex 0.88
Visible-Light-Driven Synthesis of Ketonyl Cysteine Compounds by Cysteine Decysteinylation with Enol Silyl Ethers Coupling 1.00
Coumarin-Rewired Benzothiophenes: Skeletal Editing for Peripheral Heterofunctionalization 1.00
Rh(II)-Catalyzed 1,3-Dichalcogenation of Vinyl Carbenes via [1,4]-Migratory Rearrangement of Sulfur/Selenium Ylides 1.00
Highly Enantioselective Synthesis of Chiral Hydrocarbazole-4-Carbaldehyde Scaffolds and Constrained Analogue of MS-245 via Iminium Catalysis at Elevated Temperatures 1.00
Formal Regioselective C–H Sulfinylation of Alkenes with Sulfinyl Sulfones 1.00
Assembly of N-Heterocyclic Carbenes and Nitroalkenes for Access to Isoxazole Derivatives 0.77
Old Reagent for a Trick in the Stereoselective Hydromethylation of Alkynes Enabled by Cu(I) Photosensitizer Catalysis 1.00
Cobalt-Catalyzed Hydrogen-Bond-Promoted Tandem Cyclization and Oxygen Migration: Access to Sterically Congested Fused Tetrahydro-β-Carbolines 1.00
Bioinspired Alkyl Transfer Enabled by Ca(II)/HFIP Cooperative Catalysis: Modular Synthesis of Functionalized Isoindolinones 1.00
A 6/5/6/5-Fused Indeno[7,1-bc]furan Diterpenoid Skeleton from Pinus yunnanensis Resins with Anti-Neuroinflammatory and Antidepressant Activities 1.00
Highly Regio- and Enantioselective Catalytic 1,6-Conjugate Addition of Grignard Reagents to Cyclic Dienones 1.00
Electrochemical N-Centered Radical Cyclization of Aryl Propargyl Alcohols toward Quinolines 1.00
Visible-Light-Induced Annulative Ring Expansion of Amino- Oxetane/Azetidin/Thietane Derivatives 1.00
Enantioselective Palladium-Catalyzed Desymmetric Allenylic Substitution of Allenylic Cyclic Carbonates: Access to Axially Chiral Trisubstituted α-Allenols 1.00
Nickel/Photoredox-Catalyzed Allylic Alkylation via C(sp3)–C(sp3) Cross-Coupling of Allyl Boronic Esters and Alkyl Halides 1.00
Photochemical Iron-Catalyzed Decarboxylative S-Glycosylation 1.00
Regiodivergent Metalation of Pyridines Using Mixed Ti-TMP and Ti–Fe-TMP Amides at Room Temperature 1.00
Copper-Catalyzed Asymmetric Synthesis of Heteroaryl Sulfoxide 1.00
Iron-Catalyzed Divergent Borylation of α-Aryl-Substituted Allylic Alcohols 1.00
Switchable C or C–N Insertion into N-Alkyl Enamines for Divergent Synthesis of 3-Aminopyrroles or CF3/CN-1,2-Dihydropyrazines 1.00
Aminophthalimide as a Protected Nitrogen Source for N-Insertion to Indenones 1.00
Lewis Acid-Mediated Defluorination of Trifluoromethylarenes To Access Trivalent Phosphines 1.00
Total Synthesis of Indigotinoline A and Enabled Stereochemical Revision of Isatindigotindoline B 1.00
Cascade Azide–Alkyne Cycloaddition/Azetidine Ring-Opening Reactions for Accessing Aminomethyl-Functionalized 1,2,3-Triazole-Fused Bicyclic Heterocycles 1.00
Photocatalytic anti-Markovnikov Chloroalkynylation of Unactivated Alkenes 1.00
Synthesis of Axially Chiral Styrenes via Pd-Catalyzed Atroposelective C–H Olefination 1.00
Phosphine-Catalyzed Intramolecular 7-endo-trig Annulations for Synthesis of Cycloheptadienes 1.00
Photochemical Alkylation of Heterocycles Enabled by Oxalic Dianion as Traceless Electron Donor 1.00
An Exclusive Synthesis of Macrocyclic Trimer over Polymers 1.00
Electrochemically Enabled Synthesis of Carboxylated Allenes via Carbon Dioxide Reduction 0.88
“Addition–Elimination” Transformations for Aminative Isomerization of Bicyclo[1.1.0]butanes (BCBs) 1.00
Marundihomalkins A–J and Marundisphingalkin A: Triglyceride-Lowering Marine Fungal Alkaloids Featuring Non-amide C–N Linkages between Polyketide and Homoisoleucine or Phytosphingosine 1.00
Copper-Catalyzed Divergent Rearrangement Reactions of Propargyl Ethers 1.00
A Cu(NTf2)2-Catalyzed Tandem Mannich-Cyclization Process of N-Boc-1,2,3,4-tetrahydroisoquinolin-1-ols with α-Aryl α-Diazo Ketones for the Construction of Substituted α-2-Furanyl Tetrahydro-1-isoquinolinemethanols 1.00
Spirocyclization-Enabled Remote Phosphorothiolation of Nonactivated Arenes via Dual Photoredox/Copper-Catalyzed Dearomatization 1.00
Catalytic Asymmetric Construction of Chiral Indoloazepine-Based Spirooxindoles via Formal [6+1] Cycloadditions 1.00
Photocatalytic Semireduction of Propiolamides in Microheterogeneous Solutions via Alkyne Radical Anions 1.00
Radical Haloazidation of 1,5-Enenitriles for Making N-Haloimines and Sequential Triazolation to Form Tricyclics 0.89
n-BuLi-Catalyzed Amidation Reactions of Aldehydes with 1° Amines 1.00
Pd-Catalyzed meta-C–H Arylation Using a Convertible Directing Group: Streamlined Construction of Biaryl Cores of Peptide Natural Products 1.00
Visible Light-Induced Synthesis of Esterified Quinolines and Pyrrolidones Controlled by Different Electrical Anilines 1.00
Copper-Catalyzed Decarboxylative Cascade Annulation of Propargylic Cyclic Carbamates with Allenediones 1.00
Collective Biomimetic Synthesis of Benzoxazole Xanchryones A, B, and I–N Based on Biogenetic Building Blocks 1.00
Total Syntheses of the Cyclobutane-Containing Guaiane-Type Sesquiterpene Daphnepapytone A and Certain Congeners 0.67
Synthesis and Photophysical Properties of Azaarene-Substituted Hypocrellin B Derivatives 1.00
B2pin2-Mediated Cascade Cyclization of 2-Alkenylanilines To Give 2-Difluoromethylthio/seleno-4-Aryl(alkyl)-Quinolines 1.00
Electrochemical Synthesis of Benzotriazoles and Benzotriazinones 1.00
Photoinduced Selective Hydrodefluorination of Trifluoromethylarenes Enabled by Base-Activated Hantzsch Esters 1.00
Chiral Betaine-Catalyzed Biomimetic Transamination of α-Keto Esters 1.00
Synthesis of Dibenzosiloles via Pyridine/Zn System-Enabled Cross-Couplings of Diiodidobiaryls with Dihalosilanes 1.00
Palladium-Catalyzed Photoredox Aminocarbonylative [3 + 2 + 1] Heteroannulation of Propargyl Acetates with α-Aminoazoles and CO 1.00
Construction of N–N Atropisomers Bearing Multiple Stereocenters via Desymmetrization of Indole-Derived Maleimides 1.00
Iodine-Catalyzed Oxidative [3+2] Annulation/Dehydrogenation Cascade: Synthesis of Unexpected Mesoionic [1,2,4]Triazolo[5,1-a]isoquinoliniums 1.00
Deep Molecular Bowls with Four Pentagons 1.00
Catalytic Enantioselective Formal (3 + 3) Cycloaddition of 3-Halooxindoles with Pyridinium 1,4-Zwitterionic Thiolates 1.00
Photocatalysis Enables Cross-Electrophile Coupling of Unactivated Ketones with Isothiocyanates 1.00
Photocatalyzed Radical Cross-Coupling of Allylic Esters with N-Aryl Glycinates and Benzyl Amines for sp3 C–C Bond Formation 1.00
Collective Total Synthesis of Ergot Alkaloids 1.00
Photoinduced Deacylative Phosphorylation of Unstrained Ketones 1.00
NHC-Catalyzed Desymmetrizative Amidation for C–O Axially Chiral Imides 1.00
Pd-Catalyzed Regio- and Atroposelective Hydroalkynylation of Allene to Access Axially Chiral Conjugated 1,3-Enynes 1.00
Pd-Catalyzed Annulation of Aryl Iodides with Ynamides for the Synthesis of 9-Aminophenanthrenes: Regioselectivity in Reductive Elimination of Pallada(IV)cycle 1.00
Ligand-Enabled Regioselective Cross-Coupling of Palladacycles with Aryl Halides via C–H Activation 1.00
Gold-Catalyzed Regioselective Remote B(9)–H Activation of o-Carboranes with Silylenynones: Access to B(9)-α-Furylsilyl-o-carboranes 0.86
Fast Bioorthogonal Ligation of 2-Aminobenzohydrazides and (2-Acetylphenyl)boronic Acids Providing Stable and Fluorescent Conjugates 1.00
Sulfonium Salt-Mediated Regio- and Stereoselective Aminosulfonylation of Alkynes with Sulfinates and Azoles 1.00
Visible-Light-Induced Carbonylative Synthesis of Aliphatic Thioesters 0.50
Alcohol Dehydrogenase-Mediated Generation of Cytotoxic Thiophene-Containing Eremophilane Sesquiterpenes 1.00
Visible-Light Induced Dehydrogenative Cross-Coupling of Enamides with Hydrocarbons Enabled by Aryl Thianthrenium Salt 1.00
Organophotocatalytic Synthesis of Polycyclic Sultones and Sultams with FSO2Cl through Fluorosulfonyl Radical Cation Synthon Strategy 1.00
Nickel-Catalyzed Aminocarbonylation of Aryl Trifluoromethoxides 0.67
Construction of Functionalized 2,3-Dihydropyrroles via Visible-Light-Driven Formal [3 + 2] Cycloaddition 1.00
Atroposelective Synthesis of C–N Axially Chiral Biaryls via Catalytic C–H Functionalization at a Remote Site 1.00
Cyclicurilarenes: Hybridizing Bambusurils with Macrocyclic Arenes 1.00
Rhodium-Catalyzed Atroposelective Synthesis of Conformationally Stable C(sp2)–C(sp3) Atropisomers via C–H Activation and Annulation with 9-Fluorenylacetylene 1.00
Tetracyclic β-Acid Meroterpenoids as Potent Anti-neuroinflammatory Agents via NLRP3 Inflammasome 1.00
Stereoselective Z,Z,Z-Trienylation of N-tert-Butanesulfinyl Imidates Enabled by Nucleophilic Ring Cleavage of Tropone Oxime Tosylates 1.00
Synthesis and Applications of the Se–N Clickable and Orthogonal Linker Based on Bicyclo[1.1.1]pentane 1.00
Structural Distortion and Arene π-Coordination Dual-Assisted Palladium-Catalyzed Annulation Reaction of Aromatic Carboxylic Acids with 2,2′-Diiodobiphenyls 1.00
Jatropodagines A and B: Lathyrane Diterpenoid Dimers from Jatropha podagrica, Inducing Paraptosis-Like Cell Death 1.00
Sc(OTf)3-Catalyzed Diastereoselective [3 + 3] Cycloaddition of Chiral Bicyclo[1.1.0]butanyl Imides and Nitrones 1.00
Photocatalytic [4 + 1] Annulation of Vinyl Aziridines with Alkyl Halides 1.00
Phosphine-Catalyzed Visible-Light-Induced Aminodifluoroalkylation of Alkenes: Access to α,α-Difluoro-γ-lactams 1.00
Photocatalytic Difluoromethylation Cyclization and Dioxygen Trapping: Access to gem-Difluoro-Quinolines 1.00
Asymmetric Construction of 1,4-Diketone Derivatives Containing a Less Accessible Acyclic Quaternary Carbon Stereocenter via Michael Addition/Rearrangement Cascade 1.00
[70]Fullerene-Fused Lactones: Regioselective Synthesis and Electrochemical Derivatization 1.00
P(NMe2)3-Mediated Umpolung (3 + 2) Annulation of β,γ-Unsaturated α-Keto Carbonyls with p-Quinone Methides: Synthesis of Spirocyclopentenyl p-Dienones 1.00
Iodanyl Radical Catalysis Enables a Decarboxylative Giese Reaction with Alkyl Carboxylic Acids 1.00
Rh(II)-Catalyzed Enantioselective B–H Insertion of Cyclic Alkyl-Donor Carbene Generated from Diynes 1.00
Visible-Light Photoredox Catalysis: Enabling [2π+2σ] Dearomative Cycloaddition of Unactivated Indoles with Bicyclo[1,1,0]butyl Tethers 1.00
Copper-Catalyzed Deaminative Amination of Primary Amines Enabled by a Deaminating Reagent 1.00
Photoinduced Fluoroalkylalkynylation of Unactivated Alkenes with Terminal Alkynes 1.00
Photochemical Boronate Rearrangement Enables the One-Pot Synthesis of 2,4-Difunctionalized 2H-Chromenes 1.00
Photoexcited Copper-Catalyzed Atom Transfer Radical Addition (ATRA) Reaction of Unsaturated C–C Bonds with 1-Iodo-o-carboranes 1.00
Modular Synthesis of Tetrasubstituted Thioallenoates via the Tandem Wolff Rearrangement/C–S Bond Insertion Reaction of Alkynyl Diazoketones and N,S-Acetals 1.00
Construction of α-Acyl-β-amino Amides via Multicomponent Reactions of β-Acyloxy Alkenyl Amides with Amines and Aldehydes 1.00
Chemoselective [2+1] Cycloaddition of Difluorocarbene with Conjugated Enynes: Synthesis of Alkenyl Difluorocyclopropenes 1.00
Artemverlotolides A and B, Two Sesquiterpenes from Artemisia verlotorum Lamotte: Structural Elucidation, Bioinspired Synthesis, and Antineuroinflammatory Activity 1.00
Visible Light-Induced Aerobic Ring-Opening Oxidation of Unstrained Aryl Cycloalkanes 1.00
SmI2/Sm-Mediated Desulfurative Fluoroarylation of Thioamides with Polyfluoroarenes via C═S/C─H Bond Cleavage 1.00
Electrochemical Synthesis of γ-Lactams from Amides and Alkenyl Trifluoroborates by [3 + 2] Annulation 1.00
Synthesis of Unsymmetrical C2,3-Bis-sulfenylated Indoles via Bimetallic Cu/Fe Relay Catalysis 1.00
Visible-Light-Driven (E)-β-Trifluoromethylation of Enamides via In Situ Generated Sulfur(VI) Photosensitizers 1.00
Palladium-Catalyzed Tandem Synthesis of Fused Spiroquinolinones from Bicyclobutyl Amides 1.00
Nickel Nanoparticles Catalyzed Cross-Coupling of Diazo Compounds with O-Benzoyl Hydroxylamines 1.00
Visible Light-Promoted Cascade Cyclization/Allylation of 2-Allyloxyaryl Sulfonium Salts with Morita-Baylis-Hillman Acetates 0.75
Paired Electrolysis-Promoted Ni-Catalyzed Decarboxylative Cross-Couplings of Potassium Malonate Monoesters with Aryl Bromides 1.00
A Catalyst-Free, Tyrosine-Selective Bioconjugation Strategy via Triazine-Pyridine Chemistry for Antibodies 1.00
Et3SiOBpin as a Dual Reagent Enabled Photocatalytic Stereoselective Assembly of Multisubstituted Perfluoroalkyl-boryl Styrenes 1.00
Photocatalytic Transfer of Trifluoromethylcarbenes for X–H Insertion, Oxetane Skeleton Editing, and Alkene Cyclopropanation 1.00
N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of Inherently Chiral Pillar[5]arenes 1.00
Difunctionalization of Aldehydes via Electrophilic Acylation: Access to α-Acyloxyphosphonium Salts and Subsequent Diversely Substituted Enol Esters 1.00
Electrochemical Chemo- and Regioselective Reduction of Vicinal Diketones to α-Hydroxy Ketones 1.00
Fully Substituted Cyclobutenes via [2 + 2] Cycloaddition of Ynimines with Cinnamamides 0.83
Humupulusones A and B, Two Skeletally Novel Acylphloroglucinol Derivatives from Humulus lupulus 1.00
Site-Selective Decarboxylative C–H Carbenoid Functionalization Enabled by Pyridotriazole-3-carboxylates 1.00
A Pd-Catalyzed (6+2) Cycloaddition/Ring-Contraction Relay for Chemodivergent Access to Chiral Spirooxindoles 0.78
para-Selective C–H Arylation and Alkylation of N-Arylhydroxylamines 1.00
Copper-Catalyzed Amino-alkoxycarbonylation of Unactivated Alkenes: Synthesis of β-Amino Esters via Primary Tosyl Amidyl Radical 0.60
Access to Se/S-Containing Heterocycles via Hexafluoroisopropanol-Mediated Tandem Wolff Rearrangement/Cyclization 1.00
Photoredox/Copper Dual-Catalyzed Four-Component Regioselective 1,2-Arylsulfonylation of Vinylarenes 1.00
Synthesis of C2-(N-Alkylcarbamoyl)-Substituted Pyrroles via Post-Condensation of Dipole Ugi Adducts 1.00
Direct Access to Luminescent meta-Substituted Tris(2,4,6-trichlorophenyl)methyl Radicals through Nucleophilic Substitution 1.00
Hexafluoroisopropanol-Mediated Hydroaminoalkylation–Aza-Prins for Construction of α-Amino-butenolide 1.00
Total Synthesis of Acorane-Type Sesquiterpenes (±)-Bilaiaeacorenol B and (±)-Penicibilaenes A and B 1.00
Electrochemical C–H Phosphonylation of Indole with Phosphine Enabled by Chemoselective C–P Bond Cleavage 1.00
Sulfonium Salt-Mediated Deoxyfluorination of Alcohols 1.00
N,N′-Di-Boc-N″-fluorosulfonyl-guanidine: A SuFEx-Enabled Guanylating Reagent (SuFEx-G) with Enhanced Reactivity on Water 1.00
Asymmetric Saddle-Shaped Nanographenes Integrating Helicene and Heptagon Motifs: Synthesis and Chiroptical Properties 1.00
Direct Phosphatation via Arylthianthrenium Salts 1.00
Organocatalytic Asymmetric α-C–H Allylation of N-Arylidene-Protected Alkyl Amines 1.00
Synthesis of Spiro[indoline-3,3′-pyridine]-2,2′-diones via an Annulo- and Diastereospecific [2 + 4] Annulation 1.00
Photoinduced Dearomative Oxyimination of Indoles Using Oxime Esters as Bifunctional Radical Precursors 1.00
Synthesis of N-(4-Vinylidenetetrahydrofuran-2-yl)amides and Applications in Skeletal Rearrangement to 2,3-Dihydro-1H-pyrrol-2-ols/Substituted Pyrroles and Bridged Bicyclic Scaffold Construction 1.00
Base-Promoted Denitrogenative Coupling of Nonactive 1,2,3-Triazoles with Ketones: Stereospecific Access to (Z)-β-Enaminones 1.00
Substituent-Promoted Thio-Belluš–Claisen Rearrangement with Difluoroketene 1.00
Zinc-Mediated Four-Component Carbonylation toward Direct Synthesis of α-Amino Ketones 0.50
Chemodivergent Accesses to Hetero-Bicyclo[3.3.1]nonenes 1.00
Electrochemistry Enables O-Arylation of Tyrosine with Aminoisoxazoles: Late-Stage Diversification of Peptides and Pharmaceuticals 1.00
Access to Imidazolidin-2-ones via Azocarboxamide-Enabled Enantioselective 1,2-Diamination of Aldehyde 1.00
Highly Regioselective Functionalization of Triborane (L·B3H7) through Copper-Catalyzed B–H Bond Insertion Reaction of Tosylhydrazone Compounds 1.00
Temperature-Controlled Switchable Cascade Reactions of Alkyne-Tethered Ketoximes and Cyanobenziodoxolone for Divergent Synthesis Cyano-Featured Isoxazolines and 3H-Pyrrol-3-ones 1.00
Pd(II)-Catalyzed Hydroxyl-acyloxylation of gem-Dimethyl Groups via Dual C(sp3)–H Activation 1.00
Palladium-Catalyzed Cascade Reaction of Indoles with α,α-Difluoro-β,γ-Unsaturated Ketones: One-Step Access to 2-Fluorocarbazoles 1.00
Catalytic Asymmetric Kinetic Resolution of 2,2-Disubstituted Styrenyl Aziridines via Ring Opening with Amines 1.00
Direct Synthesis of Triarylethynylphosphines from White Phosphorus and Arylacetylidene Lithiums 1.00
Electrochemically Driven Decarboxylative Primary Alkylarylation of Alkenes with Aliphatic Carboxylic Acids 1.00
Chiral Pyridoxamines Featuring Proton-Donating Auxiliary Side Chains for Asymmetric Biomimetic Transamination 1.00
Imidazolidine-Pyrroloimidazolone Pyridine-Cu(OTf)2 Complex Catalyzed Asymmetric Radical Carbo-Esterification 1.00
Copper-Catalyzed Amination of Polyfluoroarenes via Decarbonylative Metallaphotoredox 1.00
Photoinduced Smiles Rearrangement of N-Sulfonylpropargylamines for Highly Stereoselective Access to Tetrasubstituted Allylamines 1.00
The Electrochemical Functionalization of N–H Bond on N-Heterocycles with Isocyanides to Synthesize Azole Urea Compounds and Methanimines 1.00
Synthesis of (S)-Finerenone via Late-Stage Asymmetric Transfer Hydrogenation 1.00
Bioinspired Synthesis of Curtachalasin A and Δ6,12-Curtachalasin N Enabled by Tandem Transannular Epoxyalkene Cyclization and α-Ketol Rearrangement 1.00
N-Heteroaromatic Fused BODIPY Dimers: Ring-Size Effects from Five- to Six-Membered Rings 1.00
Synthesis of γ-Carbonyl Aliphatic Sulfoxonium Salts via Site-Selective Ring Opening of In Situ Formed 2-Sulfoxonium Cyclobutanone 1.00
Electrochemical Radical Addition-Initiated Ring-Opening/Functionalization of 2-Alkylidenecyclobutanols toward γ,δ-Unsaturated Ketone Synthesis 1.00
Deconstructive Alkylation of Unstrained Cyclic Amines via Lewis Base–Boryl Radical-Enabled Spin-Center Shift 1.00
Chemodivergent Multicomponent Reactions of Morita–Baylis–Hillman-Type Yne-allylic Esters with 1,3-Dicarbonyls or Aroylacetonitriles 1.00
Construction of C–S and C–Se Bonds via Deaminative Coupling of Primary Amines 1.00
Copper(II)-Catalyzed Radical-Type Selenium(II)–Nitrogen Exchange Chemistry between Benzoselenazolones and Hydrazines 1.00
Iron-Catalyzed Radical-Mediated 1,3-Azidoalkylation of Bicyclo[1.1.0]butanes: Access to 1,1,3,3-Tetrasubstituted Cyclobutanes via Strain Release 1.00
Hypervalent Iodine Diazo Esters as C1 Synthons in [3+2+1] Cascade Cyclization: Access to Fully Substituted Pyridines 1.00
Photoredox-Catalyzed Modular Synthesis of ε-Lactams via Acrylamides Cyclization Enabled by Radical-Polar Crossover-Mediated Carbanion Trapping 1.00
Photochemical Synthesis of DNA-Encoded 3H-Azepines via Skeletal Editing of Nitroarenes 1.00
Palladium-Catalyzed Enantioselective Tandem Allylation/Cyclization of ortho-Alkynylbenzaldehydes with Allyltrimethylsilane: Access to Chiral 1-Allyl-1H-isochromenes 1.00
Photocatalytic 1,2,3-Trifunctionalization of β,γ-Unsaturated Ketones via 1,2-Carbonyl Migration to Access Functionalized Indanones 1.00
Synthesizing C8-Chiral Substituted 5,6,7,8-Tetrahydroquinolines via Palladium-Catalyzed Enantioselective Arylation of Unactivated C(sp3)–H Bonds 1.00
Visible-Light-Driven Modular Synthesis of Isoquinolinone Derivatives via Palladium-Catalyzed Radical 6-endo Annulation of Aryl Halides 1.00
Synthesis of α-Trifluoromethylated Amines via Fluoroalkylation and Defluoroamination of Indoles 1.00
Biosynthesis of the l-Pyridylalanine Moiety in Antimycobacterial Pyridomycin via a PKS-NRPS Hybrid System 1.00
CO2-Driven C(sp2)–H Lactamization to 2-Quinolinones 1.00
Tetrabenz[a,c,h,j]anthracene-Bridged Carbaporphyrin Dimer 1.00
Light-Induced Copper-Catalyzed Arylamination of 1,3-Butadiene 1.00
DNA-Compatible Synthesis of β-Ketoamides as Intermediates for On-DNA Chemical Diversification 1.00
Photoinduced P–Se Bond Cleavage of Diselenophosphinic Esters: En Route to Selenoethers and Phosphine Selenides 1.00
Synthesis of Polycyclic Indolines via Spiroindolenines: Mechanistic Validation and HDAC6 Inhibition Potential 1.00
Cobalt-Catalyzed Intramolecular Dearomative Alkylation of Phenols with Alkenes 1.00
Selective Deprotonated Amide Activation of Dehydroalanine for Peptide Modification 1.00
Asymmetric Inverse-Electron-Demand Diels–Alder Reaction of 2-Pyrones with Acyclic Indolyl Alkenes for the Synthesis of Chiral N-Alkylindoles 1.00
Visible-Light-Induced Carbamoylation for Synthesis of Dibenzo[b,f][1,4]oxazepine Carbonyl Amino Acid/Peptide Derivatives 0.92
Light-Induced PdH-Catalyzed Cross-Dimerization of gem-Difluoroalkenes with Alkenes to Access CF2H Motifs 1.00
Enantioselective Synthesis of Chiral 2,2-Difluoro-spiro[indene- [1,3,4]oxadiazines] by NHC-Catalyzed [4 + 2] Cyclization Reactions 1.00
Diastereoselective Cyclopropanation of Terminal, Nonconjugated Alkenes with 2-Oxoethylpyridinium Salts via Nucleopalladation 1.00
Synthesis of Chiral (hydro)Indoloquinazolinones via Enantioselective Copper-Catalyzed Borylative Cyclization 1.00
Photocatalytic Selective Synthesis of Hemiketals from Alkenes, α-Halo Acylarenes, and Water via N-Methylindole Catalysis 1.00
Tertiary C(sp3)–Si Bond Formation via Reactivity Umpolung of Silyl Reagents 1.00
Enantioselective Synthesis of Triarylmethanes via Palladium-Catalyzed Desymmetric Carbonylation of Cyclic Diaryliodonium Salts 1.00
Electrochemical Synthesis of 1,2-Substituted N-Amido Benzimidazoles by Reduction of Nitroarenes 0.10
Regioselective 1,2-Hydrogen Atom Transfer of N-Centered Radicals for C(sp3)–C(sp3) Coupling to Generate 1,2-Diamine Derivatives 1.00
Photoinduced Lactamization/Truce–Smiles Rearrangement Cascade Enables Access to Lactam-Fused β-Arylethylamines 1.00
Electroreductive Cross-Electrophile Coupling of Aldimine with Chlorosilanes Enabling the Synthesis of α-Aminosilanes 1.00
Synthesis and Biological Evaluation of N–CF3 Diaryl Amines 1.00
Photocatalyzed Site-Selective Formal β-C(sp3)–H Sulfonylation of Ketones with Sulfinates 1.00
Enantioselective Access to Cyclopentanone-Fused Dihydrothiophenes 1.00
Construction of Cyclopenta[b]pyridine Frameworks via Pd(0) π-Lewis Base-Initiated Cascade Reaction of Enyne-Tethered Malononitriles 1.00
Pd(II)-Catalyzed [3 + 1 + 1 + 1] Cascade Annulation of N-Substituted Anilines with CO and Amines: Direct Access to N1,N3-Disubstituted Quinazoline-2,4(1H,3H)-diones 1.00
Electrochemical Dearomative Reduction of Indole Derivatives Mediated by Ph3P(O) 1.00
Biomimetic Skeleton Conversion from Tiglianes into Three Euphorbia Diterpenoid Skeletons via Regioselective Cyclopropane Ring-Opening 1.00
R3P/ICH2CH2I-Promoted Skeletal Editing of Cyclic Ethers via O/N Exchange 1.00
Pd-Catalyzed Three-Component Coupling of Aryl Bromides, Alkynes, and Anthranils To Access ortho Carbonyl N-Aryl Indoles 1.00
Samarium Diiodide-Mediated Radical Borylation of Alkyl Bromides with Pinacol Borane 1.00
Modular Access to Boron Tripyrrolic Complexes from a Sequential Buchwald–Hartwig Amination/Boron Complexation Reaction 1.00
Photoredox-Enabled Radical Ring-Opening Fluorosulfonamidation/Fluorosulfonylmethylation of Methylenecyclobutanols 1.00
Visible-Light-Induced Radical [4 + 1] Annulation of Diazosulfonium Triflates with Cyclopropenes: Direct Synthesis of Benzofulvenes 1.00
Synthesis of Stilbene Derivatives via Phosphine-Catalyzed Cascade [2+4] Annulation/Decarboxylative Aromatization of Yne-Enones with α-Pyrones 1.00
C–H Arylation of Imidazo[1,2-a]pyridines and Zolimidines Catalyzed by Synergistic Tripalladium Clusters 0.60
Pyridine Synthesis via [3 + 2 + 1] Oxidative Cyclization of Enamines, Ethyl Tertiary Amines, and Alcohols: Copper-Catalyzed Cascade Multicomponent Poly C(sp3)–H Functionalization 1.00
Construction of PROTAC Library via Liquid-Phase Synthesis Enabled by a Hydrophobic Tag 1.00
Carbon Atom Deletion Strategy Enabled Synthesis of 22-epi-6-Deoxocastasterone Using the Intact Skeleton of Tigogenin 1.00
Yb(OTf)3-Catalyzed [2π + 2σ] Cycloaddition of Bicyclo[1.1.0]butanes with Methylenimines for Modular Synthesis of 1,2,4-Trisubstituted 2-Aza-bicyclo[2.1.1]hexanes 1.00
Organocatalyzed Asymmetric Intermolecular Annulation of Nucleophilic Imines with High-Temperature-Dependent Enantioselectivity 1.00
Decarboxylative and Deoxygenative/Decarbonylative Alkylation of Heterocycles with α-Keto Acids 0.86
Photoinduced 1,2-Chlorothiolation of Unactivated Alkenes via Proton Transfer and Electron Transfer 1.00
A General Iron-Photocatalyzed Decarboxylative Arylalkylation of Carboxylic Acids with Activated Alkenes 1.00
Cu-Catalyzed Atroposelective Protoboration of Allenes to Access Stereodefined Tetrasubstituted Axially Chiral Alkenylboronates 1.00
Catalytic Asymmetric Synthesis of α-Alkenyl Quaternary Amino Acid Esters 1.00
Access to Chiral Sulfoxides by Enantioselective Imine Condensation 0.33
Palladium-Catalyzed Enantioselective [3 + 2] Cycloaddition of Vinylarylcyclopropanes (VACPs) with Photogenerated Ketenes to Tetrahydrofurans 1.00
Dithiane-Alkyne Metathesis Enables Trp(C2)-Alkene-Cross-Linked Cyclic Peptides 1.00
Merging Photoredox with Nitro Reduction for the Direct Synthesis of Unsymmetrical Ureas 1.00
Bi-Catalyzed [3 + 2] Cycloaddition of C2-Spirocyclopropyl-indolin-3-ones with Carbonyls: Access to Spiro[furan-3,2′-indolin]-3′-ones 1.00
Biomimetic Iron-Catalyzed Oxidation of 3-Substituted Indoles to 2-Oxindoles 1.00
Visible-Light-Induced Lactone-Fused Indoline Construction via Radical Dearomatization of Indoles with Alcohols 1.00
Photochemical Zincke-like Reactions Enabled the Expeditious Synthesis of 2-Polyene Sulfonylpyridines 1.00
Photocatalytic Synthesis of α-Fluoro-β-sulfonyl Carbonyl Compounds Using Nucleophilic Fluorine Sources 1.00
A General Electrochemical C(sp3)–H Amination of Hydrocarbons Suitable for Inactive Alkanes, Alkenes and Alkynes 1.00
Dual Photoredox/CpTi(IV)-Catalyzed Reductive Cyclization of Tertiary Bromide with Nitrile for Constructing 4a,9a-Heterocycle-Fused Tetrahydrocarbazole 1.00
Cu(I)-Catalyzed Radical Coupling of Alkenes with Sulfonimidoyl Chlorides: Synthesis of Vinyl Sulfoximines 1.00
Regio- and Stereoselective Synthesis of Polysubstituted γ-Lactams Enabled by Photocatalyzed Sequential Radical Aminoalkylation of MBH Acetates 1.00
Direct Photoexcitation Enables Nickel-Catalyzed C(sp3)–C(sp3) Coupling of α-Bromonitriles with Alkylzirconocenes 1.00
Tandem Nitration-Cyclization-Rearrangement of Indole-Tethered 1,6-Enynes To Access NO2-Featured Heterocycles 1.00
Enantioselective Total Synthesis of (+)-Subincanadine F via Organo-SOMO Catalysis 1.00
Synthesis of Enantioenriched Difluoromethylated Allenes via Copper-Catalyzed Stereospecific Difluoromethylation 0.83
Direct Benzylic Phosphination of Toluenes Enabled by a Heterobimetallic LiN(SiMe3)2/Cs2SO4 System 1.00
Hyperacmoses A–C, Three Seco-Norpolyprenylated Acylphloroglucinols from Hypericum acmosepalum with Lipid-Lowering Activity 1.00
Asymmetric Synthesis of 2,2-Disubstituted Dihydroquinolines via Rhodium-Catalyzed Dearomative Arylation and Alkenylation of 2-Substituted Quinolinium Salts 1.00
Light Illuminates Polarity-Mismatched Cycloaddition to Convert Isoquinoliniums into Phenylnaphthyl Sulfones 1.00
Pd-Catalyzed Aqueous Buchwald–Hartwig Amination with Amphiphilic Polymer PEG–PVEG 1.00
Enantioselective Synthesis of Medium-Sized Rings via a General Palladium-Catalyzed (6 + n) Annulation Platform 1.00
Photoinduced Radical Coupling for Si–N Bond Formation 1.00
Iron-Catalyzed Photoredox Decarboxylative Hydroalkylation with Alkynes and Alkenes 0.83
Chlorjaponoids A and B, Two Lindenane–Guaiane Sesquiterpenoid Dimers with a Cage-like Tetracyclo[8.5.0.02,7.03,13]pentadecane Scaffold from Chloranthus japonicus 1.00
Merging Borylation and Desaturation to Access Arylboronates from Carbonyls 1.00
Regioselective Thiolation and Selenylation of Cyclic Diaryl λ3-Bromanes Enabled by Visible-Light Photocatalysis 1.00
Copper-Catalyzed Intermolecular Aminotrifluoromethylation of Alkenes with Free Anilines 1.00
Yellow-Light-Mediated Synthesis of Amidoximes via Radical gem-Diamination of Diazo Compounds 1.00
Copper-Catalyzed Dearomative Cyclopropanation of Benzofurans with Diynes via Vinyl Cations 1.00
Hydrocarbon-Involved Sulfoxide Deoxygenation via Bifunctional Iron-Enabled Electron Buffering and Ligand-to-Metal Charge Transfer 1.00
(Vinyl tosyloxy)benziodolium Salts: Divergent Construction of Conjugated Diene Derivatives via Sequential Coupling Reactions 1.00
Total Synthesis of Chrysosporazines B and C 1.00
Divergent Total Synthesis of Tacaman Alkaloids: A Skeleton Reorganization Strategy 1.00
DDQ-Mediated Oxidative [5+2] Cycloaddition Reactions of Isochroman-4-ones with Alkynes 1.00
Palladium-Catalyzed Regiodivergent [4 + 2] Cycloaddition of Benzosilacyclobutenes with Phenylpropiolonitriles 1.00
Discovery of Diverse Esterified seco-Polycyclic Polyprenylated Acylphloroglucinols from Two Species of Hypericum Linn. and Their Lipid-Lowering Effect 0.95
Uranyl-Enabled Photocatalytic C(sp3)–H Functionalization with Azoles 1.00
Chiral Carboxylic Acid Assisted Ir(III)-Catalyzed Asymmetric C–H Activation/Desymmetrization of Sulfoximines 1.00
Selective Synthesis of anti-Bisbenzo[b]thieno[2,3-b:2′,3′-e][1,4]dithiin via Copper-Catalyzed Domino Formation of Eight C–S Bonds 1.00
Direct Synthesis of Fluorinated Polycyclic Aromatic Dioxanes: Mesomorphism, Luminescence, and Charge Transport 0.88
Photocatalytic Copper-Promoted Heptafluoroisopropylation of Arylsulfonium Salts with AgCF(CF3)2 1.00
Polycyclic Limonoids as Potential Nrf2 Inducers from Trichilia connaroides 1.00
Metabolic Competition between Non-reducing Polyketide Synthases Drives Hidden Chemodiversity in Deep-Sea Fungus Talaromyces radicus 1.00
Photoinduced Amination of Inert C(sp3)–H Bonds with Diazirines for Access to Diaziridines 1.00
Ring-Strain-Driven Annulation of Cyclopropenones with Hydrazones via Nucleophilic Phosphine Catalysis 1.00
Strain-Release-Driven exo-Cyclization of Bicyclo[1.1.0]butyl Ketones Promoted by Brønsted Acids to Access 2,3-Diazabicyclo[3.1.1]heptenes 1.00
Copper/Photoredox Dual Catalysis for the Redox-Neutral C(sp3)–CF2H Cross-Coupling between Benzylic Bromides and Tetracoordinated Difluoromethylborates 1.00
Chiral Phosphoric Acid-Catalyzed Asymmetric [4 + 2] Cycloadditions of Photogenerated o-Quinodimethanes with Vinylazaarenes 1.00
Electrochemical Cascade Reaction for C(sp3)–H Tetrazolation of Saturated Heterocycles: Access to Tetrazole-5-thiones 1.00
Palladium-Catalyzed Enantioselective Dearomatization of Furan To Access N,O-Spirocycles 1.00
Reverse Regioselectivity of Aminopalladation: Palladium-Catalyzed Oxidative Tandem Cyclization for the Construction of Aza-oxabicyclo[4.2.1]nonane 1.00
Direct Synthesis of Tricyclo[3.2.1.02,7]octenes via Palladium-Catalyzed Sequential Reactions of 2-Pyranones with 1,3-Dienes 1.00
Seeking Equality from an Asymmetric System: The Convergent Total Synthesis of Prostacyclin Drug (±)-Beraprost Sodium 1.00
N-Alkylsulfonamide Nucleophilicity: Experimental and Computational Assessment of Nitrogen Nucleophilicity of (S)-2-(Iodomethyl)-1-tosylpyrrolidine 0.25
Catalytic Asymmetric Synthesis of 1,2-Fused Tricyclic Indoles Containing an Eight-Membered Biaryl Bridge 1.00
Asymmetric Iodoaminocyclization for the Synthesis of Chiral 2-Heteroaryl Pyrrolidines 1.00
Asymmetric Synthesis of cis-3α-Aryloctahydroindole Alkaloids by Ene-Reductase Dehydrocyclization 1.00
Thiourea-Mediated Esterification by Redox Dehydration 1.00
Photocatalytic Radical Relay Strategy for the Synthesis of Allylic gem-Difluorides via 1,4-Difunctionalization of gem-Difluorobuta-1,3-dienes 1.00
Transition Metal- and Catalyst-Free Acylation of Alkyl Halides Using α-Hydroxyketones as Acyl Anion Equivalents 1.00
Asymmetric Synthesis of the Tricyclic Core of Ingenane Diterpenoids via a Photocatalytic de Mayo Fragmentation Strategy 1.00
1,2-Amino Alcohols via Visible-Light-Mediated Mannich-Type Reaction Enabled by Brook Rearrangement 1.00
Chiral Iminium Salt-Catalyzed Asymmetric Oxidative Dearomatization of Naphthols into ortho-Quinols 1.00
Chemodivergent [3+2] and [4+2] Annulations of Isoindigos with Morita–Baylis–Hillman (MBH) Carbonates 1.00
A Strategy for the Stereoselective Synthesis of Contiguous Triamines via Aziridine Intermediate 1.00
A One-Pot Three-Step Cu-Catalyzed Protocol to Construct Dibenzo[1,4]diazepine Derivatives and Their Analogs with Cyclopropylamine as a Surrogate of Ammonia 1.00
Green-Light-Induced Cyclopropanation of Alkenes via Cooperative NHN/Ligated Boryl Radical Activation of Dichloromethane 1.00
Copper-Catalyzed [3+3] Cycloaddition of Ethynyl Methylene Cyclic Carbamates with N,N′-Cyclic Azomethine Imines Enabled by an Extended C═C Bond 1.00
Photocatalytic α-Selective σ-Bond Hydroboration of Bicyclo[1.1.0]butanes 1.00
Mechanochemically Triggered Deaminative Halogenation of Anilines Mediated by a TEMPO-Driven Radical Manifold 1.00
A Nonpillar Shaped Pillararene Derivative, Oxgens2 Pillar[6]arene: Synthesis, Structure, and Iodine Adsorption 1.00
Phosphonium Ylide-Catalyzed Z-Stereoselective Synthesis of α-Substituted Monofluoroalkenes from gem-Difluoroalkenes and Triazoles 1.00
Divergent Access to α,β-Unsaturated Thiolated and Selenolated Lactams via a Unified Palladium-Catalyzed Carbonylative Transformation 1.00
Synthesis of 1,3-Alkylphosphoryl Bicyclo[1.1.1]pentane by Photocatalytic Cascade Radical Addition 1.00
Electrochemically Enabled [3 + 2] Cycloaddition of Alkenes with Vinyl Azides: Direct Access to 2,4,5-Trisubstituted 1-Pyrrolines 1.00
Organocatalytic Enantioselective Synthesis of Axially Chiral Tetrasubstituted Allenes via Direct 1,8-Addition to In Situ Formed Alkynyl 8-Methylenenaphthalen-2(8H)-ones 1.00
Enantioselective Construction of Chiral Azahelicenes through Catalytic Asymmetric Povarov-Type Cycloaddition Involving Alkynes 1.00
Pentafluoroethyl Sulfoximine Reagent for the Photocatalytic Pentafluoroethylation–Difunctionalization of Styrene Derivatives 0.29
Skeletal Transformation of Benzene Rings to Indoles via Arylthianthrenium Salts Strategy 1.00
Arylative Coupling of Pyridylphosphonium Salts with Aryl Thianthrenium Salts Enabled by Palladium Catalysis 1.00
Direct Difunctionalization of Unsaturated Peptides: A Strategy for Concurrent Incorporation of Trifluoromethyl and Alkynyl Groups 1.00
Aspersorbiciols A and B, Two Hybrid Sorbicillinoids with an Undescribed Skeleton from a Marine-Derived Fungus Aspergillus sp. GXIMD02072 1.00
Modular Synthesis of Geminal Triarylmethyl and Chiral Diarylmethyl Boronates via Arylation of Solid α-Boryl Organozinc Reagents 1.00
Light-Mediated g-C3N4-Catalyzed Anti-Markovnikov Hydroarylation of Enamides: Direct Access to β-Arylethylamine with Nematicidal Activity 1.00
Acylsilane as Energy Transfer Catalyst for Intermolecular [2 + 2] Cyclization of Alkenyl Triflones and Olefins 1.00
Diazotrifluoroethyl Radical in Photoinduced [3 + 2] Cycloadditions 1.00
Combining Palladium and Metal Alkoxide Enables Chemoselective Access to Flexible Allyl-Pd Oxa-dipoles for Higher-Order Cycloadditions 1.00
Copper-Catalyzed C(sp2)–H Thioglycosylation of Tryptophan: Modular Construction of S-Linked Thioglycopeptides 1.00
Catalytic Atroposelective Synthesis of C–N Axially Chiral Pyrazolyl Pyrroles via De Novo Construction of a Pyrrole Ring 1.00
Direct Catalytic Decarboxylative C1-Alkylation of Unprotected Tetrahydroisoquinolines via Photoredox Catalysis 1.00
Organophotocatalytic Single-Step Oximation through an Olefin [4 + 2] Annulation 1.00
Indium-Catalyzed Synthesis of 4-Alkynyl-2-quinolones Accompanied by Alkyne Migration 1.00
Direct Ether Synthesis Utilizing the Carbonyl Umpolung Reaction 0.06
N═N Coupling and Rearrangement of Arylamines with N-Nitrosoaromatics: Synthesis of Unsymmetric Azobenzenes 1.00
Copper-Catalyzed Remote Enantioselective [4 + 1] Cyclization of Yne–Vinyl Allylic Esters with Cyclic 1,3-Dicarbonyl Compounds Enables Access to Spirocyclic Ketones 1.00
Photoredox-Catalyzed Defluorinative Carbamoylation of α-Trifluoromethylalkenes 1.00
Palladium(II)-Catalyzed Direct C7-Acyloxylation of Indoles 1.00
Photocatalytic Kharasch-Type Cyclization Cascade for Accessing Polyhalogenated 1-Indanones and Indenes 1.00
Nitrene Generation from Iminophosphoranes: Facilitating Ring-Closing C(sp2)–H Amidation for Disubstituted Oxindoles 1.00
Cα-Umpolung of Amides Strategy for Enantioselective Propargylic Amination toward Cα-Tetrasubstituted α-Amino Acid Derivatives 1.00
Employing Arylboronic Acids in Nickel-Catalyzed Enantioselective Suzuki-Type Cross-Couplings: Access to Chiral α-Aryl Phosphonates and α-Aryl Esters 1.00
Base-Mediated Cascade Annulations of β-CF3-1,3-Enynamides with Tosylaminomethyl Enones: Synthesis of Angularly CF3-Substituted Hexahydrocyclopenta[c]pyrrole Frameworks 1.00
O2-Controlled Acid-Mediated Sulfenylation/Cyclization of Tethered Malononitriles and Sulfides toward Divergent Synthesis of Mono/Dithio-cyclopentenones 1.00
Copper-Catalyzed Regioselective Dehydrogenative Borylation: A Modular Platform Enabling C4-Borylated 2,1-Borazaronaphthalenes 1.00
Development of Axially Chiral Phosphoramidite Ligands and Their Application in Pd-Catalyzed Asymmetric Synthesis of Spiro-Pyrazolone–Pyrrolidinones via [2 + 3] Cycloaddition 1.00
Dual Cobalt/Photoredox Catalysis for the Synthesis of α,β-Unsaturated γ-Lactams and α-Enaminones 1.00
Synthesis of Axially Chiral Allenes by Pd-Catalyzed Thianthrene-Mediated Functionalization of Alkynes with Arenes 1.00
Rehmannins A–D, Anti-inflammatory Carotenoid Pigments from the Fresh Root of Rehmannia glutinosa 1.00
Deoxygenative Asymmetric Cyanation with P(OEt)3 Employing Cooperative Photoredox Catalysis and Copper Catalysis 1.00
Unsymmetric Diazaborepin Framework with Fused 6/5/7 Ring and π-Extension to Two Bis-Diazaborepin-Embedded Isomers 1.00
Bromination Functionalization of Diazo Compounds with CBr4 via Convergent Paired Electrolysis 0.57
Asymmetric Synthesis of KRAS G12C Inhibitor MK-1084 via a Crystallization-Induced Diastereomer Transformation (CIDT) 0.24
Visible-Light-Enabled Fluorosulfonylalkynylation of Alkenes 1.00
Visible Light-Promoted Thiobenzoic Acid-Catalyzed Deuteration of Alkylamines and Alkylarenes 1.00
Nickel-Catalyzed Atroposelective Synthesis of Axially Chiral Heterobiaryls via De Novo Benzene Formation 1.00
Decoupling Radical Generation and Copper Catalysis for the Remote C–H Cyanation of Unfunctionalized Sulfonamides 1.00
Hunterlanines A–F, Neuroprotective Monoterpenoid Indole Alkaloid Heterodimers from Hunteria zeylanica 1.00
Photodriven Fluoroalkylation–Alkoxylation of Enol Ethers via Electron Donor–Acceptor Complex of Bromodifluoroacetamides 1.00
Difluoromethylation of Arylsulfonium Salts with TMSCF2H 1.00
Divergent C–H Alkylation and Allylation of Indoles with Unactivated Alkene via Mechanochemical Rh(III) Catalysis 1.00
Atroposelective Synthesis of Styrenes by Alcohol-Dehydrogenase-Catalyzed Dynamic Kinetic Resolution 1.00
Developing Nitrogen-Rich High-Energy Initiating Materials: Integration of Azidotetrazole into a Heterocycle via a Two-Step Approach 1.00
Minisci-Type C–H Methylation and Silylation of Heteroarenes with Visible Light and N-Fluorobenzenesulfonimide 1.00
Site-Selective Azidation of Arenes via Hypervalent Iodine-Mediated C–H Functionalization 1.00
Difluoromethylation of Aryl Halides via Palladium-Catalyzed Redox-Neutral Deacylation 1.00
Photoredox/Copper-Cocatalyzed Difluoromethylation of Benzylic Bromides with PPh3(CF2H)2 1.00
Synthesis of γ-Aminophosphonates via Photocatalytic Radical Relay Process 1.00
Photoinduced Palladium-Catalyzed Denitrogenative Cyclization of N-Aroyl Benzotriazoles to Phenanthridinones 1.00
Electrochemical Radical Allylic Trifluoromethylation of Free Allylic Alcohols with Trifunctional Trifluoromethyl Thianthrenium Salts 1.00
Electron Donor–Acceptor Complex-Driven Minisci Reactions of N-Heteroaromatic and Inert C(sp3)–H without Brønsted Acids and External Oxidants 1.00
Carbene-Catalyzed C–H Arylation of Aldehyde-Hydrazone via Radical Cross-Coupling with Iodobenzene 1.00
Direct Indazole Synthesis via Ruthenium(II)-Catalyzed Acceptorless Dehydrogenative Annulation of Alcohols and Arylhydrazines 1.00
Photoinduced Synthesis of S-Aryl Dithiocarbamates and Arylamides via Denitrogenation and CS2/CO Insertion of Aryltriazenes 1.00
Ni-Catalyzed Asymmetric Reductive Arylation and Alkenylation of N-Sulfonyl Imines 1.00
Asymmetric Synthesis of Axially Chiral Olefins and Heterobiaryls via Rhodium-Catalyzed C–C Activation and [4 + 2] Annulation 1.00
Diastereoselective Aminoacylation of β-Methylstyrenes through Cooperative N-Heterocyclic Carbene and Photoredox Catalysis 1.00
Photocatalytic Access to Cyclopropanes Via Triplet Carbene Transfer from Acceptor-Acceptor Diazoalkanes 1.00
Copper-Catalyzed Trifunctionalization of Alkynes: One-Pot Assembly of Antifungal Benzofuro[3,2-d]pyrimidine-Containing Fused Heterocycles 1.00
Photoredox 1,4-Hydroxysulfonylation of Methylenecyclobutane via Carbon-Radical-Mediated β-Scission of Cyclobutane 1.00
Non-Kekulé Bi-Blatter Diradicals: Phenyl versus Electron-Deficient Heteroaromatic Linkers 1.00
Construction of the Dictamnine Framework via an Alkynylation/Cyclization Cascade Enabled by Quinolinone-Fused Cyclic Diaryliodonium Salts 0.88
Enantioselective Synthesis of Functionalized 2,2-Disubstituted Piperidines Enabled by Pd-Catalyzed Decarboxylative Asymmetric Allylic Alkylation 1.00
B(C6F5)3-Catalyzed (5 + 1)-Annulation of Enynamides with Trihydrosilanes en Route to the Synthesis of 1,4-Azasilines 1.00
Ten-Step Synthesis of Potent Anticancer Steroid Withanolide D 1.00
Unlocking C–N Bond Formation via a Two-Photon ETU-FRET Relay with Near-Infrared Light 1.00
Synthesis of C2-Iodoindoles via an Aromatic Finkelstein-Type Halide Exchange under Mild Conditions 0.88
Direct Synthesis of (Radio)difluoromethylated Selenides via Organic Photoredox Catalysis 1.00
Cobalt(III)-Catalyzed Selective β-C(sp2)–H Alkynylation of Acyclic Enamides with Bromoalkynes 1.00
Enantioselective Cobalt-Catalyzed C–H Activation and Annulation of Indole-3-carboxamides with Alkynes: Access to Axially Chiral γ-Carbolinones 1.00
Air-Stable and Luminescent Trityls via Methoxy Modification 1.00
Divergent Total Syntheses of (−)-Galanthamine, (−)-Narwedine, (−)-Lycoraminone and (−)-Lycoramine, and Formal Syntheses of (−)-Morphine and (−)-Codeine 1.00
Reactivity Investigation of Bis-Tetrazole Isomers Prepared through Dimroth Rearrangement 1.00
FBMN-Guided Discovery of Five Drimane Sesquiterpenoids with a Rearranged Carbon Skeleton from the Myxobacterium Nannocystis pusilla YN2B1 1.00
Synthesis of Functionalized Isoxazoline N-Oxides by Palladium-Catalyzed Cyclization of Nitro-Tethered Alkenes 1.00
Total Syntheses of Grandilodines A and C and Lapidilectam via a Photoredox-Catalyzed Decarboxylative (6 + 2) Radical Annulation 1.00
1,3-Dimethylimidazolidine-Mediated Acylation of Aryl Halides and Triflates via Photoredox/Nickel Dual Catalysis 1.00
Selective Bromination and Perbromination of 5,10,19-Trimesityl[20]smaragdyrin 1.00
Visible-Light-Induced Direct Methylation of Quinoxalin-2(1H)-ones with N,N,N′,N″,N″-Pentamethyldiethylenetriamine as the Methyl Source 1.00
Pd-Catalyzed C–H/C–C Cascade Activation for the Synthesis of γ-Lactams 1.00
Multicomponent Cascade Reactions and Skeletal Rearrangements of Isatins for the Synthesis of Functionalized Pyrrolo[1,2-c]quinazolin-5(6H)-ones 1.00
Photoredox-Catalyzed Defluorinative [4 + 2] Cycloaddition of α-Fluoro-β-keto Esters and Alkynes by Single Photosensitizer 1.00
Photoinduced Copper-Catalyzed Regiodivergent Tertiary Alkylation of α-Imino Carbonyls to Access Sterically Congested α- and β-Amino Acids 1.00
Copper-Mediated Dehydroamination of Primary Amines for Olefination 1.00
Visible Light-Induced [2+2+1] Cycloaddition of 1,6-Enones with α-Bromocarbonyls 1.00
Highly Regioselective and Stereoselective Haloazidation of Alkynes Mediated by a Halide-Bridged Charge-Transfer Complex 1.00
(CF3S)2C═S: Electrophilic Site at the Thiocarbonyl Sulfur for the Incorporation of Multiple CF3S Groups 1.00
Photoinduced Deoxygenation Reduction of Sulfoxides with HCl or HBr and Hydrocarbons 1.00
Photoinduced Palladium-Catalyzed Controllable Multicomponent Mono- or Di-C-glycosylation for the Construction of Alkyl C-Glycoconjugates 1.00
Visible-Light-Induced Acylsilylation of Nitrosoarenes for Synthesis of N-Arylhydroxamic Acid Silicon Esters 1.00
Construction of Chiral 1,2-Azaborines via Rhodium-Catalyzed Enantioselective Carbene N–H Bond Insertion 1.00
Oxone-Mediated Radical Trifunctionalization of Allyl Carboxylates via 1,2-Ester Migration 1.00
Phosphorothiolation of Benzylic C(sp3)–H via EnT-Mediated Radical–Radical Cross-Coupling 1.00
Copper-Catalyzed Enantioselective [1,3] O-to-C Rearrangement of Heteroaryl Alkyl Ethers 1.00
Harnessing Pnictogen and Chalcogen Bonding for Cross-Electrophile C–PIII Coupling of Chlorophosphines with Thianthrenium Salts 1.00
Fe(III)-Promoted ortho-Selective C–H Borylation of Aryl Selenoesters 1.00
Iodide-Induced Reductive Radical Generation from Sulfonyl Diazonium Salts: A Metal-Free Iodosulfonylation of Alkynes for (E)-β-Iodovinyl Sulfones Synthesis 1.00
(3 + 2) Annulation of Cyclopropanone Acetal with Silyl Enol Ether toward the Synthesis of Polysubstituted Cyclopentanones 1.00
How Far Can Trinitromethyl Substitution Be Pushed on a Single 1,2,3-Triazole Ring? 0.20
Chiral Phosphoric Acid and BF3·THF Relay Catalytic System Enables a Formal Asymmetric Aza-Baeyer–Villiger Rearrangement 1.00
Radical-Polar Crossover Enabled Photoredox 1,2-Carbosulfinylation of Alkenes with N-Sulfinyltritylamine 1.00
Copper-Catalyzed Asymmetric Allyl Addition of Imines with Allenylsilanes 1.00
Direct α-C–H Alkylation of Alcohols with Alkenes 1.00
Photoreductive Coupling of Unactivated Ketones and Alkenes via Kinetic Suppression of Ketyl Radical Overreduction 1.00
Tf2O-Mediated Phospha-Michael Addition to Unactivated α,β-Unsaturated Amides 1.00
Practical Post-Functionalizable Iodosulfonylation of Allenes for Integrating Multifunctional Molecules 1.00
Switchable Access to Quinolines and Isoquinolines via the Diverse Behavior of Transient Directing Groups 1.00
Gold-Catalyzed Reactions of o-Alkynylarylaldehydes with Alkenes for the Synthesis of 3,4-Dihydronaphthalene Derivatives 1.00
Ph3N as an Organocatalytic Donor for Photoactivation of Pyridinium-Masked Enols in the Formal [4 + 2] Cycloaddition with Unactivated Olefins 1.00
Unlocking Oxidative Cross-Coupling between Four Nucleophiles: Synthesis of Spiropyrrolo[2,1-a]isoquinolines 1.00
Modular One-Step Three-Component Synthesis of Vinyl Ethers by Benzoquinone Trapping of Vinyl Radicals 1.00
Regioselective Allylic Aminoalkylation Enabled by Dual Chromium/Photoredox Catalysis 1.00
Access to Five-Membered Silacycles via Pd-Catalyzed Heck-Type Coupling with Arylthianthrenium Salts 1.00
Kinetic Resolution of Unprotected BINOLs via Lewis Base-Catalyzed O-Boc Protection 1.00
Cu-Catalyzed Highly Selective Ritter-Type Reaction of Enaminonitriles with Cycloketoxime Esters: A Direct Route to Diverse α-Tertiary Amines 1.00
KOtBu-Promoted Synthesis of N-Triazolyl Alkylamide Derivatives 1.00
Microdroplets Catalyze C(sp2)–H Nitration Reactions 1.00
Asymmetric Allylation/Retro-Claisen Cascade Reaction of 1,3-Diketones and 1-Hydroxyallylphenols/Aniline Catalyzed by an Iridium Complex 1.00
DBU-Mediated Diastereoselective C3-Quaternary Alkylation of Cyclic Dipeptides 1.00
Synthesis of (E)-Silyl-Acrylates via Ruthenium-Catalyzed Selective Dehydrogenative Si–H/C–H Silylation of Acrylates 1.00
Copper-Catalyzed Stereoselective Synthesis of Fluorinated 1,3-Dienes via Sequential Iodine–Fluorine Elimination 1.00
Copper-Catalyzed Three-Component Radical 1,2-Carboazidation of 1,3-Dienes 1.00
Divergent Synthesis of Highly Functional 3-Trifluoromethylated Dihydropyrroles and Pyrroles via 6π-Photocyclization 1.00
Biomimetic Total Synthesis of Dispirocochlearoids A–C and Related Ganoderma Meroterpenoid Dimers 1.00
Rhodium-Catalyzed Regioselective C–H Amidation of Benzaldehydes with Dioxazolones: Weakly Coordinating Aldehyde as a Traceless Directing Group 1.00
Assembly of Indolo[2,1-a]isoquinolines via a C–H Oxidation/Carbene Insertion Cascade 1.00
NiCl2/Hdipm-Catalyzed 2-OH-Selective Alkylation of Glycoside trans-Diols 1.00
Electrochemical Nickel-Catalyzed Selective Defluorination for the Synthesis of α-Fluoroarylacetic Acid Derivatives 1.00
Modular Synthesis of Heptagon-Embedded Polyarenes by Double Cyclizations with Pyrones-Derived Aryliodonium Salts 1.00
Strain-Release-Driven 1,3-Halo-hydroxylamination of Bicyclo[1.1.0]butanes Enabled by Anomeric Amide Reagents 1.00
Copper-Mediated Oxidative Chloro- and Bromodifluoromethylation of Aliphatic Alcohols 1.00
Heterocyclic Tridentate Ligands for Effective Alkyne Metathesis 1.00
KF and Diaryl Iodide Salt-Mediated Ring Opening of Silacyclobutanes with Carbon Disulfide and Amines to Generate 3-(Fluorosilyl)propyl Dithiocarbamates 1.00
Photoinduced α-Amino Alkylation of Heterocyclic Compounds via Catalytic Electron Donor–Acceptor Complexes 1.00
Diversity-Oriented Synthesis of Azepinoindoles through sp3 C–H Functionalization and Skeletal Remodeling 1.00
Aromatization-Driven C–C Bond Cleavage of Unstrained Ketone Access to Vinyl Sulfones 1.00
Copper-Catalyzed Sonogashira-Type Cross-Coupling of Trifluoroalkyl Bromides with Alkynes 1.00
Photoredox/Brønsted Acid-Catalyzed Asymmetric Difluoroalkylation/Rearrangement of Alkenylfurans 1.00
Visible-Light-Driven B-to-C Atom Swap: Scalable Skeletal Editing Access to Benzimidazoles from Diazaborines 1.00
Copper-Catalyzed Radical Halocyclization of N-4-Pentenamides: Synthesis of Chloro- and Bromo-Substituted γ-Lactams 0.83
Ligand-Promoted Palladium-Catalyzed [4 + 4] Cycloaddition Affording Benzo[d]isothiazole 1,1-Dioxide-Fused Chiral Eight-Membered N-Heterocycles 1.00
Copper-Catalyzed Selective N-Sulfenylation of Tryptophan-Containing Peptides 1.00
Red-Light-Driven Recyclable mpg-C3N4-Catalyzed Minisci Reaction: Access to Heterocycle-Substituted Bicyclo[1.1.1]pentanes 1.00
Accessing Dihydroazepines and Cyclopentanes from Enynyl Ketones 1.00
Synthesis of Carborane-Functionalized Macrocycles: Bond-Angle-Modulated Cavities and Cation-Mediated Assembly 1.00
Synthesis of (Hetero)aryl Fused 4H-Quinolizin-4-ones from N-Ts Substituted (Hetero)arylamides and Pyridotriazoles 1.00
Photoinduced Lanthanum Catalysis: C–H Activation and Spirocyclization 1.00
Redox-Neutral Radical Annulation of Challenging Alkynes with Aryl Sulfoxonium Ylides for 1-Naphthol Synthesis 1.00
Photoredox-Catalyzed Strain-Release-Driven Aminopyridylation of Bicyclo[1.1.0]butanes with N-Aminopyridinium Ylides 0.89
Copper/N-Heterocyclic Carbene Cooperatively Catalyzed Remote Asymmetric ε-Alkylation of Yne-Thiophene Esters with Enals 1.00
Transient Directing Group Enabled Nickel-Catalyzed Satoh–Miura Annulation of Free Benzylamines with Alkynes 1.00
α-Selective Ring-Opening of Bicyclo[1.1.0]butanes to Access Spirocyclobutyl Lactams 1.00
Organoiodine-Catalyzed Desymmetric Fluorolactonization of α,α-Diallylcarboxylic Acids to Access α-Quaternary Fluorinated Lactones 1.00
Assembly of α-Aryl Sulfones and Allyl Sulfones and Their Amide Analogues via Copper-Catalyzed Coupling Reactions 1.00
Zn(II)-Catalyzed Isomerization/Asymmetric [3+2] Cycloaddition of 3-Butynoyl Pyrazole with Nitrones: Subsequent Exocyclic Olefin Isomerization and Capture 1.00
Copper/Nitroxyl-Catalyzed Oxidative Coupling of Methanol and Amines to Formamides 1.00
Visible Light-Mediated Thia-Paternò–Büchi Reaction of Indoles through Energy Transfer: Synthesis of Thietane-Fused Polycyclic Indolines 1.00
Asymmetric Electrooxidation of Indoles: Mechanistic Insights from an Enantioselective Bromoradical Addition Pathway 1.00
Chemo-, Regio- and Diastereoselective Synthesis of Azaspiro Tetra-/Pentacyclic Scaffolds with Anticancer Activity 1.00
Photocatalytic Decarboxylative Hydroalkylation of Alkynes and Alkenes 1.00
Serendipitous Assembly of Chiral Face-Rotating Molecular Boxes Directed by Non-Covalent Templation 1.00
Shuttle Hydrogen Atom Transfer for Hydro-Fluorosulfonylation of Haloalkynes without β-Scission 1.00
A Palladium-Catalyzed Cascade Process of 1,3-Enynes and Imines to Construct Multisubstituted Pyrrole Derivatives 1.00
Rhodium-Catalyzed O–H Insertion Reactions to (2-Diazo-1,1,3,3,3-pentafluoropropyl)phosphonate: A Convenient Route to Fluorinated β-Alkoxy Vinylphosphonates 0.25
Ti-Promoted Pd- and Fe-Catalyzed Regiodivergent C–H Arylation of Pyridines 1.00
Switchable Synthesis of Fused Dihydrobenzofuran or Spiro Benzoisoxazole Derivatives Featuring a Migrated or Merged Directing Group 1.00
Breaking the Scalability Barrier: Diversifiable Pd-Catalyzed Domino Reaction En Route to Dibenzo[b,d]azepines 0.94
Discovery and Biosynthesis of Cytotoxic Myroverols: A Phenalenone Scaffold Constructed by a Fungal Highly Reducing Polyketide Synthase and a Cytochrome P450 1.00
Rh(III)-Catalyzed Strain-Release-Enabled C–H Alkenylation/[4+1] Annulation of Benzamides with Alkylidenecyclobutanes 1.00
Visible-Light-Induced Defluorinative Giese Reaction of gem-Difluorides via the ConPET Process: A Route to tert-Alkyl Fluorides 1.00
Palladium-Catalyzed Intramolecular Hydroarylation of N-Alkynylindoles: Regioselective Synthesis of Indole-Annulated Sulfur/Phosphorus Heterocycles 1.00
Intramolecular Photocyclization of Enamide Linked 1,5-Dienes Enables Divergent Synthesis of Pyridin-2-one Derivatives 1.00
An Approach to 1,3,4-Oxadiazolidines via N,N′-Diborylated Hydrazine 1.00
Photoinitiated Aerobic α-C–H Oxidation of Amides Enabled by a Cerium(IV)-Nitrate LMCT Pathway 1.00
Photocatalytic Hydro-Fluorosulfonylation of Thioalkynes via Shuttle HAT 1.00
Enantioselective Access to Lactam-Fused Eight-Membered Bridged Biaryls via N-Heterocyclic Carbene-Catalyzed [5 + 3]-Domino Annulation 1.00
Nickel-Catalyzed Reductive Alkylation and Arylation of Arylallylamines via C–N Bond Cleavage 1.00
Lewis Base-Catalyzed Sequential [2 + 3]/[4 + 4] Annulations of α-Allylic Allenoates and Aldimine Esters: Construction of Functionalized Pyrrole-Fused Eight-Membered O-Heterocycles 1.00
Unlocking a Grignard Cascade: Three-Component Access to Complex Polycyclic Architectures from Quinolines 1.00
Palladium-Catalyzed Decarboxylative (3 + 3) Coupling Cyclization toward Diverse Fully Substituted Unsaturated Glutarimides 1.00
Phosphine-Catalyzed Allylic Fluorides Addition to gem-Difluoroalkenes 1.00
Single-Atom Skeletal Editing for One-Step Construction of 1,2,3-Triazine N-Oxide from Pyrimidine via C to N→O Transmutation 1.00
Pd-Catalyzed Asymmetric Allylic Alkylation of Carboxylic Acids for the Synthesis of Chiral Butenolidyl Ester Prodrugs and Peptide–Drug Conjugates 1.00
Solvent-Free Mechanochemistry Overcomes the Low Solubility of Inorganic Silver Fluorides in the Construction of C–F and S–F Bonds 1.00
Asymmetric Gold-Redox Catalysis in Cyclobutanol Ring Expansion toward the Formation of Quaternary Carbon Chiral Center with Hemilabile P,N-Ligand 0.40
Copper-Mediated Photoinduced Trifluoromethylation of Arylsulfonium Salts with Yagupolskii–Umemoto Reagent 0.80
Photoinduced Radical-Polar Crossover Cyclization for the Synthesis of α-Exo-Alkenyl γ-Lactones 1.00
Palladium-Catalyzed Diastereoselective Imidoylative Arylation/Carbamoylation of Conjugated 1,3-Enynes 1.00
Direct Assembly of Privileged α-CF3 Allylamines via Photoinduced Pd-Catalyzed C–H Aminoalkylation of Alkenes 1.00
Solvent-Tuned Photocatalytic (Phenylsulfonyl)difluoromethylation of Anilines: Selectivity and Postfunctionalization 1.00
Mechanistic Insights into Aerobic C(sp3)–H Hydroxylation: A Catalytic Reaction or Not 1.00
An Orthogonally Functionalizable Tetrazine Building Block for Dual-Conjugated Bioorthogonal Probes 1.00
Nickel-Catalyzed Desulfurizative Sonogashira Cross-Coupling of Terminal Alkynes with Alkenylsulfonium Salts 1.00
A Synthetic Approach to Diverse Indole/Oxindole-Annulated S-Heterocycles 1.00
Hypervalent Iodine(III) Carboxylates Enable Direct Radiosynthesis of 18F-Labeled Aliphatic Sulfonyl Fluorides 1.00
Copper-Catalyzed (5+1) Annulation of Imidazolidines with Cyclopropenes: Synthesis of Functionalized 2-Vinylpiperazines 1.00
Enantioselective Synthesis of Spiro-bis-N-heterocyclic Lactams via Formal (3+2) Cycloaddition of 3-Methylene Isoindolinones with C3-Substituted 2-Indolylmethanols 1.00
Copper-Catalyzed Sulfinylation of Boronic Acids with Sulfinates 1.00
Divergent Annulation of Isoindolinone-Derived Propargyl Alcohols for the peri-Selective Synthesis of Spirofuran-Isoindolinones and Furanylisoindolinones 1.00
Synthesis of β-Amino-α-iminonitriles and α,β-Diiminonitriles Enabled by Lewis Acid-Catalyzed Double Isocyanide Insertion with Imines 1.00
Nickel-Catalyzed Quinoline Synthesis through Skeletal Editing Strategy Using Calcium Carbide as an Inorganic C2 Source 1.00
Visible-Light-Driven C(sp3)–H Bond Carboxylation of Benzyl Amines with CO2 for the Synthesis of α-Amino Acids 1.00
Photoinduced Multicomponent Sulfonylsulfination of Alkenes via Aromatization-Driven Deconstructive and Radical-Polar Crossover Cyclization Strategies 1.00
Chemoselective Methionine Bioconjugation with Hydroxylamine Esters for Peptide/Protein Modifications 1.00
Halogen Atom Transfer (XAT)-Enabled Transition-Metal-Free Radical Annulation for the Construction of Phenanthrene-Derived Polycyclic Aromatic Hydrocarbons (PAHs) 1.00
Photoredox-Mediated C–N Bond Cleavage Enables Synthesis of Tetra-Substituted Olefins via Reductive Radical-Polar Crossover 1.00
Catalyst-Free [3 + 2] Cycloaddition of Benzimidazole Esters and Quinone Esters: Divergent Synthesis of N-Heterocycles 1.00
One-Pot Iodination and Giese Addition of Glycosyl Esters for the Synthesis of C-Alkyl Glycosides 1.00
Atroposelective Cobalt-Catalyzed Decarbonylative Transannulation of Phthalimides and Alkynes 1.00
Regioselective Radical 1,4-Difunctionalization of 1,3-Cyclohexadiene via NHC Catalysis 1.00
Photocatalyzed Nitrene Insertion into C–O Bonds: Access to Benzisoxazoline-3-ones 1.00
β-Sulfinimidoyl Esters as Sulfenamide Anion Precursors for Accessing Aza-Sulfur Stereogenic Centers 1.00
NHC-Catalyzed Access to Benzoxazepinones via Aromatization-Driven Rearrangement 1.00
Copper-Catalyzed Divergent C–S Bond Cleavage of Vinylsulfonium Salts: Controllable Phosphoryloxylation and Phosphinoylation 1.00
Copper-Catalyzed Radical-Triggered Annulation–Halocyanomethylation Reaction of Alkynyl-Bearing Bicyclo[1.1.0]butanes (BCBs) Leading to Spirocyclobutyl Quinolinones 1.00
Electrophotochemical Ce-Catalyzed Radical Truce–Smiles Rearrangement of Cycloalkanols 1.00
Ag2O/TBAI Initiated Nucleophilic Difluoromethylation of Carbonyl Compounds with Me3SiCF2H 1.00
Formal Reductive Amination of Carboxylic Acids via Iron-Catalyzed Photoredox Decarboxylative α-Aminomethylation 1.00
Electrochemical Cross-Coupling of P(O)-H with Thioesters: Green Synthesis of Phosphorothioates 1.00
Glycosyl Radical-Based C–H Glycosylation of Coumarins Enabled by Photocatalysis 1.00
Intramolecular Dearomative [2 + 2] Cycloaddition of (Hetero)arenes via Energy Transfer Catalysis: Exploration of Divergent Three-Dimensional Skeleton Editing 1.00
NHC-Catalyzed Synthesis of 3,5-Disubstituted 1,2,4-Oxadiazoles from Amidoximes and Aldehydes 1.00
Continuous-Flow Electrochemistry Enables 1,2-Arylheteroarylation of Alkenes 1.00
Photoinduced Pd-Catalyzed Alkylvinylation of Alkenes via C–H Bond Elaboration 1.00
Condition-Regulated Regiodivergent Synthesis of Biaryl Sulfones via Sulfonylation of Diaryl λ3-Bromanes and Chloranes 1.00
Access to Conjugated Dienes and Cyclic Allenes via a Diazo-Dithiane Rearrangement Cascade 1.00
Base-Promoted Azinium-N-imines and Thioamide Dimeric Annulation for the Tunable Synthesis of 1,2,4-Triazole and Polycyclic Indolylhydroquinoline Skeletons 1.00
Assembly of Nitrated Isoxazoles via a Multicomponent Cascade Reaction Using Benzoxathiazine-2,2-dioxides as C1 Synthons 1.00
Visible-Light-Induced Regioselective Thioesterification/Thiocyanation of Unactivated Alkenes Enabled by Spiro-NHC-Ir(III) Catalysis 1.00
Synthesis of 5-Aminooxazoles and Zwitterionic Fused Imidazolones by I2-Mediated C–H Amination 1.00
Photocatalytic Cascade Reaction of Allylamines for the Synthesis of Ester-Containing Imidazolines and Oxazolidines 1.00
Asymmetric Synthesis of 2-Benzyl-2-arylindolin-3-ones by Iron-Catalyzed Reductive Benzylation of 2-Aryl-3H-indole-3-ones 1.00
Electrochemical N–H Phosphorodithiolation of Sulfoximines with P4S10 and Alcohols 1.00
Copper-Catalyzed Dehydrogenative Cyclization: A Direct Route to Oxazoles from Readily Available Ketones and Amines 1.00
Photocatalyzed Dearomative [2 + 2] Cycloaddition of Indoles with Alkynes to Access Cyclobutene-Fused Indolines 1.00
Syntheses of Quaternary Carboxylic Acid Derivatives via a Photo-Wolff Rearrangement/Pd Catalysis Sequence 1.00
Pd-Catalyzed Fluorocarbonylation of Iodoarenes with Difluoromethyl Benzoates 1.00
Stereoselective Synthesis of 2-Deoxyglycosides: An Efficient Protocol for Alcohol Deoxygenation 1.00
Enzymatic Enantioselective Protonation Regulated by an Artificial Enzyme Harboring an In Situ-Biosynthesized S-(3-Aminophenyl)-cysteine 1.00
Ligand-Enabled Palladium-Catalyzed Asymmetric Synthesis of Indole-Fused Chiral Eight-Membered N-Heterocycles via [4 + 4] Cycloaddition 1.00
Persistent Radical Cation Catalysis Enables Radical-Polar Crossover Cycloisomerization of Unactivated Alkenes to CF3-Heterocycles 1.00
Ruthenium-Catalyzed C(sp2)–H Activation Using Pyridine and Imidazopyridine as Directing Groups for Selective Silylation 0.86
Visible-Light-Induced Organobismuth(III)-Initiated Halogen-Atom Transfer for the Alkylation of Heterocycles with Unactivated Alkyl Iodides 1.00
NHC Precursor Catalyzed C3-Chloromethylation of Oxindole with Dichloromethane as C1 Synthon 0.94
Iron-Catalyzed C(sp3)–H Amination Enabled by Visible-Light β-Homolysis 1.00
Dual-Co/Ni-Catalyzed Radical Hydroarylation of 1,3-Enynes: Selective Access to Tetrasubstituted Allenes 1.00
Phosphine-Catalyzed [3 + 2] and [2 + 4] Annulations of Ketenimines with Electron-Deficient Alkenes or α,β-Unsaturated Carbonyl Compounds 1.00
Development of Ts-Protected Selenocysteine for Sec-Conjugate Arylation via a Reductive Coupling Approach 1.00
Decarboxylative Bromination of Aliphatic Carboxylic Acids via Visible Light-Driven Proton-Coupled Electron Transfer 1.00
Stereodivergent α-Addition of Yne-allylic Esters by the Z/E-Selective Multicomponent Reaction 1.00
Scalable Synthesis of a Dual TLR7/8 Agonist via Highly Selective N2-Alkylation of 1H-Pyrazolo[4,3-d]pyrimidine 0.43
Rapid Access to Selenium-Containing Heterocycles Exhibiting Diverse Antimicrobial Activity via BF3·Et2O-Mediated [3 + 3] Annulation 1.00
Fluoride-Catalyzed [2 + 2] Cycloadditions of Allenoates: Access to Azetidine and Cyclobutene Scaffolds 1.00
Modular Amide Synthesis via Dual C–O and N–O Bond Cleavage: Palladium-Catalyzed Deoxygenative Carbonylation of Benzyl Alcohols with Nitroarenes 1.00
Asymmetric Synthesis of MK-7845, an Investigational Treatment for COVID-19 0.05
Enantioselective Desymmetrization of Sulfonimidamides with 2-Bromoenals via Asymmetric N-Heterocyclic Carbene Catalysis 1.00
Electricity-Induced Radical 7-endo-Cyclization from Aryldiazonium Salts: Synthesis of Trifluoromethylated Azepines 1.00
Aryl Carboxylic Acids as Structure-Tunable HAT Agents for Photochemical Site-Selective C(sp3)–H gem-Difluoroallylation of Amides 1.00
Visible-Light-Promoted Metal-Free Three-Component Reaction for the Synthesis of Sulfonated 4-Amino-chromans, 4-Amino-tetrahydroquinolines, and 5-Amino-dihydrobenzo[b]oxepines 1.00
Ligand-Promoted Copper-Catalyzed Radical Relay for Alkyl-Alkynylation of Alkenes 1.00
Synthesis of Dihydroisoquinolone-Fused Cyclobutanes via Tandem Palladium-Mediated Olefin Migration and Photosensitized [2 + 2] Cycloaddition 1.00
Nickel-Catalyzed Regioselective Markovnikov Hydrosilylation of Vinylarenes via Hydrogen Atom Transfer 1.00
Photoredox Fe-Catalyzed Truce–Smiles Rearrangement of N-Arylsulfonyl Acrylamides with Aliphatic Carboxylic Acids 1.00
Catalytic Synergy Drives Triazole-Directed ortho-C(sp2)–H Functionalization 1.00
Carbene-Catalyzed Esterification for the Synthesis of Inherently Chiral Saddle-Shaped Eight-Membered Lactones 1.00
Catalytic Asymmetric Synthesis of Chiral Oxaspirolactones and Tetrahydropyrans via Ammonium-Catalyzed Reactions of Vinyl Ketones and Nitroalcohols 1.00
Rh(III)-Catalyzed Regioselective B(4)–H Alkylation of o-Carboranes with Alkenes 1.00
Organocatalytic syn-Selective [3 + 2]/[4 + 2] Annulations of (E)-Pyrazoloneyldiene Oxindole 1.00
Cobalt-Catalyzed Chemo-, Regio-, Diastereo-, and Enantioselective Cascade Coupling of 1,1-Disubstituted Allenes and Aldehydes 0.75
Nickel- and Lewis Acid-Catalyzed Intramolecular Iminocyanation of Alkenes via N(sp2)–CN Activation 1.00
Streamlined Assembly of Pyrimidinones via Wolff Rearrangement-Triggered [3 + 3] Cycloaddition of Alkynyl Diazoalkyl Ketones and 2-Aminoheteroarenes 1.00
Nonenzymatic Formation of Streptoindoles Reveals an Unexplored Chemical Space of Tryptamine-Derived Natural Products 1.00
Cooperative NHC and Photoredox Catalyzed Deaminative Acylation of Primary Amines via Isonitrile Formation 1.00
Rhodium-Catalyzed Atroposelective Hydroarylation of Alkynes with Biarylhemiboronic Esters for Biaryl Atropisomer Synthesis 1.00
Transition-Metal-Free Base-Promoted Divergent Synthesis of 5-Amide-1,2,3-triazole and 5-Imide-1,2,3-triazole Derivatives 1.00
Metal-Free Photoinduced Halogen-Atom Transfer: A Novel Approach for Tetracoordinate Boron Compound Synthesis and One-Carbon Homologation and Amination of Styrenes 1.00
Tungstate-Catalyzed Selective Oxidation of Naphthalenols to Afford Diverse Products under Mild Conditions 1.00
Self-Assembly of Macrocyclic Hosts with Kinetic Inertness 1.00
Benzophenone-Based Phenylogous Peptide Linkage via Friedel–Crafts Acylation 0.29
Rh-Catalyzed Asymmetric Hydrogenation of α-Aminomethyl Acrylates for Enantioselective Synthesis of Chiral β-Amino Propanoates 1.00
Three-Component Copper-Catalyzed 1,4-Carboamination of 1,3-Dienes 1.00
Palladium-Catalyzed ipso-Didefluoroannulation of Allylic gem-Difluorides with Salicylic Acids 1.00
Radical Sulfimidation via Visible-Light Photoredox Catalysis: N-Acyloxyamides as Bench-Stable Nitrene Surrogates 1.00
Sarcglabates A/B, Aromatized Pentanor Lindenane Sesquiterpenoid Dimers from Sarcandra glabra 1.00
Tandem Palladium-Catalyzed C–H Activation of Biaryls and Ring Opening of Benzofurans: Access to 2-(9-Phenanthryl)phenol Derivatives 1.00
HPLC–UV-Guided Discovery of Eurotamines A–F: Six Pairs of Isoquinoline Derivative Enantiomers from Marine-Derived Fungus Eurotium sp. SCSIO F452 0.92
A Macrocyclic Arene Derived from Pagoda[4]arene: Cavity Reshaping, Complexation with Neutral Guests, and CPL Property 1.00
Development of Ir(III) Photocatalysts Enabling Blue-Light-Induced Hydrocarboxylation of Unactivated Alkenes and Arenes 1.00
Anti-inflammatory Alkaloids, Papaversomni A, a Hexacyclic-Membered Morphinan, and Two Pairs of E/Z Nonseparable Stereoisomers, Papaversomni C and Sinoracutinal, from Papaver somniferum 1.00
Palladium-Catalyzed Cyclization of N-(2-Iodoaryl)-N-methylbenzenesulfonamide with Aryl Iodides to Access Phenanthridine Derivatives 1.00
Synthesis and Two-Dimensional Chiral Self-Assembly of Oxygen-Incorporated Dibenzo[hi,st]ovalene 0.07
Regioselective Synthesis of Spiro-Ganoderma Meroterpenoid Motifs via Lewis Acid-Catalyzed Divergent Cycloadditions: [3 + 2] and Water Accelerated [5 + 2] Annulations 1.00
DeepSAT-Driven Discovery of Pimarane Diterpenoids from Arthrinium arundinis with Ulcerative Colitis Inhibitory Activity via NF-κB/MAPK Pathways 1.00
Electrocatalytic Synthesis of Aryl-Propargyl Alcohols from Arylacetylenes with N,N-Dimethylacetamide and Water 0.06
Enantioselective Friedel–Crafts Alkylation of Aniline Derivatives with 4-Arylidenepyrrolidine-2,3-diones Catalyzed by Chiral Cu(II) Complex Bearing Binaphthyl-Proline-Imidazoline-type Chiral Ligands 1.00
Tandem Nitro Reduction and Amide Condensation for the On-DNA Synthesis of Natural Product-Inspired Skeletons 1.00
Palladium-Catalyzed Ring Opening of Vinyl Oxetanes Enables Asymmetric Dearomative [6 + 2] Cycloaddition of 3-Nitroindoles to Access Indoline-Fused Oxa-Eight-Membered Rings 1.00
Ring-Opening Reconstruction of Indoles Enabled by C–N Bond Cleavage: Synthesis of Benzo[c]pyrazolo[3,4-h][2,6]naphthyridine Derivatives 1.00
Three-Component Cycloaddition Reaction of Aryne, Acrylate, and Imine Derivatives: Divergent Synthesis of Hexahydropyrrolo[1,2-a]quinolines and 1,4-Dihydroquinolines 1.00
Synthesis of Chromeno[4,3-d][1,3]oxazines through Copper(I)-Catalyzed Cycloisomerization of 1,11-Enynes 1.00
Three-Component Cyclization/Haloazidation of Bicyclo[1.1.0]butane-1-carboxamides: Construction of Halogenated Spiro[cyclobutane-1,3′-quinolin]-2′-one Derivatives 1.00
Sc(OTf)sub3/sub-Catalyzed Construction of Fused Bisindolylmethanes: Unified Access to 1,2- and 1,7-Linked Indole Frameworks 1.00
Chlorobactine A, a Dimeric Dichlorated Metabolite from Marine-Derived iStreptomyces thermolineatus/i NAK03196 1.00
Copper-Catalyzed Diastereoselective Defluoroborylation of Pentafluoroethyl Alkenes Using (pin)B–B(dan) 1.00
Chemodivergent Synthesis of Multiborylalkanes via Deoxygenative Polyborylation of Silyl Enol Ethers 1.00
Photoinduced Pd-Catalyzed Carbonylative Formal [2 + 2] Cycloaddition of Alkylarenes and Imines 0.90
Visible-Light-Induced Direct Photolysis of Phosphorus Iodide Salts for Difluoroalkylation of C(sp2)–H by an Intramolecular Charge-Transfer Complex 1.00
Visible-Light-Excited Lewis Acid Catalyzed Intermolecular [2σ + 3π] Photocycloadditions 1.00
Bis(sulfone) as Bifunctional Reagent for the Alkylarylation of Alkenes and Alkynes under Photoredox Conditions 1.00
Cobalt-Catalyzed Intramolecular Fluoroalkylative Carbonylation of Unactivated Alkenes 1.00
Enantioselective Ring-Opening of Cyclic Diaryliodoniums with 3-Hydroxy Benzo[d][1,2,3]triazin-4(3H)-ones: A 1,2-Difunctionalization Strategy 1.00
Synthesis of Densely Functionalized Pyrroles via Photoinduced C-Insertion into N-Alkylenamines: Sequential C(sp2)–H/C(sp3)–H Activation with Bromine Radicals 1.00
Rapid Alternating Polarity as an Approach for Electrocatalytic Synthesis of Remote meta-C–H Alkenylation 1.00
Palladium-Catalyzed Cross-Couplings of Aryl Thianthrenium Salts with N-Tosylhydrazones for the Synthesis of 1,1-Diarylalkenes 1.00
Complete Supramolecular Encapsulation of Paraquat for Detoxification 1.00
Catalytic Base-Induced Trifluoromethylation of Selenosulfonates and Beyond 1.00
Cobalt-Catalyzed Methylselenation of Boronic Reagents with PhSO2SeCH3 1.00
Synthesis of Bicyclo[n,3,0]alkanes and Aza-Bicyclo[n,3,0]alkanes by Phosphine-Mediated Domino Reaction of Enones with Morita–Baylis–Hillman (MBH) Carbonates 1.00
Synthesis of Oxindole Spiropyrrolidines Based on [1 + 1 + 1 + 2] Spiroannulation Featuring Release and Reuse of Me2NH 1.00
Visible-Light-Induced CdSeS/CdZnSe/ZnSe/ZnS Quantum-Dot-Catalyzed Three-Component Reaction for the Synthesis of α-(4-Pyridyl)benzylaniline Derivatives 1.00
Synthesis of α-Substituted β,γ-Unsaturated Cyclobutanecarboxamides via Palladium-Catalyzed Aminocarbonylation of Vinylcyclobutanols 0.25
Construction of Pyridine-Fused Azacorroles through Multicomponent-Coupling Strategy 0.75
Deaminative Functionalization of Olefins and Dienes with Katritzky Salts: A Highly Selective Route to Diverse Deuterium-Labeled Molecules 1.00
Electroreductive 1,4-Hydro(deutero)arylation of 1,3-Enynes Enabled by Terephthalonitrile: Entry to Trisubstituted Allenes 1.00
Rh-Catalyzed C–H Activation, [5 + 2] Cycloaddition/Oxidative for the Synthesis of Highly Functionalized Benzo[f]pyrazolo[1,5-a][1,3]diazepin-6-ones 1.00
Electrochemical Decyanative Carboxylation of Cyanoaromatics with CO2 Leading to Aryl Carboxylic Acids 1.00
Total Synthesis of (±)-Larutienine B and (±)-Melokhanine B, D, E, F, and H 1.00
Visible-Light-Mediated Cascade Construction of Polysubstituted Naphthalene Scaffolds from 2-Methylbenzophenones and (Trifluoromethyl)alkenes 1.00
Photocatalytic 1,4-Carbocarboxylation of 1,3-Enynes with CO2 1.00
Modular Iminophosphorane as Hydrogen Atom Transfer Catalyst for Selective C(spsup3/sup)–H Functionalization 1.00
Synthesis of Neokotalanol and Its Derivatives as Potent α-Glucosidase Inhibitors 0.78
Synthesis of 3-Alkenyl Isoquinolines through Redox-Neutral C–H Annulation of Oximes with Alkylacetylenes followed by Dehydrogenation 1.00
Asymmetric Synthesis of Benzofused N-Bridged [3.2.1] Skeletons via Bifunctional Phosphonium Salt-Catalyzed Annulation 1.00
Photoinduced and Thiophenolate Anion-Enabled Functionalization of Aryl Halides via Catalytic Electron Donor–Acceptor Complex 1.00
Synthesis of Dibenzo[a,c]phenazines through Brønsted Acid-Catalyzed Skeletal Editing of 2-Arylindoles with 1,2-Diaminoarenes 1.00
cis and trans Forms of Near-Infrared Diazaborepin Frameworks with Two Tetracoordinate Boron Atoms 1.00
Harnessing gem-Diboron Radicals: A Ni-Catalyzed Reductive Coupling Platform for Diverse sp3-Rich Molecular Architectures 1.00
Photocatalytic Ring-Opening/1,3-Peroxyesterification of Arylcyclopropanes with Carboxylic Acids and tert-Butyl Hydroperoxide 1.00
“Green” Oxidant (Oxygen) Mediated Synthesis of N-(2-(Methylsulfonyl)ethyl)amide Derivatives Using DMSO as a Dual Synthon and Solvent 1.00
Ruthenium-Catalyzed Selective C4 C–H Phosphorylation of Indoles and Mechanistic Insights 1.00
Unified Asymmetric Hydrogenation Enables Stereocontrolled Total Synthesis of Tacaman Alkaloids 1.00
Asymmetric Dearomatization of 3H-Indoles via Copper-Catalyzed Enantioselective [4 + 1] Spiroannulation with Vinyl Ethynylethylene Carbonates 1.00
Enantioselective Synthesis of 3-Iodo-4-arylcoumarinyl Atropisomers via Cu-Catalyzed Asymmetric Ring-Opening of Cyclic Hetero Diaryliodoniums 1.00
Dual-Copper-Catalyzed Enantioselective Decarboxylative [2 + 3] Cycloaddition of Ethynyl Cyclic Carbamates/Carbonates with 4-Hydroxycoumarins 1.00
Benzophenone[3]arene: Supramolecular Modulation of Semi-crystalline toward Crystalline Transformation 1.00
Organophotocatalytic Decarboxylative Allylation of Carboxylic Acids with Allylic Acetates 0.92
Humulupones A-F, Bitter Acid Derivatives from Humulus lupulus 1.00
Electro-Palladium-Catalyzed Asymmetric Allylic Benzylation with Electrophilic Benzylic Reagents 1.00
Oxidative Amination Ring Cleavage of Catechols for Muconic Acid Mononitriles 1.00
Photochemical Formal [4 + 2] Cycloaddition of α-Bromo Phenylsulfones and Acetophenones with Alkenes 1.00
Curved Nanographene Featuring Two sp3 Stereocenters via Oxidative Cyclodehydrogenation with Aryl Rearrangement 1.00
Construction of the Tetracyclic Core of Isoabietenin A 1.00
Photoinduced Copper-Catalyzed Radical Cascade Sonogashira-Type Coupling of Unsaturated Oxime Esters with Alkynes 1.00
Make it Double: [4]Cumulene Thermal Core Transformation and Chemical Reduction 0.07
Toward the Total Synthesis of Myrindole A: Assembly of Fully Functionalized Cyclohexenone 1.00
Chemoenzymatic Decarboxylative Bromination of Acetylenic Acids Using Vanadium-Dependent Chloroperoxidase 1.00
Organoelectrochemistry-Enabled Biomimetic Syntheses of Alstoscholarinoids A and B 1.00
Halophosphonium Salts-Mediated Photochemical C(sp3)–H Functionalization 1.00
Catalyst-Controlled Switchable Mono-/Di-C–H Arylation of Aromatic Amides with Arylsilanes 1.00
Intermolecular Double C–H Annulation via 1,4-Pd Migration: A Modular Strategy for Heteropolycycle Construction 1.00
Visible-Light-Induced Palladium-Mediated Allylic C–H Alkylation Reaction 1.00
Two Cationic Antiaromatic Free-Base Corroles 0.80
Diversifiable Total Synthesis of Pleurotin Natural Products through Alternative Endgame Strategies Enabling Unprecedented C7/C8-Axial Functionalization 1.00
Radical Addition-Induced Dearomative Spirocyclization/1,4-Alkyloximation of Unactivated Arenes 1.00
Aryl-Alkenylation and Aryl-Iodination of Strained C–C σ Bonds via Palladium Photoredox Catalysis 1.00
Modular Access to Sulfondiimidoyl Fluorides by NaH-Mediated Fluorination of Sulfenamides 1.00
A Silicon-Doped Nanographenic Bowl for Supramolecular Assembly with Fullerenes 1.00
Visible-Light-Driven [2+2] Cycloaddition of Coumarins with Diverse Olefins Using a 4CzIPN Photosensitizer: Application to the Total Synthesis of (±)-Lindleyanin 1.00
Enantioselective N–H Insertion of Sulfonamides: Access to Chiral α-Aminoesters 1.00
Bioinspired One-Step Oxidative Cleavage of Paxilline Enables Rapid Generation of Indole Diterpenoid Derivatives with Antibiofilm Activity 1.00
Multicomponent Synthesis of Isoquinuclidines via Pd-Catalyzed Selective Dechlorination 0.75
Palladium-Catalyzed Suzuki–Miyaura Couplings of Glycal Boronates with Aryl Thianthrenium Salts for the Synthesis of C-Aryl Glycals 1.00
Distahlianins A–C: Architecturally Diverse Cadinane-Type Sesquiterpenoid Dimers from Stahlianthus involucratus 1.00
Asymmetric Dearomative Hydrofunctionalization of Enyne-Tethered Biaryls Via Pd(0)/Chiral Phosphoric Acid Co-Catalysis 1.00
The Application of Trifluoroacetic Acid in the Minisci Silylation of Heteroarenes 1.00
Minisci-Type Reaction Enabled by Copper-Mediated Radical-Coupling: Photocatalytic C2-Selective C–H Bis(trifluoromethyl)carbinolation of Quinolines 1.00
Synthesis of a Phosphate-Bridged Photoaffinity Labeling Probe via Transesterification of Phenols and Alcohols 1.00
Multicomponent Assembly of 1,2,3-Dithiazole-5-thiones via Triple Sulfur Donor Integration 1.00
Copper-Catalyzed Remote C(sp3)-H Sulfoximination and Silylation of N-Fluorocarboxamides 1.00
Synthesis of α-Trifluoromethyl Pyrroles by Formal [3 + 2] Cycloaddition of Vinyl Carbenes and Nitriles 1.00
Visible-Light-Mediated Three-Component Minisci-Type Reaction of 4-Cyanopyridines 1.00
Enantioselective Synthesis of N-Cyclopentenyl Sulfoximines via the Catalytic Asymmetric Aza-Piancatelli Reaction 1.00
A Cupin Epoxidase Catalyzes Epoxycyclohexenone Formation in Fungal Meroterpenoid Biosynthesis 1.00
Stereodivergent 3,4-Hydroalkoxylation of 1,3-Dienes Via Dual Photo and Copper Catalysis 1.00
Umpolung Approach for the α-Alkylation of Benzylic Amines Enabled by Superelectron Donors 0.83
Diastereoselective Iron-Catalyzed [4 + 1] Cycloadditions of Imines with Sulfoxonium Ylides Enable Modular Synthesis of Oxazolidin-2-ones: O- versus N-Nucleophilic Attack 0.93
Copper-Catalyzed Coupling of N-Acyl-N′-Substituted Hydrazines with (Hetero)aryl Chlorides/Bromides 1.00
Synthesis of a Face-to-Face Porphyrin Nanoring 0.46
Visible Light-Mediated Syntheses of γ-CF3 Pyridines via 1,2-Radical Migration 1.00
1,3,5-Triazine-Mediated Electrochemical Carboxylation of Aryl Thianthrenium Salts with CO2 1.00
Conformationally Preorganized Cage Enables Enhanced Anion Binding in Water 1.00
Thioesterification of Polyfluoroarenes via Copper-Catalyzed Radical Cross-Coupling with K2S and Aldehydes in Water 1.00
Visible-Light-Induced Cascade Annulation of N-Cyanamide Alkenes with Unsaturated α-Halogenocarbonyls 1.00
Regioselective Dual Gold/Silver-Catalyzed C3–H Alkynylation of Triazolopyridazines 1.00
Enantioselective Total Synthesis of (+)-Lucidumone via Organocatalytic Double Michael Addition 1.00
Photoredox/Cobalt Cooperative Catalysis for Cycloisomerization of 1,6-Enynes 1.00
Decarboxylative Pyrazolylation of Aryl Carboxylic Acids via Synergetic Organic-Photoredox and Copper Catalysis 1.00
Isoxazoles to Multisubstituted Thiazoles via an Ammonium Iodide-Catalyzed Formal [3+2] Cycloaddition Reaction 1.00
Photoredox-Catalyzed Dearomatization of Indoles with Amines: An Approach to Highly Strained Polycyclic Indolines 1.00
Integration of SuFEx and Sonogashira Cross-Coupling for the Synthesis of Structurally Diverse Aryl Acetylenes on DNA 1.00
Enantioselective Construction of Fused N-Heterocycles via Sequential Annulation and Catalytic Transfer Hydrogenation 1.00
Photosensitized Radical-Mediated 1,n-Trifluoromethylthioamination of Alkenes with Bifunctional Benzophenonoxime S-(Trifluoromethyl) Thiocarbonate 1.00
Scalable Solvent-Free Synthesis of a Linear Heteroaromatic Trimer with Crystallization-Induced Phosphorescence 0.90
Visible Light-Driven Benzylic C(sp3)–H Carboxylation Enables Synthesis of 13C-Labeled (±)-α-Amino Acids with 13C-Formate 1.00
Stereoselective Synthesis of α-Aminophosphonates and Their Derivatives via Asymmetric α-Azidation of the CAMDOL-Derived Phosphonates 1.00
Light-Promoted C(sp3)–H Functionalization: Alkyl Amines as C2 Synthons in Formal [3+2] Cycloaddition with N-Imino(iso)quinolinium Ylides 1.00
A Design for Achieving Robustness in Molecular Machines Based on Self-Assembled Pyrene Cavitands 0.70
Base-Promoted Synthesis of Triazenes via Formal Substitution of Arylazo Sulfones with Amines 1.00
NaBr-Mediated Electrochemical Hydration of Alkenes: A Minimalist Synthesis of Anti-Markovnikov Alcohol 1.00
Ni-Catalyzed and Pentafluorobenzoate-Leaving-Group-Enabled Stereoselective C-Aryl Glycosylation 1.00
Metal-Free, Regiodivergent N-Alkylation of 1H-Indazoles Enabled by Brønsted Acid Catalysis 1.00
C2-Benzylic C(sp3)–H Alkylation of Indoles Enabled by Photoinduced, EDA-Complex-Mediated Radical–Radical Cross-Coupling 1.00
Palladium-Catalyzed Asymmetric Aminomethylative Pyridonation of Conjugated Dienes 1.00
Organophotoredox Cascade Cyclization for the Synthesis of Silyl/Fluoroalkylated Tetracyclic Pyrrolizidinediones 1.00
Calix[n]azanediyldibenzoate: Intramolecular Hydrogen Bond-Assisted Synthesis, Acidichromism, and Oriented Self-Assembly 1.00
NiII and CuII Complexes of 5-Oxa-, 5-Sulfa-, 5-Selena-, and 5-Telluracorroles 0.88
Iodine-Promoted Ring-Opening α,β-Difunctionalization of Cyclopropanols with Enaminones: A Selective Route to 2,4-Diacylpyrroles 0.90
Iron(III)-Catalyzed Methanesulfonic-Acid-Mediated [3 + 2 + 1C] Annulation of Enaminones with 1,3-Dioxolane: Access to 2-Hydroxy-1,2-dihydropyridines 1.00
Photocatalyst-Free Visible-Light-Induced Decarbonylation/Truce–Smiles Rearrangement Cascade to Access 2-Aminobenzophenones 1.00
Structurally Flexible (Thiazol-2-ylidene)Pd(Allyl)Cl Complexes for Suzuki–Miyaura Cross-Coupling of Aryl Halides and Amides 0.86
Photocatalytic Synthesis of 1,2-Sulfinate-Sulfonate Esters by Four-Component Radical-Polar Crossover Cyclization 1.00
Manganese-Catalyzed Asymmetric Hydrogenation of Multi-Nitrogen Heteroaromatic Compounds 1.00
Transition Metal-Free γ-C(sp3)–H Functionalization of Enaminones for Methylene 1,2-Dihydropyridine Synthesis and Application in Fused Tricyclic Pyrido[1,2-a]indole Construction 1.00
Organic Photoredox Catalytic Functionalization of Alkynones To Acess Heterocycles Containing 1,4-Dicarbonyl Structures and 3-Thioarylated Thioflavones 1.00
Palladium-Catalyzed Synthesis of Amino β-Lactones Using Aryl Amines and Alkenyl Carboxylic Acidss 1.00
Biomimetic Oxidation of Disulfides for the Synthesis of Sulfonyl Fluorides and Primary Sulfonamides Catalyzed by Copper/Lewis Acid 1.00
Palladium-Catalyzed Allylic C–F Bond Functionalization of Pentafluoroethyl Alkenes with Heteroatom Nucleophiles 1.00
Effects of π-Extended Aromatic Fragments on Tris(hexa-peri-hexabenzocoronenyl)methyl Radical and Cation: Synthesis, Radical Transformation, and Reactivity Insights 1.00
Cu-Catalyzed Desaturation-Relay Imidation of 2-Piperidones 1.00
Visible-Light-Driven C-3 Selenocyanation of Indoles with Elemental Selenium and TMSCN 1.00
Divergent Synthesis of gem-Difluoro-2-oxabicyclo[2.1.1]hexanes Enabled by 1,3-Oxygen Rearrangement 1.00
Iron-Catalyzed Photochemical Defluorinative Functionalization of Polyfluorinated Aromatics 1.00
Photocatalytic [4 + 1] Cycloaddition Access to Multisubstituted 2-Imino-2,5-dihydrofurans 1.00
Tunable Site Selectivity and Chemo- and Regioselectivity: Diversification of Indole Alkaloid Privileged Scaffolds Enabled by λ3-Iodane-Mediated Cross-Nucleophile Coupling Cascade 1.00
A Synthesis of 4-(Hydroxymethyl)-1H-isochromen-1-one Analogs by Hydroxyl Oxetane Rearrangement in Protonic Acids 1.00
Gold-Catalyzed Highly Regioselective Cage B(9)-H Alkylation of io/i-Carboranes with 1,6-Enynes 0.88
Visible-Light-Catalyzed Regioselective 1,4-Carbon/Carboxylation of 1,3-Enynes with Malonates and COsub2/sub toward 2,3-Allenoic Acids 1.00
Synthesis of Indole-Fused Bicyclo[3.1.1]heptanes through (3+3) Cycloaddition of 2-Indolylmethanols with Bicyclo[1.1.0]butanes 1.00
Photoinduced Amination of Endocyclic 1-Azaallyl Radicals 1.00
Iron-Catalyzed Radical Addition Reaction of Dehydroglycine with Aliphatic Carboxylic Acids 1.00
Oxidative Chloro- and Bromodifluoromethylation of Thiophenols 1.00
Visible-Light-Driven Photoredox-Catalyzed Radical Cyclization via a TEMPO-Intercepted Cascade: Regioselective and Access to Cyclopentene Skeletons 1.00
Synthesis of Nanographene-Fused Carbaporphyrin(2.1.0.1) and Its Organopalladium(II) Complex 1.00
Nickel-Catalyzed Carbonylative Cyclization of Bromodifluoroacetamides with Arylboronic Acids toward δ-Lactams 0.90
meta-Substituted Diaryliodonium Salts Enabled Aryne 1,2,4′-Trifunctionalization 1.00
Photo/Copper-Catalyzed Sulfinamidation of Arenes and Alkenes 1.00
Visible-Light-Induced sp3 C–H Functionalization of Alkyl Amines toward Tetrahydroquinoline Spiro[5.6] Compounds 1.00
Photoinduced EDA Complexes Enabled C3 (Hetero)arylation of Indoles Using Amine as a Transient Occupying Group 1.00
Photoinduced Asymmetric Dearomative Hydroalkylation of Electron-Deficient Indoles with Alkyltrifluoroborates 1.00
Cooperative Copper/Eosin Y-Catalyzed Photochemical Oxidative Coupling Reactions of Indolines for the Synthesis of 1,5′-Biindoles 1.00
Construction of Fused Polycyclic Skeletons via Palladium-Catalyzed Dearomatization of Naphthalenes and Benzenes 1.00
Asymmetric Total Synthesis of Leptosphin C 1.00
Chiral Phosphoric Acid-Catalyzed Asymmetric Doyle Indolization: Enantiodivergent Access to Indolizinylindoles 1.00
Late-Stage Pyridination via Pd-Catalyzed Transformation of Arylthianthrenium Salts 1.00
B2pin2-Enabled Nickel/Brønsted Acid Relay-Catalyzed Reductive [2+2+2] Cycloaddition: Facile Access to Unsymmetric Pentacyclic Pyridine Derivatives 1.00
Palladium-Catalyzed Denitrative Sulfoximination of Nitroarenes 1.00
Pillarureaarenes: Urea-Embedded Pillararenes for Amino Acid Derivative Recognition 0.89
Copper-Catalyzed Enantioselective Reduction of Biaryl Dialdehydes via Bora-Brook Rearrangement 1.00
Synthesis and Enantioselective Recognition of Chiral Macrocycles with Abundant Binding Sites 1.00
Radical 1,2-Boron Shift-Enabled Synthesis of β-Thioalkylboronic Esters from β-Boryl NHPI Esters 1.00
Strategic Leverage of β-OH Elimination for Catalytic Assembly of Alkylidenecyclopropanes 1.00
Oxygenative Amidation of Metal Carbynoids via Pd-Catalyzed Three-Component Reaction of Alcohols, Imines, and α-Bromo Diazoacetates 1.00
Copper-Mediated C4–H Sulfonylation of Indoles via a Transient Directing Group Strategy 1.00
Synthesis of 2-Aminodihydrobenzofurans through Copper-Catalyzed iN/i-Alkenylation/[3,3]-Rearrangement of Aryloxyamines with Alkenyl Boronic Acids 1.00
Mild Cu-Catalyzed Nitrogen–Iodine Exchange Strategy for the Synthesis of Non-Symmetric iN/i,iN′/i-Bicarbazole Scaffolds Using Cyclic Iodoniums 1.00
Visible-Light-Driven Photocatalytic Cascade Multioxidation: A Route to α-Sulfinylphthalides 1.00
Dual Copper/Photoredox Catalysis: Photoreductive 1,4-Dicarbofunctionalization of 1,3-Enynes with Dibenzothiophenium Salts and Trimethylsilyl Cyanide 1.00
Electrochemical Hydroarylation of Alkenes To Access Dihydroquinazolin-4(1iH/i)-ones 1.00
A Unified Photocatalytic Strategy for Fluoroalkylated and Cyanated α-Tertiary Amino/Glycolic Acids via a Radical-Polar Cascade 1.00
On-DNA Synthesis of Privileged Dihydropteridinones via Diboron-Mediated Cyclizations 1.00
Rhodium(III)-Catalyzed C–H Activation/Annulation of Indoles with Cyclopropanols: A Rapid Assembly of Indole-Fused Diazepinones 1.00
A Dual Functional Molecular Tweezer: pH-Driven C60 Capture/Release and Ba2+ Selective Recognition 0.67
Visible-Light-Induced α-Trifluoromethylation of Unactivated α,β-Unsaturated Carbonyl Compounds: Pyruvic Acid as an Additive 1.00
A Synthesis of the Carbon Skeleton of Erectcyanthin C 1.00
Copper-Catalyzed Selective C(sp3)–H Esterification Using Azidobenziodoxole Derivatives as the Mediator 1.00
One-Pot Multicomponent Synthesis of 2-Amino-3,4,6-triarylpyridine 1.00
Electrochemical [2+2+1] Dimerization Annulation of Styrenes and TMSNsub3/sub via Schmidt Rearrangement: Direct Access to 1-Pyrrolines 1.00
Photochemical Copper-Catalyzed Reductive Arylation of Nitroarenes with Arylboronic Acids 1.00
Palladium-Catalyzed Late-Stage Maleimidation of Phenylalanine-Containing Peptides 1.00
Palladium-Catalyzed Carbonylative Fluoroalkylation of 1,3-Enynes to Access Allenyl Primary Amides 0.67
Ring Expansion Strategy toward Seven/Eight-Membered 1,4-Diazaheterocycle Ketones from Imidazolidines with Cyclobutenones/Diarylcyclopropenones 1.00
Decarboxylative Fluorination Catalyzed by Pyridine-Containing Charge-Transfer Complex 1.00
Palladium-Catalyzed Cycloisomerization of Bicyclobutyl (BCB) Amides to Access Polycyclic Quinolinones 1.00
De Novo Synthesis of Oligofurans via Copper-Catalyzed Dimerization of Ethynylethylene Carbonates 1.00
Umpolung C–N Bond Formation Enabled by Rhodium-Catalyzed Arylation of Sulfilimines with Arylboronic Acids 1.00
Acid-Promoted Cyclization of N,N-Disubstituted Malononitriles with Substituted Propiolaldehydes: A Metal-Free Strategy for the Construction of 3-Dicyanovinylindoles 1.00
Access to Tetrahydropyrido[1,2-a]indol-6-one Derivatives via NHC-Catalyzed Radical Dearomatization of Indoles 1.00
gem-Difluoroalkenes as C1 Building Blocks: Iron-Catalyzed Synthesis of Trisubstituted 2-Aroyl-1,3,5-Triazines 1.00
Nickel-Catalyzed Intramolecular Direct Arylation of Cyclopropanols: Synthesis of Indanones 1.00
Silver-Catalyzed [3 + 2] Annulation of 2iH/i-Azirines and CFsub3/sub-Imidoyl Sulfoxonium Ylides: Access to CFsub3/sub-Substituted 1iH/i- and 2iH/i-Pyrroles 1.00
DNA-Compatible Synthesis of Pyrrolidine-Fused Scaffolds via a One-Pot Three-Component Cycloaddition Strategy 1.00
Formal α-Nucleophilic Addition to Electron-Deficient Alkenes by Photoredox and Copper Dual Catalysis 1.00
Adaptive Cyclooctatetrathiophene-Tetrazine Macrocycles: Efficient Synthesis, Structures, and Fullerene Recognition 1.00
Total Synthesis of (−)-Steganacin via Stereocontrolled Atroposelective Intramolecular Mizoroki-Heck Reaction and Evaluation of Biological Activity 1.00
Switchable Divergent Synthesis of Cyclopropane Scaffolds Enabled by Photoredox Catalytic Cascade 1.00
Asymmetric Nickel-Catalyzed Denitrogenative Transannulation to Construct Axially Chiral C–N Atropisomers 1.00
Copper-Catalyzed Enantioselective ε-Site Yne-Allylic Amination 1.00
Iridium-Catalyzed Regio- and Enantioselective C7-Allylic Alkylation of 4-Aminoindoles 1.00
Synthesis and Mechanistic Study of Unsymmetric Dibenzo[d,d′]thieno[2,3-b;4,5-b′]dithiophenes from 1-Haloethynyl-2-halobenzenes 1.00
A Catalyst-Free Approach to Cyclic Sulfides via Tandem Nucleophilic Substitution and Intramolecular Thiosulfonylation 1.00
Noncovalent Interactions in the Palladium-Catalyzed Diastereo- and Enantioselective Hydroalkylation of Alkoxyallenes with 2-Acylimidazoles 1.00
Photoinduced Diastereoselective Hydrophosphination of Cyclopropenes with Diarylphosphine Oxides via EDA Complex 1.00
Phosphine Oxide-Induced Strong Emission and Multistimuli-Responsive Fluorochromism of o-Carborane-Based Luminogens 1.00
Cu(I)-Catalyzed Tetradehydro-Diels–Alder Reaction of Enediynols: Modular Assembly of Multi-substituted Fluorenols 1.00
Photocatalytic Aminative Suzuki–Miyaura C(sp2)–N–C(sp3) Cross-Coupling 1.00
Asymmetric (4 + 2) Cyclization of γ-Substituted Propargyl Carboxylates with o-Quinone Methides Catalyzed by Chiral Tertiary Phosphine 1.00
Alkyl Sulfinate Anion-Mediated Hydrosulfonylation of Alkenes/Alkynes via SO2 Insertion: Access to Alkyl Sulfones 1.00
Rhodium-Catalyzed [3 + 1 + 2] Cycloaddition of Type II Diene-Vinylcyclopropanes and Carbon Monoxide for the Synthesis of 5/6 Skeletons with Two Adjacent Bridgehead Quaternary Centers 1.00
Visible-Light Catalyzed Desulfurative Cyclization for Synthesis of 3-Amino-[1,2,4]-triazolo Pyridine 1.00
Iron-Catalyzed Radical Hydrothiolation of gem-Difluoroalkenes 1.00
Organocatalytic Enantioselective Construction of Chiral Tetraarylmethanes from 4-(2-Hydroxyphenyl)benzyl Alcohols 1.00
Photocatalyzed Oxycarboranylation and Hydrocarboranylation of Unsaturated C–C Bonds with 1-Iodo-2-methyl-io/i-carboranes as the Synthon 1.00
Tetralone Formation through Visible-Light-Driven Photocyclization of Aryl Sulfoxonium Ylides with Unactivated Alkenes 1.00
Copper(I)-Catalyzed Cycloisomerization of 1H-Indole N-Tethered o-Alkynylnitroarenes to C2-Spiropseudoindoxyl Compounds 0.67
Electrochemical Conversions of Sulfinamidines into Sulfonimidoyl Fluorides 1.00
Annulation of α-Diazo Sulfonium Salts with α-Vinylanilines via a Dicationic Intermediate toward Quinolines 1.00
Total Synthesis, Stereochemical Assignment, and Structural Revision of HA 23 1.00
Visible-Light/Copper-Catalyzed Three-Component Synthesis of Unprotected β-Arylethylamines and β-Aryl Isothiocyanates via Thianthrenium Salts 1.00
NaOH-Mediated Intermolecular Cascade Cyclization Reaction of Conjugated Dieneimines with α-Halomalonates to Access Functionalized Cyclopentene Cores 1.00
Phosphine-Promoted Photoredox [3+2] Cycloaddition of Alkynes and Isocyanides 1.00
Synthesis of Tricyclic Azepine Derivatives and ε-Caprolactam-Tethered β-Diaminoacrylates and Guanidines via Reactions of DBU with Ketenimines or Carbodiimides 1.00
Electron-Donating Boronic Salicylhydrazones as Dual-State Emissive Fluorophores for Lipid Droplet Imaging 1.00
An iS/isub4/sub-Symmetrical Multi-Macrocyclic Nanohoop Derived from a 1,3-Alternate Calix[4]arene Core 1.00
Bioinspired Total Synthesis of (+)-α-Tocopherol 1.00
E-Selective 1,2-Bromochalcogenation of Acetylene under Mild Conditions 1.00
Nickel-Catalyzed Umpolung Allylation of Imines with Allylic Alcohols 1.00
Self-Assembled Cationic Cages for Anion Recognition in Aqueous Solution 1.00
A Palladium-Catalyzed Cascade Double Annulation Strategy for Modular Access to Dihydrocyclopenta[b]chromenes 1.00
Electrochemical Synthesis of Sulfonimidoyl Fluorides from Sulfenamides 1.00
Selectivity Control in Visible-Light-Induced Three-Component Cascade Thiolation–Difluoroalkylation of Alkynes 1.00
Indole Synthesis from an Alkynyl-Containing Conjugated System: Substrate Scope and Application in Total Synthesis 1.00
Synthesis of Azuleno[1,2,3-cd]phenalene and Its π-Extended Buckybowl Derivative 1.00
Electrochemical Ni-Catalyzed α-Selective Hydrocarboxylation of Styrenes with CO2 1.00
Enantioselective Propargylic Substitution of Ketone Enolates with Propargylic Alcohol Derivatives through Cooperative B/Cu Catalysis 1.00
Construction of the Lactone-Bridged Scaffold of Alstoscholactine through an Acid-Catalyzed Prins Cyclization/Lactonization Cascade 1.00
Photoredox Catalytic Approach for Difluoroallylation of Electron-Deficient sp3 C–H Bonds 1.00
Pyridine-N-oxide-Catalyzed N-Acylative Kinetic Resolution of Sulfoximines 1.00
Base-Controlled Rhodium(III)-Catalyzed Regioselective C–H Alkylation and Annulation of 2-Arylindoles with α-Cl Ketones 1.00
A Modular Approach to Trisubstituted Chiral Piperidines 0.14
Rh(III)-Catalyzed Direct C–H Selenylation/Cyclization of Benzylamines with Elemental Selenium for the Rapid Construction of Benzoisoselenazole Frameworks 1.00
Rh(III)-Catalyzed Ipso and Remote Hydroamidation of Alkenyl Carboxylic Acids to Access Valuable β-Amino Acids 1.00
Palladium-Catalyzed Intermolecular Tandem Difunctional Carbonylation of 1,3-Enynes: Synthesis of Fluoroalkylated Butenolides 0.67
Amide-Enabled Distal and Multiple Dehydrogenative C–H Alkynylation with Tuning Site Selectivity 1.00
Fluoride-Effect-Directed Catalyst-Controlled Regioselective Acylation of Carbohydrate Diols and Triols 0.86
Hypervalent Iodine(III)-Promoted Cyclization of Imidazoles with Alkenes: Divergent Synthesis of Ring-Fused Tricyclic Imidazoles Bearing Azide or Exocyclic Olefin Substituents 0.86
Asymmetric Permanganate Oxidative Cyclization of 1,4-Dienoates Enables Direct Access to Chiral Tetrahydrofurans 1.00
Silica Gel-Promoted Tryptamine-Ynamide Cyclization Strategy Enabling Total Synthesis of Elacomine 1.00
Cr-Catalyzed Cyclic Homoallylic 1,2-Diol Synthesis through Photoredox Direct Hydrogen Atom Transfer 1.00
Visible-Light-Driven Photocatalytic [3+2]- and [3+2+3]-Annulation Reactions of N-[(Trimethylsilyl)methyl]phthalimide with Electron-Deficient Alkenes and Alkynes 1.00
Additive-Free EDA Photochemical Arylative Trifluoromethylation of Enamides with Trifluoromethyl Benzothiazole Sulfones 1.00
Visible-Light-Mediated Cascade Arylcarboxylation/Cyclization of N-Aryl/Benzoyl Acrylamide with CO2 0.91
Seco-Prenylated Butylphloroglucinol Derivatives from Hypericum elodeoides and Their Anti-Alzheimer’s Disease Activities 1.00
Electrochemical Site-Specific Dehydrogenative Hydroxyalkylation of Purine Nucleosides with Alcohols 1.00
Ligand-Controlled Acyl and Decarbonylative Sonogashira Cross-Coupling of α,β-Unsaturated Thioesters 1.00
Discovery of Diverse Seven-Membered Ring Vibsane Diterpenoids from Viburnum awabuki Utilizing a MassQL-Integrated Strategy and Their Antihepatoma Effect 1.00
Palladium/Norbornene-Catalyzed C–H/C–H [3 + 2] Annulation of Imidazopyridines with 2-Halobenzoic Acids via Six-Membered Palladacycles 1.00
Catalytic Decarboxylative Alkylation of Glycine Derivatives by Aliphatic Carboxylic Acids 1.00
Nitrite-Catalyzed Stereoselective Bromocyclization to Access Tetrahydrofuran Scaffolds under Batch and Flow: An Economic and Sustainable Approach to Gram-Scale Total Synthesis of Posaconazole 1.00
Sulfonium Salt-Mediated Difunctionalization of Alkynes for Access to Z-Alkenyl Phosphorothioates and Selenophosphates 1.00
Rh(III)-Catalyzed Atroposelective C–H Cyanation of 1-Aryl benzo[h]isoquinolines 1.00
Asymmetric Synthesis of Chiral Diamines via a Low-Loading Ir-Catalyzed Umpolung Allylation of Imines 1.00
Rhodium-Catalyzed Regio- and Enantioselective Synthesis of Conjugated Enynyl Amines 1.00
Telescoping Synthesis of γ-Lactone-Fused Indanones via C–H Activation and Rearrangement-Cyclization 1.00
Photochemical Synthesis of α-Substituted Vinylazaarenes Enabled by Thia-Paternò–Büchi Reactions 1.00
Nickel-Catalyzed Direct Enantioselective Alkynylation of Alkynyl Bromide with Secondary Phosphine Oxides 1.00
Photoinduced, Pd-Catalyzed Enantioselective Cascade Carboamidation of Dienes to Access γ-Lactams 1.00
Aldehyde-Assisted Oxidative [3 + 2] Cascade Annulation of Indolecarbaldehydes with Alkynes: Access to Cyclopenta[b]indol-1(4H)-one and Spirooxindole Derivatives 1.00
Bromodifluoromethyl Phenoxathiinium Salt: A Practical and Competent Reagent Enabling Visible-Light-Promoted Bromodifluoromethylation of C(sp3)–H and Alkenes 1.00
Intramolecular Friedel–Crafts Arylation of Achmatowicz Rearrangement Products for Construction of 1,5-Oxygen-Bridged Medium-Sized Carbocycles 1.00
Palladium-Catalyzed Enantioselective Aryl-thiolation of Indoles: An Approach to Chiral Thioindoline 1.00
Annulation of Enyne-Amide with Enaminone Enables Divergent Synthesis of Furo[2,3-b]pyridine Derivatives 1.00
Palladium-Catalyzed Substrate-Controlled Regiodivergent Hydroamination of gem-Difluoroallenes 1.00
Thermolides D and E: Total Synthesis and Stereochemical Revision 0.75
Photocatalytic Hydrosilylation of Azobenzenes with Hydrosilanes for Radical N–Si Bond Construction 1.00
Dual Photoredox/Ni-Catalyzed Decarboxylative Coupling of α-Amino Acids to Uridine Derivatives 0.17
Photocatalytic Fluorosulfonylation/Fluorosulfonamidation of N-Homoallyl Aldehyde Hydrazones to Access FSO2-/FSO2N-Functionalized Tetrahydropyridazines 1.00
Copper-Catalyzed Chemoselective Ring-Opening Hydroselenation and C–H Selenylation of Isoxazol-5-amines 1.00
Organocatalytic Diastereo- and Enantioselective Synthesis of Chlorinated and Trifluoromethylated Pyrrolidines Featuring a Removable Nitro Group 0.82
Electrochemical Continuous-Flow Fluorosulfonylation of Allenols 1.00
Photoinduced Formal Intermolecular Ene-Yne Metathesis: Regioselective Synthesis of Chromene Derivatives via an Electron Donor–Acceptor Complex 1.00
Construction of Eight-Membered N-Heterocycles via Palladium-Catalyzed Cyclization of Allenyl Isocyanides 1.00
I2-Mediated One-Pot Three-Component Tandem Cyclization: Synthesis of 1H-Pyrrolo[3,4-c]quinoline-1,3(2H)-diones and Their Photophysical Property Studies 1.00
Palladium-Catalyzed Sequential Hydroamination and Hydroxylation of 1,3-Enynes with 2-Aminophenols 1.00
1,3-Stereocontrol in Stereoconvergent Allenylic Alkylation Enabled by Palladium and Chiral Phase-Transfer Cooperative Catalysis 1.00
Triphenylamine-Mediated Intramolecular Remote Cyano Migration via Electron Donor–Acceptor Complex Photoactivation 1.00
t-BuOK-Induced, NH3·MeOH-Promoted Electrochemical C(sp3)–H Amination of Saturated Heterocycles with Sulfoximines 1.00
Elucidation of Acetyl-Branched Sugar Pathway in Type II Polyketide Biosynthesis via One-Pot Enzymatic Synthesis 1.00
Sodium Trifluoromethanesulfinate-Promoted Photocatalytic C–H Acylation of N-Heterocycles with 4-Acyl-1,4-dihydropyridines in Air 1.00
A Heptagon-Embedded Structural Isomer of Azacorannulene 1.00
Synthesis of Chemoproteomic Photoaffinity Probes via Sequential Azidation/Staudinger Ligation from Alcohols and a Benzylic C–H bond 1.00
Electrochemically Driven Dearomative Spirocyclization of Anisole-Based Cyclopropanols: Total Synthesis of Anhydro-β-rotunol 1.00
Palladium-Catalyzed Direct C(sp3 )−H Arylations of Benzylsilanes with Aryl Halides 1.00
Traceless Nitro Group Directing Strategy: Modular Syntheses of the Scaffolds of Polycyclic Alkaloids 1.00
2-Arylphthalazine-1,4-diones as Nitrene Precursors for the Synthesis of Phenazine Derivatives 1.00
Zn(II)-Catalyzed Asymmetric Reactions of Aminocyclopropanes: (3 + 2) Cycloaddition with Thioketones and Ring Opening with Thioureas 1.00
Synthesis of Polysubstituted Cyclohexenes via Pyridine-Boryl Radical-Catalyzed Formal [4 + 2] Cycloadditions of Cyclobutanes with Alkynes 1.00
Palladium-Catalyzed Hydroalkynylation of 1,3-Dienes: Access to 1,5-Enynes 1.00
Chemodivergent Construction of Seven-Membered Silacycles via Palladium-Catalyzed Ring Expansion from 4- to 7-Membered Rings 1.00
Visible-Light-Mediated Desulfonylation of gem-Difluorovinyl Sulfonates for the Synthesis of α-Difluorothiomethylated Ketones 1.00
Electrochemical-Promoted Homocoupling of 2′-Hydroxychalcones for the Synthesis of 1,6-Diketones 1.00
Electrochemical 1,5-Aryl Migration for Stereo- and Regioselective Synthesis of Tetrasubstituted Alkenes 1.00
Hupserrine A, a Caged Lycopodium Alkaloid with a 6/6/5/6/7 Pentacyclic Skeleton from Huperzia serrata 1.00
Visible-Light-Induced Decarbonylative Truce–Smiles Rearrangement of N-Sulfonylbenzamides 1.00
Late-Stage Aryl C–H Bond Carboxylation with CO2 via Combining Metal-Free C–H Bond Borylation and ZnEt2-Promoted C–B Bond Carboxylation 1.00
Phase-Transfer-Catalyzed Asymmetric Isomerization of Allylic Amines to Enamides via Kinetic Resolution 1.00
Pd-Catalyzed Selective ortho-C–H Silylation of Benzaldehydes Using Transient Directing Group 1.00
Enantioenriched α-Quaternary α-Amino Amides via Copper-Catalyzed Propargylic Amination 1.00
Palladium-Catalyzed Selenylative Alkoxycarbonylation of Alkynes toward β-Selenated Cinnamic Acid Esters 0.83
Nickel-Catalyzed Cascade Carbocyclization/Alkenylation of Bisallenes and Organoboronic Acids 1.00
Cycloaddition Reaction of N-Homoallylacetohydrazides with O-Benzoylhydroxylamines under Copper Catalysis: Access to Tetrahydropyridazine Skeletons 1.00
Light-Induced 1,4-Difunctionalization of Doubly Activated Cyclopropanes for the Synthesis of 3-Ethylacylamino-2-quinolones 1.00
Copper-Catalyzed Formal C(sp3)–H Insertions via 1,5-Diyne Cyclization Triggered by a 1,6-Hydride Shift 1.00
Photocatalytic Reactions of α-CF3 Alkenes with Alcohols by Controllable Non-, Mono- and Dual-Defluorination 1.00
Photoredox/Copper Dual-Catalyzed Regioselective 1,4-Arylcyanation of 1,3-Enynes for Multifunctionalized Allenyl Nitriles 1.00
Cooperative NHC and Photoredox-Catalyzed Radical Azidoacylation of Alkenes to β-Amino Ketones 1.00
Substrate-Controlled Palladium(II)-Catalyzed Regiodivergent Oxypalladation/C–H Annulation of Alkynylaryl Carboxylates with o-Bromobenzoic Acids 1.00
Pd-Catalyzed Convergent Coupling of Alkenyl Bromide, Isocyanides, and Thiocarboxylate to Synthesize Thiophene Derivatives 1.00
Thiolate-Promoted Carbo/Carboxylation or Thio/Carboxylation of Unsaturated Carbon–Carbon Bonds with CO2 1.00
Enantioselective Palladium-Catalyzed Domino Carboetherification Reaction: Access to Isoxazoline-Linked Bis-Heterocycles 1.00
Isodesmic C(sp2)–H Iodination of 2-Phenethylamines Directed by Native Primary Amino Groups 1.00
Ti-Catalyzed Functional Group Tolerant and Regioselective Cross Couplings of (Hetero)aryl Grignard Reagents with Halopyridines 1.00
Visible-Light-Promoted Copper-Catalyzed Etherification of Aryl Bromides via Energy Transfer 1.00
Diaporlabanoids A–C, Immunosuppressive Dinorlabdane Diterpene Alkaloids with an Unprecedented Carbon Skeleton from Mangrove Endophytic Fungus Diaporthe phaseolorum H3-2 1.00
Total Synthesis of Daphenylline via Diels–Alder Cycloaddition and Rhodium-Catalyzed C–H Alkynylation 1.00
Photoinduced Three-Component 1,2-Dicarbofunctionalization of Unactivated Alkenes via Polarity-Matched Control 1.00
Photoredox-Catalyzed Formal [4 + 2] Cycloaddition of Pyridinium Masked Enols with Unactivated Olefins 1.00
Copper-Catalyzed Difluoroalkylative Benzylation of Alkenes 1.00
Dual 1,2-Migration-Enabled β-Boryl Amide Synthesis 1.00
Synthesis of Doubly Mislinked N,N’-Diphenyl Amethyrin and Its Dithia-, Diseleno-, and Ditelluro Analogues Via Zr(II)-Mediated Cyclometalation Reactions 1.00
Selective Synthesis of Unsymmetrical Disulfides from Thiols via Water-Removable SuFEx Reagent 1.00
Catalytic Enantioselective (4+4) Annulation of o-Hydroxybenzyl Alcohols with 4-Indolylmethanols 1.00
Catalytic Quantities of Inorganic Salt Promote an Electron Donor–Acceptor Complex to Achieve Defluorinated Cycloaddition 1.00
Iodine-Mediated Photocatalytic Disulfonylation of Allenes with Sodium Sulfinates 1.00
B(C6F5)3-Catalyzed [2π + 2σ] Cycloadditions of Carbodiimides with Bicyclo[1.1.0]butanes 0.83
Switchable Photocatalytic Stereoselective Synthesis of C- and S-Glycosides with Ethyl Xanthate Donors 1.00
Difunctionalization of Sulfamate-Derived Cyclic Imines through Phosphine Catalysis 1.00
Palladium(0)-Catalyzed Asymmetric Cross Inverse-Electron-Demand Diels–Alder Reaction between Distinct Electron-Deficient Dienes 1.00
Site-Selective α-Alkoxylation of Iodonium Ylides with Alcohols via Ruthenium Catalysis 1.00
Palladium-Catalyzed Construction of Trisubstituted Oxazoles from Trifluoroalanine Derivatives 1.00
Visible Light-Promoted Construction of Cage-Like Frameworks by Sequential [2 + 2] Cycloaddition 0.86
Ternary Synthon Strategy for 1,3,5-Trisubstituted Benzenes via [3 + 3] Benzannulation of Propargyl Alcohols 1.00
Biomimetic Skeleton Conversion from Lathyrane into Euphoractine A-Type Euphorbia Diterpenes: Semisynthesis of Natural Diterpenes Euphoractins M and N 1.00
Stereoselective Synthesis of Tetrasubstituted Alkenes from 1,2-Diketones via Oxyphosphonium Salts-Engaged Suzuki–Miyaura Coupling 1.00
Polyene Cyclization/Mannich Cascade for Streamlined Construction of the A/E/F Tricyclic System of Diterpenoid Alkaloids 1.00
General Strategy to Access N-Aryl Heptamethine Indocyanines for Optical Tuning 1.00
Harnessing Radicals for the Selenotrifluoromethylation within a Confined Metal–Organic Framework 1.00
Iron-Catalyzed Reductive Carboxylation of Arenes with CO2 via Thianthrenium Salts 1.00
Unified Synthesis of Cycloheptatriene-Fused Heterobicyclo[3.1.1]heptanes by Lewis Acid-Catalyzed Higher-Order (8 + 3) Cycloaddition of Bicyclo[1.1.0]butanes with Troponoids 1.00
B(C6F5)3-Catalyzed Decarboxylative Formation of Benzofurans via Intermolecular (3 + 2) Cyclization from Phenols 1.00
A Visible Light Promoted Regioselective Cascade Radical Trifluoromethylation/Cyclization of N-Isopentenyl Aldehyde Hydrazones: Access to Trifluoromethylated Tetrahydropyridazine Derivatives 1.00
Anion-Mediated Synthesis of Diethynyl-Substituted Doubly N-Confused Dioxohexaphyrin Dyes That Exhibit Enhanced Photoacoustic Signals in the NIR-II Region 0.05
Atroposelective N-Allylic Alkylation Enables Construction of Axially Chiral Arylimidazoles 1.00
Ligand-Controlled Cobalt-Catalyzed Regioselective Annulation: Divergent Synthesis of Indenols from o-Haloaromatic Ketones and Terminal Alkynes 1.00
Visible-Light-Driven Synthesis of Sulfinamides via Deoxygenative Sulfinamidation of Alcohols with iN/i-Sulfinyltritylamine 1.00
Chemodivergent Sulfenylation of Trifluoromethylalkenes: Controlled Synthesis of Fluorinated 1,3-Dithioethers and β-Trifluoromethyl Thioethers 1.00
Silver-Mediated Dual Oxidation of 1,3-Dicarbonyls for Migration–Annulation 1.00
Alkyl-Trifluoromethylation of Glycine Derivatives 1.00
Enantioselective Synthesis of Chiral Triarylmethanes via Cu-Catalyzed Desymmetric Acyloxylation of Cyclic Non-coordinating Diaryliodoniums 1.00
Regioselective Sulfenylation/Phosphorylation of Unactivated Alkenes via Thianthrenation 1.00
Self-Assembled Topologically Chiral Catenane via Ketone–Hydrazide Condensation 1.00
Nickel-Catalyzed C–N Bond Formation from Ring Remodeling through C–C Bond Activation 1.00
Reductive Dicarbofunctionalization of Unactivated Internal Alkenes via Iron Catalysis 1.00
Norcolocynins A and B, Ring B seco-Norcucurbitane Triterpenoids from the Fruits of Citrullus colocynthis and Their Cytotoxicity 1.00
Copper-Catalyzed Chan–Lam Reaction and Sequential Oxidative Fischer Indole Synthesis to Prepare Indole Derivatives 1.00
Visible-Light-Driven Fischer-Type Indole Synthesis: Direct Synthesis of 2-Phosphinoylindoles from Anilines 1.00
Palladium-Catalyzed “Cut-and-Sew” Reaction of C(sp3)–NC: Direct Synthesis of Bulky Nitriles Containing an All-Carbon Quaternary Center 1.00
Photocatalyzed Oxycarboranylation of Alkenes with 1-Iodo-io/i-carboranes through a Halogen-Atom Transfer Strategy 1.00
Synthesis of Perfluoro-itert/i-butyl Triazoles via Decarboxylative CuAAC of (Perfluoro-itert/i-butyl)propiolic Acid with Azides 1.00
Catalyst- and Base-Free Synthesis of Pyridine-Fused Uracils from 6-Methyluracils, Aldehydes, and Ammonium Iodide via a One-Pot Multicomponent Reaction 1.00
Electro-enzymatic Cascade Stereodivergent Synthesis of β-Hydroxy Selenides via Engineered Ketoreductases 1.00
Formal [3 + 2] Annulation of β,β-Disubstituted Enesulfinamides with Vinyl Thianthrenium Salt: Asymmetric Construction of 3,3-Disubstituted 1-Pyrrolines 1.00
Divergent Synthesis of Symmetric Benzenes and Fluorenones 1.00
Phosphine-Catalyzed Asymmetric Dearomative Annulation of 4-Nitroisoxazoles with Allenoates: Construction of Isoxazoline-Fused Bicyclo[3.3.0]octenes 1.00
Palladium-Catalyzed Regio- and Monoselective B(2)–H Alkylation of Zwitterionic nido-Carboranes at Room Temperature in Water 1.00
Catalytic Intramolecular Reductive Amination Using Secondary Amines: Expanding Access to Chiral Tertiary Amine Heterocycles 1.00
Phosphine-Catalyzed Modular Synthesis of (iE/i)-Allyl Hydrazones, Tetrahydropyridazines, and Pyridazines 1.00
Phosphine-Mediated ide Novo/i Arylamidation of α-Allylic Allenoates and Isocyanates via Bicyclo[3.1.0]hexene Access to Aryl Amides 1.00
Triconnarins A–D: Four Secophragmalin-Type Limonoids from the Twigs and Leaves of iTrichilia connaroides/i 1.00
Copper-Promoted Reductive Cross-Coupling for Cyanodifluoromethylation of (Hetero)aryl Iodides with BrCFsub2/subCN 1.00
Photocatalytic Functionalization of Olefins with Triaryl Phosphine and Dibenzyl Sulfoxide: Preparation of Tertiary Phosphine Oxide 1.00
Base-Mediated Formal Denitrogenative Insertion of Nonactivated Triazoles into Aldehydes: Stereospecific Synthesis of Highly Substituted Acrylamides 0.88
Synthesis of 8H-Indolo[3,2,1-de]phenanthridin-8-ones via Pd(OAc)2-Catalyzed Double Oxidative Coupling Dehydrogenations 1.00
Photoinduced Copper-Catalyzed Coupling of Acylsilanes with Indoles or Electron-Rich Arenes 1.00
Lewis Base-Catalyzed DYKAT of Racemic Chlorosilanes En Route to Si-Stereogenic Silazanes 1.00
Asymmetric Synthesis of Biaryl Sulfilimines Bearing Multiple Chiral Elements Involving Cyclic Diaryliodoniums 1.00
Photoinduced Aminosulfonylation of Unactivated Alkenes via N–N Bond Cleavage and Distal Migration of Imine 1.00
Iron Photocatalysis Enabling Decarboxylative Bromination of (Hetero)Aryl Carboxylic Acids 1.00
Chromium(II)-Catalyzed Decarboxylative Alkyl Acylation under Visible Light Irradiation 1.00
Divergent Annulations via Organocatalysis: Remote-Controlled and Switchable Reactions of Pyrrolidinone-Based Morita–Baylis–Hillman Carbonates with 2-Arylideneindane-1,3-diones 1.00
Enantioselective Synthesis of Tetrahydroanthraquinones via Pd-Catalyzed Asymmetric [2 + 4] Annulation 1.00
Rh(III)-Catalyzed [3 + 4] Annulation of 3-Arylisoindolinones with 2-Methylidenetrimethylene Carbonate via C–H Activation to Access Isoindolinone Spirobenzoxepines 1.00
Synthesis of Fused Polycyclic Indole-Indenone Scaffolds via Pd-Catalyzed Sequential Cycloaddition Reactions 1.00
Synthesis of γ-Carboline Derivatives via the Rh(III)-Catalyzed Regioselective C–H Activation/[4+2] Annulation Cascade 1.00
Photocatalytic Dealkylation of Aryl Alkyl Ethers 1.00
Ligand-Enabled Palladium-Catalyzed Asymmetric Synthesis of Cyclic Sulfamidate-Fused Imidazolidinones 1.00
Electrochemical Synthesis of β-Keto Phosphorodithioates via Difunctionalization of Alkenes under Metal-Free Conditions 1.00
Ascomycotols A–C: Rare Sulfur/Sulfone-Containing Scaffolds from Mushroom Endophytes with Dual Anti-inflammatory and Antirenal Fibrosis Effects 1.00
Dearomatization of Electron-Deficient Indoles with N-Alkylanilines via Visible-Light-Induced Hydroalkylation 1.00
[2 + 3] Cycloaddition of para-Quinamines and para-Quinols with C,N-Cyclic Azomethine Imines: Access to 6/5/6/6-Fused Tetracyclic Pyrazolidines 1.00
Ag(I)-Catalyzed C–C Bond Cleavage and Re-Assembly Reactions Between 2H-Azirines and α-Carbonyl Sulfoxonium Ylides 1.00
Oxidative Kinetic Resolution of Alkyl-Substituted 1,2-Diamines 1.00
Iron-Catalyzed Reductive Deuteration of Ketones and Imines 1.00
Iridium(III)-Catalyzed C–H Bond Activation of Phenols to Build Up Phenothiazine-Containing 2-(2-Hydroxyphenyl)azoles: Access to Single-Molecule White-Light Materials and Room-Temperature Phosphorescence Materials 1.00
Synthesis of Pyridinone-Fused [2.2]Paracyclophane by Ruthenium(II)-Catalyzed C–H Activation 1.00
Synthesis of Benzo[a]carbazoles via Palladium-Catalyzed Tandem Cyclization of Diarylalkynes with Isocyanides 1.00
C3-Formylation of Pyridines via Streptocyanine Intermediates 1.00
Macrocyclization of Unprotected Peptides via Cycloaddition between o-Diones and Furan-2(3H)-one 1.00
Late-Stage Oxime iO/i-Glycosylation with Unprotected Glycosyl Fluorides 1.00
Discovery and Biomimetic Syntheses of Phloroglucinol-Monoterpene-Triketone Hybrids from Chamelaucium uncinatum with Hypoglycemic Activity 1.00
Closed-Loop Sulfur Dioxide Utilization in Photocatalytic Smiles Rearrangement 1.00
Collective Biomimetic Synthesis of Myrcaulones A and C and Myrcauones B–D 1.00
The NHC-Catalyzed Enantio- and Diastereoselective [2 + 3] Annulation of Phthalide-Derived Alkenes with Enal Access to Bispiroheterocyclic Compounds Bearing Three Vicinal Stereogenic Centers 1.00
Copper-Catalyzed Stereoconvergent 1,4-Protosilylation of E/Z Dienes 0.80
Dechlorinative Pyrazinylation of Glycine Derivatives 1.00
Iron-Catalyzed Double Annulation of O-Acyl Oximes with Fumaronitrile for the Synthesis of 4-Cyano-7-azaindoles 1.00
Bioinspired Total Synthesis of Penisuloxazin A 1.00
Synthesis of Remote C–N Diaxially Chiral Compounds via Cobalt-Catalyzed Atroposelective C–H Activation 1.00
Dipolar Cycloaddition Approach toward Harmicine-Type Alkaloids: Synthesis and Stereochemical Determination 1.00
Lewis Acid-Mediated Deoxygenative Synthesis of Trivalent Sterically Hindered Phosphines from Aldehydes 1.00
EDA Complex-Mediated Aerobic Three-Component CDC Reactions of Quinoxalinones under Visible-Light Irradiation 1.00
Catalytic Asymmetric Intramolecular Domino Allylic O-Alkylation/Allylic Dearomatization of Allyl Aryl Ethers 1.00
Steric Gating of Excited-State Channel: Controllable AIE/RTP Switching through Tuning π-Bond Twisting 1.00
Sorbicillalanines A and B, Two [6,5,6] Hybrid-Sorbicillinoid Alkaloids from Deep-Sea-Derived Penicillium sp. Co-Cultured with Sponge-Derived Setosphaeria sp. 1.00
Mild Lewis-Acid-Promoted Cysteine–Tryptophan Conjugation Involving a Radical Process 1.00
Application of Indolyl Ynones in the Construction of Chiral Carbazoles and Pyrroloindolines by Organo and Metal Sequential Catalysis 1.00
Direct Synthesis of cis-Bicyclic γ-Lactam Derivatives from Iminosugar C-Coumarinyl Glycosides 1.00
Photoinduced Double 1,2-Carbon Migration toward All-Carbon Tetrasubstituted Olefins 1.00
Enantio- and E-Selective Copper-Catalyzed Three-Component Hydrofunctionalization of Internal Allenes Bearing Methylidenecyclobutanes with Diborons and Ketones 1.00
A Unified Strategy for Transition-Metal-Free Synthesis of Benzothienopyridines, Benzoselenopyridines, and Benzotelluropyridines and Related Analogues 1.00
Direct Carbon Isotope Exchange of α-Keto Acids Enabled by Photoredox Self-Catalysis 1.00
Ir-Catalyzed Friedel–Crafts-Type Asymmetric Allylation of Furans 1.00
Traceless Aminoalkyl Radical-Induced Halogen-Atom Transfer for Minisci Reactions 1.00
Accommodating Styrenes and Unactivated Olefins: Hydrotrifluoromethylation Using O,O′-Dimethyldithiophosphoric Acid as SET Reductant and H Atom Donor 1.00
Atroposelective Suzuki–Miyaura Coupling Reaction with Benzoxaboroles 1.00
Identification of a Privileged Scaffold for Induction of Lysosomal Biogenesis through Synthesis of the Scaffold of Cipadonoid A 1.00
Base-Catalyzed Chemo-, Regio- and Stereoselective Addition of Quinazolinones to Trifluoromethylated Internal Alkynes for Access to N3-Vinylquinazolinones 1.00
Flexible Synthesis of Highly Substituted Pyridines Bearing 2-Fluoroalkyl Groups 1.00
TEMPO-Mediated Polyyne Cyclization 1.00
Energy-Transfer-Enabled 1,4-Amino Migration and C–O Diradical Recombination for Norrish–Yang-Type Epoxidation 1.00
Electrocatalytic 1,6-Difunctionalization of Bicyclopropanes 1.00
Iron-Catalyzed [3 + 2] Annulation of O-Acyl Oximes with 2-Hydroxy-1-Naphthoates for the Synthesis of Benzo[g]indoles 1.00
Alkynyl Sulfide: An Unexplored yet Versatile Alkynyl Species for Chemoselective Cross-Electrophile Coupling 1.00
Photocatalytic Ring-Closing Metathesis/Amination of 1,6-Enynes and 1,7-Enynes: Synthesis of α,β-Unsaturated γ-Lactams and Quinolin-2-ones 1.00
Pd-Catalyzed Regioselective Homobenzannulation of Enynals 1.00
Annulative Editing of Peptide Side Chains: N-Pyridination of Lysine via Chichibabin Pyridine Synthesis in Hexafluoroisopropanol 1.00
Synthesis of 3,4-Fused Pyrroles with Seven-Membered Carbocycles via Cascade C–C σ-Bond Cleavage/Intramolecular Cyclization Reactions 1.00
Intramolecular Cyclopropanation of Alkene-Tethered CF3-Imidoyl Sulfoxonium Ylides: Synthesis of Cyclopropane-Fused Quinolines 1.00
Copper-Catalyzed Cysteine S-Arylation via Photoredox Mediation 1.00
Boron Catalysis-Enabled Regioselective Ring-Retentive Hydrosilylation of Methylenecyclopropanes 1.00
Visible-Light-Induced Arylcarboxylation of Activated Alkenes with Aryl Halides and Oxalate Enabled by Electron Donor–Acceptor Complex Formation 1.00
Trichloroacetonitrile-Mediated Oxidation of Sulfides and Benzylic C–H Bonds via Photoexcited Radical Reactions under Clean Conditions 1.00
Reductive N-Heterocyclic Carbene Catalysis via Hydride Transfer: Generating Homoenolates from Unsaturated Esters 0.88
Cascade Reactions of α-Carbonyl Radicals Enabled by Photocatalytic Hydrogen Atom Transfer for the Synthesis of Benzonaphthyridinone Derivatives 1.00
A Reductive Ugi Reaction with Carboxylic Acids Replacing Aldehydes 1.00
Visible Light-Mediated Anaerobic Oxidation of α-Glucoside: Site-Selective Dehydrogenation Promoted by Aromatic Aldehydes 1.00
(Vinyl triflimide)benziodolium Salts: Palladium-Catalyzed Cascade Reactions toward Unsymmetrical Benzils 1.00
Enantioselective Total Synthesis of (−)-Vallesamidine Enabled by Asymmetric Hydrogenation and Aza-Wacker Cyclization to Construct the Core Spirocyclopentane-1,2′-indoline Structure 1.00
Radical Fluorosulfonylation/Double Diels–Alder Sequence to Access Tricyclo[3.2.1.02,7]octanes 1.00
Visible-Light-Initiated Aggregation-Enabled Transformation of Thiophenols to Unsymmetrical Disulfides via Photo-Fries Rearrangement 1.00
Remote Copper-Catalyzed Atroposelective Synthesis of N–N Axially Chiral Compounds Bearing Minimally Different Alkyl Groups 1.00
A General Deoxygenative Hydrosilylation of Oxo Chemicals Catalyzed by a Bipyridine-Ligated Chromium Complex 1.00
Photoinduced 1,2-Carbosulfenylation of Alkenes 1.00
Photoexcited Copper-Catalyzed Difunctionalization of Alkenes for the Synthesis of 2,5-Diamino Acid Derivatives via Uncommon 1,2-Hydrogen Atom Transfer of Amidyl Radicals 1.00
C3–H Trifluoroacetylation of Quinolines and Pyridines: Access to Heteroaryl Ketones, Carboxylic Acids, and Amides 1.00
2-(Cyanomethyl)benzimidazole Derivatives as 1,3-Dicarbonyl Analogues for a Kinetically Controlled Diastereo- and Enantioselective Mannich-Type Reaction Catalyzed by Chiral Phosphoric Acid 0.19
2 2.00
FaTRAB1, a bZIP transcription factor, enhances anthocyanin biosynthesis in strawberry leaves via tissue-specific regulation 1.00
The PavMYB.C2-UFGT module contributes to fruit coloration via modulating anthocyanin biosynthesis in sweet cherry 1.00
1 1.00
Accelerating ground-state auxiliary-field quantum Monte Carlo simulations by delayed update and block force-bias update 1.00
26 23.33
DcH3.3 and DcNAC1 Regulate the Expression of UGT73A93 Involved in the Changes in Flower Colour and Fungal Resistance in Carnation 1.00
Transcriptional Regulation of the Novel Theacrine Synthase Gene CsTcS2 by the CsTINY–CsWRKY33 Module Underpins Theacrine Biosynthesis in Camellia sinensis 1.00
Regulatory Mechanism of CsMYB1-CsMYB82/CsbHLH48‑CsCAD4 Model for Resistance Against Colletotrichum gloeosporioides in Camellia sinensis 1.00
<atl>Multi‐Omics Insights Into Anthraquinone Biosynthesis in iRheum tanguticum/i</atl> 1.00
Natural Variations in the Activity of Hydroxycinnamoyl Transferases Promote Accumulation of Metabolites Conferring Rice Resistance 1.00
Loss‐of‐Function Mutation in scpCER/scp2‐scpLIKE/scp1 Reduced Accumulation of Cuticular Wax and Susceptibility to Thrips in Welsh Onion 1.00
Genome Assembly Revealed MdZAT5 Coordinates Anthocyanin Biosynthesis in Apple Fruit Peel and Flesh by Interacting With MdHY5 1.00
The PtrC2H2.2-6-PtrCYP86A7/A8 Module Regulates Poplar Drought Tolerance Through Mediating Cutin and Wax Biosynthesis Pathways 1.00
VvERF045 Integrates Ethylene, Brassinosteroid and Abscisic Acid Pathways to Orchestrate Anthocyanin Biosynthesis in Grapevine 1.00
Overexpression of a Tonoplast Malate Transporter Gene Leads to Enhanced Anthocyanin Biosynthesis in Apple 0.33
Aquilaria sinensis MYB-Like Transcription Factor AsMYB1 Promotes 2-(2-Phenylethyl)Chromone Biosynthesis Through Interacting With 14-3-3 Family Protein AsGRF1 1.00
Polyacylated Delphinidin Biosynthesis Catalysed by PhF3′5′H-PhBGLU12-PhSCPL2 Determines the Blue Pigmentation in Cineraria (Pericallis hybrida) 1.00
CYP82G1 Enzyme Functions as Chromone Hydroxylase in the Biosynthesis of 6-Hydroxy-2-(2-Phenylethyl)chromone in Aquilaria sinensis 0.93
A Repression-Activation System Involving miR164a-NACs Regulates Tissue-Specific Anthocyanin Accumulation in Peach Fruit 0.70
A Novel ZjbZIP33-ZjPRX1 Module Positively Regulates Lignin Formation in the Jujube Fruit Stone 1.00
PME10 Is a Pectin Methylesterase Driving PME Activity and Immunity Against Botrytis cinerea in Grapevine (Vitis vinifera L.) 0.04
Spatial regulation of chlorophyll degradation in kiwifruit: AcNAC2-AcSGR1/2 cascades mediate rapid de-greening in the inner pericarp 0.61
Modulation of lignin and anthocyanin homeostasis by iGTP cyclohydrolase1/i in maize 0.90
Unveiling the catalytical roles of three glycosyltransferases in triterpenoid saponins in quinoa 1.00
A novel function for the transcription factor sensitive to proton rhizotoxicity1 in promoting anthocyanin accumulation in strawberry 1.00
PpMYC2 and PpJAM2/3 antagonistically regulate lignin synthesis to cope with the disease in peach fruit 1.00
Calcium disrupts CML38/WRKY46-NAC187-CCR cascade to inhibit the formation of lignin-related physiological disorders in pear fruit 1.00
Molecular characterization and structural basis of a promiscuous glycosyltransferase for β-(1,6) oligoglucoside chain glycosides biosynthesis 1.00
Ecotype-specific phenolic acid accumulation and root softness in Salvia miltiorrhiza are driven by environmental and genetic factors 1.00
Phosphorylation of MdWRKY70L by MdMPK6/02G mediates reactive oxygen accumulation to regulate apple fruit senescence 1.00
Bi-functional transcription factor SlbHLH95 regulates fruits flavonoid metabolism and grey mould resistance in tomato 0.82
12 9.60
A sugar chain–dependent two-component chemical defense in Hedera helix reveals substrate-driven β-glucosidase evolution in Apiales 1.00
A ribosomally synthesized and posttranslationally modified peptide with ADP-ribosylation 1.00
Methionine-specific nonreversible bioconjugation: Advancing precision protein modification 0.28
A balance between glycitein and glyceollins governed by isoflavone 6-hydroxylase confers soybean resistance to Phytophthora sojae 1.00
Artificial cells with liquid–liquid phase separation–regulated cell-free protein synthesis 1.00
Structure and encapsulation of carbonic anhydrase within the α-carboxysome 0.08
Living/controlled supramolecular protein polymerization 1.00
A supporting-electrolyte-free four-compartment electrochemical reactor for aqueous and organic phase electrosynthesis 1.00
Divergent sustainability profiles of molnupiravir synthesis routes are governed by solvent use and process design 0.54
Characterization of SrUGT76G4 reveals a key residue for regioselectivity and efficient Reb M synthesis 1.00
Thioether editing generally increases the photostability of rhodamine dyes on self-labeling tags 0.83
Photothermal catalysis of waste plastics into propionic acid and hydrogen via Ni single-atom site isolation effect 0.86
9 6.90
A relay energy transfer paradigm for asymmetric photocatalyzed [4+2] cycloadditions 1.00
Divergent and consecutive skeletal editing of saturated primary amines 1.00
Precision indole skeletal editing for single-carbon replacement 0.83
Bromine-mediated electrochemical propane dehydrogenation by self-assembled ionic liquid-SnO2 hollow spheres 1.00
Engineered aldehyde dehydrogenases for amide bond formation 0.80
Integrated low-temperature PVC and polyolefin upgrading 0.08
Enantioconvergent benzylic C(sp3)‒N coupling with a copper-substituted nonheme enzyme 0.18
Artificial farnesol epoxidase enables a concise synthesis of meroterpenoids 1.00
Skeletal editing of pyrrolidines by nitrogen-atom insertion 1.00
28 24.46
On-demand linkage cleavage in two-dimensional conjugated metal-organic frameworks for closed-loop recyclable electronics 0.30
Nanographenic bowls based on contorted hexabenzocoronene: Synthesis, structure, and supramolecular assembly with fullerene C60 1.00
Precise borylation of targeted methyl group via an orderly chain-walking strategy 1.00
Synergy of liberated anions and intense electric field in frustrated ion pairs for enhancing CO2 cycloaddition 1.00
Rational design of tetrahydrotetrazinones as potent nonclassical radical-trapping antioxidants for inhibition of ferroptosis 1.00
A dual role of Arabidopsis PAL nuclear localization in fine tuning flavonoid biosynthesis 0.88
Electrochemically deuterated silane synthesis with D2O 1.00
Enantioselective rapid assembly of bis-heterocycles by sequential palladium-catalyzed aza-Heck cyclization coupling reaction 1.00
Three-component synthesis of β-thio tertiary alkylamines from simple alkenes via SH2 homolytic substitution 0.85
β-Carbon functionalization of amines via α-amino Cu-carbenes 1.00
Anode-induced arylthiol-amine cross-coupling: A nontraditional strategy to access sulfinamides 1.00
Transition-metal-free electrochemical cross-electrophile coupling of activated benzyl alcohols and primary alkyl bromides 1.00
Photoredox-controlled chemo-divergent, regio-, and stereoselective difunctionalization of olefins via switchable SO2 reintegration 1.00
Asymmetric synthesis of chiral boronic esters featuring nonadjacent axial and flexible, acyclic central chirality 1.00
Achieving cysteine-selective peptide/protein bioconjugation via tunable triazine-pyridine chemistry 1.00
Molecular basis of very-long-chain fatty acid elongation by the CER6-GL2 enzyme complex in plant wax biosynthesis 1.00
Electrochemical C4 alkylation of pyridine derivatives: Enhanced regioselectivity via silane assistance 0.89
Magmatic immiscibility provides phosphate for prebiotic chemistry 0.06
Functional divergence of tandem duplicate SCPL acyltransferase genes reveals convergent evolution of chicoric acid biosynthesis 0.86
β-Acyloxyl alkenyl amide synthesis via multiple defluorination: α-Trifluoromethyl ketone–amine as synergystic peptide coupling reagent 1.00
Organocatalyzed atroposelective dynamic kinetic resolutions via transient seven-membered cyclic hemiacetals 0.72
Molecular basis of the biogenesis of a protein organelle for ethanolamine utilization 0.28
Comprehensive engineering of novel glycosyltransferase for efficient, donor-promiscuous, and regioselective glycosylation of flavonoids 1.00
Preparation of ketonyl C-glycosides from designed glycosyl sulfides and styrenes by a radical pathway 1.00
Difluoroboronated tetrazine probes for rapid bioorthogonal fluorescence activation, no-wash STED imaging, and triggered drug release 1.00
Asymmetric catalytic reductive transformation of S(VI) to S(IV) for modular access to S(IV)-stereogenic sulfilimine derivatives 0.93
A general leaving group assisted strategy for synthesis of pentafluorosulfanyl allylic compounds 0.89
Insertion of anthranilyl unit into inert amides: A facile route to oligoamides and cyclic peptides 0.81
22 21.50
Cost-Effective Digital Discovery of Aza-Hydrocarbons via Isomerization for Inverted Singlet–Triplet Emitters 1.00
Vibrational Control of Spin–Orbit Coupling Enhances Triplet–Triplet Annihilation Upconversion Efficiency 1.00
Superatomic-Based Ion−π Interactions 1.00
Volumetric Properties and Microscopic Interactions of Allyl-Functionalized Imidazolium Ionic Liquid Aqueous Dilute Solutions: A Combined Experimental, Machine Learning, and Pitzer Modeling Study 1.00
Chiral Supramolecular Structures Formed by Dibenzo-18-crown-6-ether and NaCl/KCl on Au(111) and Cu(111) Surfaces 1.00
Orbital Topology Overcomes Energetic Constraints: Conjugation Expansion Breaks the Inverse Relationship between SOMO Splitting and Spin Coupling for Giant Ferromagnetic Coupling in Organic Diradicals 1.00
Intrinsic Spin Effect beyond Aqueous Systems: Selectivity Control in Organic Electrochemistry via Spin-Polarized Radical Intermediates 1.00
Selective Oxidative Dehydrogenation of Cyclohexene into 1,3-Cyclohexadiene on TiO2 1.00
Excited-State Sudden Polarization Dynamics of Sulfone-Functionalized Symmetric Stable Diradicaloids 1.00
Vibrational-State-Regulated Hot-Band Thermal Activation for Anti-Stokes Luminescence 1.00
Symmetry-Regulated Argentophilic Interactions via Homochiral Proline Dodecamers 1.00
Tuning the Hydroxyl Microenvironment of Fe-Zeolite for Selective Oxidation of Benzene by N2O 1.00
Effect of Halide Ions on Single-Electron Oxidation Reactions in Microdroplets 1.00
Deciphering Carbene Reactivity: Ultrafast Spectroscopy and Computational Insights into Photochemical Heterocycle Formation 1.00
Mapping the Relationship of the Dynamic Active Site and the Activation Barrier for Cross-Coupling Reactions on Geminal-Cu Catalyst 1.00
Quantum Tunneling Governs Dual-Pathway Amino Acid Racemization via Water Bridges 1.00
Chemical Bonding from the Perspective of In Situ Orbital Correlation 0.50
Facet-Engineered Highly Active and Stable Ag/TiO2 Photocatalysts for Selective Oxidative Coupling of Methane 1.00
A Molecular Descriptor for Characterizing the Strength of Through-Space Conjugation for Luminescent Property in Organic Materials 1.00
Revisiting the Linear Relationship between Hydroxyl Stretch Frequency and Bond Length: A Data-Driven Analysis Connecting Structure to Electrostatic Potential 1.00
Biomimetic Geminal-Atom Catalysts Empowered by Jahn–Teller Distortion: A Theoretical Study for Efficient PET Degradation 1.00
Improving Performance and Stability of Solution-Processed Organic Poly-gridofluorene Light-Emitting Diodes via Deuterated Solvents 1.00
1 0.11
Vepdegestrant, a PROTAC Estrogen Receptor Degrader, in Advanced Breast Cancer 0.11
2 2.00
The deubiquitinase UBP15 and the E3 ubiquitin ligase PUB17 coordinate GLK1 stability in apple anthocyanin deposition 1.00
Reduced proteasome degradation of HsfB2a at higher temperatures is responsible for the inhibition of anthocyanin synthesis in pear 1.00
5 4.90
D-Band Broadening Drives Pollutant Oxidative Polymerization for Intermediate-Free Water Purification 1.00
Unraveling the phototransformation of 2,4,6-tribromophenol: Aqueous mechanisms involving ·OH and the emergence of hydroxylated PBDEs 1.00
Dynamic Inner-Outer Dual-Cycles Drive Selective Periodate Activation for Nearly Exclusive Singlet Oxygen Production toward Sustainable Water Purification 1.00
Thermal Stimulation Unlocks Ligand-Dependent Selective Pathways in Cu(II)/PMS Oxidation of Recalcitrant Phosphonates 1.00
Photoinduced thiol formation in dissolved organic matter: The role of sulfur-containing precursor and source of electron 0.90

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